Agua

temperatura(`C) densidad (kj/kg) Cp (J/kg.K) temperatura

0.01 999.8 2501 4217 20
5 999.9 2490 4205
10 999.7 2478 4194

15 999.1 2466 4185

20 998 2454 4182

25 997 2442 4180
30 996 2431 4178
35 994 2419 4178
40 992.1 2407 4179
45 990.1 2395 4180
50 988.1 2383 4181
55 985.2 2371 4183
60 983.3 2359 4185
65 980.4 2346 4187
70 977.5 2334 4190
75 974.7 2321 4193
80 971.8 2309 4197
85 968.1 2296 4201
90 965.3 2283 4206
95 961.5 2270 4212
100 957.9 2257 4217
110 950.6 2230 4229
120 943.4 2203 4244
130 934.6 2174 4263
140 921.7 2145 4286
150 916.6 2114 4311
160 907.4 2083 4340
170 897.7 2050 4370
180 887.3 2015 4410
190 876.4 1979 4460
200 864.3 1941 4500
220 840.3 1859 4610
240 813.7 1767 4760
260 783.7 1663 4970
280 750.8 1544 5280
300 713.8 1405 5750
320 667.1 1239 6540
340 610.5 1028 8240
 360 528.3 720 14690

temperatura densidad (kj/kg) Cp(J/kg.K)

Lim inferior 20 998 2454 4182
Lim superior 25 997 2442 4180

valor 20 998 2454 4182

densidad (kj/kg) Cp(J/kg.K)
998.0000 2454 4182
 ECUACION DE ANTOINE

Log(Psat) = A0 -

compuestos puros

N Formula

NOMBRE 0 H20
PESO MOLECULAR 1 CCL4
TEMPERATURA 5 CF4
A 6 CO
B 7 CO2
C 8 COS
Cp 9 CS2
Cp 10 CHCL3
11 CHCL2F
13 CHF3
14 CHI3
16 CH2CL2
17 CH2CLF
18 CH2F2
20 CH2O
22 CH3BR
23 CH3CL
24 CH3F
26 CH3NO2
29 CH4
30 CH4O
33 C2CL4
54 C2H3CL
60 C2H4
72 C2H5BR
73 C2H5CL
79 C2H6
97 C3H6
98 C3H6
107 C3H6O
121 C3H8
167 C4H10
200 C5H8
208 C5H10
218 C5H12
228 C6CL6
229 C6F6
236 C6H5BR
237 C6H5CL
238 C6H5F
239 C6H5I
240 C6H6
241 C6H6O
245 C6H7N
252 C6H12
269 C6H12
274 C6H14
293 C7H8
309 C7H16
344 C8H18
 ANEXO 10
Constantes de Antoine para determinar la Presion
de Vapor de Saturacion de Liquidos puros

ECUACION DE ANTOINE
T : Temperatura [C]
Log(P ) = A0 -
sat _0/(+_0
P sat
: )Presion de vapor liquido puro [kPa]
A0, B0, C0 : Constantes de Antoine

