Academia.eduAcademia.edu

Treatment of galvanic sludge in an arc thermal plasma reactor

2019

The performance of arc thermal plasma in treating galvanic sludge was investigated. The inductively coupled plasma optical emission spectrometry analysis conducted to characterise the raw galvanic sludge reveals the presence of chromium (Cr), copper (Cu), iron (Fe), magnesium (Mg), manganese (Mn), lead (Pb) and zinc (Zn). Product gas was measured at varying applied current of 170 A to 190 A and residence time of 2 to 5 minutes. The fourier transform infrared spectrometry analysis of the gaseous product identified the presence of carbon monoxide (CO), carbon dioxide (CO2), methane (CH4), ethene (C2H4), ethyne (C2H2) and water (H2O) in different concentrations. In general, the trend in CO and CO2 concentrations initially shows an increase as the applied current was increased and thereafter decreases. Low concentrations of hydrocarbon were persistent, which is due to the low amount of hydrocarbon in the galvanic sludge. From the analysis the concentration of CH4, C2H4 and C2H2 revealed...

T R E A T M E N T O F G A L V A N IC S L U D G E IN A N A R C T H E R M A L P L A S M A REACTOR B A L A IS A H A B D U L K A R IM A th / s is s u 6 m itt / % in r / q u ir / m / n ts 8or th / 8 u l 8 ilm / n t 4 w 4 r% o 8 th / o 8 th / % / g r/ / o8 D o 3 to r o 8 P h ilo s o p h y S 3 h o o l o 8 C h / m i3 4 l 4n% E n / r g y E n g i n / / r in g F 4 3 u lty o 8 E n g in / / r in g U n iv / r s iti T / k n o lo g i M 4 l 4 y s i 4 M A Y 2019 D E D IC A T IO N I h / r/ 6 y % /% i 3 4 t / th is P h .D r / s / 4 r 3 h w o r k to A ll 4 h ( S W T ) , m y l 4 t / F 4 th / r A 6 % u lk 4 r im A li (M 4 n 4 g / r ) , lo v / ly w i 8 / ( H 4 8 s 4 t I s 4 h I s m 4 il) K h4% / / j4 h , Sum 4yy4h iii 4n% Is 4 h ) 4n% my 3 h il % r / n (A li, ACKNOW LEDGEM ENT I 84m 4m th 4 n k 8 u l to A ll 4 h ( S W T ) ily . Y o u h 4 v / g r 4 titu % H 4 ss4 n 4 lw 4 y s 6 / in g h is m / r 3 y m y s tr / n g th , m y 4n% 84vour 3o u r4 g / 4 n% 4n% 3 o -s u p / rv iso r / n 3o u r4 g / m / n t s u p p o r t th r o u g h o u t th / P h .D th 4 n k s g o / s to m y m o th / r , w i 8 / p r 4 y / rs . I w o u l% 4 ls o lik / to 4n% 3 h il % 4 p p r/ 3 i4 t/ E n g i n / / r in g U T M w h o m h 4 v / o r s h 4 p in g m y 8 in 4 l to 3om m /n% / q u ip m / n t. A 6 % u ll 4 h o 8 3 / n tr / 8or th / 4n% 4 p p r/ 3 i4 t/ I ’m 4 ls o 4n% m / in / ith / r 4 p p r/ 3 i4 t/ 3om my % / /p/ st 6 in A 6u 8or th / ir p r o g r 4 m m / . S p / 3 i4 l 4n% l / 3 tu r / r s o 8 th / s 3 h o o l o 8 o 8 th / r / 4 3 to r th / I 6 r 4 h im 4n% th / i r s 4 3 r i 8 i 3 / , m o r 4 l s u p p o r t / x 3 / ll / n t 4 s s is t / % % / v / lo p m / n t o 8 M u h 4 m m / % Y u s u 8 S h 4 h u l H 4 m i% th / u s / o 8 r/ n r / s / 4 r 3 h th / s i s . I im m / n s / ly S h u 4 i 6 u B 4 l o g u n to w 4 r % th / 34 n n o t 8 o rg / t A r i 8 8 in D r R 4 j 4 K 4 m 4 r u lz 4 m 4 n B in R 4 j 4 4n% upon m / p r o t / 3 to r . M y g o / s to m y s u p / r v is o r A s s o 3 i 4 t / P r o 8 / s s o r D r M o h % / g u i% 4 n 3 / , 3 h / m i3 4 l 8or u s in g th / i r / q u ip m / n t th / 3 o n tr i 6 u tio n % / s ig n . m itm / n t 4n% o 8 Engr A t th is m o m / n t I w illin g n / s s to 4 s s is t N i k N o r h 4 n 4 n i B in ti M o h % G h 4 n i % u r in g th 4 n k 8 u l to A s s o 3 i 4 t / P r o 8 T u 4 n A m r 4 n T u 4 n h y % ro g / n / n / rg y U T M 8or p r o v i % in g g 4 s / s n / / % /% 8 o r 3 4 li 6 r 4 tio n o 8 / q u ip m / n t, D r N 4 % r il H 4 s r 4 8 M 4 t N 4 y 4 n o 8 F 4 3 u lty o 8 E n g i n / / r in g T / 3 h n o lo g y , UTHM 8or s p / 3 tr o m / tr y E n g i n / / r in g to 4 n 4 ly s is 4n% 4n% I ’m M u s t4 p h 4 4 s s is tin g u n % / r s t4 n % in % / 6 t/ % to M r M o h % o 8 P l 4 s m 4 T / 3 h n o lo g y 4m 4 ls o w o u l % th 4 n k A 664 s p l4 s m 4 Z 4 in i 4n% 8 ro m 4n% 4 3 k n o w l/ % w o rk S 4 u 8 8 i / B in M 4 n s o r 4n% o8 o p ti 3 4 l C / n tr / 4n% my 4n% /m is s io n o 8 L ip i% s N u r s y 4 h i r 4 h B in ti O p ti 3 4 l D i 4 g n o s ti 3 l 4 6 o r 4 to r y , g r 4 t / 8 u l to w o n % / r 8 u l A 6 u 6 4 k 4 r A li M o h 4 m m 4 % 4 6s/ n3/ M uh4m m 4% 3 o u p l/ A p p li / % R / s / 4 r 3 h . s 3 i/ n 3 / U T M . I my Dr I n % u 3 tiv / 3 o ll / 4 g u / s 6 r o th / r 4n% 4 33/ ss (T E T F U N D ) s 3 h o l 4 rs h ip . iv o8 r/ s / 4 r 3 h t/ 4 m m 4 t/ in U n iv / r s ity o 8 A 6 u j 4 . F in 4 lly , I g / th / U n iv / r s ity o 8 A 6 u j 4 m 4 n 4 g / m / n t g iv / n m / 8 4 3 u lty 8 o r 4 p p r o v in g to T / r ti 4 r y E % u 3 4 tio n T r u s t F u n % A BSTR A C T T h / p / r8 o rm 4 n 3 / o 8 4 r3 in v / s tig 4 t / % . T h / in % u 3 tiv / ly 3on% (C r), u 3 t / % to 3opp/r 3 h 4 r 4 3 t / r is / th / r m 4 l p l 4 s m 4 in tr / 4 tin g g 4 lv 4 n i 3 s lu % g / w 4 s 3 o u p l/ % p l 4 s m 4 o p ti 3 4 l / m is s io n s p / 3 tr o m / tr y th / r 4 w g 4 lv 4 n i 3 s lu % g / r / v / 4 ls th / p r / s / n 3 / o 8 (C u ), ir o n (F / ), m 4 g n / s iu m (M g ), m 4 n g 4 n / s / (M n ), l / 4 % (P 6 ) (Z n ). P r o % u 3 t g 4 s w 4 s m / 4 s u r / % r / s i % / n 3 / tim / o 8 2 to 4t v 4 r y in g 5 m in u t / s . T h / 4 p p li / % 8 o u ri/ r 3 u rr/ n t 4 n 4 ly s is o 8 th / g 4 s / o u s p r o % u 3 t i % / n ti 8 i / % th / p r / s / n 3 / o 8 io x i % in % i8 8 / r/ n t in iti 4 lly 4m 3 o n 3 / n tr 4 tio n s . show s % / 3r/ 4 s/ s. lo w Low ount 3 o n 3 / n tr 4 tio n 4n In g / n / r 4 l, th / tr / n % in 3 r / 4 s / 4s 3 o n 3 / n tr 4 tio n s o8 th / o 8 C H 4, C 2H 4 goo% 8or 8 it . Th/ w ith % / v / lo p / % 4 p p li / % in 4n% th / g 4 lv 4 n i 3 o 6 t 4 in / % 8or CO 8 lo w r4 t/ th / 4n% o 8 1. T r / 4 tm / n t 8oun% 3 u rr/ n t 4n% th / r m 4 l p l 4 s m 4 r 3 h / 4 p / r th 4 n th / o 8 th / 4 t 4 p p li / % r / 4 3 tio n 3 u rr/ n t 3 h 4 r 4 3 t / r is ti 3 % u / to th / 4 n 4 ly s is 4n% th / 73 p p m 3on% 8 o r 4 p p li / % w4s 1622 4 itio n s 3 u rr / n t, ppm o 8 1 7 0 A r / v / 4 l / % m / t 4 ls w / r / % / t/ 3 t/ % 4n% . Th/ 8or 3 o n t 4 in / % 3o st l/ 4 % w ith / ith / r 3 o n 3 / n tr 4 tio n 4 p p li / % tr / 4 tm / n t o 8 g 4 lv 4 n i 3 s lu % g / r / v / 4 ls 3o st o8 w / r/ n o t 3 u rr/ n t in th / g 4 lv 4 n i 3 s lu % g / . T h / o8 4 r3 4 % / t/ 3 t/ % . Th/ s u 8 8 i3 i/ n t / 3 o n o m i 3 4 n 4 ly s is 8or o8 p r o 8 it m 4 r g in o 8 R M th / r m 4 l p l 4 s m 4 tr / 4 tm / n t is R M 6 .4 9 w h i 3 h is o 8 tr / 4 tm / n t ( R M 2 7 .8 1 1 ) u s in g in 3 in / r 4 tio n . F u r th / r m o r / , w o u l% 6/ r / 4 liz / % o p / r 4 tio n . T h / r m 4 l p l 4 s m 4 tr / 4 tm / n t t / 3 h n iq u / is, th / r / 8 o r / , 8or th / th / r/ 4 8 t/ r in th / g 4 s / o u s p r o % u 3 t w 4 s s y st/ m lim it o r n o t p o s itiv / r / tu r n o n i n v / s t m / n t o 8 5 .8 1 % m / th o % F ro m 3 .1 2 m in u t / s o 8 1 7 0 A r / p r / s / n ts th / m in im u m 5 .8 9 p / r k g o 8 s lu % g / . T h / 84 3 o n 3 / n tr 4 tio n s 2 4n% in th / tr / 4 t / % s lu % g / w / r / C r ( 0 .4 1 0 m g /l) , C u ( 0 .3 5 0 m g /l) , F / (4 .0 im m o 6 ilis 4 tio n o 8 m / t 4 ls 4 r3 s lu % g / . (C O ), / w 4 t / r ( H 2O ) o 8 9 9 .6 3 % . T h / o p tim u m o p / r 4 tin g m g /l) , Z n (0 .8 m g /l) w h il / m 4 g n / s iu m , n i 3 k / l 4 p p li / % CO 4n% r / s i % / n 3 / tim / r / s p / 3 tiv / ly . T h / o p tim u m r / s p o n s / o 8 C O o p tim iz 4 tio n w ith in th / to x i 3 ity l / 4 3 h in g th / m / t 4 ls 4n% m o n o x i% 4n% w 4 s in 3 r / 4 s / % 3 o n 3 / n tr 4 tio n z in 3 m o % / l u s in g th / r / s p o n s / s u r 8 4 3 / m / th o % o lo g y s h o w / % 3 o r r / l 4 tio n 3 o / 8 8 i 3 i / n ts 8 ro m % / s ir 4 6 ility 34 r6o n C 2H 2 r / v / 4 l / % w / r / 4 6 p p m , 3 9 p p m th / tr / 4 tm / n t w / r / 1 7 0 .4 A , 2 0 .1 3 L / m in p l4 s m 4 g 4 s in C O 3 u rr/ n t 4n% s p / 3 tr o m / tr y o 8 h y % r o 3 4 r 6 o n w / r / p / r s is t / n t, w h i 3 h is h y % ro 3 4 r6 o n r / s p / 3 tiv / ly . A q u 4 % r 4 ti 3 m o % / l % / v / lo p / % in 8 r 4 r / % ( C O 2), m / th 4 n / ( C H 4), / th / n / ( C 2H 4), / th y n / ( C 2H 2) / iu m o 8 1 7 0 A to 1 9 0 A tr 4 n s 8 o r m 3 4 r6 o n % 4 n 4 ly s is 3 h ro m tr / 4 tin g g 4 lv 4 n i 3 s lu % g / . v in th / 4 v i4 6 l/ 8 i 8 th 4 y/4r o8 4 lt / r n 4 tiv / A B ST R A K P r/ s t4 s i A n 4 lis is p l4 s m 4 s p / k tr o m / r i m / n 3 ir ik 4 n 6/ si 2 - 5 % 4 l4 m p l4 s m 4 o p tik iu k u r p 4 % m in it. A n 4 lis is 4 4 ru s p / l6 4 g 4 i S / 34 r4 um um ny4, k / n 4 ik 4 n ( C 2H 4), 4 p 4 6 il 4 K / p / k 4 t4 n / ty n / tr / n % 4 ru s r/ n % 4 h % 4n ( C 2H 2), % 4n k / p / k 4 t4 n y4ng % 4 4 ir CO y4ng % g 4 lv 4 n i k 4 % 4 l4 h % 4 l4 m % 4 l4 m p / k 4 li k o r / l 4 s i s / 6 4 n y 4 k 9 9 .6 3 % . K / 4 % k4% 4r % 4 lir 4 n ip / r o l / h g 4 s p l4 s m 4 % 4 r ip 4 % 4 m / n u n ju k k 4 n 6 / rk u r4 n g 4 n . o l/ h 4 n 4 lis is k / in g in 4 n 1. R 4 w 4 t 4 n p 4 % p / n y in g k ir 4 n it / m u k 4 n % 4 l4 m % 4n 3 .1 2 m in it m 4 s 4 m 4 s t 4 u tin . T in % 4 k 4 3 iri /n4 p3/ m 4 r 4 ru s % 4n 64 gi 73 p p m . M o % / l 6 4 l4 s 4 t4 u y 4 n g t/ l4 h % ti % 4 k ir 4 w 4 t % 4 % 4 l4 h ik / s 4 n . A ru s p4% m / n g h 4 l 4 n g p / m in % /konom i p l4 s m 4 170 4 44n 4 rk 4 A m / w 4 k ili lo g 4 m y 4 n g t / r % 4 p 4 t h 4 6 4 u n tu k r 4 w 4 t 4 n k / u n tu n g 4 n s / 6 4 n y 4 k R M 5 .8 9 p / r k g 4 % 4 l4 h RM 6 .4 9 4 ru s y 4 n g j4 u h l / 6 ih % 4 l4 m / n 4 p 3/ m 4 r. m u r4 h ig u n 4 k 4 n , CO y4ng 6 / r4 % 4 % /ng4n % 4 l4 m lo g 4 m h4% y4ng C r ( 0 .4 1 0 m g /l) , C u ( 0 .3 5 0 m in im u m / n 4 p3/ m 4 r 4 % 4 l4 h % 1622 p p m K / p / k 4 t4 n m g /l) , F / (4 .0 m g /l) , Z n (0 .8 m g /l) m 4 n 4 k 4 l 4 m 4 g n / s iu m , n ik / l % y4ng ij 4 n 4 % % /ng4n o p tim u m 4 % 4 l4 h ik / s 4 n . 