E/mV 0.5 LPM 0.8 LPM 1 LPM 1.2 LPM 1.

5 LPM
-200 -57.898 -68.0195 -75.642 -73.323 -73.671
-250 -242.826 -281.822 -290.711 -269.946 -284.851
-300 -290.426 -344.513 -343.506 -351.927 -352.075
-400 -328.281 -375.269 -375.933 -393.514 -434.063
-500 -351.595 -414.662 -388.233 -408.511 -437.332

0.5 LPM 0.8 LPM 1 LPM 1.2 LPM 1.5 LPM

Km -0.0002847 -0.0003358 -0.0003144 -0.0003308 -0.0003541
Cb 0.0001 molcm-3
n 2
F 96485 Cmol-1
A 64 cm2

0
-550 -500 -450 -400 -350 -300 -250 -200 -150
-50

-100

-150

-200

-250

-300

-350

-400

-450

-500
 t/s Abs ∆t c∆t t*c∆t t2*c∆t θ E
0 0 0.3371 0.0000 0.0000 0.0000 0.0000 0.0000
0.33714 0 0.3402 0.0000 0.0000 0.0000 0.1157 0.0000
0.67729 0 0.3359 0.0000 0.0000 0.0000 0.2325 0.0000
1.01314 0 0.1120 0.0000 0.0000 0.0000 0.3478 0.0000
1.12515 0.00566667 0.1145 0.0006 0.0007 0.0008 0.3863 0.0269
1.23962 0.03666667 0.1125 0.0041 0.0051 0.0063 0.4256 0.1741
1.35214 0.07166667 0.1122 0.0080 0.0109 0.0147 0.4642 0.3403
1.4643 0.11266667 0.1119 0.0126 0.0185 0.0270 0.5027 0.5350
1.57615 0.13666667 0.2300 0.0314 0.0495 0.0781 0.5411 0.6490
1.80617 0.16366667 0.1124 0.0184 0.0332 0.0600 0.6201 0.7772
1.91853 0.14766667 0.2246 0.0332 0.0636 0.1221 0.6587 0.7012
2.14313 0.10966667 0.1123 0.0123 0.0264 0.0566 0.7358 0.5208
2.2554 0.08266667 0.3391 0.0280 0.0632 0.1426 0.7743 0.3925
2.59448 0.04566667 0.4537 0.0207 0.0537 0.1395 0.8907 0.2169
3.04813 0.02066667 0.4480 0.0093 0.0282 0.0860 1.0465 0.0981
3.49611 0.01366667 0.4532 0.0062 0.0217 0.0757 1.2003 0.0649
3.94926 0.00466667 0.4480 0.0021 0.0083 0.0326 1.3558 0.0222
4.39727 0.00466667 0.4509 0.0021 0.0093 0.0407 1.5096 0.0222
4.84814 0.00366667 0.5600 0.0021 0.0100 0.0483 1.6644 0.0174
5.40814 0.00033333 0.7890 0.0003 0.0014 0.0077 1.8567 0.0016
6.19713 0.00166667 0.5632 0.0009 0.0058 0.0360 2.1275 0.0079
6.7603 0.00066667 0.4480 0.0003 0.0020 0.0136 2.3209 0.0032
7.2083 0.00266667 0.5650 0.0015 0.0109 0.0783 2.4747 0.0127
7.77327 0.00033333 0.5633 0.0002 0.0015 0.0113 2.6687 0.0016
8.33657 0.00133333 0.5626 0.0008 0.0063 0.0521 2.8620 0.0063
8.89912 0.00266667 0.5674 0.0015 0.0135 0.1198 3.0552 0.0127
9.46654 0.00266667 0.3357 0.0009 0.0085 0.0802 3.2500 0.0127
9.80228 0.00066667 0.4459 0.0003 0.0029 0.0286 3.3652 0.0032
10.24813 0.00266667 0.3388 0.0009 0.0093 0.0949 3.5183 0.0127
10.58692 0.00033333 0.3381 0.0001 0.0012 0.0126 3.6346 0.0016
10.92502 0.00266667 0.4481 0.0012 0.0131 0.1426 3.7507 0.0127
11.37311 0.00566667 0.3392 0.0019 0.0219 0.2486 3.9045 0.0269
11.71234 0.00133333 0.3395 0.0005 0.0053 0.0621 4.0210 0.0063
12.05187 0.00466667 0.3361 0.0016 0.0189 0.2278 4.1376 0.0222
12.38799 0.00666667 0.3393 0.0023 0.0280 0.3471 4.2529 0.0317
12.72726 0.00166667 0.3396 0.0006 0.0072 0.0917 4.3694 0.0079
13.06686 0.00066667 0.3363 0.0002 0.0029 0.0383 4.4860 0.0032
13.40313 0.00166667 0.3407 0.0006 0.0076 0.1020 4.6015 0.0079
13.74387 0.00133333 0.4501 0.0006 0.0082 0.1134 4.7184 0.0063
14.194 0.00166667 0.5599 0.0009 0.0132 0.1880 4.8730 0.0079
14.75387 0.00266667 0.5500 0.0015 0.0216 0.3193 5.0652 0.0127

