Kilogram

"Kg" redirects here. For other uses, see Kg (disambiguation).

Kilogram
A computer-generated image of the International Prototype Kilogram (“IPK”). The IPK is the kilogram. It sits next to an inch-based ruler for scale. The IPK is made of a platinum-iridium alloy and is stored in a vault at the BIPM in Sèvres, France. Like the other prototypes, the edges of the IPK have a four-angle chamfer to minimize wear. For other kilogram-related images, see External links, below.
General information
Unit system	SI base unit
Unit of	Mass
Symbol	kg
Conversions
1 kg in ...	... is equal to ...
Natural units	4.59467(23)×107 Planck masses
Energy	1.356392733(68)×1050 hertz
	89,875,517,873,681,764 joules (precisely)
U.S. customary	≈ 2.204622622 pounds-avoirdupois

The kilogram (symbol: kg) is the base unit of mass in the International System of Units (SI, from the French [Le Système International d’Unités] Error: {{Lang}}: text has italic markup (help)), which is the modern standard governing the metric system. The kilogram is defined as being equal to the mass of the International Prototype Kilogram (IPK), which is almost exactly equal to the mass of one liter of water. It is the only SI base unit with an SI prefix as part of its name. It is also the only SI unit that is still defined by an artifact rather than a fundamental physical property that can be reproduced in different laboratories.

In everyday usage, the mass of an object, which is measured in kilograms, is often referred to as its weight. However, the term weight in strict scientific contexts refers to the gravitational force of an object. Throughout most of the world, force is measured with the SI unit newton and the non-SI unit kilogram-force. Similarly, the avoirdupois (or international) pound, used in both the Imperial system and U.S. customary units, is a unit of mass and its related unit of force is the pound-force. The avoirdupois pound is defined as exactly 0.45359237 kg, making one kilogram approximately equal to 2.2046 avoirdupois pounds.

Many units in the SI system are defined relative to the kilogram so its stability is important. After the International Prototype Kilogram had been found to vary in mass over time, the International Committee for Weights and Measures (known also by its French-language initials CIPM) recommended in 2005 that the kilogram be redefined in terms of a fundamental constant of nature. No final decision is expected before 2011.

Nature of mass

See also: Mass versus weight

The chains on the swing hold all the child’s weight. If one were to stand behind her at the bottom of the arc and try to stop her, one would be acting against her inertia, which arises purely from mass, not weight.

The kilogram is a unit of mass, the measurement of which corresponds to the general, everyday notion of how “heavy” something is. However, mass is actually an inertial property; that is, the tendency of an object to remain at constant velocity unless acted upon by an outside force. According to Sir Isaac Newton's 337-year-old laws of motion and an important formula that sprang from his work, F = ma, an object with a mass, m, of one kilogram will accelerate, a, at one meter per second per second (about one-tenth the acceleration due to earth’s gravity) when acted upon by a force, F, of one newton.

While the weight of matter is entirely dependent upon the strength of gravity, the mass of matter is invariant. Accordingly, for astronauts in microgravity, no effort is required to hold objects off the cabin floor; they are “weightless”. Since objects in microgravity still retain their mass and inertia, an astronaut must still exert the same force (ignoring friction) to accelerate an object, eg across a room, when in microgravity as compared to on earths surface.

On earth, a common swing set can demonstrate the relationship of force, mass, and acceleration without being appreciably influenced by weight (downward force). If one were to stand behind a large adult sitting stationary in a swing and give him a strong push, the adult would accelerate relatively slowly and swing only a limited distance forwards before beginning to swing backwards. Exerting that same effort while pushing on a small child would produce much greater acceleration.

History

Early definitions

For more on the history of the kilogram, see grave (mass).

On 7 April 1795, the gram was decreed in France to be equal to “the absolute weight of a volume of water equal to the cube of the hundredth part of the meter, at the temperature of melting ice.” The concept of using a specified volume of water to define a unit measure of mass was first advanced by the English philosopher John Wilkins in 1668.

Since trade and commerce typically involve items significantly more massive than one gram, and since a mass standard made of water would be inconvenient and unstable, the regulation of commerce necessitated the manufacture of a practical realization of the water-based definition of mass. Accordingly, a provisional mass standard was made as a single-piece, metallic artifact one thousand times more massive than the gram—the kilogram.

At the same time, work was commissioned to precisely determine the mass of a cubic decimeter (one liter) of water. Although the decreed definition of the kilogram specified water at 0 °C—its highly stable temperature point—the French chemist, Louis Lefèvre-Gineau and the Italian naturalist, Giovanni Fabbroni after several years of research chose to redefine the standard in 1799 to water’s most stable density point: the temperature at which water reaches maximum density, which was measured at the time as 4 °C. They concluded that one cubic decimeter of water at its maximum density was equal to 99.9265% of the target mass of the provisional kilogram standard made four years earlier. That same year, 1799, an all-platinum kilogram prototype was fabricated with the objective that it would equal, as close as was scientifically feasible for the day, the mass of one cubic decimeter of water at 4 °C. The prototype was presented to the Archives of the Republic in June and on 10 December 1799, the prototype was formally ratified as the Kilogramme des Archives (Kilogram of the Archives) and the kilogram was defined as being equal to its mass. This standard stood for the next ninety years.