6 4 ik r4 w 4 t4 n 6 4 g i 4 ru s 1 70 A m / n u n ju k k 4 n lo g 4 m to k s ik ju m l4 h k / p / k 4 t 4 n C H 4, ij 4 n 4 . M o % / l y 4 n g o p / r 4 s i o p tim u m % 4n p / n g o p tim u m 4 n s is t / m tin % 4 k 6 4 l 4 s p ro s/ % u r % 44n 1 7 0 .4 A , 2 0 .1 3 L /m in 4 6 / r6 / z 4 . 4 w 4 ln y 4 g 4 lv 4 n ik . D 4 r i % g4s ( C O 2), m / t 4 n 4 is / 6 4 6 k 4 n % z in k r/ s i% / n 3 / p ro % u k 4 m / n g g u n 4 k 4 n k 4 / % 4 h s 4 m 6 u t 4 n p / r m u k 4 4 n m / n u n ju k k 4 n k / l / k 4 p 4 n m 4 s i n g - m 4 s in g p 4 % % 4n k / m u % i4 n 4 % 4n p r o % u k g 4 s t/ l4 h 64 gi io k s i % C 2H 2 m / n u n ju k k 4 n m 4 s in g - m 4 s in g 4 6 p p m , 3 9 p p m k u 4 % r 4 tik u n tu k k / p / k 4 t 4 n C O u n tu k (C r) , % 4n k / p / k 4 t4 n y 4 n g CO 2 p4% 6 / rt/ ru s 4 n , / n 4 p 3/ m 4 r % % 4 l4 m m / n in g k 4 t ik 4 ji. il 4 k s 4 n 4 k 4 n in 8 r 4 m / r 4 h (C O ), k 4 r 6 o n ( H 2O ) % k / h 4 % ir 4 n k r o m iu m 1 7 0 A h in g g 4 1 9 0 A 8 o u ri/ r % 4n ig u n 4 k 4 n h i% ro k 4 r6 o n h i% r o k 4 r 6 o n y 4 n g r/ n % 4 h C 2H 4 /% 4hk4n % 4 ri tr 4 n s 8 o r m 4 s i m / n u n ju k k 4 n k / h 4 % ir 4 n k 4 r 6 o n m o n o k s i % / t4 n 4 /n4 p3/ m 4 r in % u k ti8 g 4 lv 4 n i k m / n t 4 h m / n % % ( C H 4), m / r4 w 4 t (F / ), m 4 g n / s iu m (M g ), m 4 n g 4 n (M n ), p lu m 6 u m (P 6 ) (Z n ). P r o % u k g 4 s tim / h464 p / l/ p 4 s /n4 p3/ m 4 r t / m 6 4 g 4 (C u ), 4 rk 4 % 4n y4ng / n4 p3/ m 4 r % p lu m 6 u m ti % 4 k ip / r lu k 4 n u n tu k g 4 lv 4 n ik . A n 4 lis is g 4 lv 4 n i k m / n u n ju k k 4 n m 4 r g in K o s r4 w 4 t4 n p l4 s m 4 % 4 r ip 4 % 4 kos r4 w 4 t4 n 4 rk 4 (R M h4 64 2 7 .8 1 1 ) m / n g g u n 4 k 4 n p / m 6 4 k 4 r 4 n . D i s 4 m p in g itu , p u l 4 n g 4 n p o s i t i 8 p / l 4 6 u r 4 n s / 6 4 n y 4 k 5 .8 1 % 6 o l/ h % ir / 4 lis 4 s ik 4 n p 4 % m / ru p 4 k 4 n k 4 / % 4 h 4 4 t 4 h u n k / lim 4 o p / r 4 s i. T / k n ik r 4 w 4 t 4 n p l 4 s m 4 l t / r n 4 t i 8 y 4 n g s / s u 4 i u n tu k m / r 4 w 4 t / n 4 p 3 / m 4 r g 4 lv 4 n ik . vi TABLE OF CONTENTS T IT L E PAGE D E C L A R A T IO N ii D E D IC A T IO N ii i ACKNOW LEDGEM ENT iv A BSTR AC T v A BSTRAK vi TABLE OF CONTENTS v ii L IS T O F TABLES x ii L IS T O F F IG U R E S x iii L IS T O F A B B R E V IA T IO N S x v ii L IS T O F A P P E N D IC E S CHAPTER 1 x ix IN T R O D U C T IO N 1 1.1 B 4 3 k g r o u n % o 8 th / S tu % y 1.2 P r o 6 l/ m S t4 t/ m / n t 1.3 R / s / 4 r 3 h A im 1.4 S 3op / o 8 R / s/ 4 r3h 1.5 S ig n i 8 i 3 4 n 3 / 1.6 O r g 4 n is 4 tio n o 8 S tu % y CHAPTER 2 4n% 4n% 1 3 O 6 j / 3 tiv / s 4 5 C o n tr i 6 u tio n o 8 th / R / s / 4 r 3 h 5 6 L IT E R A T U R E R E V IE W 7 2 .1 I n tr o % u 3 tio n 7 2 .2 B 4 3 k g r o u n % o 8 G 4 lv 4 n iz in g P r o 3 / s s 7 2 .3 M / th o % s o 8 A p p ly in g Z in 3 C o 4 tin g 8 2 .3 .1 E l / 3 tr o g 4 lv 4 n is in g 2 .3 .2 H o t D ip G 4 lv 4 n iz in g 2 .3 .2 .1 M 2 .3 .2 .2 P ro 3/ ss 8 / 3 h 4 n is m 8 o 8 H o t D ip G 4 lv 4 n is in g o8 G 4 lv 4 n iz in g v ii M / t4 l P r o t / 3 tio n 11 in 13 2 .3 .3 2 .3 .4 F 4 3 to r s A 8 8 / 3 tin g th / C h 4 r 4 3 t / r is ti 3 s o 8 Z in 3 C o 4 tin g 16 I m m / r s io n T im / 16 2 .3 .4 .1 W ith % r 4 w 4 l T im / 16 2 .3 .4 .2 B 4 t h C o m p o s itio n 16 G 4 lv 4 n i 3 S lu % g / C h 4 r 4 3 t / r is 4 tio n 17 H / 4 v y M / t 4 ls 18 2 .5 .1 S o u r 3 / s o 8 H / 4 v y M / t 4 ls in th / E n v i r o n m / n t 19 2 .5 .2 A p p li 3 4 tio n o 8 H / 4 v y M / t 4 ls 19 2 .5 .3 E 8 8 / 3 ts o 8 H / 4 v y M / t 4 ls 20 T r / 4 tm / n t M / th o % s o8 H /4vy M / t4 l in G 4 lv 4 n i 3 22 S lu % g / S o li % i 8 i 3 4 tio n 2 .6 .2 C h / m i 3 4 l T r / 4 tm / n t M / th o % 23 2 .6 .3 E l / 3 tr o k in / ti 3 M / th o % 24 2 .6 .4 T h / r m 4 l T r / 4 tm / n t M / th o % s 26 2 .6 .4 .1 S lu % g / V itr i 8 i 3 4 tio n 26 2 .6 .4 .2 S lu % g / I n 3 in / r 4 tio n 26 2 .6 .4 .3 S lu % g / G 4 s i 8 i 3 4 tio n 27 A % v 4 n t4 g / s T / 3 h n o lo g y 4n% 8or 4n% S t 4 6 iliz 4 tio n M / th o % 22 2 .6 .1 D is 4 % v 4 n t 4 g / o8 T r / 4 tm / n t H / 4 v y M / t 4 l C o n t 4 in in g S lu % g / 28 C 4 t / g o r is 4 tio n o 8 P l 4 s m 4 31 P l 4 s m 4 G / n / r 4 tio n 33 F 4 3 to r s A 8 8 / 3 tin g P / r 8 o r m 4 n 3 / o 8 T h / rm 4 l P l4 s m 4 35 R / 4 3 to r 2 .1 0 .1 D is t 4 n 3 / B / t w / / n E l / 3 tr o % / s ( E l / 3 tr o % / G 4p) 35 2 .1 0 .2 R / s i % / n 3 / T im / 36 2 .1 0 .3 E 8 8 / 3 t o 8 M o is tu r / C o n t / n t 41 2 .1 0 .4 E 8 8 / 3 t o 8 P l 4 s m 4 G 4 s F lo w R 4 t / 42 A p p li 3 4 tio n o 8 T h / r m 4 l P l 4 s m 4 T / 3 h n o lo g y in W 4 s t / T r / 4 tm / n t 42 2 .1 1 .1 P 4 p / r S lu % g / 49 2 .1 1 .2 S to rm W 4 t / r S lu % g / 50 2 .1 1 .3 S p / n t B 4 tt / r i / s P 4 s t / 51 v iii 2 .1 1 .4 W 4 s t / W 4 t / r S lu % g / 4n% F ly A s h 52 2 .1 1 .5 T 4 n n / r y S lu % g / 52 2 .1 1 .6 S h ip O il S lu % g / 53 2 .1 1 .7 G 4 lv 4 n i 3 4n% E l / 3 tr o p l 4 tin g S lu % g / 54 2 .1 2 T h / r m 4 l P l 4 s m 4 R / 4 3 to r s U tilis / % in T r / 4 tin g S lu % g / s 2 .1 3 S t 4 n % 4 r % P r 4 3 ti 3 / T r / 4 tm / n t 2 .1 4 4t P ro 3/ % u r/ 8or S 3 h / % u l/ % W 4 s t/ K u 4 liti A l 4 m 64 O p tim iz 4 tio n T h / r m 4 l P l 4 s m 4 R / 4 3 to r P / r 8 o r m 4 n 3 / 65 2 .1 4 .1 N o n - s t 4 tis t i 3 4 l O p tim iz 4 tio n 65 2 .1 4 .2 S t 4 tis ti 3 4 l O p tim iz 4 tio n 66 2 .1 4 .2 .1 2 .1 4 .2 .2 CHAPTER 3 4n% 60 R / spons/ S u r8 4 3/ M / th o % o lo g y (R S M ) 67 E m p ir i 3 4 l M / th o % s 69 M ETHODOLOGY 71 3 .1 I n tr o % u 3 ti o n 71 3 .2 D / s 3 r ip tio n o 8 G 4 lv 4 n i 3 S lu % g / S 4 m p l / 73 3 .3 C h 4 r 4 3 t / r is 4 tio n o 8 R 4 w G 4 lv 4 n i 3 S lu % g / 73 3 .3 .1 P r o x im 4 t / A n 4 ly s is 74 3 .3 .1 .1 M o is tu r / C o n t / n t 74 3 .3 .1 .2 V o l 4 til / M 4 t t / r 75 3 .3 .1 .3 A sh 75 3 .3 .1 .4 F ix / % C 4 r 6 o n 76 3 .3 .2 T h / r m o g r 4 v im / tr i 3 A n 4 ly s is 78 3 .3 .3 U ltim 4 t / A n 4 ly s is o 8 G 4 lv 4 n i 3 S lu % g / 79 3 .3 .4 D / t / r m in 4 t io n o 8 T o t 4 l O r g 4 n i 3 C 4 r 6 o n 3 .3 .5 I n % u 3 tiv / ly C o u p l / % P l 4 s m 4 O p ti 3 4 l E m is s io n 79 S p / 3 tr o m / tr y 3 .4 D / s 3 r ip tio n 4n% 79 S p / 3 i 8 i 3 4 tio n s o8 C o m p o n / n ts L 4 6 o r 4 to r y S 3 4 l / A r 3 T h / r m 4 l P l 4 s m 4 3 .5 T r / 4 tm / n t P r o 3 / s s o 8 G 4 lv 4 n i 3 S lu % g / T h / rm 4 l P l4 s m 4 o8 81 in 4n A r3 85 3 .6 A n 4 ly s is o 8 S o li % 4n% 3 .7 D / s i g n o 8 E x p / r im / n t G 4 s / o u s P r o % u 3 ts 85 86 ix R E S U L T S A N D D IS C U S S IO N 89 I n tr o % u 3 tio n 89 C h 4 r 4 3 t / r is ti 3 s o 8 R 4 w G 4 lv 4 n i 3 S lu % g / 89 4 .2 .1 P r o x im 4 t / A n 4 ly s is G 4 lv 4 n i 3 S lu % g / 89 4 .2 .2 U ltim 4 t / A n 4 ly s is o 8 G 4 lv 4 n i 3 S lu % g / 90 4 .2 .3 T h / r m o g r 4 v im / tr i 3 A n 4 ly s is o 8 R 4 w G 4 lv 4 n i 3 S lu % g / 91 4 .2 .4 M / t 4 l C o m p o s itio n o 8 R 4 w G 4 lv 4 n i 3 S lu % g / 92 4 .2 .5 F i / l % E m is s io n S 3 4 n n in g E l / 3 tr o n M i 3 r o s 3 o p y ( F E - S E M ) A n 4 ly s is 4 .2 .6 93 E n / r g y D is p / r s iv / X - r 4 y S p / 3 tr o s 3 o p y (E D X ) o8 R4w 4n% 94 T r / 4 t / % G 4 lv 4 n i 3 S lu % g / E 8 8 / 3 t o 8 A p p li / % C u rr/ n t C o m p o s itio n o 8 G 4 s / o u s 4n% 4n% R / s i % / n 3 / T im / o n 96 S o li % P r o % u 3 t 96 4 .3 .1 G 4 s/ o u s P ro % u 3t 4 .3 .2 S o li % P r o % u 3 t 104 4 .3 .2 .1 C 4 r6 o n C o n t/ n t 104 4 .3 .2 .2 V o lu m / 4n% M 4 ss R / % u 3 tio n o8 106 T r / 4 t / % G 4 lv 4 n i 3 S lu % g / 4 .3 .2 .3 M / t 4 l C o m p o s itio n o 8 S #4 g 4 .3 .2 .4 F i/ l% E m is s io n M i3 r o s 3 o p y 108 S 3 4 n n in g E l / 3 tr o n (F E -S E M ) o 8 T r/ 4 t/ % 112 G 4 lv 4 n i 3 S lu % g / 4 .3 .2 .5 L / 4 3 h 4 6 ility o8 M / t 4 ls in S o li % 113 P ro % u 3t O p tim iz 4 tio n o8 G 4 s/ ous P ro % u 3t U s in g S u r8 4 3/ R / s p o n s / M / th o % o lo g y 117 4 .4 .1 119 M o % / l A n 4 ly s is E 3 o n o m i 3 A n 4 ly s is o 8 G 4 lv 4 n i 3 S lu % g / T r / 4 tm / n t in A r3 T h / rm 4 l p l4 s m 4 126 C h 4 p t/ r S u m m 4 ry 130 C O N C L U S IO N A N D R E C O M M E N D A T IO N 131 C o n 3 lu s io n 131 R / 3 o m m / n % 4 tio n 132 x REFERENCES 133 A P P E N D IC E S 152 L IS T O F P U B L IC A T IO N 174 xi L IST O F T A B L E S T IT L E C o m p 4 r is o n o 8 / l / 3 tr o g 4 lv 4 n s in g A v / r4 g / / l/ m / n t4 l s lu % g / (R o s s in i Th/ 3 h / m i3 4 l 4n% 3om hot % p o s itio n ip g 4 lv 4 n is in g . o8 4n% 18 r / 4 3 tio n ty p / o 8 g 4 s i 8 i 3 4 tio n o 8 27 e t a l., 2 0 1 3 ) 4n% % 11 g 4 lv 4 n i 3 B / rn 4 r% / s, 2 0 0 6 ) r / 4 3 tio n s w 4 s t/ (F r/ % / ri3 A % v 4 n t4 g / s 3 h / m i34 l 4n% is 4 % v 4 n t 4 g / s o 8 tr / 4 tm / n t t / 3 h n o lo g y 8or 29 s lu % g / s C h 4 r 4 3 t / r is ti 3 o 8 % 35 ir / 3 t 3 u r r / n t 4 r 3 p l 4 s m 4 R / s / 4 r 3 h / s o n th / r m 4 l p l 4 s m 4 tr / 4 tm / n t o n in 3 in / r 4 tio n 43 r/ s i% u / P u 6 li s h / % r / s / 4 r 3 h / s o n th / r m 4 l p l 4 s m 4 m u n i 3 ip 4 l s o li % w 4 s t / ( C / r q u / ir 4 4 r3 tr / 4 tm / n t o 8 e t a l., 2 0 0 4 ; G o m / z e t 45 a l., 2 0 0 9 ) T h / rm 4 l p l4 s m 4 p / r 8 o rm 4 n 3 / 4n% / 8 8 i3 i/ n 3 y o n tr / 4 t / % 47 s lu % g / s F o 3 u s o 8 s tu % y 4n% r / s u lt o 6 t 4 in / % 8 ro m tr / 4 t / % m / t 4 lli 3 58 s lu % g / in th / r m 4 l p l 4 s m 4 T y p / s o 8 th / r m 4 l p l 4 s m 4 u tiliz / % 8or s lu % g / tr / 4 tm / n t 61 S p / 3 i 8 i 3 4 tio n / 3 o m p o n / n ts o 8 it / m s o 8 th / th / r m 4 l p l 4 s m 4 84 s y st/ m R / s u lts o 8 p r o x im 4 t / R / s u lts o 8 u ltim 4 t / M / t4 l 3om 4 n 4 ly s is 4 n 4 ly s is g 4 lv 4 n i 3 s lu % g / 3o m 4n% 4t 3 4 r6 o n 3 o n t/ n t v 4 r y in g 4 p p li / % 93 p 4 r is o n o 8 tr / 4 tm / n t in r 4 w 3u rr/ n t / 8 8 i3 i/ n 3 y 8or tr / 4 t / % 106 o 8 r / s u lt o 6 t 4 in / % 117 m / 4 su r/ C O r/ sp o n s/ 118 th / q u 4 % r 4 ti 3 m o % / l (C O ). 