Tpromedio 2.91280277
Σtc∆t 0.61340628
Σc∆t 0.21058971
T 2.91280277
Σt2*c∆t 3.34708186
Varianza 7.40943307
Pe 2.29016712
Dispersion
E(θ)
0.0000
0.0000
0.0000
0.0000 CURVA DTR
0.0092 0.3000
0.0598
0.2500
0.1168
0.1837 0.2000
0.2228
E(θ)

0.2668 0.1500
0.2407
0.1000
0.1788
0.1348 0.0500
0.0744
0.0337 0.0000
0.0000 1.0000 2.0000 3.0000 4.0000 5.0000 6.0000
0.0223
0.0076 θ
0.0076
0.0060
0.0005
0.0027
0.0011
0.0043
0.0005
0.0022
0.0043
0.0043
0.0011
0.0043
0.0005
0.0043
0.0092
0.0022
0.0076
0.0109
0.0027
0.0011
0.0027
0.0022
0.0027
0.0043
 Chart Title
0.18

0.16

0.14

0.12

0.1

0.08

0.06

0.04

0.02

0
0 2 4 6 8 10 12 14 16
t(min) CCu (ppm) Ccu(mol/cm3) Qreal Qteórica  Econs (J/cm3)
0 866 1.362920995E-05 0 0 0 0
10 528.102 8.311331445E-06 373.2 1.60383763 0.42975285 12720.2699479
20 208.501 3.281413283E-06 746.4 0.63321432 0.08483579 64437.1010211
30 27.405 4.313031161E-07 1119.6 0.08322856 0.00743378 735369.458128
40 3.699 5.821529745E-08 1492.8 0.01123381 0.00075253 7264233.57664
50 0.476 7.491344035E-09 1866 0.0014456 7.7471E-05 70563025.2101
60 0.085 1.337740006E-09 2239.2 0.00025814 1.1528E-05 474183529.412

n 2
F 96485 c/mol
M 63.54 g/mol
A 64 cm2
Vr 350 cm3
E 1.8 V
I (A) Km Δ[Cu] Sn
0 0 0 0
0.622 0.00605968 5.029918E-06 0.00048176
0.622 0.01534828 2.85011E-06 0.00122024
0.622 0.11677181 3.730878E-07 0.00928372
0.622 0.86513422 5.072395E-08 0.06878086
0.622 6.72296533 6.153604E-09 0.53449662
0.622 37.6486058 1.33774E-09 2.99318109

Xa
0
0.39018245
0.75923672
0.9683545
0.99572864
0.99945035
0.99990185
A= 64 cm2
L= 16 m
B= 4m
s= 0.55 m
Dcu= 0.000005 cm2/s
de= 0.96703297
v= vel cinematica del compuesto= 0.0108 cm2/s
[]= 0.000001 mol/cm3
km