International Prototype Kilogram

Since 1889, the SI system defines the magnitude of the kilogram to be equal to the mass of the International Prototype Kilogram, often referred to in the professional metrology world as the “IPK”. The IPK is made of a platinum alloy known as “Pt‑10Ir”, which is 90% platinum and 10% iridium (by mass) and is machined into a right-circular cylinder (height = diameter) of 39.17 millimeters to minimize its surface area. The addition of 10% iridium improved upon the all-platinum Kilogram of the Archives by greatly increasing hardness while still retaining platinum’s many virtues: extreme resistance to oxidation, extremely high density, satisfactory electrical and thermal conductivities, and low magnetic susceptibility. The IPK and its six sister copies are stored at the International Bureau of Weights and Measures (known by its French-language initials BIPM) in an environmentally monitored safe in the lower vault located in the basement of the BIPM’s House of Breteuil in Sèvres on the outskirts of Paris (see External images, below for photographs). Three independently controlled keys are required to open the vault. Official copies of the IPK were made available to other nations to serve as their national standards. These are compared to the IPK roughly every 50 years.

The IPK is one of three cylinders made in 1879. In 1883, it was found to be indistinguishable from the mass of the Kilogram of the Archives made eighty-four years prior, and was formally ratified as the kilogram by the 1st CGPM in 1889.

Modern measurements of Vienna Standard Mean Ocean Water, which is pure distilled water with an isotopic composition representative of the average of the world’s oceans, show it has a density of 0.999975 ±0.000001 kg/L at its point of maximum density (3.984 °C) under one standard atmosphere (760 torr) of pressure. Thus, a cubic decimeter of water at its point of maximum density is 25 parts per million less massive than the IPK. This small difference, and the fact that the mass of the IPK was indistinguishable from the mass of the Kilogram of the Archives, speak volumes of the scientists’ skills over 225 years ago when making their measurements of water’s properties and in manufacturing the Kilogram of the Archives.

Stability of the International Prototype Kilogram

Mass drift over time of national prototypes K21–K40, plus two of the IPK’s sister copies: K32 and K8(41). All mass changes are relative to the IPK. The initial 1889 starting-value offsets relative to the IPK have been nulled. The above are all relative measurements; no historical mass-measurement data is available to determine which of the prototypes has been most stable relative to an invariant of nature. There is the distinct possibility that all the prototypes gained mass over 100 years and that K21, K35, K40, and the IPK simply gained less than the others.

By definition, the error in the measured value of the IPK’s mass is exactly zero; the IPK is the kilogram. However, any changes in the IPK’s mass over time can be deduced by comparing its mass to that of its official copies stored throughout the world, a process called “periodic verification.” For instance, the U.S. owns four 90% platinum / 10% iridium (Pt‑10Ir) kilogram standards, two of which, K4 and K20, are from the original batch of 40 replicas delivered in 1884. The K20 prototype was designated as the primary national standard of mass for the U.S. Both of these, as well as those from other nations, are periodically returned to the BIPM for verification.

Note that none of the replicas has a mass precisely equal to that of the IPK; their masses are calibrated and documented as offset values. For instance, K20, the U.S.’s primary standard, originally had an official mass of 1 kg − 39 micrograms (µg) in 1889; that is to say, K20 was 39 µg less than the IPK. A verification performed in 1948 showed a mass of 1 kg − 19 µg. The latest verification performed in 1999 shows a mass precisely identical to its original 1889 value. Quite unlike transient variations such as this, the U.S.’s check standard, K4, has persistently declined in mass relative to the IPK—and for an identifiable reason. Check standards are used much more often than primary standards and are prone to scratches and other wear. K4 was originally delivered with an official mass of 1 kg − 75 µg in 1889, but as of 1989 was officially calibrated at 1 kg − 106 µg and ten years later was 1 kg − 116 µg. Over a period of 110 years, K4 lost 41 µg relative to the IPK.

Beyond the simple wear that check standards can experience, the mass of even the carefully stored national prototypes can drift relative to the IPK for a variety of reasons, some known and some unknown. Since the IPK and its replicas are stored in air (albeit under two or more nested bell jars), they gain mass through adsorption of atmospheric contamination onto their surfaces. Accordingly, they are cleaned in a process the BIPM developed between 1939 and 1946 known as “the BIPM cleaning method” that comprises lightly rubbing with a chamois soaked in equal parts ether and ethanol, followed by steam cleaning with bi-distilled water, and allowing the prototypes to settle for 7–10 days before verification. Cleaning the prototypes removes between 5 and 60 µg of contamination depending largely on the time elapsed since the last cleaning. Further, a second cleaning can remove up to 10 µg more. After cleaning—even when they are stored under their bell jars—the IPK and its replicas immediately begin gaining mass again. The BIPM even developed a model of this gain and concluded that it averaged 1.11 µg per month for the first 3 months after cleaning and then decreased to an average of about 1 µg per year thereafter. Since check standards like K4 are not cleaned for routine calibrations of other mass standards—a precaution to minimize the potential for wear and handling damage—the BIPM’s model of time-dependent mass gain has been used as an “after cleaning” correction factor.

File:Denmark’s K48 Kilogram.jpg

K48, above, came from the second batch of kilogram replicas to be produced. It was delivered to Denmark in 1949 with an official mass of 1 kg + 81 µg. Like all other replicas, it is stored under two nested bell jars virtually all the time. Still, its mass and that of the IPK diverged markedly in only 40 years; the mass of K48 was certified as 1 kg + 112 µg during the 1988–1992 periodic verification.