120 % / s ig n 4 n % A N O V A t4 6 l/ 4n% in 5 m in u t / s . p r / v io u s s tu % . E x p / r im / n t 4 l 90 91 o 8 r 4 w g 4 lv 4 n i 3 s lu % g / p o s itio n in r 4 w g 4 lv 4 n i 3 s lu % g / P / r 3 / n t 4 g / r / % u 3 tio n o 8 A o 8 r 4 w g 4 lv 4 n i 3 s lu % g / x ii L IS T O F F IG U R E S F IG U R E N O . T IT L E F ig u r / 2 .1 B 4 t3 h h o t F ig u r / 2 .2 G 4 lv 4 n i 3 s / r i / s o 8 m / t 4 ls F ig u r / 2 .3 D i 8 8 / r / n t z in 3 - ir o n l 4 y / r s in 3 o 4 tin g % PAGE ip g 4 lv 4 n i z in g (A G A , 2 0 1 1 ) 4n% 4 llo y (G 4 ry , 2 0 1 5 ) 6 4 t3 h 4 10 hot 12 ip g 4 lv 4 n is / % % (A G A , 2 0 1 1 ) 13 F ig u r / 2 .4 P r o t / 3 tio n w 4 y s o 8 g 4 lv 4 n iz in g (G A A , 2 0 1 2 ) F ig u r / 2 .5 D / v / lo p m / n t o 8 Z i n 3 p 4 tin 4 (G A A , 2 0 1 2 ) F ig u r / 2 .6 A ty p i 3 4 l / l / 3 tr o k in / ti 3 s / tu p 8or 13 15 h / 4 v y m / t 4 l p o llu t / % so il ( B 4 / k e t a l., 2 0 0 9 ) 25 F ig u r / 2 .7 C l 4 s s i 8 i 3 4 tio n o 8 p l 4 s m 4 (R u j F ig u r / 2 .8 T y p i3 4 l r 4 n g / s o 8 t/ m p / r 4 tu r / s th / r m 4 l 4n% 4n% G h o sh , 2 0 1 4 ) 4n% n o n - / q u ili 6 r iu m / l / 3 tr o n p l4 s m 4 s 32 % / n s iti / s 8 o r ( B o u lo s , 1991; T 4 n % / r o e t a l., 2 0 0 6 ) F ig u r / 2 .9 E l / 3 tr o n 34 s34 % / F ig u r / 2 .1 0 ( 4 ) D C tr 4 n s 8 / r p r o 3 / s s o 8 io n is 4 tio n ( L / 4 l- Q u ir o s , 2 0 0 4 ) 4 r3 th / r m 4 l p l 4 s m 4 ( 6 ) D C n o n - tr 4 n s 8 / r th / r m 4 l p l 4 s m 4 ( S / o 34 v o lt 4 g / ( M o u s t 4 k 4 s e t a l., 2 0 0 8 6 ) F ig u r / 2 .1 2 E 8 8 / 3 t o 8 r / s i % / n 3 / tim / o n T O C r / m o v 4 l tr 4 n s 8 / r m o % F ig u r / 2 .1 4 F ig u r / 2 .1 5 F ig u r / 2 .1 7 CPU 4n% C x H y in tr 4 n s 8 / r 4n% N O 2 in t r 4 n s 8 / r th / r m 4 l p l 4 s m 4 r / 4 3 to r (L i 4n% 4 ir 4n% e t a l., 2 0 1 5 4 ) 4 r3 4n% 8or 8or 8or 4 38 n o n - tr 4 n s 8 / r r / % 39 n o n - tr 4 n s 8 / r r / % 39 n o n - tr 4 n s 8 / r r / % 40 2 0 k w n o n - tr 4 n s 8 / r K h o n g k r4 p 4 n , 2 0 0 9 ) x iii 38 n o n - tr 4 n s 8 / r p l 4 s m 4 (L i e t a l., 2 0 1 5 4 ) m 4 s s lo s s w ith tim / in t o r 3 h ( T ip p 4 y 4 w o n g 4n% p l 4 s m 4 (L i e t a l., 2 0 1 5 4 ) H 2S w ith tim / p 4 r ti 4 lly tr 4 n s 8 / r r / % 6 o 4 r% 4 r3 non­ p l 4 s m 4 (L i e t a l., 2 0 1 5 4 ) N O 2 w ith tim / p 4 r ti 4 lly tr 4 n s 8 / r r / % 4n% 4 r3 4n% e t a l., 2 0 1 5 4 ) C x H y w ith tim / p 4 r ti 4 lly tr 4 n s 8 / r r / % V 4 r i 4 tio n o 8 S O 2 4n% F ig u r / 2 .1 8 / V 4 r i 4 tio n o 8 N O 4n% i8 8 / r / n t 37 th / r m 4 l p l 4 s m 4 r / 4 3 to r (L i V 4 r i 4 tio n o 8 C O 4n% F ig u r / 2 .1 6 / E 8 8 / 3 t o 8 tim / o n N O m o% 4t % 36 - r 4 t / ( C h 4 n g e t a l., 2 0 0 8 ). E 8 8 / 3 t o 8 tim / o n C O 33 4 %3 H ong, 2012) A no% F ig u r / 2 .1 3 3 4 th o % / 4n% F ig u r / 2 .1 1 8 lo w / 4n% 32 41 S 3 h / m 4 ti 3 % i 4 g r 4 m o 8 p l 4 s m 4 r / 4 3 to r s y s t / m 8or tr / 4 tm / n t 49 o 8 p 4 p / r s lu % g / (S h i / e t a l., 2 0 1 4 6 ). E D X m / t4 l 3om p o s itio n o 8 r 4 w 4n% tr / 4 t / % s lu % g / ( C u 6 4 s 51 e t a l., 2 0 1 5 6 ). E D X m / t4 l 3om p o s itio n o 8 r 4 w 4n% tr / 4 t / % s lu % g / ( C u 6 4 s 55 e t a l., 2 0 1 5 6 ) D ir / 3 t 3 u rr/ n t e t al., n o n - tr 4 n s 8 / r th / r m 4 l p l 4 s m 4 (C u 6 4 s 55 20144) F lo w 3h 4 rt s lu % g / in 4 on m / th o % o lo g y l 4 6 o r 4 to r y s 3 4 l / 4 r3 o 8 tr / 4 tm / n t o 8 g 4 lv 4 n i 3 72 th / r m 4 l p l 4 s m 4 73 R 4 w ( u n tr / 4 t / % g 4 lv 4 n i 3 s lu % g / ). S 3 h / m 4 ti 3 6 lo 3 k S / tu p o 8 4 r3 % i4 g r4 m 8or TGA th / r m 4 l p l 4 s m 4 4 n 4 ly s is 8or 78 tr / 4 tm / n t o 8 g 4 lv 4 n i 3 81 s lu % g / P ro 3/ ss 4 n 4 r3 8 lo w % i4 g r4 m 8or tr / 4 tm / n t o 8 g 4 lv 4 n i 3 s lu % g / in 82 th / r m 4 l p l 4 s m 4 E x p lo % v i / w o 8 r / 4 3 tio n /% I n n / r r / 4 3 tio n R / s u lts o8 3h4m 6/ r 83 3h4 m 6/ r o 8 8 u rn 4 3/ th / r m o g r 4 v im / tr i 3 83 4 n 4 ly s is (T G A ) o8 r4 w 92 g 4 lv 4 n i 3 s lu % g / C 4 p tu r / % % F E -S E M im 4 g / s i 8 8 / r / n t m 4 g n i 8 i 3 4 tio n s o 8 r4 w u s in g g 4 lv 4 n i 3 H it 4 3 h i s lu % g / SU 8020 4t M o% /l 94 E q u ip m / n t E n / rg y % is p / r s iv / 4n% X - r 4 y s p / 3 tr o s 3 o p y (E D X ) o 8 r 4 w 95 g 4 lv 4 n i 3 s lu % g / E n / rg y % is p / r s iv / 4n% X -r4 y s p / 3 tr o s 3 o p y (E D X ) o8 95 tr / 4 t / % g 4 lv 4 n i 3 s lu % g / T r / n % in 4 p p li / % T r / n % in 4 p p li / % T r / n % in 4 p p li / % T r / n % in C O poun% 4t v 4 r y in g 96 o 8 g4 s/ o u s 3om poun% 4t v 4 r y in g 97 o 8 g4 s/ o u s 3om poun% 4t v 4 r y in g 97 in 4 m in u t / s r / s i % / n 3 / tim / 3 o n 3 / n tr 4 tio n 3 u rr/ n t 3om in 3 m in u t / s r / s i % / n 3 / tim / 3 o n 3 / n tr 4 tio n 3 u rr/ n t o 8 g4 s/ o u s in 2 m in u t / s r / s i % / n 3 / tim / 3 o n 3 / n tr 4 tio n 3 u rr/ n t T r / n % in 4 p p li / % 3 o n 3 / n tr 4 tio n 3 u rr/ n t o 8 g4 s/ o u s 3om poun% 4t in 5 m in u t / s r / s i % / n 3 / tim / 3 o n 3 / n tr 4 tio n 4 t v 4 r y in g r / s i % / n 3 / tim / x iv v 4 r y in g 98 98 F ig u r / 4 .1 0 T r / n % in C O 2 3 o n 3 / n tr 4 tio n 4t v 4 r y in g r / s i % / n 3 / tim / 99 F ig u r / 4 .1 1 T r / n % in C H 4 3 o n 3 / n tr 4 tio n 4t v 4 r y in g r / s i % / n 3 / tim / 99 F ig u r / 4 .1 2 T r / n % in C 2H 4 3 o n 3 / n tr 4 tio n 4t v 4 r y in g r / s i % / n 3 / tim / 1 00 F ig u r / 4 .1 3 T r / n % in C 2H 2 3 o n 3 / n tr 4 tio n 4t v 4 r y in g r / s i % / n 3 / tim / 1 00 F ig u r / 4 .1 4 T r / n % in H 2 O 3 o n 3 / n tr 4 tio n 4 t v 4 r y in g r / s i % / n 3 / tim / 101 F ig u r / 4 .1 5 F I T R s p / 3 tr u m s h o w in g tr / n % o8 CO 6 / tw / / n 1 7 0 A to 190 A F ig u r / 4 .1 6 101 F I T R s p / 3 tr u m s h o w in g tr / n % o 8 C O 2 6 / tw / / n 170 A 4n% 190 A 102 F ig u r / 4 .1 7 T o t4 l o rg 4 n i3 3 4 r6o n in r 4 w F ig u r / 4 .1 8 P / r 3 / n t 4 g / m 4 s s r / % u 3 tio n o 8 tr / 4 t / % g 4 lv 4 n i 3 s lu % g / 1 07 F ig u r / 4 .1 9 P / r 3 / n t 4 g / v o lu m / r / % u 3 tio n o 8 tr / 4 t / % g 4 lv 4 n i 3 s lu % g / 1 07 F ig u r / 4 .2 0 M / t4 l 3 o n 3 / n tr 4 tio n o8 4n% tr / 4 t / % g 4 lv 4 n i 3 s lu % g / tr / 4 t / % g 4 lv 4 n i 3 s lu % g / 1 06 4t 2 m in u t / s F ig u r / 4 .2 1 M / t4 l 109 3 o n 3 / n tr 4 tio n o8 tr / 4 t / % g 4 lv 4 n i 3 s lu % g / 4t 3 m in u t / s F ig u r / 4 .2 2 M / t4 l 109 3 o n 3 / n tr 4 tio n o8 tr / 4 t / % g 4 lv 4 n i 3 s lu % g / 4t 4 m in u t / s F ig u r / 4 .2 3 M / t4 l 110 3 o n 3 / n tr 4 tio n o8 tr / 4 t / % g 4 lv 4 n i 3 s lu % g / 4t 5 m in u t / s F ig u r / 4 .2 4 110 F E - S E M im 4 g / s o 8 r 4 w 4n% tr / 4 t / % s lu % g / 4t x10, 000 m 4 g n i 8 i 3 4 tio n F ig u r / 4 .2 5 112 I m m o 6 ilis 4 tio n o 8 h / 4 v y m / t 4 ls 4t 1 7 0 A to 1 9 0 A in 4 m in u t / s F ig u r / 4 .2 6 114 I m m o 6 ilis 4 tio n o 8 h / 4 v y m / t 4 ls 4t 1 7 0 A to 1 9 0 A in 5 m in u t / s F ig u r / 4 .2 7 114 P lo t o 8 p r/ % i3 t/ % v / rs u s 4 3 tu 4 l r/ sp o n s/ 8or CCD 4 n 4 ly s is o 8 C O in g 4 s / o u s p r o % u 3 t F ig u r / 4 .2 8 D i 4 g n o s ti 3 g r 4 p h o 8 n o r m 4 l p r o 6 4 6 ility o 8 r / s i % u 4 l p o in ts 8or F ig u r / 4 .2 9 CCD 4 n 4 ly s is o 8 C O in g 4 s / o u s p r o % u 3 t P l o t o 8 r / s i % u 4 l v / r s u s p r / % i 3 t / % v 4 lu / s m o n o x i% F ig u r / 4 .3 0 121 / CCD o8 3 4 r6o n in g 4 s / o u s p r o % u 3 t R / s p o n s/ su r8 4 3/ o 8 C O p l4 s m 4 g 4 s 8or 122 8 lo w - r4 t/ 4n% 122 3 o n 3 / n tr 4 tio n 4 p p li / % xv m o % / l; 3 u rr/ n t / 88/ 3t o8 123 F ig u r / 4 .3 1 R / s p o n s / su r8 4 3/ o 8 C O 4 p p li / % F ig u r / 4 .3 2 3 u rr/ n t 4 n % R / s p o n s / s u r8 4 3/ o 8 C O p l4 s m 4 g 4 s F ig u r / 4 .3 3 8 lo w r4 t/ 3 o n 3 / n tr 4 tio n m o % / l; / 88/ 3t o8 r / s i % / n 3 / tim / 4n% 3 o n 3 / n tr 4 tio n 1 24 m o % / l; r / s i % / n 3 / tim / D / s ir 4 6 ility p lo t 8 o r th / o p tim iz 4 tio n o 8 C O xvi / 8 8 / 3t o8 125 126 L IS T O F A B B R E V IA T IO N S A - A m p / r/ Ar - A rg o n AAS A to m i 3 A 6 s o r p tio n S p / 3 tr o p h o to m / t / r A STM - A m / r i 3 4 n S t 4 n % 4 