Peso
puestos puros Constantes de Antoine Rango
Molecular

A0 B0 C0 Tmin Tmax
Nombre [kg/Kmol] C C
AGUA 18.015 7.07406 1657.459 227.02 11 168
TETRACLORURO DE CARBONO
153.823 6.019 1219.58 227.17 -20 101
TETRAFLUORURO DE CARBONO
88.005 6.0972 540.5 260.1 -180 -125
MONOXIDO DE CARBONO 28.01 5.3651 230.27 260.01 -210 -165
DIOXIDO DE CARBONO44.01 8.9355 1347.79 273 -119 -69
SULFURO DE CARBONILO60.07 6.03213 804.48 250 -111 -49
DISULFURO DE CARBONO
76.131 6.0668 1168.62 241.54 -45 69
CLOROFORMO 119.378 6.062 1171.2 227 -13 97
DICLOROFLUOROMETANO
102.923 6.10065 996.267 234.172 -91 9
TRIFLUOROMETANO70.014 6.2135 705.33 249.78 -128 -82
TRIYODOMETANO393.732 5.72088 1567.8 204 137 254
DICLOROMETANO 84.933 6.2052 1138.91 231.46 -44 59
CLOROFLUOROMETANO 68.478 5.32942 740.39 231.86 -55 12
DIFLUOROMETANO52.024 6.2638 821.7 244.7 -82 -32
FORMALDEHIDO 30.026 6.281 957.24 243.01 -88 -2
BROMOMETANO 94.939 6.0846 986.59 238.3 -58 53
CLOROMETANO 50.488 6.1193 902.45 243.61 -93 -7
FLUOROMETANO 34.033 6.2225 740.22 253.89 -132 -64
NITROMETANO 61.04 6.1689 1291 209.01 5 136
METANO 16.043 5.82051 405.42 267.777 -181 -152
METANOL 32.042 7.1973 1574.99 238.87 -16 91
TETRACLOROETENO165.834 6.1449 1415.49 221.01 34 187
CLOROETENO 62.499 5.622 783.4 230.01 -88 17
ETILENO 28.054 5.87246 585 255 -153 -91
BROMOETANO 108.966 6.0449 1090.81 231.72 -47 60
CLOROETANO 64.514 6.0649 1012.78 236.68 -73 37
ETANO 60.069 5.95942 663.7 256.47 -143 -75
PROPANO 42.08 5.9445 785 247 -112 -32
CICLOPROPANO 42.08 6.0128 856.01 246.51 -93 -28
 ACETONA 58.08 6.3565 1277.03 237.23 -32 77
PROPANO 44.096 5.92888 803.81 246.99 -108 -25
BUTANO 58.123 5.93386 935.86 238.73 -78 19
CICLOPENTANO 68.118 6.0456 1121.81 233.46 -29 105
CICLOPENATNO 70.134 6.01166 1124.162 231.31 -40 72
PENTANO 72.15 6.00122 1075.78 233.205 -50 58
HEXACLOROBENZENO284.784 8.91092 4597.57 355.961 114 309
HEXAFLUOROBENZENO
186.056 6.1579 1227.98 215.5 -3 117
BROMOBENZENO 157.01 5.9855 1438.82 205.45 47 117
CLOROBENZENO 112.558 6.103 1431.05 217.56 47 147
FLUOROBENZENO 96.104 6.3119 1381.83 235.57 -23 97
IODOBENZENO 204.01 6.1368 1640.13 208.78 17 197
BENZENO 78.113 6.03055 1211.033 220.79 -16 104
FENOL 94.113 6.2594 1516.07 174.57 72 208
ANILINA 93.128 6.3667 1675.3 200.01 67 227
1-HEXANO 84.161 5.99062 1152.971 225.849 -29 87
CICLOHEXANO 84.161 539662 1201.531 222.647 6 105
HEXANO 86.177 5.99514 1168.72 224.21 -25 92
TOLUENO 92.14 6.07954 1344.8 219.482 6 136
HEPTANO 100.203 6.01875 1264.37 216.636 -2 123
OCTANO 114.23 6.0343 1349.82 209.385 19 152
 a) constantes para determinar el calor especifico de liquido

ec. Cuadratica para el calor especifico de liquidos

CPL= A+BT+CT 2

Ec de Watson para el calor latente de vaporizacion:

= c(Tc-T/Tc-Tb)0.38

Ec. De REIDEL(er), es usado para el calculo de b en casos que n

disponga el valor del calor latente de vaporizacion normal:
b=1.093RTb[Ln(Pc)-1.013/0.930-Tb/Tc]

TEMPERATURA 26 C
TEMPERATURA 299.15 K
NOMBRE METANOL
FORMULA C7H8
PESO MOLECULAR 92.14
A 74.86274
B -0.102315
C 0.000407
Cp 80.6779 J/molK
Cp 875.601259 J/Kg k

b 35.254
Tb 337.8
Tc 513
33.9413112 KJ/mol
368.366737 KJ/Kg
T DE VAPOR 81.3 C
T DE VAPOR 354.45 K
 ANEXO 12
a) constantes para determinar el calor especifico de liquido y el calor latente de vaporizacion de compuestos puros