Because the first forty official copies are made of the same alloy as the IPK and are stored under similar conditions, periodic verifications using a large number of replicas—especially the national primary standards, which are rarely used—can convincingly demonstrate the stability of the IPK. What has become clear after the third periodic verification performed between 1988 and 1992 is that masses of the entire worldwide ensemble of prototypes have been slowly but inexorably diverging from each other. It is also clear that the mass of the IPK lost perhaps 50 µg over the last century, and possibly significantly more, in comparison to its official copies. The reason for this drift has eluded physicists who have dedicated their careers to the SI unit of mass. No plausible mechanism has been proposed to explain either a steady decrease in the mass of the IPK, or an increase in that of its replicas dispersed throughout the world. This relative nature of the changes amongst the world’s kilogram prototypes is often misreported in the popular press, and even some notable scientific magazines, which often state that the IPK simply “lost 50 µg” and omit the very important caveat of “in comparison to its official copies.” Moreover, there are no technical means available to determine whether or not the entire worldwide ensemble of prototypes suffers from even greater long-term trends upwards or downwards because their mass “relative to an invariant of nature is unknown at a level below 1000 µg over a period of 100 or even 50 years.” Given the lack of data identifying which of the world’s kilogram prototypes has been most stable in absolute terms, it is equally as valid to state that the first batch of replicas has, as a group, gained an average of about 25 µg over one hundred years in comparison to the IPK.

What is known specifically about the IPK is that it exhibits a short-term instability of about 30 µg over a period of about a month in its after-cleaned mass. The precise reason for this short-term instability is not understood but is thought to entail surface effects: microscopic differences between the prototypes’ polished surfaces, possibly aggravated by hydrogen absorption due to catalysis of the volatile organic compounds that slowly deposit onto the prototypes as well as the hydrocarbon-based solvents used to clean them.

Scientists are seeing far greater variability in the prototypes than previously believed. The increasing divergence in the masses of the world’s prototypes and the short-term instability in the IPK has prompted research into improved methods to obtain a smooth surface finish using diamond-turning on newly manufactured replicas and has intensified the search for a new definition of the kilogram. See Proposed future definitions, below.

Importance of the kilogram

The magnitude of many of the units comprising the SI system of measurement, including most of those used in the measurement of electricity and light, are highly dependent upon the stability of a 145-year-old, golf ball-size cylinder of metal stored in a vault in France.

The stability of the IPK is crucial because the kilogram underpins much of the SI system of measurement as it is currently defined and structured. For instance, the newton is defined as the force necessary to accelerate one kilogram at one meter per second squared. If the mass of the IPK were to change slightly, so too must the newton by a proportional degree. In turn, the pascal, the SI unit of pressure, is defined in terms of the newton. This chain of dependency follows to many other SI units of measure. For instance, the joule, the SI unit of energy, is defined as that expended when a force of one newton acts through one meter. Next to be affected is the SI unit of power, the watt, which is one joule per second. The ampere too is defined relative to the newton, and ultimately, the kilogram. With the magnitude of the primary units of electricity thus determined by the kilogram, so too follow many others; namely, the coulomb, volt, tesla, and weber. Even units used in the measure of light would be affected; the candela—following the change in the watt—would in turn affect the lumen and lux.

Because the magnitude of many of the units comprising the SI system of measurement is ultimately defined by the mass of a 145-year-old, golf ball-sized piece of metal, the quality of the IPK must be diligently protected to preserve the integrity of the SI system. Yet, in spite of the best stewardship, the average mass of the worldwide ensemble of prototypes and the mass of the IPK have likely diverged another 8.3 µg since the third periodic verification 35 years ago. Further, the world’s national metrology laboratories must wait for the fourth periodic verification to confirm whether the historical trends persisted.

Fortunately, definitions of the SI units are quite different from their practical realizations. For instance, the meter is defined as the distance light travels in a vacuum during a time interval of 1⁄299,792,458 of a second. However, the meter’s practical realization typically takes the form of a helium-neon laser, and the meter’s length is delineated—not defined—as 1579800.298728 wavelengths of light from this laser. Now suppose that the official measurement of the second was found to have drifted by a few parts per billion (it is actually exquisitely stable). There would be no automatic effect on the meter because the second—and thus the meter’s length—is abstracted via the laser comprising the meter’s practical realization. Scientists performing meter calibrations would simply continue to measure out the same number of laser wavelengths until an agreement was reached to do otherwise. The same is true with regard to the real-world dependency on the kilogram: if the mass of the IPK was found to have changed slightly, there would be no automatic effect upon the other units of measure because their practical realizations provide an insulating layer of abstraction. Any discrepancy would eventually have to be reconciled though because the virtue of the SI system is its precise mathematical and logical harmony amongst its units. If the IPK’s value were definitively proven to have changed, one solution would be to simply redefine the kilogram as being equal to the mass of the IPK plus an offset value, similarly to what is currently done with its replicas; e.g., “the kilogram is equal to the mass of the IPK + 42 parts per billion” (equivalent to 42 µg).

The long-term solution to this problem, however, is to liberate the SI system’s dependency on the IPK by developing a practical realization of the kilogram that can be reproduced in different laboratories by following a written specification. The units of measure in such a practical realization would have their magnitudes precisely defined and expressed in terms of fundamental physical constants. While major portions of the SI system would still be based on the kilogram, the kilogram would in turn be based on invariant, universal constants of nature. While this is a worthwhile objective and much work towards that end is ongoing, no alternative has yet achieved the uncertainty of a couple parts in 10⁸ (~20 µg) required to improve upon the IPK. However, as of April 2007, the U.S.’s National Institute of Standards and Technology (NIST) had an implementation of the watt balance that was approaching this goal, with a demonstrated uncertainty of 36 µg. See Watt balance, below.

Proposed future definitions

In the following section, wherever numeric equalities are shown in ‘concise form’—such as 1.85487(14)×10⁴³—the two digits between the parentheses denote the uncertainty at 1σ standard deviation (68% confidence level) in the two least significant digits of the significand.

