Taller Segundo Corte Plantas

EJEMPLO 6.
5 Selectividad de las reacciones del cloruro de

alilo Para demostrar las ventajas de ejecutar las reacciones a
temperaturas intermedias, muestre las constantes de
velocidad para las tres reacciones en competencia en
función de la temperatura.
T 1/T LNK1
980 0.00102041 -1.64191957
988.9 0.00101122 -1.51702302
997.7 0.00100231 -1.39572066
EJEMPLO 6,5 1006.6 0.00099344 -1.27519708
Rxns H A E/R Ln(A) 1015.4 0.00098483 -1.15810501
1 -4800 206000 13600 12.2356314 1024.3 0.00097628 -1.0417287
2 -79200 11.7 3430 2.45958884 1033.1 0.00096796 -0.92863145
3 -91800 4.60E+08 21300 19.946737 1042 0.00095969 -0.81619197
T
Chart Title
0
0.000950.000960.000970.000980.00099 0.001 0.001010.001020.00103
-0.2
-0.4
-0.6
-0.8
Axis Title K1
-1 K2
-1.2 K3
-1.4
LNK2 LNK3 -1.6
-1.04041116 -1.78795683 -1.8
-1.00891151 -1.59234678 -2
-0.97831834 -1.40236589 Axis Title

-0.94792159 -1.2136047
-0.91839028 -1.03021785
-0.88903949 -0.84795201
-0.8605157 -0.67082176 Como se muestra en el siguiente gráfico, la
-0.8321578 -0.49472169 velocidad constante de la Reacción 1 deseable es
la más grande en relación con las constantes de
velocidad de las otras dos reacciones a las
temperaturas intermedias
103
K1
K2
K3
Rxns A(m^6/kmol^E(kJ/kmol) E/R LN(A)
1 3700000 65800 7913.91203 15.1238434 𝑙𝑛𝑘=𝑙𝑛𝐴−𝐸/(𝑅∗𝑇)
2 3600000 74100 8912.17145 15.0964444 8
3 5700000 74500 8960.28034 15.5559767
4 11000000 74400 8948.25312 16.2134058 7
R[KJ/kmol*K] 8.314472
6
ln k
T 1/T LNK1 LNK2 LNK3 LNK4
730 0.00136986 4.28286799 2.88799036 3.2816201 3.95552485
3
735 0.00136054 4.35661612 2.97104107 3.36511913 4.03891179
740 0.00135135 4.42936766 3.05296947 3.44748979 4.12117189 2
745 0.00134228 4.50114266 3.13379816 3.5287548 4.20232782
750 0.00133333 4.57196067 3.21354913 3.60893628 4.28240167 1
755 0.0013245 4.64184069 3.2922438 3.68805575 4.36141495
760 0.00131579 4.71080123 3.36990302 3.76613418 4.43938857 0
765 0.00130719 4.77886033 3.44654708 3.84319197 4.51634293 0.001 0.00105 0.0011 0.0
770 0.0012987 4.84603554 3.52219576 3.91924902 4.59229789