T: Temperatura(k)
. Cuadratica para el calor especifico de liquidos CpL: calor especifico del liquido(j/mol.k)
CPL= A+BT+CT 2
A, B, C : constantes del Cp
rango: Tmin a Tmax(k)
T: Temperatura(k)
Tc: temperatura critica(K)
de Watson para el calor latente de vaporizacion: Tb: temperatura de ebullicion normal(K)
= c(Tc-T/Tc-Tb)0.38 b: calor latente de vaporizacion normal (kj/mol)
: calor latente de vaporizacion(kj/mol)
rango: Tf a Tc(k)
Tc: temperatura critica(K)
Tb: temperatura de ebullicion normal(K)
Ec. De REIDEL(er), es usado para el calculo de b en casos que no se Pc: presion critica(bar)
disponga el valor del calor latente de vaporizacion normal:
b=1.093RTb[Ln(Pc)-1.013/0.930-Tb/Tc]
R= 0.008314KJ/MOL.K

Peso
Molecula CALOR ESPECFICO DEL LQUIDO: Cp
Frmula
NOMBRE DEL COMPUESTO r Constantes para el CPL
global
[kg/kmol A B C
AGUA H20 ]
18.015 103.08 -0.1748 2.75E-04
TETRACLORURO DE CARBONO CCL4 153.823 139.7338 -0.2045 5.87E-04
TETRAFLUORURO DE CARBONO CF4 88.005 86.44433 -0.07612 8.45E-0.4
MONOXIDO DE CARBONO CO 28.01 61.53487 -0.17697 2.05E-03
DIOXIDO DE CARBONO CO2 44.01 98.63061 -0.29415 9.33E-04
SULFURO DE CARBONILO COS 60.07 71.81666 -0.0295 2.38E-04
DISULFURO DE CARBONO CS2 76.131 68.39258 -0.0457 2.43E-04
CLOROFORMO CHCL3 119.378 110.5378 -0.12157 4.41E-04
DICLOROFLUOROMETANO CHCL2F 102.923 98.07049 -0.0261 2.22E-04
TRIFLUOROMETANO CHF3 70.014 79.87337 -0.0537 4.71E-04
TRIYODOMETANO CHI3 393.732 194.6557 -0.09151 1.86E-04
DICLOROMETANO CH2CL2 84.933 117.1086 -0.14964 6.16E-04
CLOROFLUOROMETANO CH2CLF 68.478 86.91451 -0.036 2.66E-04
DIFLUOROMETANO CH2F2 52.024 70.30925 -0.0251 2.87E-04
FORMALDEHIDO CH2O 30.026 77.73247 -0.0567 3.24E-04
BROMOMETANO CH3BR 94.939 101.7486 -0.046 2.50E-04
CLOROMETANO CH3CL 50.488 72.76645 -0.044 2.29E-04
FLUOROMETANO CH3F 34.033 64.32159 -0.0529 3.65E-04
 NITROMETANO CH3NO2 61.04 114.6402 -0.17491 4.96E-04
METANO CH4 54.87106 -0.0947 8.59E-04
METANOL CH4O 32.042 74.86274 -0.10232 4.07E-04
TETRACLOROETENO C2CL4 165.834 145.6195 -0.17954 5.12E-04
CLOROETENO C2H3CL 62.499 69.85845 -0.0162 1.77E-04
ETILENO C2H4 28.054 62.89727 -0.038 3.79E-04
BROMOETANO C2H5BR 108.966 89.6772 -0.0596 3.32E-04
CLOROETANO C2H5CL 64.514 95.86747 -0.0227 2.03E-04
ETANO C2H6 30.069 66.3402 -0.0209 3.04E-04
PROPANO C3H6 42.08 82.1637 -0.0128 2.50E-04
CICLOPROPANO C3H6 42.08 76.03351 -0.0337 2.38E-04
ACETONA C3H6O 58.08 117.8108 -0.15924 6.34E-04
PROPANO C3H8 44.096 87.31411 -0.0124 2.59E-04
BUTANO C4H10 58.123 120.0291 -0.0378 3.09E-04
CICLOPENTANO C5H8 68.118 103.1864 -0.0742 4.39E-04