The kilogram is the only SI unit that is still defined by an artifact. Note that the meter was also once defined as an artifact (a single platinum-iridium bar with two marks on it). However, it was eventually redefined in terms of invariant, fundamental constants of nature (the wavelength of light emitted by krypton, which depends on the speed of light and Planck's constant) so that the standard can be reproduced in different laboratories by following a written specification. Today, physicists are investigating various approaches to doing the same with the kilogram. Some of the approaches are fundamentally very different from each other. Some are based on equipment and procedures that enable the reproducible production of new, kilogram-mass prototypes on demand (albeit with extraordinary effort) using measurement techniques and material properties that are ultimately based on, or traceable to, fundamental constants. Others are devices that measure either the acceleration or weight of hand-tuned, kilogram test masses and which express their magnitudes in electrical terms via special components that permit traceability to fundamental constants. Measuring the weight of test masses requires the precise measurement of the strength of gravity in laboratories. All approaches would precisely fix one or more constants of nature at a defined value. These different approaches are as follows:

Atom-counting approaches

Carbon-12

Though not offering a practical realization, this definition would precisely define the magnitude of the kilogram in terms of a certain number of carbon‑12 atoms. Carbon‑12 (¹²C) is an isotope of carbon. The mole is currently defined as “the quantity of entities (elementary particles like atoms or molecules) equal to the number of atoms in 12 grams of carbon‑12.” Thus, the current definition of the mole requires that 1000⁄12 (83⅓) moles of ¹²C has a mass of precisely one kilogram. The number of atoms in a mole, a quantity known as the Avogadro constant, is experimentally determined, and the current best estimate of its value is 6.02214179(30)×10²³ entities per mole (CODATA, 2006). This new definition of the kilogram proposes to fix the Avogadro constant at precisely 6.02214179×10²³ with the kilogram being defined as “the mass equal to that of 1000⁄12 · 6.02214179×10²³ atoms of ¹²C.”

The accuracy of the measured value of the Avogadro constant is currently limited by the uncertainty in the value of the Planck constant—a measure relating the energy of photons to their frequency. That relative standard uncertainty has been 50 parts per billion (ppb) since 2006. By fixing the Avogadro constant, the practical effect of this proposal would be that the uncertainty in the mass of a ¹²C atom—and the magnitude of the kilogram—could be no better than the current 50 ppb uncertainty in the Planck constant. Under this proposal, the magnitude of the kilogram would be subject to future refinement as improved measurements of the value of the Planck constant become available; electronic realizations of the kilogram would be recalibrated as required. Conversely, an electronic definition of the kilogram (see Electronic approaches, below), which would precisely fix the Planck constant, would continue to allow 83⅓ moles of ¹²C to have a mass of precisely one kilogram but the number of atoms comprising a mole (the Avogadro constant) would continue to be subject to future refinement.

A variation on a ¹²C-based definition proposes to define the Avogadro constant as being precisely 84,446,886³ (≈6.02214098×10²³) atoms. An imaginary realization of a 12-gram mass prototype would be a cube of ¹²C atoms measuring precisely 84,446,886 atoms across on a side. With this proposal, the kilogram would be defined as “the mass equal to 84,446,886³ × 83⅓ atoms of ¹²C.” The value 84,446,886 was chosen because it has a special property; its cube (the proposed new value for the Avogadro constant) is evenly divisible by twelve. Thus with this definition of the kilogram, there would be an integer number of atoms in one gram of ¹²C: 50,184,508,190,229,061,679,538 atoms.

Avogadro project

One of the master opticians at the Australian Centre for Precision Optics (ACPO) is holding a 1 kg, single-crystal silicon sphere for the Avogadro project. These spheres are among the roundest man-made objects in the world. If the best of these spheres were scaled to the size of earth, its high point—a continent-size area—would gently rise to a maximum elevation of only 2.4 meters above “sea level.”

Another Avogadro constant-based approach, known as the Avogadro project, would define and delineate the kilogram as a softball-size (93.6 mm diameter) sphere of silicon atoms. Silicon was chosen because a commercial infrastructure with mature processes for creating defect-free, ultra-pure monocrystalline silicon already exists to service the semiconductor industry. To make a practical realization of the kilogram, a silicon boule (a rod-like, single-crystal ingot) would be produced. Its isotopic composition would be measured with a mass spectrometer to determine its average relative atomic mass. The boule would be cut, ground, and polished into spheres. The size of a select sphere would be measured using optical interferometry to an uncertainty of about 0.3 nm on the radius—roughly a single atomic layer. The precise lattice spacing between the atoms in its crystal structure (≈192 pm) would be measured using a scanning X-ray interferometer. This permits its atomic spacing to be determined with an uncertainty of only three parts per billion. With the size of the sphere, its average atomic mass, and its atomic spacing known, the required sphere diameter can be calculated with sufficient precision and uncertainty to enable it to be finish-polished to a target mass of one kilogram.

Experiments are being performed on the Avogadro Project’s silicon spheres to determine whether their masses are most stable when stored in a vacuum, a partial vacuum, or ambient pressure. However, no technical means currently exist to prove a long-term stability any better than that of the IPK’s because the most sensitive and accurate measurements of mass are made with dual-pan balances like the BIPM’s FB‑2 flexure-strip balance (see External links, below). Balances can only compare the mass of a silicon sphere to that of a reference mass. Given the latest understanding of the lack of long-term mass stability with the IPK and its replicas, there is no known, perfectly stable mass artifact to compare against. Single-pan scales, which measure weight relative to an invariant of nature, are not precise to the necessary long-term uncertainty of 10–20 parts per billion. Another issue to be overcome is that silicon oxidizes and forms a thin layer (equivalent to 5–20 silicon atoms) of silicon dioxide (quartz) and silicon monoxide. This layer slightly increases the mass of the sphere, an effect which must be accounted for when polishing the sphere to its finish dimension. Oxidation is not an issue with platinum and iridium, both of which are noble metals that are roughly as cathodic as oxygen and therefore don’t oxidize unless coaxed to do so in the laboratory. The presence of the thin oxide layer on a silicon-sphere mass prototype places additional restrictions on the procedures that might be suitable to clean it to avoid changing the layer’s thickness or oxide stoichiometry.

