Metallurgy

Georgius Agricola, author of De re metallica, an important early work on metal extraction

Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their intermetallic compounds, and their mixtures, which are called alloys. Metallurgy is also the technology of metals: the way in which science is applied to the production of metals, and the engineering of metal components for usage in products for consumers and manufacturers. The production of metals involves the processing of ores to extract the metal they contain, and the mixture of metals, sometimes with other elements, to produce alloys. Metallurgy is distinguished from the craft of metalworking, although metalworking relies on metallurgy, as medicine relies on medical science, for technical advancement.

Metallurgy is subdivided into ferrous metallurgy (sometimes also known as black metallurgy) and non-ferrous metallurgy or colored metallurgy. Ferrous metallurgy involves processes and alloys based on iron while non-ferrous metallurgy involves processes and alloys based on other metals. The production of ferrous metals accounts for 95 percent of world metal production.

Etymology and pronunciation

The roots of metallurgy derive from Ancient Greek: μεταλλουργός, metallourgós, "worker in metal", from μέταλλον, métallon, "metal" + ἔργον, érgon, "work".

The word was originally an alchemist's term for the extraction of metals from minerals, the ending -urgy signifying a process, especially manufacturing: it was discussed in this sense in the 1797 Encyclopaedia Britannica. In the late 19th century it was extended to the more general scientific study of metals, alloys, and related processes.

In English, the /meˈtælədʒi/ pronunciation is the more common one in the UK and Commonwealth. The /ˈmetələrdʒi/ pronunciation is the more common one in the USA, and is the first-listed variant in various American dictionaries (e.g., Merriam-Webster Collegiate, American Heritage).

History

Gold headband from Thebes 750–700 BC

See also: Chalcolithic, Bronze Age, History of ferrous metallurgy, Metallurgy in pre-Columbian America, Metallurgy in pre-Columbian Mesoamerica, History of metallurgy in the Indian subcontinent, and Non-ferrous extractive metallurgy

The earliest recorded metal employed by humans appears to be gold which can be found free or "native." Small amounts of natural gold have been found in Spanish caves used during the late Paleolithic period, c. 40,000 BC. Silver, copper, tin and meteoric iron can also be found in native form, allowing a limited amount of metalworking in early cultures. Egyptian weapons made from meteoric iron in about 3000 BC were highly prized as "daggers from heaven."

Certain metals, notably tin, lead and (at a higher temperature) copper, can be recovered from their ores by simply heating the rocks in a fire, a process known as smelting. The first evidence of this extractive metallurgy dates from the 5th and 6th millennium BC and was found in the archaeological sites of Majdanpek, Yarmovac and Plocnik, all three in Serbia. To date, the earliest evidence of copper smelting is found at the Belovode site, including a copper axe from 5500 BC belonging to the Vinča culture. Other signs of early metals are found from the third millennium BC in places like Palmela (Portugal), Los Millares (Spain), and Stonehenge (United Kingdom). However, the ultimate beginnings cannot be clearly ascertained and new discoveries are both continuous and ongoing.

Mining areas of the ancient Middle East. Boxes colors: arsenic is in brown, copper in red, tin in grey, iron in reddish brown, gold in yellow, silver in white and lead in black. Yellow area stands for arsenic bronze, while grey area stands for tin bronze.

These first metals were single ones or as found. About 3500 BC, it was discovered that by combining copper and tin, a superior metal could be made, an alloy called bronze, representing a major technological shift known as the Bronze Age.

The extraction of iron from its ore into a workable metal is much more difficult than for copper or tin. The process appears to have been invented by the Hittites in about 1200 BC, beginning the Iron Age. The secret of extracting and working iron was a key factor in the success of the Philistines.

Historical developments in ferrous metallurgy can be found in a wide variety of past cultures and civilizations. This includes the ancient and medieval kingdoms and empires of the Middle East and Near East, ancient Iran, ancient Egypt, ancient Nubia, and Anatolia (Turkey), Ancient Nok, Carthage, the Greeks and Romans of ancient Europe, medieval Europe, ancient and medieval China, ancient and medieval India, ancient and medieval Japan, amongst others. Many applications, practices, and devices associated or involved in metallurgy were established in ancient China, such as the innovation of the blast furnace, cast iron, hydraulic-powered trip hammers, and double acting piston bellows.

A 16th century book by Georg Agricola called De re metallica describes the highly developed and complex processes of mining metal ores, metal extraction and metallurgy of the time. Agricola has been described as the "father of metallurgy".

Extraction

Furnace bellows operated by waterwheels, Yuan Dynasty, China.

Aluminium plant in Žiar nad Hronom (Central Slovakia)

Main article: Extractive metallurgy

Extractive metallurgy is the practice of removing valuable metals from an ore and refining the extracted raw metals into a purer form. In order to convert a metal oxide or sulfide to a purer metal, the ore must be reduced physically, chemically, or electrolytically.

Extractive metallurgists are interested in three primary streams: feed, concentrate (valuable metal oxide/sulfide), and tailings (waste). After mining, large pieces of the ore feed are broken through crushing and/or grinding in order to obtain particles small enough where each particle is either mostly valuable or mostly waste. Concentrating the particles of value in a form supporting separation enables the desired metal to be removed from waste products.

Mining may not be necessary if the ore body and physical environment are conducive to leaching. Leaching dissolves minerals in an ore body and results in an enriched solution. The solution is collected and processed to extract valuable metals.

Ore bodies often contain more than one valuable metal. Tailings of a previous process may be used as a feed in another process to extract a secondary product from the original ore. Additionally, a concentrate may contain more than one valuable metal. That concentrate would then be processed to separate the valuable metals into individual constituents.