r % T / s t M / th o % . CO - C 4 r6 o n m o n o x i% Cu - C opp/r B4 - B 4 r iu m CO2 - C 4 r 6 o n % io x i % CH4 - M / th 4 n / C2H 4 - E th 4 n / C2H 2 - E th y l / n / Cr - C h r o m iu m DC - D ir/ 3 t C u rr/ n t EC - E n / r g y C o n s u m p tio n EDX - E n / r g y D is p / r s iv / S p / 3 tr o s 3 o p y EPA - E n v ir o n m / n t 4 l P r o t / 3 tio n A g / n 3 y FC - F ix / % C 4 r 6 o n F/ - Iro n F E -S E M - F i / l % E m is s io n S 3 4 n n in g E l / 3 tr o s 3 o p / M i 3 r o s 3 o p y F T IR - F o u r i / r T r 4 n s 8 o r m / % I n 8 r 4 r / % S p / 3 tr o s 3 o p y FW W - F o r / s tr y W o o % W 4 s t / GCV - G r o s s C 4 lo r i 8 i 3 V 4 lu / H2 - H y % ro g / n H 2S - H y % r o g / n S u lp h i % H/ - H / liu m IB A - I n 3 in / r 4 tio n B o tto m A s h IC - In o rg 4 n i3 C 4 r6 o n ID - In t/ rn 4 l D i4 m / t/ r IC P - O E S - I n % u 3 tiv / ly C o u p l / % P l 4 s m 4 O p ti 3 4 l LC - L / 4 3 h 4 t / C o n 3 / n tr 4 tio n / / x v ii / S p / 3 tr o m / tr y M rs - M 4 ss O 8 R 4 w G 4 lv 4 n i 3 S lu % g / MS - M 4 ss O 8 S o li % P r o % u 3 t Mn - M 4 ng4 n/ s/ Mg - M 4 g n / s iu m MJ - M / g 4 J o u l/ M SW - MT - M / tr i 3 T o n n / Ni - N i3 k / l NO - N itr i3 O x i% NO2 - N itr o g / n D io x i % NOX - O x i% / s O OD - O u ts i % P - Pow /r PAED - P6 - L/4% PA RF - P l 4 s m 4 A p p li 3 4 tio n R / s / 4 r 3 h F 4 3 ility ppm - P 4 r t P / r m illio n RGS - R 4 w g 4 lv 4 n i 3 s lu % g / SEM - S 3 4 n n in g E l / 3 tr o n M i 3 r o s 3 o p y Si - S ili 3 o n SO 2 - S u lp h u r (I V ) O x i % SW - S 3 h / % u l/ % W 4 s t/ TC - T o t4 l C 4 r 6 o n TCLP - TGA - T h / r m o g r 4 v im / tr i 3 A n 4 ly s is T IG - T u n g s t/ n In / r t G 4 s TOC - T o t4 l O rg 4 n i3 C 4 r6 o n V RS - V o lu m / o 8 R 4 w G 4 lv 4 n i 3 S lu % g / VM - V o l 4 til / M 4 tt / r W PS - W / t P 4 p / r S lu % g / W PC - WW - M u n i 3 ip 4 l S o li % W 4 s t / / 8 / / N itr o g / n D i4 m / t/ r P u ls / % A r 3 E l / 3 tr o h y % r 4 u li 3 D is 3 h 4 r g / / T o x i 3 ity C h 4 r 4 3 t / r is ti 3 s L / 4 3 h in g P r o 3 / % u r / W / s tin g h o u s / P l 4 s m 4 C o r p o r 4 tio n W 4 s t/ W 4 t/ r x v iii L IS T O F A P P E N D IC E S A P P E N D IX T IT L E A p p / n % ix A E x i s tin g T h / r m 4 l P l 4 s m 4 P l 4 n t A p p / n % ix B W o r k s h / / t o 8 P r o x im 4 t / A n 4 ly s is o 8 R 4 w G 4 lv 4 n i 3 S lu % g / A p p / n % ix C A n 4 ly ti 3 4 l E q u i p m / n t 155 A p p / n % ix D F T I R S p / 3 tr u m o 8 G 4 s / o u s P r o % u 3 t 158 A p p / n % ix E D / t / r m in 4 t io n o 8 C o m p o n / n t G 4 s F r o m F T I R S p / 3 tr u m x ix PAGE 4n% O n g o in g P r o j / 3 t 152 154 170 CHAPTER 1 IN T R O D U C T IO N 1 .1 B a c k g r o u n d o f th e S tu d y G 4 lv 4 n i 3 s lu % g / is g / n / r 4 t / % 3 o 4 tin g to ir o n o r s / / l s o m 4 t / r i 4 l. T h / m / th o % w h / r / 6 y Z in 3 3 o 4 tin g o 8 m o lt / n z in 3 4t 4 m 4 t / r i 4 l r 4 n g in g 3 o n s ti tu / n t 4s in th / p r o 3 / s s o 8 p r / v / n t r u s tin g o 8 g 4 lv 4 n iz in g m o s tly t / m p / r 4 tu r / o 8 8 ro m 4 6out % /p/n% h / 4 v y m / t 4 l ( 3 h r o m iu m , n i 3 k / l, z in 3 , 4n% 4n% h 4 z 4 r % o u s to th / 6y 34 % is th / h o t v / ry 4 p p li / % l4 rg / m iu m , tin , l / 4 % , ( N ik o l 4 y 3 4 r 6 o n iz 4 tio n (S h / n 4n% o8 /m p lo y / % % /hy% th / r m 4 l m / th o % 8or sh 4 p/ s. Th/ 6 4 s i 3 4 lly it is 3 o p p / r , / t 3 .) 4 l4 % / n w 4 s t/ M 4 r i 4 , 2 0 1 7 4 ; R o s s in i tr / 4 tm / n t Z h 4 n g , 2 0 0 5 ; W 4 n g e t a l., 2 0 0 7 ) 4 s s o 3 i4 t/ % w ith 3 o n t 4 in in g C 0 2, th / % p r o % u 3 tio n io x in s 4n% 6//n 4 p p li / % P l4 s m 4 t/ 3 h n o lo g y p 4 s s in g 6 r/ 4 k % / l / 3 tr i 3 o w n . S in 3 / 4n% g 4 s s tr / 4 m , o r p l 4 s m 4 . 4n% s/ 3o n % 4 ry in 3 lu % / s g 4 s i 8 i 3 4 tio n o 8 s o li % 6ut % r i / % s lu % g / ( D o g r u th / s / t / 3 h n o lo g i / s w 4 s t/ 4n% /o r 4 r/ p ro % u 3t g 4 s M o s t r / 3 / n tly th / r m 4 l p l 4 s m 4 t / 3 h n o l o g y w h i 3 h / n v ir o n m / n t 4 lly in v o lv / s th / th r o u g h / l / 3 tr i 3 4 l g / n / r 4 t / % , w h i 3 h s trip s s lu % g / 8 ri/ n % ly w 4 s t / m 4 n 4 g / m / n t to h 4 n % l / l 4 r g / v o lu m / o 8 h 4 z 4 r % o u s in % u s tr i 4 l s lu % g / . 6 4 s i 3 4 lly 3 u rr/ n t o8 8 u r4 n s. s h o r t r / s i % / n 3 / tim / p r o 3 / s s t / 3 h n iq u / is o8 r 4 t / % s lu % g / ( K 4 to h e t a l., 2 0 0 5 ) , lo w t / m p / r 4 t u r / p y r o ly s is e t a l., 2 0 0 2 ; M u r 4 k 4 m i e t a l., 2 0 0 6 ; W / r l / , 2 0 1 5 4 , 2 0 1 5 6 ) 4 i 8 8 / r / n t ty p / o 8 s tr u 3 tu r 4 l 4n% 4 6 4 th B / r n 4 r % / s , 2 0 0 6 ). M 4 jo r ly is 8or % o n th / in s t 4 ll / % p r o 3 / s s , 6 u t / n v ir o n m / n t p g 4 lv 4 n iz in g , % im m / r s io n o 8 m 4 t / r i 4 l in 4 5 0 oC . T h is is s m 4 ll m / t 4 l p i / 3 / to p r o t / 3 tiv / z in 3 4 im p r o v / th / li 8 / s p 4 n o 8 m / t 4 lli 3 4 p p li / % is p r o % u 3 / % o n th / m 4 t / r i 4 l o 8 th / g 4 lv 4 n i 3 s lu % g / t h 4 t is to x i 3 4n% 4 p p ly in g 4 r / s is tiv ity 3 r / 4 tio n g4s in / x is t 4 w 4 y / l / 3 tr o n s 8 r o m 4 o8 4 p ro 3 / ss 4 3ro ss s u s t 4 in / % r/ 8 / rr/ % / l / 3 tr i 3 4 l to 4s 4 r3 6y / l / 3 tr i 3 4 l th / s y s t / m , s ig n i 8 i 3 4 n t h / 4 t is th / g 4 s m o l / 3 u l / s r / s u ltin g in 4n io n is / % A ir is th / m o s t H / liu m ( H / ) 4n% m on g4 s us/ % , A r g o n (A r ) h 4 v / S h im 6 4 r 4 , 2 0 0 3 ). I n o r % / r l4 r g / 4 r/ 4n% 3om % i 8 8 / r / n ti 4 l in s/ p 4 r4 t/ % 8 ro m 6y / l / 3 tr i 3 4 l 6/ / n 8 o r 4 ir 6ut w i % / ly u s / % (H r 4 6 o v s k y , 2 0 0 2 ; W 4 t 4 n 4 6 / to 3on% 8 i/ l% / x p o n / n ti 4 l 4 / . / l / 3 tr o n s 4 r / 4 '. T h is p h / n o m / n o n is m o v in g w ith th / 4n% 6 / tw / / n /nough, T h/ s/ 4 6out 3 4 ll / % / l / 3 tr i 3 8 i / l % , 4n / l / 3 tr o n s / l / 3 tr o n 4 n 4 r3 is 4 r / 6 4 s i 3 4 lly p r o 3 / s s / s : th / r m 4 l o r ( / q u ili 6 r iu m ) p l 4 s m 4 s / l / 3 tr o % / s 34 n 8 r/ / w h i3 h p u ll / % 6/ / l / 3 tr o n s 4n% 6 / tw / / n / l / 3 tr o n s 4 n % 4t on3/ 4 /nough th / / l / 3 tro % / s . 6/ 3om / tw o ty p / s o 8 p l 4 s m 4 4n% 4 th / n m o v / w ith th / 34 s34 % / 3 r/ 4 t/ % 3 0 0 0 oC g 4 s m o l / 3 u l / s lo s / F l 4 m m , 1 9 8 9 ). T h / r / tw o s u 6 j / 3 t / % to 6/ / l / 3 tr o n s im p 4 3 t o th / r m o l / 3 u l / s , r / l / 4 s in g m o r / A t t/ m p / r4 tu r/ s o 8 (A u 3 i / llo on/ % W h / n th is p o t / n ti 4 l is l 4 r g / 4 ' 4n% u 3 t / l / 3 tr i 3 ity , it m u s t p o t / n ti 4 l. T h is is th / n o r m 4 lly n / u tr 4 l m o l / 3 u l / s in th / / l / 3 tr i 3 s / v / r 4 l in / r t g 4 s / s s u 3 h n itr o g / n ( N 2), 8or io n is / % in % u s tr i 4 l n o n - / q u ili 6 r iu m p l 4 s m 4 s (B o u lo s , 1 9 9 1 ; K o g / ls 3 h 4 tz , 2 0 0 4 ). T h / rm 4 l p l4 s m 4 h 4 s io n iz in g r 4 % i 4 tio n th / r m 4 l p l 4 s m 4 s 4n% 34 n 4% h ig h v 4 n t 4 g / s o 8 h ig h t / m p / r 4 tu r / , h ig h in t / n s ity , n o n ­ / n / rg y r/ 4 3 h t/ m p / r4 tu r/ s o 8 46ov/ t / m p / r 4 t u r / u tilis / % in tr / 4 tm / n t o 8 th / w 4 s t / th / r m 4 l p l 4 s m 4 s 4 r/ /m 4 tm 3 h / m i3 4 l su 3h v4por 4s 3on% th / r m 4 l p l 4 s m 4 % / p o s itio n ) , p l 4 s m 4 m / t 4 llu r g y 4n% 3 h / m i3 4 l 3om 4n% 34 n 6/ 3om p 4 3 tio n 3 o n s is t 8 r 4 3 tio n m 4 t / r i 4 l, m / ltin g in o r g 4 n i 3 m 4 t / r i 4 l 5/ .g . 4 s ili 3 4 t / ). Th/ 3o v / rs / q u ili 6 r iu m 4% v 4 n t4 g / s o 8 P l4 s m 4 g 4 s/ s w / r/ 4 w i% s p / 3 tr u m / 8 in / 4n% o8 p l4 s m 4 p o w % / r s , th / r m 4 l % / s tr u 3 tio n . M u r p h y ( 2 0 0 8 ) th / 4n% Th/ 4 p p li 3 4 tio n s . s y n th / s is o 8 o 8 th / w h i3 h o 8 w 4 s t/ 4 p p ro 4 3h 8 o r 8 o llo w is % p l 4 s m 4 tr / 4 tm / n t in g ; th / r m 4 l 3 4 ll / % 4n% u s / % to g / n / r 4 t / / l / 3 tr i 3 p o w / r o r p l 4 s m 4 g 4 s i 8 i 3 4 tio n , 8 4 r / s s . th / t / 3 h n i q u / s ( p l 4 s m 4 s p r 4 y in g p o n / n ts w ith o u t o x i % 4 tio n in 3 o m p l / t / o x i % 4 tio n o 8 o r g 4 n i 3 g 4 s / s w h i3 h 3 o 4 tin g th / r m 4 l p l 4 s m 4 i 8 8 / r / n t ty p / s o 8 w 4 s t / m 4 y m 4 tr ix 6/ 6ut itio n s s im il 4 r to th o s / w h / n m is s il / s r / - / n t / r th / r m 4 l p l 4 s m 4 w 4 s t / A 3 3 o r % in g to H / 6 / r l in % 3 o u l% o s p h / r / . T o % 4 y th / r m 4 l p l 4 s m 4 t / 3 h n o l o g y 4 p p li 3 4 tio n s o8 2 0 ,0 0 0 K p lo y / % in m 4 n y in % u s tr i 4 l u s / % to s im u l 4 t / h ig h t / m p / r 4 t u r / th / A 3 3 o r % in g to T 4 n % / r o e t a l , ( 2 0 0 6 ) % / n s ity . p l4 s m 4 6 r/ 4 k % ow n o 8 p y r o ly s is , th / g / n / r 4 tio n o 8 s y n g 4 s 4n% r iv / s t / 4 m tu r 6 i n / s k n o w n o th / r 4 v itr i 8 i 3 4 ti o n o 8 s o li % w 4 s t / s 6 y g 4 s i 8 y in g o r g 4 n i 3 4n% in t / g r 4 tio n 6 in % in g h 4 z 4 r % o u s m / t 4 ls in o 8 p l4 s m 4 2 p y r o ly s is , 3om 4 3 / r4 m i3 p 4 3 tio n 4 n% v itr i 8 i 3 4 tio n p ro 3/ ss v itr i 8 i 3 4 ti o n or 3 4 n 6 / 4 p p li / % I n th is r / s / 4 r 3 h , p l4 s m 4 3 o m 6 in 4 tio n 4 8 i/ l% 3 r/ 4 t/ % 8or 4 r3 6y % o 8 p l4 s m 4 s o li % s w ith h ig h 8 r 4 3 tio n s th / r m 