All silicon-based approaches would fix the Avogadro constant but vary in the details of the definition of the kilogram. One approach would use silicon with all three of its natural isotopes present. About 7.78% of silicon comprises the two heavier isotopes: ²⁹Si and ³⁰Si. As described in Carbon‑12 above, this method would define the magnitude of the kilogram in terms of a certain number of ¹²C atoms by fixing the Avogadro constant; the silicon sphere would be the practical realization. This approach could accurately delineate the magnitude of the kilogram because the masses of the three silicon nuclides relative to ¹²C are known with great precision (relative uncertainties of 1 ppb or better). An alternative method for creating a silicon sphere-based kilogram proposes to use isotopic separation techniques to enrich the silicon until it is nearly pure ²⁸Si, which has a relative atomic mass of 27.9769265325(19). With this approach, the Avogadro constant would not only be fixed, but so too would the atomic mass of ²⁸Si. As such, the definition of the kilogram would be decoupled from ¹²C and the kilogram would instead be defined as 1000⁄27.9769265325 · 6.02214179×10²³ atoms of ²⁸Si (≈35.74374043 fixed moles of ²⁸Si atoms). Physicists could elect to define the kilogram in terms of ²⁸Si even when kilogram prototypes are made of natural silicon (all three isotopes present). Even with a kilogram definition based on theoretically pure ²⁸Si, a silicon-sphere prototype made of only nearly pure ²⁸Si would necessarily deviate slightly from the defined number of moles of silicon to compensate for various chemical and isotopic impurities as well as the effect of surface oxides.

Ion accumulation

Another Avogadro-based approach, ion accumulation, since abandoned, would have defined and delineated the kilogram by precisely creating new metal prototypes on demand. It would have done so by accumulating gold or bismuth ions (atoms stripped of an electron) and counted them by measuring the electrical current required to neutralize the ions. Gold (¹⁹⁷Au) and bismuth (²⁰⁹Bi) were chosen because they can be safely handled and have the two highest atomic masses among the mononuclidic elements that are virtually non-radioactive (bismuth) or thought to be perfectly stable (gold). See also Table of nuclides.

With a gold-based definition of the kilogram for instance, the relative atomic mass of gold could have been fixed as precisely 196.9665687, from the current value of 196.9665687(6). As with a definition based upon carbon‑12, the Avogadro constant would also have been fixed. The kilogram would then have been defined as “the mass equal to that of precisely 1000⁄196.9665687 · 6.02214179×10²³ atoms of gold” (precisely 3,057,443,620,887,933,963,384,315 atoms of gold or about 5.07700371 fixed moles).

In 2003, German experiments with gold at a current of only 10 µA demonstrated a relative uncertainty of 1.5%. Follow-on experiments using bismuth ions and a current of 30 mA were expected to accumulate a mass of 30 g in six days and to have a relative uncertainty of better than 1 part in 10⁶. Ultimately, ion‑accumulation approaches proved to be unsuitable. Measurements required months and the data proved too erratic for the technique to be considered a viable future replacement to the IPK.

Among the many technical challenges of the ion-deposition apparatus was obtaining a sufficiently high ion current (mass deposition rate) while simultaneously decelerating the ions so they could all deposit onto a target electrode embedded in a balance pan. Experiments with gold showed the ions had to be decelerated to very low energies to avoid sputtering effects—an phenomenon whereby ions that had already been counted ricochet off the target electrode or even dislodged atoms that had already been deposited. The deposited mass fraction in the 2003 German experiments only approached very close to 100% at ion energies of less than around 1 eV (<1 km/s for gold).

If the kilogram had been defined as a precise quantity of gold or bismuth atoms deposited with an electric current, not only would the Avogadro constant and the atomic mass of gold or bismuth had to have been precisely fixed, but also the value of the elementary charge (e), likely to 1.602176487×10⁻¹⁹ C (from the present 2006 CODATA value of 1.602176487(40)×10⁻¹⁹). Doing so would have effectively defined the ampere as a flow of 1⁄1.602176487×10⁻¹⁹ (6,241,509,647,120,417,390) electrons per second past a fixed point in an electric circuit. The SI unit of mass would have been fully defined by having precisely fixed the values of the Avogadro constant and elementary charge, and by exploiting the fact that the atomic masses of bismuth and gold atoms are invariant, universal constants of nature.

Beyond the slow speed of making a new mass standard and the poor reproducibility, there were other intrinsic shortcomings to the ion‑accumulation approach that proved to be formidable obstacles to ion-accumulation-based techniques becoming a practical realization. The apparatus necessarily required that the deposition chamber have an integral balance system to enable the convenient calibration of a reasonable quantity of transfer standards relative to any single internal ion-deposited prototype. Furthermore, the mass prototypes produced by ion deposition techniques would have been nothing like the freestanding platinum-iridium prototypes currently in use; they would have been deposited onto—and become part of—an electrode imbedded into one pan of a special balance integrated into the device. Moreover, the ion-deposited mass wouldn’t have had a hard, highly polished surface that can be vigorously cleaned like those of current prototypes. Gold, while dense and a noble metal (resistant to oxidation and the formation of other compounds), is extremely soft so an internal gold prototype would have to be kept well isolated and scrupulously clean to avoid contamination and the potential of wear from having to remove the contamination. Bismuth, which is an inexpensive metal used in low-temperature solders, slowly oxidizes when exposed to room-temperature air and forms other chemical compounds and so would not have produced stable reference masses unless it was continually maintained in a vacuum or inert atmosphere.

