Iron-enhanced remediation of water and soil containing atrazine

Atrazine is the most widely used herbicide in the U.S. and has been detected in surface water and groundwater. Technologies are needed for onsite and in situ remediation of water and soil containing atrazine. We investigated the potential of using fine-grained, zero-valent iron (Fe0) to remove atrazine and promote its degradation in contaminated water and soil. Atrazine loss from aqueous solution increased with increasing Fe0concentration (w/v). Agitating 20 μg14C-ring-labeled atrazine L−1with 10% Fe0(w/v) removed 92% of the14C from solution within 48 h. Only about 4% of the14C lost from solution was extractable from the iron with 3 mM CaCl2(readily available pool), 81% was extractable with CH3CN (potentially available pool), and 11% was unextractable residues. A companion experiment indicated that most of the14C extracted from the iron with 3 mM CaCl2after the 48-h Fe0treatment was unaltered atrazine, while the CH3CN extract contained approximately 33% atrazine and 48% was unidenti...