PARA -200 V
flujo LPM cm3/s I lim (A) km (cm/s) V Re ln Re
0.5 8.33333333 0.057898 0.00468807 3.78787879 cm/s 339.167006 5.82649263
0.8 13.3333333 0.0680195 0.00550762 6.06060606 542.667209 6.29649626
1 16.6666667 0.075642 0.00612482 7.57575758 678.334012 6.51963981
1.2 20 0.073323 0.00593705 9.09090909 814.000814 6.70196137
1.5 25 0.073671 0.00596522 11.3636364 1017.50102 6.92510492

PARA -250 V
flujo LPM cm3/s I lim (A) km (cm/s) V Re ln Re
0.5 8.33333333 0.242826 0.0196619 3.78787879 cm/s 339.167006 5.82649263
0.8 13.3333333 0.281822 0.02281945 6.06060606 542.667209 6.29649626
1 16.6666667 0.290711 0.0235392 7.57575758 678.334012 6.51963981
1.2 20 0.269946 0.02185783 9.09090909 814.000814 6.70196137
1.5 25 0.284851 0.02306471 11.3636364 1017.50102 6.92510492

PARA -300 V
flujo LPM cm3/s I lim (A) km (cm/s) V Re ln Re
0.5 8.33333333 0.290426 0.02351612 3.78787879 cm/s 339.167006 5.82649263
0.8 13.3333333 0.344513 0.02789561 6.06060606 542.667209 6.29649626
1 16.6666667 0.343506 0.02781407 7.57575758 678.334012 6.51963981
1.2 20 0.351927 0.02849593 9.09090909 814.000814 6.70196137
1.5 25 0.352075 0.02850791 11.3636364 1017.50102 6.92510492

PARA -400 V
flujo LPM cm3/s I lim (A) km (cm/s) V Re ln Re
0.5 8.33333333 0.328281 0.02658129 3.78787879 cm/s 339.167006 5.82649263
0.8 13.3333333 0.375269 0.03038596 6.06060606 542.667209 6.29649626
1 16.6666667 0.375933 0.03043972 7.57575758 678.334012 6.51963981
1.2 20 0.393514 0.03186328 9.09090909 814.000814 6.70196137
1.5 25 0.434063 0.03514657 11.3636364 1017.50102 6.92510492

PARA -400 V
flujo LPM cm3/s I lim (A) km (cm/s) V Re ln Re
0.5 8.33333333 0.351595 0.02846905 3.78787879 cm/s 339.167006 5.82649263
0.8 13.3333333 0.414662 0.03357565 6.06060606 542.667209 6.29649626
1 16.6666667 0.388233 0.03143567 7.57575758 678.334012 6.51963981
1.2 20 0.408511 0.0330776 9.09090909 814.000814 6.70196137
1.5 25 0.437332 0.03541127 11.3636364 1017.50102 6.92510492
Sc Sh Sc^1/3 ln(Sh/Sc^1/3)
2160 906.703029 12.9266081 4.25052714
2160 1065.20928 12.9266081 4.41163873
2160 1184.58031 12.9266081 4.51785598
2160 1148.26395 12.9266081 4.48671864
2160 1153.71375 12.9266081 4.49145353

ln(Sh/Sc^1/3)
Sc Sh Sc^1/3 ln(Sh/Sc^1/3) 7
2160 3802.7405 12.9266081 5.68418944
6 f(x) = 0.232764094x + 4.6294451005
2160 4413.43157 12.9266081 5.83311997 R² = 0.9427386629
2160 4552.63643 12.9266081 5.86417395 5
2160 4227.44924 12.9266081 5.79006624
4
2160 4460.86677 12.9266081 5.84381054
3

Sc Sh Sc^1/3 ln(Sh/Sc^1/3) 2

2160 4548.17323 12.9266081 5.86319311 1

2160 5395.19466 12.9266081 6.03397613
2160 5379.42469 12.9266081 6.03104888 0
5.6 5.8 6 6.2 6.4 6.6
2160 5511.30051 12.9266081 6.05526807
2160 5513.61824 12.9266081 6.05568852 ln Re