Electronic approaches

Watt balance

The NIST’s watt balance is a project of the U.S. Government to develop an “electronic kilogram.” The vacuum chamber dome, which lowers over the entire apparatus, is visible at top.

The watt balance is essentially a single-pan weighing scale that measures the electric power necessary to oppose the weight of a kilogram test mass as it is pulled by earth’s gravity. It is a variation of an ampere balance in that it employs an extra calibration step that nulls the effect of geometry. The electric potential in the watt balance is delineated by a Josephson voltage standard, which allows voltage to be linked to an invariant constant of nature with extremely high precision and stability. Its circuit resistance is calibrated against a quantum Hall resistance standard.

The watt balance requires exquisitely precise measurement of gravity in a laboratory (see “FG‑5 absolute gravimeter” in External images, below). For instance, the NIST compensates for earth’s gravity gradient of 3.09 µGal per centimeter when the elevation of the center of the gravimeter differs from that of the nearby test mass in the watt balance; a change in the weight of a one-kilogram test mass that equates to about 3.16 µg/cm.

In April 2007, the NIST’s implementation of the watt balance demonstrated a combined relative standard uncertainty (CRSU) of 36 µg and a short-term resolution of 10–15 µg. The UK’s National Physical Laboratory’s watt balance demonstrated a CRSU of 70.3 µg in 2007. That watt balance was disassembled and shipped in 2009 to Canada’s Institute for National Measurement Standards (part of the National Research Council), where research and development with the device could continue.

With the watt balance, the kilogram would be redefined and internationally recognized in terms of two invariants of nature: the speed of light (c) and the Planck constant (h), which is a measure that relates the energy of photons to their frequency. The Planck constant would be fixed; for example, to h = 6.62606896×10⁻³⁴ J·s (from the 2006 CODATA value of 6.62606896(33)×10⁻³⁴ J·s). The kilogram would relate to these two fundamental constants of nature via the formula 1 kg = c²/h = f, which is to say, the mass of the kilogram would be equivalent to the square of the speed of light divided by the Planck constant, where the defined amount of energy is expressed as a simple frequency. The kilogram would thus be defined as “the mass of a body at rest whose equivalent energy equals the energy of photons whose frequencies sum to ( 299,792,458²⁄6.62606896×10⁻³⁴ ) hertz.”  This quotient is approximately 1.356392733×10⁵⁰ hertz (symbol = Hz), which is expressed here at a precision of better than one part per billion—better precision than the watt balance will be able to operate at for the foreseeable future.

When operating at its full planned output of 10 megawatts, the YAL-1 Airborne Laser will, during a single 4.5‑second firing of its COIL laser, emit photons whose total energy is equivalent to one-half billionth of a kilogram.

A “sum of photon frequencies” means the photon energy that is equivalent to one kilogram could be expressed in terms of a single photon oscillating at about 1.356×10⁵⁰ Hz, two photons that each have half that frequency (about 6.78×10⁴⁹ Hz), 100 photons with one‑hundredth the specified value (about 1.356×10⁴⁸ Hz), or approximately 5.95×10³⁵ photons from a chemical oxygen-iodine laser, which oscillate at about 2.279×10¹⁴ Hz. This sum of frequencies is an extraordinarily high value; a single photon oscillating at 1.356×10⁵⁰ Hz would be oscillating over a trillion-trillion times faster than the highest-energy gamma ray photons ever observed.

By fixing the value of the Planck constant and defining the kilogram in terms of its equivalent energy, the magnitude of the kilogram is being measured in terms of Albert Einstein’s famous equation E = mc², which holds that mass can be expressed in terms of energy and vice versa. Due to the way the SI system of measurement is logically structured, E = mc² means one kilogram is precisely equivalent to an energy of 89,875,517,873,681,764 joules, which is the square of the speed of light in meters per second (299,792,458²), or as stated above, this energy in joules can be divided by the Planck constant to express the energy as a sum of photon frequencies. Regardless of the units of measure employed, one kilogram has an exceedingly great deal of equivalent energy; it is comparable to that released in the explosion of a fairly powerful hydrogen bomb: a yield of approximately 21 megatons. At a slower rate, the largest electric power-producing facility in the United States, Grand Coulee Dam, would typically require over 14 months to generate nearly 90 quadrillion joules of energy. In terms of a collection of photons that have a total energy equivalent to one kilogram, the approximately 5.95×10³⁵ near‑infrared photons from the above-mentioned chemical oxygen-iodine laser, which is a weapon system intended for destroying intercontinental ballistic missiles, would require a beam length that could reach beyond any of the 200 stars nearest the sun; with a beam intensity of one megawatt per square centimeter and a diameter of 3.6 centimeters, it would have a length of 280 light‑years.

Gravity is measured with exceptional precision with the help of a laser interferometer. The laser’s pattern of interference fringes—the dark and light bands above—blooms at an ever faster rate as a free-falling corner reflector drops inside an absolute gravimeter. The pattern’s frequency sweep is timed by an atomic clock.