4 l p l 4 s m 4 w 4 s ir / 3 tin g g 4 s i 8 i 3 4 tio n , 4 n / l / 3 tr i 3 8 i / l % 4 p p li / % 4 3 h i/ v / % in to th / i r to r 3 h 1 .2 v 4 r y in g 4 to m i 3 / l / m / n t 34 n o rg 4 n i3 4t m / lt 3om 4n% p o n / n ts 4 p p li / % 3u rr/ n t 4 n % in th / r / 4 3 tio n 4 6 / tw / / n 1 7 0 0 oC u s / % to H / 4 t g / n / r 4 t/ % % 8 ro m 4n% is s o 3 i 4 t / w 4 s t / th / p l 4 s m 4 34n 6/ v 4 p o r iz / % 4n% % /3om pos/ % 6y th / in t / n s / h / 4 t. P r o b le m S ta te m e n t g 4 lv 4 n i 3 s lu % g / s lu % g / is m 4 jo r ly 8 ro m 4 r is in g 8 r o m 4 3 4 t/ g o ry h 4 z 4 r% o u s 4n% 4 llo w / % to 6/ % 4n% 8oun% 4s g 4 lv 4 n i 3 s lu % g / h 4 s v 4 r io u s h u m 4 n h / 4 lt h u p o n th / 4 33u m 3 4 n 4 ls o e t a l., 2 0 1 5 ). A p 4 r t 3 o n t 4 in s , s u r 8 4 3 t 4 n ts , o il / n v ir o n m / n t 4 l, to so il 34 us/ 3o n su m 6y hum 4n s lu % g / ir r / p 4 r 4 6 l / 34 n % 4m 4g/ 4n% l/ 4 % 3 o n t 4 in in g h / 4 lth to / 8 8 / 3 t. / l/ v 4 t/ % to th / p l 4 n ts . It p tio n o 8 th / p l 4 n ts s in 3 / th / s / p l 4 n ts u l 4 t / % l / v / ls o 8 th / h / 4 v y m / t 4 ls w ith in th / ir tis s u / s . T h / h / 4 v y 4 p p li / % r / % u 3 / th / s lu % g / v o lu m / p l / t / ly ir / 3 tly to l 4 n % 8 ill. T h / s lu % g / l / 4 % to u n % / r g r o u n % w 4 t / r p o llu tio n . I n 3 in / r 4 tio n is th / m o s t 3 o m m o n tr / 4 tm / n t m / th o % 3om % G 4 lv 4 n i 3 S W 1 0 5 in M 4 l 4 y s i 4 t h 4 t is is p o s 4 l o 8 u n tr / 4 t / % o r n o t p r o p / r ly m 4 n 4 g / % h / 4 v y m / t 4 l 3 4 n 4 ls o 4 8 8 / 3 t m / t4 l 4s 3 o n tr i 6 u to r . 4n% h y % r 4 t/ o x i% / s . u p t 4 k / o 8 h / 4 v y m / t 4 ls 6 y p l 4 n ts . T h is m 4 y o8 m 4 jo r in th / s lu % g / , it 4 ls o E x 3 / s s l / v / ls o 8 h / 4 v y m / t 4 ls in tr o % u 3 / % 3 o n s is t is p o s / % 4 e t a l., 2 0 1 3 ; K o 6 y 4 h / 4 v y m / t 4 ls ( E m in / g r/ 4 s/ , h y % ro x i% / s s lu % g / s u 3 h s lu % g / s is g / n / r 4 t / % g lo 6 4 lly , g 4 lv 4 n iz in g p r o 3 / s s / s is th / p r / s / n 3 / o 8 h / 4 v y m / t 4 l % 3 o n t 4 in in g o 8 S 3 h / % u l / % W 4 s t / ( S W ) r / 8 / r to n o lo n g / r 3 o n s titu t / s T h/ not 34 n 6/ lo w p r / s s u r / g 4 s s tr / 4 m v itr i 8 y th / in o r g 4 n i 3 p o r tio n o 8 th / g 4 lv 4 n i 3 s lu % g / w h il / th / L 4 r g / v o lu m / o 8 h / 4 v y m / t 4 l 4n% 3h 4 m 6/ r. 4n% to t r / 4 t g 4 lv 4 n i 3 s lu % g / . A th ro u g h tim / p 4 3 tio n o 8 o rg 4 n i 3 . g / n / r 4 t / h ig h t / m p / r 4 tu r / s . T h / in t / n s / h ig h t / m p / r 4 tu r / o 8 2 2 0 0 oC 3om % / s tr o y s lu % g / w ill r / m 4 in 4n% to h 4 z 4 r % o u s w 4 s t / s u 3 h 8 o r 8 in 4 l % 4s g 4 lv 4 n i 3 s lu % g / . T h is m / th o % is p o s 4 l, h o w / v / r it h 4 s 4 lo t o 8 % r4 w 6 4 3k . It % o/s th / m / t 4 ls in th / s lu % g / , w h i 3 h m / 4 n s t h 4 t th / m / t 4 ls in th / s till p o llu t / th / / n v ir o n m / n t. 3 It 4 ls o g / n / r4 t/ h 4 z 4 r% o u s 8 "y 4 sh 4 n% 6 o tto m 4 sh / s T / h e t a l., 2 0 0 7 ). I t th 4 t r / q u ir / s 4 ls o g / n / r4 t/ 8 u r th / r 8 ly 4 s h 4 n % 6 o tto m 8 ly 4 s h s u 6 s t 4 n 3 / s w h i 3 h w ill s till r / q u ir / l 4 n % 8 illin g . T h / 3 h / m i3 4 l h 4 s th / m 4 jo r p r o 6 l / m o 8 w 4 s t / s / p 4 r 4 tio n 3o nsu m io n / x 3 h 4 n g / is o n ly ( N ik o l 4 y 4s 4n% / 8 8 / 3 tiv / w h/n % / 4 lin g 4n% w ith lo w 3o n v / rt 3on% su 3h u 3 t/ % 4s 6y g 4 lv 4 n i 3 s lu % g / . 4 6 ility T h is h 4 s to 6//n 4 r/ n o t 8 r / / o 8 to x i 3 m / th o % s o 8 tr / 4 tm / n t p tio n o 8 r / 4 g / n ts w h il / 3 o n 3 / n tr 4 tio n 8or 4 o 8 h / 4 v y m / t 4 ls tr / 4 tm / n t o p tio n s s u 3 h / 8 8 i 3 i / n tly p ro v / n 6y % / to x i 8 y h 4 z4 r% o u s p r / v io u s r / s / 4 r 3 h / s ( B i / n e t a l., 2 0 1 3 ; C h 4 n g e t a l., 2 0 0 8 ; C u 6 4 s e t a l., 2 0 1 4 6 ; G o m / z a l., 2 0 0 9 ; L i e t a l., 2 0 1 2 ; L i e t a l., 2 0 1 5 4 ; S z / n t / p l 4 s m 4 t / 3 h n o lo g y to 4n 6/ / 8 8 i3 i/ n t n o tw ith s t 4 n % in g th / tr / 4 tm / n t p r o 3 / s s t h 4 t h 4 s g o tt / n n o r / s / 4 r 3 h m /4ns o 8 3om / s 4 tt / n tio n . % / to x i 8 i 3 4 tio n 4 lo n g in v / s tig 4 tio n o n th / / 8 8 / 3t o 8 th / s lu % g / 6ut w ith g 4 s / o u s p r o % u 3 t ( S y n g 4 s ) T h / o n ly r / s / 4 r 3 h / s s o 84r 8o3us/ % e t a l., 2 0 1 4 6 ) . P r / s / n tly , th / r / is n o (C u 6 4 s et e t a l., 1 9 9 8 ) h 4 v / p r o v / n th / r m 4 l t r / 4 tin g g 4 lv 4 n i 3 s lu % g / u s in g th / r m 4 l p l 4 s m 4 t / 3 h n o l o g y v itr i 8 i 3 4 ti o n th 4 t th / r / m n 4 n t w 4 s t / in to in / r t o r h 4 r m l / s s m 4 t / ri 4 l. T h / r m 4 l p l 4 s m 4 t / 3 h n o l o g y h 4 s th / w 4 s t/ l4 rg / M 4 r i 4 , 2 0 1 7 6 ) . T h / r / 8 o r / , th / r / is th / n / / % th / r m 4 l p l 4 s m 4 t h 4 t w ill e t a l., 1 9 9 9 ; C h u n - t r / 4 tm / n t.( C / % z y n s k 4 % 3on% u 3 t/ % o n in / r tis 4 tio n o 3 u m / n t/ % o 8 p r o 3 / s s v 4 r i 4 6 l / o n th / g 4 s / o u s p r o % u 3 t 8 ro m on 4n% r/ s/ 4 r3h th / r m 4 l p l 4 s m 4 tr / 4 tm / n t o 8 g 4 lv 4 n i 3 s lu % g / . I t is th / r / 8 o r / th / in t / n tio n o 8 t h is r / s / 4 r 3 h to in v / s tig 4 t / th / o8 s l4 g / 8 8 / 3t (s o li % o 8 p ro 3 / s s v 4 ri4 6 l/ o n g 4 s / o u s p ro % u 3 t p r o % u 3 t) o 6 t 4 in / % 8 ro m tr / 4 tm / n t im m o 6 ilis 4 tio n o 8 th / m / t 4 ls in th / s o li % p r o % u 3 t / x p o su r/ h ig h 3 h / m i 3 4 lly 6 o n % / % 1 .3 i. ii. T o r/ n % / rs 4n% n o n -h / 4 v y 8 o rm s 4 m / t 4 ls o8 l / v / l o 8 in / r tis 4 tio n g 4 lv 4 n i 3 3 4 n 6 / 4 3 h i/ v / % o 8 th / g 4 lv 4 n i 3 s lu % g / to th / h ig h t / m p / r 4 t u r / t/ m p / r4 tu r/ 4n% w h i3 h 8 ro m 4 r/ 4s 4 s lu % g / . r / s u lt o 8 th / th / r m 4 l p l 4 s m 4 . T h / n o n - v o l 4 til / s p / 3 i/ s n o n - l / 4 3 h 4 6 l / s o li % m 4 trix . R e s e a r c h A im a n d O b je c tiv e s To 3 h 4 r 4 3 t / r is / % % / t/ rm in / th / g 4 lv 4 n i 3 s lu % g / p r io r to th / r m 4 l p l 4 s m 4 tr / 4 tm / n t. / 8 8 / 3t o8 4 p p li / % 3 u rr/ n t 4 n % g 4 s / o u s p ro % u 3 t. 4 Th/ r / s i % / n 3 / tim / o n s o li % 4n% iii. T o o p tim iz / C O in th / g 4 s / o u s p r o % u 3 t u s in g s u r 8 4 3 / r / s p o n s / m / th o % o lo g y ( R S M ). iv . To 3on% u 3t / 3 o n o m i 3 4 n 4 ly s is o n th / tr / 4 tm / n t o 8 g 4 lv 4 n i 3 s lu % g / in 4 n 4 r3 th / r m 4 l p l 4 s m 4 . 1 .4 S cop e o f R esea rch T h / s 3 o p / o 8 th is r / s / 4 r 3 h in 3 lu % / s th / K IS W IR E S% n B h% . T h / m o is tu r / , v o l 4 til / s , 3om p o s itio n 4n% 4 s h 3 o n t / n t, 8 ix / % 4 n 4 ly s is 3 4 r6 o n , p o u n % , h / 4 v y m / t4 l o 8 th / s o li % 3om to t 4 l o r g 4 n i 3 4n% % / s ig n in g g 4 s / o u s to p o s itio n , l / 4 3 h 4 6 ility p r o % u 3 t. F in 4 lly , O p tim iz 4 tio n 4n% o 8 g 4 lv 4 n i 3 s lu % g / o 8 th / g 4 lv 4 n i 3 s lu % g / to m o r p h o lo g i 3 4 l s tru 3 tu r / . T h / p l 4 s m 4 r / 4 3 to r . T h / 3om 3 h 4 r 4 3 t / r iz 4 tio n 3 o ll / 3 tio n 4n% 34 r6o n 4n% 3om / 3 o n o m i 3 4 n 4 ly s is % / t/ rm in / th / (T O C ) , / l / m / n t 4 l 8 4 6 r i 3 4 tio n % / t/ rm 8 ro m o 8 th / 4 3 in / th / to t 4 l o r g 4 n i 3 p o s itio n o 8 th / g 4 s / o u s o 8 th / l 4 6 o r 4 to r y 4 r3 th / r m 4 l p l4 s m 4 . 1 .5 S ig n ific a n c e a n d C o n tr ib u tio n o f th e R e s e a r c h R / 3 / n tly , g 4 lv 4 n i 3 s lu % g / s m / th o % 6 o tto m 4 sh/ s % o/s not 4 sh/ s th 4 t t h 4 t r / q u ir / s 3om 4 r/ I n v / s tig 4 tio n s o n g 4 s/ o u s p ro % u 3t % 4 t4 4n% is 4 lt / r n 4 tiv / r/ % u 3/ th / in in 3 in / r 4 to r s in M 4 l 4 y s i 4 . T h is 34 n / n v ir o n m / n t. It 4 ls o tr 4 n s 8 o r m th / s lu % g / in to n o n - to x i 3 o8 4 p p li / % v o lt 4 g / 4n% 4 r is in g 8 ro m 4n% 4 n% 6 o tto m 3 4 n / 8 8 i 3 i / n tly tr / 4 t h 4 r m l / s s m 4 t / ri 4 ls . r / s i % / n 3 / o n th / g 4 lv 4 n i 3 in % u s tr i / s . T h / w h / n u p g r4 % v o lu m / h 4 z 4 r% o u s w 4 s t/ s u 3 h 8 ly 3om p o s itio n o 8 tr / 4 tm / n t o 8 g 4 lv 4 n i 3 s lu % g / in th / r m 4 l p l 4 s m 4 w ill p r o v i % 4s o 8 h/4vy 4n% th / % / n v ir o n m / n t % / v / lo p / % to p ilo t o r in % u s tr i 4 l /% tr / 4 tm / n t t / 3 h n i q u / w h i 3 h l4 rg / g / n / r4 t/ 8 ly 4 s h 4 n % tr / 4 tm / n t. T h / r m 4 l p l 4 s m 4 t / 3 h n o lo g y / 8 8 / 3t / x p / 3 t/ % 4 ls o g / n / r4 t/ in 8 o r m 4 tio n t h 4 t w ill h / lp s 4 8 / g u 4 r % h u m 4 n to x i 3 p o llu tio n s y st/ m to x i 3 to th / 8 ro m tr / 4 t / % p l / t / ly im m o 6 ilis / h / 4 v y m / t 4 ls . I t 8 u r th / r g 4 lv 4 n i 3 s lu % g / s . I t 4 r/ 3 o n t 4 in in g S 3 h / % u l / % W 4 s t / in M 4 l 4 y s i 4 . 