CICLOPENTANO C5H10 70.134 116.2369 -0.12205 5.20E-04
PENTANO C5H12 72.15 143.6066 -0.14477 7.62E-04
HEXACLOROBENZENO C6CL6 284.784
HEXAFLUOROBENZENO C6F6 186.056
BROMOBENZENO C6H5BR 157.01 158.5244 -0.14435 4.40E-04
CLOROBENZENO C6H5CL 112.558 150.4141 -0.14255 4.64E-04
FLUOROBENZENO C6H5F 96.104 151.1213 -0.20539 6.31E-04
IODOBENZENO C6H5I 204.01 160.6757 -0.12 3.73E-04
BENCENO C6H6 78.113 155.6259 -0.27105 6.75E-04
FENOL C6H6O 94.113 207.4793 -0.10375 2.74E-04
ANILINA C6H7N 93.128 206.272 -0.21151 5.64E-04
1-HEXANO C6H12 84.161 157.713 -0.11578 6.79E-04
CICLOHEXANO C6H12 84.161 178.9841 -0.32157 7.97E-04
HEXANO C6H14 86.177 181.7722 -0.2155 8.76E-04
TOLUENO C7H8 92.14 147.0419 -0.11405 4.90E-04
HEPTANO C7H16 100.203 211.9577 -0.22993 9.03E-04
OCTANO C8H18 114.23 256.3503 -0.32216 1.04E-03
ETANOL C2H6O 46.069 100.992 -0.11184 4.99E-04
 CALOR LATENTE VAPORIZACION
FICO DEL LQUIDO: CpL
b a Hvap =
Tmn (K) Tmx(K) Tb(kj/mo Tb (K) Tc(K)
l)
273.15 423.15 40.669 373.15 647.3
250 379.84 29.999 349.8 556.5
86.4 175.15 11.966 145.2 227.5
68.1 111.61 6.042 81.6 133.4
216.56 258.57 15.326 216.6 304.2
134.3 252.91 20.887 222.9 378
161.3 349 26.736 319 552
209.6 364.33 29.706 334.3 535.5
138 312.07 24.937 282.1 451.6
110 221 16.694 191 299.1
396.16 521.16 42.359 491.2 794.6
178.1 343.15 27.991 313.2 508.3
140.16 294.06 22.744 264.1 424.9
101.71 251.49 20.476 221.5 351.5
156 279.55 23.012 249.6 4022.7
179.5 307.5 23.912 277.5 464
175.4 279.15 21.422 249.2 416.2
131.4 224.79 16.677 194.8 317.9
244.6 403.99 34.413 374 588
90.7 141.62 8.18 111.6 190.7
175.5 367.77 35.254 337.8 513
251 424.22 34.727 394.2 620.2
119.4 289.4 22.263 259.4 425
104 199.39 13.544 169.4 282.8
154.6 341.73 26.485 311.7 505.7
136.8 315.5 24.686 285.5 460.4
89.9 214.63 14.707 184.6 305.4
87.9 255.65 18.41 225.7 365
145.7 270.29 20.041 240.3 398
178.2 359.35 29.121 329.4 508.4
85.5 261.14 18.774 231.1 369.7
134.8 302.98 22.393 273 425.6
138.1 347.38 26.987 317.4 506
179.3 352.41 27.296 322.4 511.8
143.4 339.22 25.773 309.2 470
63.593 582.6 825.8
31.677 353.4 516.6
242.3 459.1 42.501 429.1 670.1
227.6 435.06 36.547 405.1 632.6
234 388.05 33.388 358.1 559.8
241.8 491.57 39.497 461.6 721.1
278.7 383.31 30.761 353.3 562
314 484.89 45.606 454.9 692.9
267 487.2 41.84 457.2 698.9
133.3 367.91 28.284 337.9 508.5
279.6 383.9 29.957 353.9 553.5
177.8 371.93 28.853 341.9 507.9
178 413.73 33.179 383.7 593.1
182.6 401.56 31.698 371.6 540.1
216.4 428.77 34.413 398.8 569.1
159.1 381.45 38.744 351.5 515.8
 ANEXO 16
DATOS DE EQUILIBRIO LIQUIDO VAPOR : ELV PARA
ALGUNOS SITEMAS BINARIOS