Fortunately, the kilogram’s mass/energy equivalence is established indirectly in the watt balance; gravity serves as a crucial translation tool that is exploited to measure the “mass vs. energy” relationship via a “force vs. electrical power” relationship. Since gravity is the weakest of nature’s fundamental forces and since earth’s gravity is relatively modest compared to other celestial bodies, only a relatively small amount of electrical power is required to counter the weight of one kilogram on earth. However, the force of gravity varies significantly—nearly one percent—depending upon where on earth’s surface the measurement is made (see Earth’s gravity ). Even more problematic, there are subtle seasonal variations in gravity due to changes in underground water tables, and even semimonthly and diurnal changes due to tidal distortions in the earth’s shape caused by the moon. Although gravity would not be a term in the definition of the kilogram, gravity would be a crucial term used in the delineation of the kilogram when relating energy to power. Accordingly, the ‘gravity’ term must be measured with at least as much precision and accuracy as are the other terms. It is therefore highly desirable that gravity measurements also be traceable to fundamental constants of nature. For the most precise work in mass metrology, gravitational acceleration is measured using dropping-mass absolute gravimeters that contain an iodine-stabilized helium–neon laser interferometer. The fringe-signal, frequency-sweep output from the interferometer is measured with a rubidium atomic clock. Since this type of dropping-mass gravimeter derives its accuracy and stability from the constancy of the speed of light as well as the innate properties of helium, neon, and rubidium atoms, the ‘gravity’ term in the delineation of an all-electronic kilogram is also measured in terms of invariants of nature—and with very high precision. For instance, in the basement of the NIST’s Gaithersburg facility in 2009, when measuring the gravity acting upon Pt‑10Ir test masses (which are denser, smaller, and have a slightly lower center of gravity inside the watt balance than stainless steel masses), the measured value was typically within 8 ppb of 9.80101644 m/s².

The virtue of electronic realizations like the watt balance is that the definition and dissemination of the kilogram would no longer be dependent upon the stability of kilogram prototypes, which must be very carefully handled and stored. It would free physicists from the need to rely on assumptions about the stability of those prototypes, including those that would be manufactured under atom-counting schemes. Instead, hand-tuned, close-approximation mass standards would simply be weighed and documented as being equal to one kilogram plus an offset value. With the watt balance, the kilogram would not only be delineated in electrical and gravity terms, all of which are traceable to invariants of nature; it would be defined in electrical terms in a manner that is directly traceable to just two fundamental constants of nature. Mass artifacts—physical objects calibrated in a watt balance, including the IPK—would become transfer standards.

Scales like the watt balance also permit more flexibility in choosing materials with especially desirable properties for mass standards. For instance, Pt‑10Ir could continue to be used so that the specific gravity of newly produced mass standards would be the same as existing national primary and check standards (≈21.55 g/ml). This would reduce the relative uncertainty when making mass comparisons in air. Alternately, entirely different materials and constructions could be explored with the objective of producing mass standards with greater stability. For instance, osmium-iridium alloys could be investigated if platinum’s propensity to absorb hydrogen (due to catalysis of VOCs and hydrocarbon-based cleaning solvents) and atmospheric mercury proved to be sources of instability. Also, vapor-deposited, protective ceramic coatings like nitrides could be investigated for their suitability to isolate these new alloys.

The challenge with watt balances is not only in reducing their uncertainty, but also in making them truly practical realizations of the kilogram. Nearly every aspect of watt balances and their support equipment requires such extraordinarily precise and accurate, state-of-the-art technology that—unlike a device like an atomic clock—few countries would currently choose to fund their operation. For instance, the NIST’s watt balance used four resistance standards in 2007, each of which was rotated through the watt balance every two to six weeks after being calibrated in a different part of NIST headquarters facility in Gaithersburg, Maryland. It was found that simply moving the resistance standards down the hall to the watt balance after calibration altered their values 10 ppb (equivalent to 10 µg) or more. Present-day technology is insufficient to permit stable operation of watt balances between even biannual calibrations. If the kilogram is defined in terms of the Planck constant, it is likely there will only be a few—at most—watt balances initially operating in the world.

Ampere-based force

File:Meissner effect zoom.jpg

A magnet floating above a superconductor bathed in liquid nitrogen demonstrates perfect diamagnetic levitation via the Meissner effect. Experiments with an ampere-based definition of the kilogram flipped this arrangement upside-down: an electric field accelerated a superconducting test mass supported by fixed magnets.

This approach would define the kilogram as “the mass which would be accelerated at precisely 2×10⁻⁷ m/s² when subjected to the per-meter force between two straight parallel conductors of infinite length, of negligible circular cross section, placed one meter apart in vacuum, through which flow a constant current of 1⁄1.602176487×10⁻¹⁹ (≈6,241,509,647,120,417,390) elementary charges per second.”

Effectively, this would define the kilogram as a derivative of the ampere rather than present relationship, which defines the ampere as a derivative of the kilogram. This redefinition of the kilogram would specify elementary charge (e) as precisely 1.602176487×10⁻¹⁹ coulomb rather than the current 2006 CODATA value of 1.602176487(40)×10⁻¹⁹. Effectively, the coulomb would be the sum of 6,241,509,647,120,417,390 elementary charges. It would necessarily follow that the ampere (one coulomb per second) would also become an electrical current of this precise quantity of elementary charges per second passing a given point in an electric circuit.

The virtue of a practical realization based upon this definition is that unlike the watt balance and other scale-based methods, all of which require the careful characterization of gravity in the laboratory, this method delineates the magnitude of the kilogram directly in the very terms that define the nature of mass: acceleration due to an applied force. Unfortunately, it is extremely difficult to develop a practical realization based upon accelerating masses. Experiments over a period of years in Japan with a superconducting, 30 g mass supported by diamagnetic levitation never achieved an uncertainty better than ten parts per million. Magnetic hysteresis was one of the limiting issues. Other groups are continuing this line of research using different techniques to levitate the mass.

SI multiples

Because SI prefixes may not be concatenated (serially linked) within the name or symbol for a unit of measure, SI prefixes are used with the gram, not the kilogram, which already has a prefix as part of its name. For instance, one-millionth of a kilogram is 1 mg (one milligram), not 1 µkg (one microkilogram).