5 s lu % g / s 3 4 l / to 4n% 4 g 4 in s t th / r m 4 l p l 4 s m 4 s/ rv / o / s n o t g iv / r is / to s / 3 o n % 4 r y p o llu t 4 n t m / t4 l / 4s 4 4n% o th / r r / l 4 t / % 1 .6 O r g a n is a tio n o f S tu d y T h is r / s / 4 r 3 h w o r k C h a p te r 64 3k g ro u n % 4n% 3on% is O ne u 3 t/ % th / o 8 th / r / s / 4 r 3 h . I t 3 o n s is t o 8 8 iv / in tr o % u 3 tio n : 4 ls o 3 r iti 3 4 lly 3 h 4 p t / r s 4 s 8 o llo w s : Th/ 3 h 4 p t/ r o u tlin / th / 4 im 4 n % 3o v / rs in tr o % u 3 to r y o 6 j / 3 tiv / s , th / s 3 o p / s ig n i 8 i 3 4 n 3 / o 8 th / r / s / 4 r 3 h . C h a p t e r T w o is th / lit / r 4 tu r / r / v i / w : T h / r / l / v 4 n t p r / v io u s r / s / 4 r 3 h / s to th / s tu % y t / 3 h n o lo g y 4n% its C h a p te r 4 p p li 3 4 tio n p r o 3 / % u r/ o n s 4 m p l/ % / s 3 r ip tio n is T h ree 6 4 s i 3 4 lly 8 o3us o n th / T h / p r in 3 ip l / o 8 th / r m 4 l p l 4 s m 4 t o w 4 s t / tr / 4 tm / n t. th / m / th o % o lo g y 3 o ll / 3 tio n 4 n % o 8 p ro 3/ ss 4 r/ 4 . 3 h 4 p t / r, / q u ip m / n t, o 8 r/ s/ 4 r3h : p r / p 4 r 4 tio n o 6 t 4 in / % m / th o % s o 8 T h is 8 ro m 3 h 4 p t/ r 3o v / rs K IS W IR E S % n B h% , 3 h 4 r 4 3 t / r is 4 tio n o 8 g 4 lv 4 n i 3 s lu % g / , p r o 3 / % u r / o n th / r m 4 l p l 4 s m 4 t r / 4 tm / n t o 8 g 4 lv 4 n i 3 s lu % g / in th / r m 4 l p l 4 s m 4 s y s / m . I t 4 ls o / n t 4 ils 3 h 4 r 4 3 t / r is 4 tio n o 8 g4 s/ o us C h a p t e r F o u r is r / s u lts / l4 6 o r 4 t/ % r / s u lts 4n% th / r m 4 l 3om is 3 u s s io n o 8 / x p / r im / n t % is 3 u s s io n o n p l4 s m 4 s y s t/ m , 4n% 4n% % is 3 u s s io n : T h is 4n% 4 n 4 ly s is % 3 h 4 r 4 3 t / r is 4 tio n / 88 /3t s o li % p ro % u 3 t. o8 4 p p li / % p r / s / n t r / s u lts o n / in th is r / s / 4 r 3 h . I t o 8 g 4 lv 4 n i 3 s lu % g / 3 u rr/ n t p o s itio n o 8 g 4 s / o u s p r o % u 3 ts , l / 4 3 h in g t / s t 4 n 4 ly s is 3 h 4 p t/ r 4n% 4 n 4 ly s is , 4n% % o 3 u m / n ts p r o % u 3 ts r/ s i% / n 3 / tim / o p tim is 4 tio n 4n% 4 n% on 8 ro m th / / 3 o n o m i3 o 8 th / tr / 4 tm / n t p ro 3 / s s . C h a p te r F iv e is th / im p o r t 4 n t in 8 / r / n 3 / s w / r / r / 4 3 h / % R / 3 o m m / n % 4 tio n o n 8 u tu r / C o n 3 lu s io n 64 s/ % 4n% r / 3 o m m / n % 4 tio n : o n th / r / s u lts w o r k w 4 s s u g g / s t/ % . 6 4n% th / % In th is 3 h 4 p t/ r is 3 u s s io n . P o s s i 6 l / REFERENCES A 6 % u ll 4 h i, M . E .A 6 u H 4 s s 4 n , M . A .Z 4 in o n - N o o r , Z . In t/ g r4 t/ % v o l 4 til / 4 ir o rg 4 n i3 D / s 4 lin 4 tio n A 8 8 4 m , A . C. 4m s tr ip p in g 4n% 4n% o x i 3 illin 3om 4n% 4n% I 6 r 4 h im , R . K . (2 0 1 6 ). n o n - th / r m 4 l p l 4 s m 4 s y s t / m poun% s 8 ro m w 4 st/ w 4 t/ r: 8or th / tr / 4 tm / n t o 8 s t 4 tis ti 3 4 l o p tim iz 4 tio n . W 4 t / r T r / 4 tm / n t, 5 7 (3 4 ), 1 6 0 6 6 -1 6 0 7 7 . C h 4 u % h u r i, M . (2 0 1 4 ). O p tim iz 4 tio n o 8 F / n to n tr / 4 tm / n t o 8 4n% 3 lo x 4 3 illin 4 n ti 6 io ti 3 4qu/ous s o lu tio n . D / s 4 lin 4 tio n 4n% W 4 t / r T r / 4 tm / n t, 5 2 ( 1 0 - 1 2 ) , 1 8 7 8 -1 8 8 4 . A G A . (2 0 1 1 ). Z i n 3 3 o 4 tin g : A C o m p 4 r 4 tiv / A n 4 ly s is o 8 P r o 3 / s s 4n% P / r8 o rm 4 n 3/ C h 4 r 4 3 t / r is ti 3 s . A m / ri 3 4 : A m / r i 3 4 n G 4 lv 4 n iz / r s A s s o 3 i 4 tio n . A h m 4 % ip o u r r o u % p o s h t, M .F 4 ll 4 h i 4 r / z o u % 4 r , E .Y u s o 8 , N . M . A p p li 3 4 tio n o8 / l / 3 tr o s p in n in g r/ sp o n s/ p r o 3 / s s to su r8 4 3/ 8 4 6 ri3 4 t/ n 4 n o 8 i 6 / r s . M 4 t / r i 4 ls S 3 i / n 3 / 4n% m / th o % o lo g y in ( 8 / r r o 8 lu i % /p o ly v in y l I % r is , A . (2 0 1 5 ). o p tim iz 4 tio n 4 l 3 o h o l) o8 m 4 g n / ti 3 E n g in / / r in g : C , 5 0 , 2 3 4 -2 4 1 . A l- M 4 y m 4 n , S .I 6 r 4 h im , A .A 6 % u ll 4 h , A .I m / % , G . 8 ly 4 s h 8 r o m 4n% 4n% S 4 u % , B . (2 0 1 7 ) . T r / 4 tm / n t o 8 p o w / r p l 4 n ts u s in g th / r m 4 l p l 4 s m 4 . B / i ls t / in J. N 4 n o t / 3 h n o l., 8 , 1 0 4 3 -1 0 4 8 . A lv im - F / r r 4 z , M . C . 4n% m 4n4g/m /nt o 8 A 8 o n s o , S. A . (2 0 0 5 ) . I n 3 in / r 4 tio n o 8 h / 4 lth 3 4 r / w 4 s t / s : 4 tm o s p h / ri3 /m is s io n s t h r o u g h w 4 s t / s / g r / g 4 tio n . W 4 s t / M 4 n 4 g , 2 5 (6 ) , 6 3 8 -6 4 8 . A m r 4 t / , S .A k r / t 3 h / , D . E .I n n o 3 / n t, C . 3 4 l3 4 r/ o u s so il % 4n% / 4 , u r in g E D T A - / n h 4 n 3 / % P . (2 0 0 5 ). R / m o v 4 l o 8 P 6 / l / 3 tr o k in / ti 3 / x tr 4 3 tio n . 8 ro m 4 S 3 i/ n 3 / o 8 T h / T o t 4 l E n v ir o n m / n t, 3 4 9 ( 1 ) , 5 6 -6 6 . A n % r / , R .P in to , F .F r 4 n 3 o , C .D i 4 s , M .G u ly u r tlu , I.M 4 to s , M . A . A . (2 0 0 5 ) . F lu i % is / % 6/% 3 o - g 4 s i 8 i 3 4 tio n o8 3o4 l 4n% 4n% C 4 6 r it 4 , I. o liv / o il in % u s tr y w 4 s t / s . F u / l, 8 4 ( 1 2 - 1 3 ) , 1 6 3 5 -1 6 4 4 . A n % r / o l 4 , F .B 4 r 6 i / r i, L .B o n % io li, F .C 4 n n io , M .F / r r 4 r i, A . S y n th / s is o8 3h ro m iu m 3 o n t 4 in in g p ig m / n ts 4n% 8 ro m L 4 n 3 / llo tti, I. (2 0 0 8 ). 3h ro m s lu % g / s . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 5 6 (1 ), 4 6 6 -4 7 1 . 133 iu m g 4 lv 4 n i 3 A ny4 /g6un4 m , F. N. C. (2 0 1 4 ). H 4 z 4 r% o u s W 4 s t/ V itr i 8 i 3 4 tio n 6y P l4 s m 4 G 4 s i 8 i 3 4 tio n P r o 3 / s s . O S R J o u r n 4 l o 8 E n v ir o n m / n t 4 l S 3 i / n 3 / , T o x i 3 o lo g y 4n% F o o % T / 3 h n o lo g y ( I O S R - J E S T F T ) , 8 (3 ), 1 5 -1 9 . A u 3 i / llo , O . 4n% F l 4 m m , L . D . (1 9 8 9 ) . P l 4 s m 4 D i 4 g n o s ti 3 s , P l 4 s m 4 - m 4 t / r i 4 ls I n t / r 4 3 tio n s V o l. v o l. 1. B 4 / k , K .K im , D . H .P 4 r k , S. W .R y u , B . G .B 4 tj 4 r g 4 l, T . E l / 3 tr o ly t / 3 o n t4 m 3on% itio n in g - / n h 4 n 3 / % / l / 3 tr o k in / ti 3 4n% Y 4 n g , J. S. (2 0 0 9 ). r / m / % i 4 tio n o8 4 rs / n i3 - in 4 t / % m in / t 4 ilin g . J H 4 z 4 r % M 4 t / r , 1 6 1 (1 ), 4 5 7 -4 6 2 . B 4 jp 4 i, P . (2 0 1 4 ). M 4 n 4 g / m / n t o 8 P u lp 4n% P 4 p / r M ill W 4 s t / : S p r in g / r I n t / r n 4 tio n 4 l P u 6 lis h in g . B 4 r 4 k 4 t, M . A . (2 0 1 1 ). N / w T r / n % s in R / m o v in g H / 4 v y M / t 4 ls 8 ro m I n % u s tr i 4 l W 4 s t / w 4 t / r . A r 4 6 i 4 n J o u r n 4 l o 8 C h / m is tr y , 4 (4 ) , 3 6 1 -3 7 7 . B 4 s h ir , M . J. K .A m r , S. S. A .A z iz , S. Q .A u n , N . C . W 4 s t/ w 4 t/ r tr / 4 tm / n t m / th o % o lo g y 3om (R S M ) p ro 3/ ss/ s o p tim iz 4 tio n 3om w ith p 4 r 4 tiv / s tu % y . M i % % p 4 r/ % 4n% u s in g 3 o n v / n tio n 4 l S / th u p 4 th i, S. (2 0 1 5 ). r/ sp o n s/ m / th o % s : su r8 4 3/ r/ v i/ w 4n% l / - E 4 s t J o u r n 4 l o 8 S 3 i / n ti 8 i 3 R / s / 4 r 3 h , 2 3 ( 2 ) , 2 4 4 ­ 252. B / % n 4 r ik , V .V o n % r u s k 4 , M . g 4 lv 4 n i 3 s lu % g / s 6y 4n% K o u tn y , M . (2 0 0 5 ). S t 4 6 iliz 4 tio n /s o li % i 8 i 3 4 tio n o 8 4 s p h 4 lt /m u ls io n s . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 2 2 (1 ), 1 3 9 -1 4 5 . B / n % / r , O .S 3 h r o / t / r , R .G 4 r 3 i 4 , M . 4n% S z / n t / , R . (1 9 9 8 ). T r / 4 tin g / l / 3 tr o p l 4 tin g r / s i % u / s w ith th / r m 4 l p l 4 s m 4 s . J O M , 5 0 (7 ), 3 2 -3 5 . B / z / r r 4 , M . A .S 4 n t / lli, R . E .O liv / ir 4 , E . P .V ill 4 r , L . S. R / s p o n s / s u r 8 4 3 / m / th o % o lo g y ( R S M ) 3h/m 4s 4 to o l 4n% 8or E s 3 4 l / ir 4 , L . A . (2 0 0 8 ). o p tim iz 4 tio n in 4 n 4 ly ti 3 4 l is tr y . T 4 l 4 n t 4 , 7 6 (5 ) , 9 6 5 -9 7 7 . B h 4 r g 4 v 4 , P .G u p t 4 , N .V 4 ts , S. 4n% G o / l, R . (2 0 1 8 ). H / 4 lth I s s u / s 4n% H /4vy M / t 4 ls . A u s tin J E n v i r o n T o x i 3 o l., 3 (1 ), 1-7. B i 4 n 3 h in i, A .B o n 8 ig lio li, L .P / ll / g r in i, M . % r y in g p ro 3/ ss in t / g r 4 tio n w ith 4n% 4 S 4 3 3 4 n i, C . (2 0 1 5 ) . S / w 4 g / s lu % g / w 4 s t / - to - / n / r g y pow /r p l 4 n t. W 4 s t/ M 4 n 4 g / , 4 2 , 1 5 9 -1 6 5 . B i / n , J .C / l 4 r y , P .M o r z y k , B .S o 6 i k - S z % t y s / k , J. 4% % itiv / s on h/ 4 vy 4n% m / t 4 l im m o 6 iliz 4 tio n W y s t 4 ls k 4 , K . (2 0 1 3 ). E 8 8 / 3 t o 8 % u r in g v itr i 8 i 3 4 ti o n s / w 4 g / s lu % g / . E n v i r o n m / n t P r o t / 3 tio n E n g in / / r in g , 3 9 (2 ), 3 3 --4 0 . 1 34 o 8 t4 n n / ry B in g , G .Y i, D .Y u 4 n y i, S o li % i 8 i 3 4 tio n S o li % Y .S w / / , N ., 4n% T Q i 4 n n i, L . 4n% W / iz h o n g , Y. (2 0 1 7 ). B io to x i 3 ity A s s / s s m / n t o 8 T h / r m 4 lly T r / 4 t / % M u n i 3 ip 4 l W 4 s t / I n 3 in / r 4 tio n (M S W I ) F ly A s h . In t. J. E n v ir o n . R / s . P u 6 li 3 H / 4 lth , 1 4 (6 ), 1 -1 0 . B is w 4 jit, R . (2 0 1 2 ). T h / r m 4 l p l 4 s m 4 tr / 4 tm / n t o 8 m o 6 il / p h o n / w 4 s t / u n % / r r / % u 3 / % 3on% B o r o w s k i, itio n . I n t / r n 4 tio n 4 l J o u r n 4 l o 8 E n v ir o n m / n t 4 l S 3 i / n 3 / s , 2. N o . 4 (4 ), 1-8. G . (2 0 1 5 ). U s in g V itr i 8 i 3 4 tio n 8or S/w 4g/ S lu % g / C o m 6 u s tio n A sh D is p o s 4 l P o l. J. E n v ir o n . S tu % ., 2 4 (5 ) , 1 8 8 9 -1 8 9 6 . B o u lo s , M . I. (1 9 9 1 ) . T h / r m 4 l p l 4 s m 4 p r o 3 / s s in g . I E E E T r 4 n s P l 4 s m 4 3 19, 1 0 7 8 ­ 1089. B r 4 % l, H . B . (2 0 0 5 ). S o u r 3 / s E n v ir o n m / n t. 4n% D / p 4 rtm / n t o r ig in o 8 h / 4 v y m / t 4 ls H / 4 v y m / t 4 ls in th / o 8 E n v ir o n m / n t 4 l E n g in / / r in g , U n iv / r s ity o8 A p p li / % S 3 i / n 3 / s T ri / r, U m w / lt- C 4 m p u s B ir k / n 8 / l % . B r 4 % l / y , N . (2 0 0 7 ). T h / r / s p o n s / s u r 8 4 3 / m / th o % o lo g y . ( M 4 s t / r o 8 S 3 i / n 3 / ), I n % i 4 n 4 U n iv / r s ity S o u th B / n % . B r u n n / r , C . R . (1 9 8 9 ). I n % u s tr i 4 l s lu % g / w 4 s t / in 3 in / r 4 tio n . E n v ir o n m / n t 4 l P r o g r / s s , 8 (3 ), 1 6 3 -1 6 6 . B y u n , Y .M o o h y u n , C .S o o n , M . H . 