Alloys

Casting bronze

Common engineering metals include aluminium, chromium, copper, iron, magnesium, nickel, titanium and zinc. These are most often used as alloys. Much effort has been placed on understanding the iron-carbon alloy system, which includes steels and cast irons. Plain carbon steels (those that contain essentially only carbon as an alloying element) are used in low-cost, high-strength applications where weight and corrosion are not a problem. Cast irons, including ductile iron, are also part of the iron-carbon system.

Stainless steel or galvanized steel are used where resistance to corrosion is important. Aluminium alloys and magnesium alloys are used for applications where strength and lightness are required.

Copper-nickel alloys (such as Monel) are used in highly corrosive environments and for non-magnetic applications. Nickel-based superalloys like Inconel are used in high-temperature applications such as gas turbines, turbochargers, pressure vessels, and heat exchangers. For extremely high temperatures, single crystal alloys are used to minimize creep.

Production

In production engineering, metallurgy is concerned with the production of metallic components for use in consumer or engineering products. This involves the production of alloys, the shaping, the heat treatment and the surface treatment of the product. The task of the metallurgist is to achieve balance between material properties such as cost, weight, strength, toughness, hardness, corrosion, fatigue resistance, and performance in temperature extremes. To achieve this goal, the operating environment must be carefully considered. In a saltwater environment, ferrous metals and some aluminium alloys corrode quickly. Metals exposed to cold or cryogenic conditions may endure a ductile to brittle transition and lose their toughness, becoming more brittle and prone to cracking. Metals under continual cyclic loading can suffer from metal fatigue. Metals under constant stress at elevated temperatures can creep.

Metalworking processes

Main article: Metalworking

Metals are shaped by processes such as:

• casting – molten metal is poured into a shaped mold.
• forging – a red-hot billet is hammered into shape.
• rolling – a billet is passed through successively narrower rollers to create a sheet.
• laser cladding – metallic powder is blown through a movable laser beam (e.g. mounted on a NC 5-axis machine). The resulting melted metal reaches a substrate to form a melt pool. By moving the laser head, it is possible to stack the tracks and build up a three-dimensional piece.
• extrusion – a hot and malleable metal is forced under pressure through a die, which shapes it before it cools.
• sintering – a powdered metal is heated in a non-oxidizing environment after being compressed into a die.
• machining – lathes, milling machines, and drills cut the cold metal to shape.
• fabrication – sheets of metal are cut with guillotines or gas cutters and bent and welded into structural shape.

Cold-working processes, in which the product’s shape is altered by rolling, fabrication or other processes while the product is cold, can increase the strength of the product by a process called work hardening. Work hardening creates microscopic defects in the metal, which resist further changes of shape.

Various forms of casting exist in industry and academia. These include sand casting, investment casting (also called the "lost wax process"), die casting, and continuous casting.

Heat treatment

Metals can be heat-treated to alter the properties of strength, ductility, toughness, hardness and/or resistance to corrosion. Common heat treatment processes include annealing, precipitation strengthening, quenching, and tempering. The annealing process softens the metal by heating it and then allowing it to cool very slowly, which gets rid of stresses in the metal and makes the grain structure large and soft-edged so that when the metal is hit or stressed it dents or perhaps bends, rather than breaking; it is also easier to sand, grind, or cut annealed metal. Quenching is the process of cooling a high-carbon steel very quickly after heating, thus "freezing" the steel's molecules in the very hard martensite form, which makes the metal harder. There is a balance between hardness and toughness in any steel; the harder the steel, the less tough or impact-resistant it is, and the more impact-resistant it is, the less hard it is. Tempering relieves stresses in the metal that were caused by the hardening process; tempering makes the metal less hard while making it better able to sustain impacts without breaking.

Often, mechanical and thermal treatments are combined in what are known as thermo-mechanical treatments for better properties and more efficient processing of materials. These processes are common to high-alloy special steels, superalloys and titanium alloys.

Plating

Main article: Plating

Electroplating is a chemical surface-treatment technique. It involves bonding a thin layer of another metal such as gold, silver, chromium or zinc to the surface of the product. It is used to reduce corrosion as well as to improve the product's aesthetic appearance.

Thermal spraying

Main article: Thermal spraying

Thermal spraying techniques are another popular finishing option, and often have better high temperature properties than electroplated coatings.

Microstructure

Metallography allows the metallurgist to study the microstructure of metals.

Metallurgists study the microscopic and macroscopic properties using metallography, a technique invented by Henry Clifton Sorby. In metallography, an alloy of interest is ground flat and polished to a mirror finish. The sample can then be etched to reveal the microstructure and macrostructure of the metal. The sample is then examined in an optical or electron microscope, and the image contrast provides details on the composition, mechanical properties, and processing history.

Crystallography, often using diffraction of x-rays or electrons, is another valuable tool available to the modern metallurgist. Crystallography allows identification of unknown materials and reveals the crystal structure of the sample. Quantitative crystallography can be used to calculate the amount of phases present as well as the degree of strain to which a sample has been subjected.

See also

• Archaeometallurgy
• CALPHAD
• Carbonyl metallurgy
• Cupellation
• Experimental archaeometallurgy
• Georg Agricola
• Goldbeating
• Gold phosphine complex
• Metallurgical failure analysis
• Mineral industry
• Pyrometallurgy

External links

• Media related to at Wikimedia Commons
• Learning materials related to Topic:Metallurgical engineering at Wikiversity