SI multiples of gram (g)

Submultiples			Multiples
Value	SI symbol	Name	Value	SI symbol	Name
10−1 g	dg	decigram	101 g	dag	decagram
10−2 g	cg	centigram	102 g	hg	hectogram
10−3 g	mg	milligram	103 g	kg	kilogram
10−6 g	μg	microgram (mcg)	106 g	Mg	megagram (tonne)
10−9 g	ng	nanogram	109 g	Gg	gigagram
10−12 g	pg	picogram	1012 g	Tg	teragram
10−15 g	fg	femtogram	1015 g	Pg	petagram
10−18 g	ag	attogram	1018 g	Eg	exagram
10−21 g	zg	zeptogram	1021 g	Zg	zettagram
10−24 g	yg	yoctogram	1024 g	Yg	yottagram
10−27 g	rg	rontogram	1027 g	Rg	ronnagram
10−30 g	qg	quectogram	1030 g	Qg	quettagram
Common prefixes are in bold face.

• When the Greek lowercase “µ” (mu) in the symbol of microgram is typographically unavailable, it is occasionally—although not properly—replaced by Latin lowercase “u”.
• The microgram is often abbreviated “mcg”, particularly in pharmaceutical and nutritional supplement labeling, to avoid confusion since the “µ” prefix is not well recognized outside of technical disciplines. Note however, that the abbreviation “mcg”, is also the symbol for an obsolete CGS unit of measure known as the “millicentigram”, which is equal to 10 µg.
• The unit name “megagram” is rarely used, and even then, typically only in technical fields in contexts where especially rigorous consistency with the units of measure is desired. For most purposes, the unit “tonne” is instead used. The tonne and its symbol, t, were adopted by the CIPM in 1879. It is a non-SI unit accepted by the BIPM for use with the SI. In English speaking countries it is usually called “metric ton”. Note also that the unit name “megatonne” or “megaton” (Mt) is often used in general-interest literature on greenhouse gas emissions whereas the equivalent value in scientific papers on the subject is often the “teragram” (Tg).

Glossary

• Abstracted: Isolated and its effect changed in form, often simplified or made more accessible in the process.
• Artifact: A simple human-made object used directly as a comparative standard in the measurement of a physical quantity.
• Check standard:
  1. A standard body’s backup replica of the International Prototype Kilogram (IPK).
  2. A secondary kilogram mass standard used as a stand-in for the primary standard during routine calibrations.
• Definition: A formal, specific, and exact specification.
• Delineation: The physical means used to mark a boundary or express the magnitude of an entity.
• Disseminate: To widely distribute the magnitude of a unit of measure, typically via replicas and transfer standards.
• IPK: Abbreviation of “International Prototype Kilogram” (CG image), the mass artifact in France internationally recognized as having the defining mass of precisely one kilogram.
• Magnitude: The extent or numeric value of a property
• National prototype: A replica of the IPK possessed by a nation.
• Practical realization: A readily reproducible apparatus to conveniently delineate the magnitude of a unit of measure.
• Primary national standard:
  1. A replica of the IPK possessed by a nation
  2. The least used replica of the IPK when a nation possesses more than one.
• Prototype:
  1. A human-made object that serves as the defining comparative standard in the measurement of a physical quantity.
  2. A human-made object that serves as the comparative standard in the measurement of a physical quantity.
  3. The IPK and any of its replicas
• Replica: An official copy of the IPK.
• Sister copy: One of six official copies of the IPK that are stored in the same safe as the IPK and are used as check standards by the BIPM.
• Transfer standard: An artifact or apparatus that reproduces the magnitude of a unit of measure in a different, usually more practical, form.

See also

• 1795 in science
• 1799 in science
• Inertia
• International System of Units (SI)
• International Bureau of Weights and Measures (BIPM)
• International Committee for Weights and Measures (CIPM)
• General Conference on Weights and Measures (CGPM)
• Gram
• Grave (orig. name of the kilogram, history of)
• Gravimetry
• Kilogram-force

• Litre
• Metric system
• Mass
• Mass versus weight
• Milligrams per cent
• National Institute of Standards and Technology (NIST)
• newton
• SI base units
• Standard gravity
• Tonne (metric ton)
• Watt balance
• Weight

External links

External images
BIPM: The IPK in three nested bell jars
NIST: K20, the US National Prototype Kilogram, resting on an egg crate fluorescent light panel
BIPM: Steam cleaning a 1 kg prototype before a mass comparison
BIPM: The IPK and its six sister copies in their vault
The Age: Silicon sphere for the Avogadro Project
NPL: The NPL’s Watt Balance project
NIST: This particular Rueprecht Balance, an Austrian-made precision balance, was used by the NIST from 1945 until 1960
BIPM: The FB‑2 flexure-strip balance, the BIPM’s modern precision balance featuring a standard deviation of one ten-billionth of a kilogram (0.1 µg)
BIPM: Mettler HK1000 balance, featuring 1 µg resolution and a 4 kg maximum mass. Also used by NIST and Sandia National Laboratories’ Primary Standards Laboratory
Micro-g LaCoste: FG‑5 absolute gravimeter, (diagram), used in national laboratories to measure gravity to 2 µGal accuracy

• National Institute of Standards and Technology (NIST): NIST Improves Accuracy of ‘Watt Balance’ Method for Defining the Kilogram
• The U.K.’s National Physical Laboratory (NPL): An overview of the problems with an artifact-based kilogram
• NPL: Avogadro Project
• NPL: NPL watt balance
• Metrology in France: Watt balance
• Australian National Measurement Institute: Redefining the kilogram through the Avogadro constant
• International Bureau of Weights and Measures (BIPM): Home page
• NZZ Folio: What a kilogram really weighs
• NPL: What are the differences between mass, weight, force and load?
• BBC: Getting the measure of a kilogram
• NPR: This Kilogram Has A Weight-Loss Problem, an interview with National Institute of Standards and Technology physicist Richard Steiner