Sc Sh Sc^1/3 ln(Sh/Sc^1/3)
2160 5140.99584 12.9266081 5.98571425
2160 5876.84443 12.9266081 6.1194874
2160 5887.24291 12.9266081 6.12125524
2160 6162.56755 12.9266081 6.16696095
2160 6797.57914 12.9266081 6.26503399

Sc Sh Sc^1/3 ln(Sh/Sc^1/3)
2160 5506.10127 12.9266081 6.05432425
2160 6493.75266 12.9266081 6.21930803
2160 6079.86523 12.9266081 6.15344998
2160 6397.42584 12.9266081 6.20436314
2160 6848.77283 12.9266081 6.27253693
 = 0.232764094x + 4.6294451005
= 0.9427386629

-200 mV
-250 mV
-300 mV
-400 mV
Li nea r (-400 mV)
-500 mV

6 6.2 6.4 6.6 6.8 7

ln Re
Ca0 5 g/L
Xa 0.0007
tresidencia 1.408 s
0.0234 min

t Ca Ca/Ca0
0 5 1
5 4.30537939 0.86107588
10 3.70725835 0.74145167
15 3.19223074 0.63844615
20 2.74875289 0.54975058
25 2.36688481 0.47337696 Gráfica
30 2.03806742 0.40761348 1.2
35 1.75493069 0.35098614
1
40 1.51112849 0.3022257
45 1.30119629 0.26023926 0.8
50 1.12042874 0.22408575

Ca/Ca0
0.6
55 0.96477416 0.19295483
60 0.83074376 0.16614875 0.4

65 0.71533341 0.14306668 0.2

70 0.61595635 0.12319127
0
75 0.53038515 0.10607703 0 20 40 60 80
80 0.45670186 0.09134037 t/min
85 0.39325496 0.07865099
90 0.33862236 0.06772447
95 0.29157954 0.05831591
100 0.25107211 0.05021442
 Gráfica

0 40 60 80 100 120
t/min
Ca0 0.008 g/L km 0.0007 cms-1
Xa 0.0007 V 35.2 cm3
tresidencia 1.408 s A 64 cm2
0.0234 min

Reactor Batch con recirculación Reactor PFR

t Ca Ca/Ca0 t Ca Ca/Ca0
0 0.008 1 0 0.008 1
5 0.00688861 0.86107588 5 0.00794925 0.99365657
10 0.00593161 0.74145167 10 0.00789883 0.98735338
15 0.00510757 0.63844615 15 0.00784872 0.98109017
20 0.004398 0.54975058 20 0.00779893 0.97486669
25 0.00378702 0.47337696 25 0.00774946 0.96868269
30 0.00326091 0.40761348 30 0.0077003 0.96253792
35 0.00280789 0.35098614 35 0.00765146 0.95643212
40 0.00241781 0.3022257 40 0.00760292 0.95036506
45 0.00208191 0.26023926 45 0.00755469 0.94433649
50 0.00179269 0.22408575 50 0.00750677 0.93834615
55 0.00154364 0.19295483 55 0.00745915 0.93239382
60 0.00132919 0.16614875 60 0.00741183 0.92647924
65 0.00114453 0.14306668 65 0.00736482 0.92060219
70 0.00098553 0.12319127 70 0.0073181 0.91476241
75 0.00084862 0.10607703 75 0.00727168 0.90895968
80 0.00073072 0.09134037 80 0.00722555 0.90319375
85 0.00062921 0.07865099 85 0.00717972 0.89746441
90 0.0005418 0.06772447 90 0.00713417 0.8917714
95 0.00046653 0.05831591 95 0.00708892 0.88611451
100 0.00040172 0.05021442 100 0.00704395 0.88049351
 1.2

0.8
Ca/Ca0

0.6
Rea ctor Batch
Rea ctor PFR
0.4

0.2

0
0 20 40 60 80 100 120
t/min