775 0.00129032 4.91234398 3.59686834 3.99432468 4.66727278 seleccione una temperatura d
780 0.00128205 4.97780231 3.67058357 4.06843784 4.74128645 favorezca la producción de C.
785 0.00127389 5.04242678 3.74335975 4.14160687 4.81435727 preexponencial y la energía d
reacciones se tabulan de la si
790 0.00126582 5.10623321 3.81521472 4.21384972 4.88650315
795 0.00125786 5.16923705 3.88616585 4.28518385 4.95774153
800 0.00125 5.23145334 3.95623009 4.35562631 5.02808943
805 0.00124224 5.29289675 4.02542397 4.4251937 5.09756345
810 0.00123457 5.35358161 4.0937636 4.49390224 5.16617976
815 0.00122699 5.41352187 4.16126471 4.56176773 5.23395415
820 0.00121951 5.47273114 4.22794263 4.62880559 5.30090203
825 0.00121212 5.53122273 4.29381234 4.69503087 5.36703841 a partir de una temperatura meno
830 0.00120482 5.5890096 4.35888844 4.76045825 5.43237798 reaccion 1 se dificulta. por tanto se
835 0.0011976 5.64610442 4.42318518 4.82510207 5.49693503 favorecida a altas temperaturas
840 0.00119048 5.70251953 4.48671648 4.88897633 5.56072355
845 0.00118343 5.75826701 4.54949594 4.95209467 5.62375717
850 0.00117647 5.81335863 4.61153681 5.01447045 5.68604922
855 0.00116959 5.86780591 4.67285206 5.07611669 5.74761271
860 0.00116279 5.92162008 4.73345434 5.1370461 5.80846034
865 0.00115607 5.97481213 4.79335602 5.19727114 5.86860454
870 0.00114943 6.02739277 4.85256917 5.25680393 5.92805742
875 0.00114286 6.07937248 4.9111056 5.31565634 5.98683084
880 0.00113636 6.13076152 4.96897684 5.37383998 6.04493638
885 0.00112994 6.1815699 5.02619417 5.43136618 6.10238536
890 0.0011236 6.23180739 5.08276861 5.48824601 6.15918884
895 0.00111732 6.28148357 5.13871094 5.54449032 6.21535765
900 0.00111111 6.33060779 5.19403168 5.60010969 6.27090237
905 0.00110497 6.3791892 5.24874114 5.65511448 6.32583332
910 0.0010989 6.42723675 5.3028494 5.70951482 6.38016065
915 0.0010929 6.47475919 5.35636631 5.76332062 6.43389423
920 0.00108696 6.52176508 5.40930152 5.81654158 6.48704375
925 0.00108108 6.5682628 5.46166445 5.86918718 6.53961868
930 0.00107527 6.61426055 5.51346435 5.92126669 6.59162828
935 0.00106952 6.65976634 5.56471023 5.9727892 6.64308164
940 0.00106383 6.70478802 5.61541094 6.02376361 6.69398762
945 0.0010582 6.74933329 5.66557514 6.0741986 6.74435491
950 0.00105263 6.79340966 5.7152113 6.12410269 6.79419202
955 0.00104712 6.8370245 5.7643277 6.17348423 6.84350728
960 0.00104167 6.88018501 5.81293247 6.22235138 6.89230883
965 0.00103627 6.92289827 5.86103357 6.27071213 6.94060467
970 0.00103093 6.96517118 5.90863878 6.31857432 6.98840262
975 0.00102564 7.00701052 5.95575573 6.36594561 7.03571032
980 0.00102041 7.04842294 6.0023919 6.41283353 7.0825353
985 0.00101523 7.08941492 6.0485546 6.45924542 7.1288849
990 0.0010101 7.12999284 6.09425102 6.50518851 7.17476632
995 0.00100503 7.17016294 6.13948817 6.55066986 7.22018662
1000 0.001 7.20993135 6.18427295 6.59569639 7.26515271
1005 0.00099502 7.24930404 6.22861211 6.6402749 7.30967138
1010 0.0009901 7.28828691 6.27251227 6.68441204 7.35374928
1015 0.00098522 7.32688571 6.31597992 6.72811433 7.39739291
1020 0.00098039 7.36510609 6.35902141 6.77138816 7.44060866
1025 0.00097561 7.40295359 6.40164299 6.81423982 7.48340279
1030 0.00097087 7.44043364 6.44385076 6.85667543 7.52578144
1035 0.00096618 7.47755156 6.48565073 6.89870104 7.56775064
1040 0.00096154 7.51431258 6.52704878 6.94032256 7.60931629
1045 0.00095694 7.55072182 6.56805067 6.98154579 7.65048419
1050 0.00095238 7.5867843 6.60866207 7.02237641 7.69126
1055 0.00094787 7.62250496 6.64888852 7.06282001 7.73164932
1060 0.0009434 7.65788863 6.68873549 7.10288207 7.77165761
1065 0.00093897 7.69294006 6.7282083 7.14256796 7.81129023
1070 0.00093458 7.72766391 6.7673122 7.18188296 7.85055245
1075 0.00093023 7.76206474 6.80605235 7.22083223 7.88944944
1080 0.00092593 7.79614705 6.8444338 7.25942086 7.92798628
1085 0.00092166 7.82991524 6.8824615 7.29765384 7.96616793
1090 0.00091743 7.86337362 6.92014032 7.33553605 8.0039993
1095 0.00091324 7.89652645 6.95747504 7.37307231 8.04148517
1100 0.00090909 7.92937789 6.99447036 7.41026733 8.07863027
1105 0.00090498 7.96193204 7.03113087 7.44712575 8.11543921
1110 0.0009009 7.9941929 7.06746111 7.4836521 8.15191654
1115 0.00089686 8.02616443 7.10346552 7.51985087 8.18806671
1120 0.00089286 8.05785049 7.13914846 7.55572643 8.22389412
1125 0.00088889 8.0892549 7.17451422 7.5912831 8.25940306
1130 0.00088496 8.1203814 7.20956701 7.6265251 8.29459776
1135 0.00088106 8.15123366 7.24431097 7.66145661 8.32948238
1140 0.00087719 8.18181528 7.27875015 7.6960817 8.36406099
1145 0.00087336 8.21212981 7.31288855 7.73040438 8.39833761
1150 0.00086957 8.24218074 7.3467301 7.76442861 8.43231616
1155 0.0008658 8.27197149 7.38027864 7.79815826 8.46600053
1160 0.00086207 8.30150542 7.41353798 7.83159713 8.49939452
1165 0.00085837 8.33078584 7.44651183 7.86474897 8.53250187
1170 0.0008547 8.359816 7.47920385 7.89761747 8.56532624
1175 0.00085106 8.3885991 7.51161764 7.93020623 8.59787126
1180 0.00084746 8.41713827 7.54375673 7.96251882 8.63014048
1185 0.00084388 8.4454366 7.57562461 7.99455872 8.66213738
1190 0.00084034 8.47349713 7.6072247 8.02632939 8.6938654
1195 0.00083682 8.50132285 7.63856034 8.05783419 8.72532791
1200 0.00083333 8.52891668 7.66963486 8.08907645 8.75652823
1205 0.00082988 8.55628153 7.7004515 8.12005944 8.78746963
1210 0.00082645 8.58342021 7.73101345 8.15078637 8.81815532
1215 0.00082305 8.61033553 7.76132387 8.1812604 8.84858845
1220 0.00081967 8.63703024 7.79138584 8.21148465 8.87877213
1225 0.00081633 8.66350703 7.8212024 8.24146217 8.90870941
Chart Title
8
5
k1
4 k2
k3
k4
3
0
0.001 0.00105 0.0011 0.00115 0.0012 0.00125 0.0013 0.00135 0.0014
1/Temperatura
seleccione una temperatura de operación que
favorezca la producción de C. El factor
preexponencial y la energía de activación para las
reacciones se tabulan de la siguiente manera:
partir de una temperatura menor de 946K se puede observar que la

accion 1 se dificulta. por tanto se concluye que la reaccion1 se ve
vorecida a altas temperaturas

Taller Segundo Corte Plantas

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EJEMPLO 6.

5 Selectividad de las reacciones del cloruro de

-0.97831834 -1.40236589 Axis Title

770 0.0012987 4.84603554 3.52219576 3.91924902 4.59229789

partir de una temperatura menor de 946K se puede observar que la

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