4n% J4 / w o o , C. (2 0 1 1 ). T h / rm 4 l P l4 s m 4 G 4 s i 8 i 3 4 tio n o 8 M u n i 3 ip 4 l S o li % W 4 s t / (M S W ). B y u n , Y .N 4 m k u n g , W .C h o , M .C h u n g , J. W .K im , Y .L / / , J. H .L / / , C . 4n% H w 4 n g , S. M . (2 0 1 0 ). D / m o n s tr 4 ti o n o 8 th / r m 4 l p l 4 s m 4 g 4 s i 8 i 3 4 tio n /v itr i 8 i 3 4 tio n m u n i 3 ip 4 l s o li % w 4 s t / tr / 4 tm / n t. E n v ir o n m / n t 4 l S 3 i/ n 3 / & 8or T / 3 h n o lo g y , 4 4 ( 1 7 ) , 6 6 8 0 -6 6 8 4 . C 4 r t/ r , G . W . 4n% T s 4 n g 4 r is , A . (1 9 9 4 ). M u n i 3 ip 4 l s o li % w 4 s t / % is p o s 4 l p ro 3 / s s : G o o g l / P 4 t / n ts . C 4 r t/ r , G . W . 4n% T s 4 n g 4 r is , A . V . (1 9 9 5 ). P l 4 s m 4 G 4 s i 8 i 3 4 tio n o 8 M u n i 3 ip 4 l S o li % W 4 s t/ P 4 p / r p r/ s / n t/ % 4n% 4 p p li 3 4 tio n s , 4t th / E n v ir o n m / n t 4 l t / 3 h n o lo g i / s : p l 4 s m 4 s y s t / m s G / o r g i 4 I n s titu t / o 8 T / 3 h n o lo g y / U n iv / r s ity o 8 B o r % C / % z y n s k 4 , K .K o l 4 3 in s k i, Z .I z y % o r 3 z y k , M . v itr i 8 i 3 4 ti o n o 8 w 4 s t/ S y m p o s iu m . C / n tr / C / l 4 ry , P. 4n% 8or in 3 in / r 4 t o r 4n% 4 s h / s ,in : /4ux I. S r o 3 z y n s k i, W . (1 9 9 9 ) . P l 4 s m 4 I n t / r n 4 tio n 4 l A sh U tiliz 4 tio n A p p li / % E n / r g y R / s / 4 r 3 h , U n iv / r s ity o 8 K / n tu 3 k y . S o 6 ik - S z o lty s / k , J. (2 0 1 4 ) . V itr i 8 i 3 4 tio n 4s 4n 4 lt / r n 4 tiv / l 4 n % 8 illin g o 8 t 4 n n / r y s / w 4 g / s lu % g / . W 4 s t / M 4 n 4 g , 3 4 (1 2 ) , 2 5 2 0 - 2 5 2 7 . 135 to C / r q u / ir 4 , N .V 4 n % / n s t / / n % 4 m , C .B 4 r o n n / t, J. M . m / t 4 ls v o l 4 tility E n v ir o n . E n g . C h 4 n g , J. S .L i, O . L . % / t / n tio n % 3 i., 4n% u r in g th / r m 4 l p l4 s m 4 G iro l % , C . (2 0 0 4 ). H / 4 v y v itr i 8 i 3 4 ti o n o8 m in / r 4 l w 4 s t/ . 21, 8 3 -9 2 . G u o , Y . (2 0 0 8 ). T h / r m 4 l p l 4 s m 4 tr / 4 tm / n t o 8 s to r m w 4 t / r p o n % s lu % g / . J o u r n 4 l o 8 p u r / C h 4 n g m in g , D .C h 4 o , S .G o n g , X .T in g , W . 8or 4n% m / t 4 ls r / 3 o v / r y 8 ro m 4n% 4n% 4 p p li / % 3h/ m is tr y , 8 0 , 1 9 9 3 -2 0 0 2 . X i 4 n g / , W . (2 0 1 8 ) . P l 4 s m 4 m / th o % s m / t 4 l - 3 o n t 4 i n i n g w 4 s t / . W 4 s t / M 4 n 4 g / m / n t, 7 7 , 3 7 3 -3 8 7 . C h 4 r lo t / / , E . ( 1 9 9 2 ) A n 4 n / 3 to % 4 l h is to r y o 8 th / g 4 lv 4 n iz in g in % u s tr y . A m / r i 3 4 n G 4 lv 4 n iz / r s A s s o 3 i 4 tio n . C h i 6 u ik / , G . U . P l 4 n ts 4n% O 6 io r 4 , S. C . (2 0 1 4 ). H / 4 v y M / t 4 l P o ll u t / % 4n% B io r / m / % i 4 ti o n M / th o % s . A p p li / % 4n% S o ils: E 8 8 / 3 t o n E n v ir o n m / n t 4 l S o il S 3 i/ n 3 / , 2 0 1 4 , C h o i, S .L i, T .W 4 t 4 n 4 6 / , T. 4n% N 4 k 4 y 4 m 4 , T . (2 0 1 3 ). N u m / r i 3 4 l A n 4 ly s is o 8 T / m p / r 4 tu r / D is tr i 6 u tio n in th / L o n g D C A r 3 T h / r m 4 l P l 4 s m 4 8or W 4 s t/ T r / 4 tm / n t. J o u r n 4 l o 8 C h / m i 3 4 l E n g i n / / r in g o 8 J 4 p 4 n , 4 6 ( 3 ) , 2 0 1 -2 0 8 . C h o i, S. 4n% W 4 t 4 n 4 6 / , T . (2 0 1 2 ) . D / 3 o m p o s itio n o 8 1 -D / 3 4 n o l E m u ls io n 6y W 4 t/ r T h / r m 4 l P l 4 s m 4 J / t. I E E E T r 4 n s 4 3 tio n s O n P l 4 s m 4 S 3 i / n 3 / , 4 0 (1 1 ) . C h u n - T / h , L .W (2 0 0 7 ) . / n - J h y , L .K u o -L in , H .S h / n g - F V itr i 8 i 3 4 tio n o 8 C h r o m iu m / n g, F. 4n% E l / 3 tr o p l 4 tin g Y i-C h i S lu % g / . / h, L. E n v ir o n . S 3 i. T / 3 h n o l.( 4 1 ) , 2 9 5 0 -2 9 5 6 . C o n / s 4 , J. A .M 4 r 3 ill 4 , A .M o r 4 l, R .M o r / n o - C 4 s / ll / s , J. 4n% P / r / z - E s p in o s 4 , A . (1 9 9 8 ) . E v o l u tio n o 8 g 4 s / s in th / p r im 4 r y p y r o ly s is o 8 % i8 8 / r/ n t s / w 4 g / s lu % g / s . T h / r m o 3 h im . A 3 t 4 , 3 1 3 (1 ) , 6 3 -7 3 . C o r / ll 4 , J. 4n% F 4 t/ 4n% T o l / % o , J. M . (2 0 0 0 ). I n 3 in / r 4 tio n o 8 % o p / % s lu % g / s in 8 lu i % iz / % p 4 r titio n in g o 8 s ix t 4 r g / t / % h / 4 v y m / t 4 ls . I. P il o t p l 4 n t u s / % 6/ % 4n% r / s u lts . J H 4 z 4 r % M 4 t / r , 8 0 ( 1 - 3 ) , 8 1 -1 0 5 . C u64 s, A. L. V .% / M / % / ir o s M 4 3h4 % o, F .M 4 g n 4 g o , R . F .M o / 3 k / , E . H . S. I n / r tiz 4 tio n o 8 h / 4 v y M .% 4n% / M G on / % / ir o s 9 m / t 4 ls p r / s / n t in g 4 lv 4 n i 3 4 lv / z M 4 3h4 % o, % / s lu % g / S o u z 4 , I. (2 0 1 4 4 ). 6y DC p l 4 s m 4 . E n v ir o n m / n t 4 l S 3 i / n 3 / & T / 3 h n o lo g y , 4 8 ( 5 ) , 2 8 5 3 - 2 8 6 1 . 1 36 M .G r o s s , th / r m 4 l . C u 6 4 s , A . L . V .M 4 3 h 4 % o , M . D .- M .M E . H . S .F i / % l / r , H . D . 6 4 tt / r i / s 6y 4n% 4 3h4 % o , M . D .- M .D u tr 4 , A . R . D .- A .M o / 3 k / , B u / n o , P . (2 0 1 5 4 ). F in 4 l tr / 4 tm / n t o 8 s p / n t th / r m 4 l p l 4 s m 4 . J o u r n 4 l o 8 E n v ir o n m / n t 4 l M 4 n 4 g / m / n t, 1 5 9 , 2 0 2 -2 0 8 . C u 6 4 s , A . L . V .M 4 3 h 4 % o , M . D .- M .M F .M o / 3 k / , E . H . S. 4n% 4 3h4 % o , M . D .- M .G r o s s , F .M 4 g n 4 g o , R . D / - S o u z 4 , I. G . (2 0 1 4 6 ) . I n / r tiz 4 tio n o 8 H / 4 v y M / t 4 ls P r / s / n t in G 4 lv 4 n i 3 S lu % g / 6y D C T h / r m 4 l P l 4 s m 4 . E n v ir o n m / n t 4 l S 3 i / n 3 / & T / 3 h n o lo g y , 4 8 ( 5 ) , 2 8 5 3 -2 8 6 1 C u 6 4 s , A . L . V .M 4 3 h 4 % o , M . M .M S .F i / % l / r , H . D . 4n% 4 3h4 % o , M . M .D u tr 4 , A . R . A .M o / 3 k / , E . H . B u / n o , P . (2 0 1 5 6 ) . F in 4 l tr / 4 tm / n t o 8 s p / n t 6 4 tt / r i / s 6 y th / r m 4 l p l 4 s m 4 . J o u r n 4 l o 8 E n v ir o n m / n t 4 l M 4 n 4 g / m / n t, 1 5 9 ( S u p p l / m / n t C ), 2 0 2 -2 0 8 . D / / g 4 n , D .C h 4 p m 4 n , C .I s m 4 il, S. A .W is / , M . L . H . 4n% L y , H . (2 0 0 6 ). T h / th / r m 4 l tr / 4 tm / n t o 8 h 4 z 4 r % o u s w 4 s t / s m 4 t / r i 4 ls u s in g P l 4 s m 4 A r 3 t / 3 h n o lo g y , in: IM /3hE C o n 8 / r/ n 3/ . I n 3 / n tiv / s 4n% D / liv / r in g I n 8 r 4 s tr u 3 tu r / I M W 4 s t/ / 3hE S o lu tio n s — B 4 l 4 n 3 in g T 4 rg / ts , L o n % o n , 9. D O E . (2 0 0 5 ). E n v ir o n m / n t 4 l Q u 4 lity ( S 3 h / % u l / W 4 s t / s ) R / g u l 4 tio n 2 0 0 5 M 4 l 4 y s i 4 : D / p 4 r t m / n t o 8 E n v ir o n m / n t, M 4 l 4 y s i 4 . D O E . (2 0 0 9 ) . E n v ir o n m / n t 4 l Q u 4 lity ( 3 o n tr o l o 8 p o llu tio n s t 4 tio n 4n% 8 ro m s o li % w 4 s t / tr 4 n s 8 / r l 4 n % 8 ill) R / g u l 4 tio n , u n % / r M 4 l 4 y s i 4 E n v ir o n m / n t 4 l Q u 4 lity A 3 t 1974. D o g r u , M .M i % illi, A . u s in g 4 4n% th r o 4 t / % % H o w 4 r th , C . R . (2 0 0 2 ). G 4 s i 8 i 3 4 tio n o 8 s / w 4 g / s lu % g / o w n % r4 8 t g 4 s i8 i/ r 4n% u n 3 / r t 4 in ty 4 n 4 ly s is . F u / l P r o 3 / s s in g T / 3 h n o lo g y , 7 5 (1 ), 5 5 -8 2 . D o n 4 l % , R . M . (2 0 0 0 ) . w 4 s t / in 3 in / r 4 tio n 4n% p u 6 li 3 h / 4 lth . 3 o n s titu tio n 4v/nu/, N / w Y o rk , W 4 s h in g to n D C : N 4 tio n 4 l A 3 4 % / m y p r / s s . D u 3h 4 rm / , C. 4n% T h / m / lis , N . ( 2 0 1 0 , M 4 y 1 1 -1 3 , 2 0 1 0 ). A n 4 ly s is o 8 T h / r m 4 l P l 4 s m 4 - A s s is t / % W 4 s t / - to E n / r g y P r o 3 / s s / s . P 4 p / r p r / s / n t / % A n n u 4 l N o r th A m / ri3 4 n W 4 s t / - to - E n / r g y C o n 8 / r/ n 3/ , 4t th / 1 8 th O r l 4 n % o , F lo r i % 4 , U SA . D u r / t, A .M 4 r / 3 h 4 l, F . G4s (S N G ) 4n% F r i / % li, C . (2 0 0 5 ). P r o 3 / s s p r o % u 3 tio n u s in g w oo% P r o % u 3 tio n , 1 3 (1 5 ), 1 4 3 4 -1 4 4 6 . 1 37 % / s ig n g 4 s i 8 i 3 4 tio n . o 8 S y n th / ti 3 N 4 tu r 4 l Jo u rn 4 l o8 C l/ 4 n / r E m in / , E . O .C / m 4 l, E . G .S in 4 n , G .H u s / y in , K . O .N 4 im , S .S / r % 4 r , A . ( 2 0 1 3 ) . C o m p 4 r 4 tiv / m / t 4 l (C u , N i, Z n , to t 4 l C r, g 4 lv 4 n i 3 s lu % g / 6y 4n% 4n% N ilg u n , B . F / ) r/ m o v 4 l 8 ro m m o l 4 s s / s h y % r o ly s 4 t / . J C h / m T / 3 h n o l B io t / 3 h n o l, 8 8 , 2 0 4 6 -2 0 5 3 . F 4 k h r/ % in / , O .A h m / % , K . % 4n% J / 4 n M 4 r i / , C . (2 0 0 9 ). P r o % u 3 ti o n U s i n g A tm o s p h / r i 3 N o n - th / r m 4 l P l 4 s m 4 . P l 4 s m 4 C h / m is tr y 8 ro m P ro p 4 n / 4n% P l4 s m 4 P r o 3 / s s in g , S p r in g / r V / r l 4 g , 2 9 , 1 1 9 -1 3 0 . F 4 ll 4 h i 4 r / z o u % 4 r , E .A h m 4 % ip o u r r o u % p o s h t, M .Y u s o 8 , N . M .I % r is , A . N. H. A. (2 0 1 7 ) . 3D ( T P U ) /P o ly - l- l 4 3 ti 3 B io 8 4 6 r i 3 4 t io n A 3 i% M 4 g h / m it / ( y - F / 2 O 3 ) (P L L A ) 8or o8 4n% T h / r m o p l 4 s ti 3 E l / 3 tr o s p u n N g 4 % im 4 n , P o ly u r / th 4 n / N 4 n o 8 i6 / rs C o n t 4 in in g T is s u / E n g i n / / r in g A o r ti 3 H / 4 r t V 4 lv / . P o ly m / r s , 9 (1 1 ) , 5 8 4 . F 4 s h o l 4 , M .N g o l / - J / m / , V . 