Palladium: Difference between revisions

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==Occurrence==
[[File:2005palladium (mined).PNG|thumb|upright=1.6|Palladium output in 2005]]
As overall mine production of palladium reached 210,000 kilograms in 2022, [[Russia]] was the top producer with 88,000 kilograms, followed by South Africa, Canada, the U.S., and Zimbabwe.<ref>{{Cite journalreport |last=Survey |firstauthor=U. S. Geological Survey |date=2023 |title=Mineral commodity summaries 2023 |page=210 |url=https://pubs.er.usgs.gov/publication/mcs2023 |language=en |doi=10.3133/mcs2023}}</ref> Russia's company [[Norilsk Nickel]] ranks first among the largest palladium producers globally, accounting for 39% of the world's production.<ref>{{Cite web|url=https://www.nornickel.com/news-and-media/press-releases-and-news/norilsk-nickel-group-announces-preliminary-consolidated-production-results-for-4-th-quarter-and-full-2016-and-production-outlook-for-2017/?sphrase_id=316142|title="Norilsk Nickel" Group announces preliminary consolidated production results for 4 th quarter and full 2016, and production outl|website=Nornickel|language=en-US|access-date=2018-01-29|archive-url=https://web.archive.org/web/20180629183059/https://www.nornickel.com/news-and-media/press-releases-and-news/norilsk-nickel-group-announces-preliminary-consolidated-production-results-for-4-th-quarter-and-full-2016-and-production-outlook-for-2017/?sphrase_id=316142|archive-date=29 June 2018|url-status=dead}}</ref> <!--In 2005, Russia was the top producer of palladium, with at least 50% world share, followed by South Africa, Canada and the U.S., reports the [[British Geological Survey]].<ref name="BGS">{{cite book|first1=L. E.|last1=Hetherington|first2=T. J.|last2=Brown|first3=A. J.|last3=Benham|first4= T.|last4 = Bide|first5=P. A. J.|last5=Lusty|first6=V. L.|last6=Hards|first7=S. D.|last7=Hannis|first8=N. E.|last8=Idoine|title= World mineral statistics British Geological Survey|url=http://www.bgs.ac.uk/downloads/start.cfm?id=1388|place=Keyworth, Nottingham|page=88}}</ref>-->
 
Palladium can be found as a free metal alloyed with gold and other platinum-group metals in [[placer mining|placer]] deposits of the [[Ural Mountains]], [[Australia]], [[Ethiopia]], [[North America|North]] and [[South America]]. For the production of palladium, these deposits play only a minor role. The most important commercial sources are [[nickel]]-[[copper]] deposits found in the [[Sudbury Basin]], [[Ontario]], and the [[Norilsk|Norilsk–Talnakh]] deposits in [[Siberia]]. The other large deposit is the [[Merensky Reef]] [[platinum group]] metals deposit within the [[Bushveld Igneous Complex]] [[South Africa]]. The [[Stillwater igneous complex]] of [[Montana]] and the Roby zone ore body of the [[Lac des Îles igneous complex]] of Ontario are the two other sources of palladium in Canada and the United States.<ref name="USGS07CS" /><ref name="USGS07YB">{{cite web|url=http://minerals.usgs.gov/minerals/pubs/commodity/platinum/myb1-2007-plati.pdf|title=Platinum-Group Metals|date=January 2007|work=Mineral Yearbook 2007|publisher=[[United States Geological Survey]]}}</ref> Palladium is found in the rare minerals [[cooperite (mineral)|cooperite]]<ref>{{cite journal|journal=Mineralogical Magazine|date=1994|volume=58|issue= 2|pages=223–234|title=Compositional variation of cooperite, braggite, and vysotskite from the Bushveld Complex|first1=Sabine M. C.| last1 =Verryn|first2=Roland K. W.|last2=Merkle|doi=10.1180/minmag.1994.058.391.05|bibcode=1994MinM...58..223V|citeseerx=10.1.1.610.640|s2cid=53128786 }}</ref> and [[polarite]].<ref>{{cite journal|last1 = Genkin|first1 = A. D.|last2 = Evstigneeva|first2 = T. L.|date = 1986|title = Associations of platinum- group minerals of the Norilsk copper-nickel sulfide ores|journal = Economic Geology|volume = 81|pages = 1203–1212|doi = 10.2113/gsecongeo.81.5.1203|issue = 5| bibcode=1986EcGeo..81.1203G }}</ref> Many more Pd minerals are known, but all of them are very rare.<ref>{{Cite web|url=https://www.mindat.org/|title=Mindat.org - Mines, Minerals and More|website=www.mindat.org}}</ref>
 
Palladium is also produced in [[nuclear fission]] reactors and can be extracted from [[spent nuclear fuel]] (see [[synthesis of precious metals]]), though this source for palladium is not used. None of the existing [[nuclear reprocessing]] facilities are equipped to extract palladium from the [[high-level radioactive waste]].<ref>{{cite journal|title = Recovery of Value Fission Platinoids from Spent Nuclear Fuel. Part I PART I: General Considerations and Basic Chemistry|url =http://www.platinummetalsreview.com/pdf/pmr-v47-i2-074-087.pdf| first1 =Zdenek|last1 =Kolarik|first2 =Edouard V.|last2 =Renard| journal = Platinum Metals Review|volume = 47|issue = 2|date = 2003|pages = 74–87}}</ref> A complication for the recovery of Palladiumpalladium in spent fuel is the presence of {{chem|107|Pd}}, a slightly radioactive [[long-lived fission product]]. Depending on end use, the radioactivity contributed by the {{chem|107|Pd}} might make the recovered Palladium unusable without a costly step of [[isotope separation]].
 
==Applications==