ETANOL - AGUA ETANOL - AGUA

P = 1 atm P = 548mmHg
X Y X
T(C) T(C)
f.molar f.molar f.molar
100.00 0.0000 0.0000 91.09 0.000
95.50 0.0190 0.1700 81.95 0.050
89.00 0.0721 0.3891 78.19 0.100
86.70 0.0966 0.4375 76.18 0.150
85.30 0.1238 0.4704 74.92 0.200
84.10 0.1661 0.5089 74.03 0.250
82.70 0.2337 0.5445 73.34 0.300
82.30 0.2608 0.5580 72.77 0.350
81.50 0.3273 0.5826 72.28 0.400
80.70 0.3965 0.6122 71.86 0.450
79.80 0.5079 0.6564 71.48 0.500
79.70 0.5198 0.6599 71.14 0.550
79.30 0.5732 0.6841 70.83 0.600
78.74 0.6763 0.7385 70.57 0.650
78.41 0.7472 0.7815 70.34 0.700
78.15 0.8943 0.8943 70.16 0.750
70.04 0.800
69.97 0.850
69.98 0.900
70.09 0.950
70.30 1.000

METANOL - AGUA ACETONA - ETANOL

P = 1 atm P = 1 atm
X Y X
T(C) T(C)
f.molar f.molar f.molar
100.00 0.000 0.0000 78.30 0.000
96.40 0.020 0.1340 75.40 0.050
93.50 0.040 0.2300 73.00 0.100
91.20 0.060 0.3040 71.00 0.150
89.30 0.080 0.3650 69.00 0.200
87.70 0.100 0.4180 67.30 0.250
84.40 0.150 0.5170 65.90 0.300
81.70 0.200 0.5790 64.70 0.350
78.00 0.300 0.6650 63.60 0.400
75.30 0.400 0.7290 61.80 0.500
73.10 0.500 0.7790 60.40 0.600
71.20 0.600 0.8250 59.10 0.700
69.30 0.700 0.8700 58.00 0.800
67.60 0.800 0.9150 57.00 0.900
66.00 0.900 0.9580 56.10 1.000
65.00 0.950 0.9790
64.50 1.000 1.0000

ACETONA - CIDO ACTICO ACETONA - METANOL

P = 1 atm P = 1 atm
X Y X
T(C) T(C)
f.molar f.molar f.molar
118.10 0.000 0.0000 64.50 0.000
110.00 0.050 0.1620 63.60 0.050
103.80 0.100 0.3060 62.50 0.100
93.10 0.200 0.5570 60.20 0.200
85.80 0.300 0.7250 58.65 0.300
79.70 0.400 0.8400 57.55 0.400
74.60 0.500 0.9120 56.70 0.500
70.20 0.600 0.9470 56.00 0.600
66.10 0.700 0.9690 55.30 0.700
62.60 0.800 0.9840 55.05 0.800
59.20 0.900 0.9930 56.10 1.000
56.10 1.000 1.0000

CLOROFORMO - BENZENO n - HEXANO - BENCENO

P = 1 atm P = 1 atm
X Y X
T(C) T(C)
f.molar f.molar f.molar
80.60 0.0000 0.0000 80.10 0.000
79.80 0.0800 0.1000 78.50 0.050
79.00 0.1500 0.2000 77.10 0.100
78.20 0.2200 0.3000 76.00 0.150
77.30 0.2900 0.4000 75.10 0.200
76.40 0.3600 0.5000 74.40 0.250
75.30 0.4400 0.6000 73.70 0.300
74.00 0.5400 0.7000 72.70 0.350
71.90 0.6600 0.8000 72.20 0.400
68.90 0.7900 0.9000 71.50 0.450
61.40 1.0000 1.0000 71.00 0.500
70.60 0.550
70.30 0.600
69.90 0.650
69.50 0.700
69.30 0.750
69.10 0.800
68.90 0.850
68.80 0.900
68.70 0.950
68.70 0.970
68.70 1.000
 equilibrio

NOL - AGUA ACETONA - AGUA

= 548mmHg P = 1 atm
Y X Y
T(C)
f.molar f.molar f.molar
0.0000 100.0 0.000 0.000
0.3280 77.1 0.050 0.630
0.4416 67.4 0.100 0.754
0.5000 64.0 0.150 0.794
0.5374 62.5 0.200 0.831
0.5651 61.7 0.250 0.826
0.5880 61.0 0.300 0.834
0.6084 60.7 0.350 0.838
0.6277 60.1 0.400 0.842
0.6468 59.9 0.450 0.846
0.6663 59.6 0.500 0.850
0.6866 59.5 0.550 0.855
0.7083 58.7 0.600 0.863
0.7317 58.4 0.650 0.869
0.7573 58.2 0.700 0.875
0.7857 58.0 0.750 0.882
0.8176 57.6 0.800 0.898
0.8538 57.5 0.850 0.915
0.8953 57.1 0.900 0.935
0.9434 56.8 0.950 0.962
1.0000 56.5 1.000 1.000

ONA - ETANOL BENZENO - TOLUENO

P = 1 atm P = 1 atm
Y X Y
T(C)
f.molar f.molar f.molar
0.0000 110.40 0.000 0.0000
0.1550 109.60 0.020 0.0455
0.2620 107.90 0.060 0.1320
0.3480 106.20 0.100 0.2090
0.4170 104.60 0.140 0.2800
0.4780 102.95 0.180 0.3440
 0.5240 101.40 0.220 0.4040
0.5660 99.90 0.260 0.4585
0.6050 98.50 0.300 0.5075
0.6740 97.20 0.340 0.5555
0.7390 94.60 0.420 0.6400
0.8020 93.35 0.460 0.6790
0.8650 92.20 0.500 0.7140
0.9290 91.10 0.540 0.7470
1.0000 90.05 0.580 0.7765
89.00 0.620 0.8054
88.00 0.660 0.8305
86.95 0.700 0.8545
86.00 0.740 0.8785
85.00 0.780 0.9005
84.10 0.820 0.9215
83.20 0.860 0.9405
81.45 0.940 0.9765
80.30 1.000 1.0000

ONA - METANOL CLOROFORMO - ACETONA

P = 1 atm P = 1 atm
Y X Y
T(C)
f.molar f.molar f.molar
0.0000 56.20 0.0000 0.0000
0.1020 57.50 0.8550 0.0478
0.1860 58.30 0.1410 0.0835
0.3220 59.40 0.2045 0.1312
0.4280 60.40 0.2612 0.1765
0.5130 61.60 0.3367 0.2495
0.5860 62.80 0.4250 0.3520
0.6560 63.90 0.5229 0.4830
0.7250 64.40 0.7340 0.7630
0.8000 63.80 0.7892 0.8240
1.0000 63.10 0.8625 0.9000
62.80 0.8892 0.9350
61.30 1.0000 1.0000

SULFURO DE CARBONO -
ANO - BENCENO
TETRACLORURO DE CARBONO
P = 1 atm P = 1 atm
Y X Y
T(C)
f.molar f.molar f.molar
0.0000 76.70 0.0000 0.0000
0.1110 74.90 0.0296 0.0823
0.1910 73.10 0.0615 0.1555
0.2580 70.30 0.1106 0.2660
0.3170 68.60 0.1435 0.3325
0.3710 63.80 0.2585 0.4950
0.4220 59.30 0.3908 0.6340
0.4700 55.30 0.5318 0.7470
0.5180 52.30 0.6630 0.8290
0.5630 50.40 0.7574 0.8780
0.6020 48.50 0.8604 0.9320
0.6400 46.30 1.0000 1.0000
0.6760
0.7100
0.7440
0.7820
0.8220
0.8620
0.9060
0.9521
0.9712
1.0000