4n% B 4 6 4 lo l 4 , O . (2 0 1 6 ) . H / 4 v y m / t 4 l p o llu tio n g o l % m in / s : E n v ir o n m / n t 4 l / 8 8 / 3 ts 4 n % 6 4 3 t/ ri4 l s tr 4 t / g i / s 8or 8 ro m r / s is t 4 n 3 / . In t. J. E n v ir o n . R / s . P u 6 li 3 H / 4 lth ., 13. F r 4 n 3 o , C .P in to , F .G u ly u r tlu , I. in 8 lu / n 3 in g t h / F r/ % / ri3 , 6 io m 4 s s F .C h r is to p h / , G 4 s i 8 i 3 4 tio n C 4 6 r it 4 , I. (2 0 0 3 ) . T h / s tu % y o 8 r / 4 3 tio n s s t / 4 m g 4 s i 8 i 3 4 tio n p ro 3 / s s . F u / l, 8 2 (7 ), 8 3 5 -8 4 2 . R .V 4 n % 6y 4n% - J u li / n , 4% T h / rm 4 l R. P l4 s m 4 : A 4n% L 4 u r / n t, R / v i/ w . F. W 4 s t/ (2 0 1 3 ). 4n% W 4 s t/ B io m 4 s s V 4 lo r iz 4 tio n , 4 (3 ) , 4 2 1 -4 3 9 . F ru g i/ r, P .G ir o l % , C .M / g y , S .V 4 n % / n s t / / n % 4 m , B 4 r o n n / t, J. (2 0 0 0 ) . O E S u s / 4n% v itr i 8 i 3 4 tio n . P l 4 s m 4 C h / m is tr y C .E r s h o v - P 4 v lo v , v 4 p o r iz 4 ti o n m o % / lin g 4n% G 4 l 4 s , D .K 4 l / m 6 k i / w i 3 z , m o r p h o lo g y s lu % g / 8 ro m 4n% 8 o r 8 ly - 4 s h 4n% p l4 s m 4 S t / / l. F i r s t 4n% L 4 s t L in / o 8 4 u s tr 4 li 4 . J. 4n% S it 4 r z - P 4 l 3 z 4 k , E . l / 4 3 h 4 6 ility o 8 s / l / 3 t / % m / t 4 ls s3r/ w A. P l 4 s m 4 P r o 3 / s s in g , 2 0 , 6 5 -8 6 . G A A . (2 0 1 2 ) . T h / B 4 s i 3 s o 8 H o t D ip G 4 lv 4 n iz / % D / 8 / n 3 / . I n 1 (E % .). E. 8 4 3 to r y (2 0 1 6 ). 8 ro m P h y s i 3 o 3 h / m is tr y , p o s t- g 4 lv 4 n i z / % s / w 4 g / in L 4 n 3 u t, S E P o l 4 n % . C o n t / m p o r 4 r y T r / n % s in G / o s 3 i / n 3 / , 5 (2 ), 8 3 -9 1 . G 4 ry , W. D. (2 0 1 5 ) . C o n tin o u s hot % G A L V IN F O C E N T E R . A p ro r4 m m / G 4 v r il / s 3 u , D. (2 0 0 8 ) . E n / rg y E n v ir o n m / n t 4 l E n g i n / / r in g F ro m 4n% ip 8or g 4 lv 4 n iz in g - p r o 3 / s s t h / in t / r n 4 tio n 4 l z in 3 B io m 4 s s in P u lp 4n% 4n% 4 s s o 3 i 4 tio n . P4p/r M 4 n 4 g / m / n t J o u r n 4 l, 7 (5 ), 5 3 7 -5 4 6 . 138 p r o % u 3 ts . M ills . G o m / z , E .R 4 n i, D . A .C h / / s / m 4 n , C . R .D / / g 4 n , D .W is / , M . ( 2 0 0 9 ) . T h / r m 4 l p l 4 s m 4 t / 3 h n o lo g y 8or 4n% B o 3 3 4 3 3 in i, A . R . th / tr / 4 tm / n t o 8 w 4 s t / s : 3 riti 3 4 l 4 r / v i / w . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 6 1 (2 ), 6 1 4 -6 2 6 . G r 4 y , L . (2 0 1 4 ). P l 4 s m 4 G 4 s i 8 i 3 4 tio n M u n i 3 ip 4 l S o li % W 4 s t / : S o li % 4s 4n% V i 4 6 l / W 4 s t / - to - E n / r g y T r / 4 tm / n t o 8 4 H 4 z 4 r % o u s W 4 s t / P r / v / n tio n 4n% C o n tro l E n g in / / r in g . H 4 ji, A .M o u s 4 v i- S h o u s h t 4 r i, A .M 4 z 4 h / r i, F . o p tim iz / % 4n% T 4 6 4 t 4 6 4 / y 4 n , S. E . (2 0 1 6 ) . R S M s / l 8 - 3 l / 4 n in g n 4 n o - 8 in is h in g o n p o ly / s t / r /w o o l 8 4 6 ri3 p r / tr / 4 t / % w ith o x y g / n p l 4 s m 4 . T h / J o u r n 4 l o 8 T h / T / x til / I n s titu t / , 1 0 7 (8 ), 9 8 5 -9 9 4 . H 4 ji, A . S ., A . M . g r 4 8 tin g M 4 3ro m 4n% o8 A 6 % o u s s , M . . (2 0 1 4 ) . R S M o p tim iz 4 tio n o 8 p l 4 s m 4 in iti 4 t / % 4 3 r y li 3 4 3 i% o n to p o ly p r o p y l / n / nonw ov/n. Jo u rn 4 l o8 o l / 3 u l 4 r S 3 i / n 3 / , 5 1 (1 ), 7 6 -8 7 . H 4 u g s t/ n , K . E . 4 sh 8 ro m 4n% G u s t 4 v s o n , B . (2 0 0 0 ). E n v ir o n m / n t 4 l p r o p / r ti / s o 8 v itr i 8 i / % h 4 z4 r% o u s 4n% 8 y m u n i 3 ip 4 l w 4 s t / in 3 in / r 4 tio n . W 4 s t / M 4 n 4 g / ( 2 0 ) , ( 2 ­ 3 ). H / , Y . D .Z h 4 i, Y . B .L i, C . T .Y 4 n g , F .C h / n , L .F 4 n , X . P .P / n g , W . F . (2 0 1 0 ). T h / 4t % H / 6 / r lin , J. 8 4 t/ o 8 Cu, Z n, P6 4n% C% % 4n% Fu, Z. M . u r in g th / p y r o ly s is o 8 s / w 4 g / s lu % g / i 8 8 / r / n t t / m p / r 4 tu r / s . E n v ir o n m / n t 4 l T / 3 h n o lo g y , 3 1 (5 ), 5 6 7 -5 7 4 . 4n% M u r p h y , A . B . (2 0 0 8 ) . T o p i 3 4 l r / v i / w :T h / r m 4 l p l 4 s m 4 w 4 s t / tr / 4 tm / n t. J o u r n 4 l o 8 A p p li / % p h y s i 3 s , 4 1 , 1 -2 0. H o lg / r , E .H ir o 8 u m i, S .T o s h ih ik o , M .N o 6 u to s h i, T. tr / 4 tm / n t p r o 3 / s s / s 8or 4n% L , A . (2 0 0 1 ). S 4 / o 8 th / 4 rt m u n i 3 ip 4 l s o li % w 4 s t / in 3 in / r 4 tio n r / s i % u / s in J 4 p 4 n . E n v ir o n m / n t 4 l S 3 i / n 3 / & T / 3 h n o lo g y , 3 5 (7 ), 1 5 3 1 -1 5 3 6 H r 4 6 o v s k y , M . (2 0 0 2 ). G / n / r 4 tio n o 8 th / r m 4 l p l 4 s m 4 s in liq u i % - s t 4 6 iliz / % % 3 -4 r3 H u4ng, H. 4n% h y 6 ri% to r 3 h / s . P u r / A p p l. C h / m , 7 4 , 4 2 9 -4 3 3 . 4n% T 4 n g , L . (2 0 0 7 ). T r / 4 tm / n t o 8 o r g 4 n i 3 w 4 s t / u s in g th / r m 4 l p l 4 s m 4 p y r o ly s is t / 3 h n o lo g y . E n / r g y C o n v / r s io n H u 4 n g , H .T 4 n g , L . 4n% 4n% M 4 n 4 g / m / n t, 4 8 , 1 3 3 1 -1 3 3 7 . W u , C . Z . (2 0 0 3 ) . C h 4 r 4 3 t / r iz 4 tio n o 8 g 4 s / o u s p r o % u 3 t 8 r o m th / r m 4 l p l 4 s m 4 p y r o ly s is o 8 w 4 s t / ru 6 6 / r. E n v i r o n 3  4n% s o li % T / 3 h n o l, 3 7 (1 9 ) , 4 4 6 3 - 4 4 6 7 . I A E A - T E C D O C . (2 0 0 6 ). A p p li 3 4 tio n o 8 T h / r m 4 l T / 3 h n o lo g i / s 8or P r o 3 / s s in g o 8 R 4 % i o 4 3 tiv / W 4 s t / . W 4 s t / T / 3 h n o lo g y S / 3 tio n , I n t / r n 4 tio n 4 l A to m i 3 E n / r g y A g/ n3y. 1 39 In 4 64 , T. 4n% Iw 4 o , T. (2 0 0 0 ) . T r / 4 tm / n t o 8 w 4 s t / 6y % 3 4 r3 % is 3 h 4 r g / p l 4 s m 4 s . I E E E T r 4 n s . D i / l / 3 tr i 3 s E l / 3 tr i 3 4 l I n s u l 4 tio n , 7, 6 8 4 -6 9 2 . I n 4 6 4 , T .N 4 g 4 n o , M . 4n% E n % o , M . (1 9 9 9 ) . I n v / s tig 4 tio n o 8 p l 4 s m 4 tr / 4 tm / n t h 4 z 4 r% o u s w 4 s t/ s su 3 h 4 s 8 y 4 s h 4 n % 4 s 6 / s to s . 8or E l / 3 tr i 3 4 l E n g . J p n , 1 2 6 , 7 3 ­ 82 . Iw 4 o , T. 4n% to r 3 h Iw 4 o , T . % I n 4 6 4 , T . (2 0 0 2 ). P l 4 s m 4 l / n g th o n 4 3 . 4n% 3 h 4 r 4 3 t / r is ti 3 s o8 DC 4 rg o n p l4 s m 4 V 4 3 u u m , 6 5 (3 ) , 2 9 9 -3 0 4 . Y u m o to , M . (2 0 0 6 ). P o r t 4 6 l / is 3 h 4 r g / 8or 4 p p li 3 4 tio n w 4 s t / tr / 4 tm / n t, th / r m 4 l s p r 4 y in g T r 4 n s 4 3 tio n s o n E l / 3 tr i 3 4 l J 4 n 4 jr / h , I .R 4 z 4 , S. S. 4n% 4n% o 8 th / r m 4 l p l 4 s m 4 4n% E l / 3 tr o n i 3 E n g in / / r in g , 1 (2 ), 1 6 3 -1 7 0 . V 4 lm u n % s s o n , A . S. (2 0 1 3 ). P l 4 s m 4 g 4 s i 8 i 3 4 tio n p ro 3 / s s : 4n% E n / r g y C o n v / r s io n M 4 n 4 g / m / n t, 6 5 ( S u p p l / m / n t C ), 8 0 1 -8 0 9 . 4n% 3om p 4 r is o n w ith J i 4 , H .G 4 o , Z .M 4 , Y .Z h o n g , C .X i / , Y .Z h o u , H . p h / n o x 4 z in o n / s y n th 4 s / p r o % u 3 tio n in 4 3 s u r 8 4 3 / tr / 4 tm / n t. IE E J M o % / lin g , s im u l 4 tio n 4 p p li 3 4 tio n 4n% C ongo r/ % 6y 4n% 3 o n v / n tio n 4 l 4 ir g 4 s i 8 i 3 4 tio n . W / i, P . (2 0 1 3 ). O p tim iz 4 tio n o 8 r / s p o n s / s u r 8 4 3 / m / th o % o lo g y % / 3 o lo u r iz 4 tio n . E l / 3 tr o n i 3 4n% its Jo u rn 4 l o8 B io t / 3 h n o lo g y , 1 6 (5 ), 2 -2 . J o h n , W . K . (2 0 0 6 ). Z in 3 C o 4 tin g s : S t / / l's C o r r o s io n I n h i 6 i to r A m / r i 3 4 n G 4 lv 4 n iz / r s A s s o 3 i 4 tio n . J u n o h , H .Y ip , C . 4n% / n h 4 n 3 / 6 io g 4 s 3o n 8 / r/ n 3 / K u m 4 r 4 n , P . (2 0 1 6 ) . E 8 8 / 3 t o n C 4 (O H ) 2 p r / tr / 4 tm / n t to p r o % u 3 tio n o 8 o r g 4 n i 3 s / r / s : / 4 r th 4 n % 8oo% / n v ir o n m / n t 4 l K 4 l % 4 s , A .C 4 r 4 6 in , P .P i 3 4 r % , I .C h / v 4 li / r , P . s h ip s lu % g / o il u s in g p r/ s / n t/ % 4t p l4 s m 4 4 r3 th / IO P s 3 / n 3 / . 4n% w 4 s t/ 4t H o l 3 r o 8 t, G . (2 0 0 7 ). T r / 4 tm / n t o 8 % / s tr u 3 tio n s y s t / m (P A W D S ) . P 4 p / r th / I T 3 ’0 7 C o n 8 / r / n 3 / , P h o / n ix A Z . K 4 l % 4 s , A .T h / o % o r 4 , A . w 4 s t/ 4 w 4 s t/ . P 4 p / r p r / s / n t/ % % / s tr u 3 tio n 4n% P / t / r , T. (2 0 0 3 ). O p tim iz 4 tio n o 8 th / m 4 r in / p l 4 s m 4 t / 3 h n o lo g y . P 4 p / r p r / s / n t / % 4t th / I T 3 ’03 C o n 8 / r / n 3 / ., O r l 4 n % o , F lo r i % 4 . K 4 m o lw 4 n , T. (2 0 0 9 ) . E 8 8 / 3 ts o 8 h / 4 tin g 4n% 3opp/r % i 8 8 u s io n o n 8 / l% s p 4 r G IA L 4 6 o r 4 to r y , B 4 n g k o k . K 4 n w 4 l, R .F ., F .I q r 4 , W . o8 h/4vy 6 io 3 h / m m / t 4 ls 4n% 4n% M u h 4 m m 4 % , S. H . A . (2 0 1 7 ). P r / v 4 l / n 3 / o 8 / x p o s u r / th / i r im p 4 3 t is tr y , 1 1 9 (1 ), 1 5 7 -1 8 4 . 1 40 on h / 4 lth 3o n s/ q u / n 3/ s. C / llu l 4 r K 4 n w 4 l, R .F iz 4 , F .I q r 4 , W . / x p o su r/ 4n% o 8 h / 4 v y m / t 4 ls M uh4m m 4% , 4n% S. H . A . (2 0 1 8 ) . P r / v 4 l / n 3 / 3o n s/ q u / n 3/ s. J C / l M 4 k in o , ( th / i r im p 4 3 t o n h / 4 lth o8 B io 3 h / m , 1 1 9 , 1 5 7 -1 8 4 . K 4 to h , H .W 4 t 4 n 4 6 / , C 4 r 6 o n iz 4 tio n T .O h m o r i, H .K 4 w 4 m u r 4 , o 8 jo h k 4 s o u K. s lu % g / u s in g 4n% 6 4 t 3 h - ty p / Y. / q u ip m / n t. 2 0 0 5 ). J M 4 t/ r C y 3 l / s W 4 s t / M 4 n 4 g , 7, 5 5 -6 4 . K / z / lis , R .M / 3 iu s , V .V 4 lin 3 iu t / , V . T r / 4 tm / n t P ro 3/ ss/ s, K im , H . I. 6y 4n% E m p lo y in g 8 4n% V 4 lin 3 iu s , V . (2 0 0 4 ) . W 4 s t / P l4 s m 4 T / 3 h n o lo g y . H ig h 4n% B io m 4 s s T / 3 h n o lo g y P l4 s m 4 , 2 7 3 -2 8 2 . P 4 r k , D . W . (2 0 0 4 ) . C h 4 r 4 3 t / r is ti 3 s o 8 8 ly 4 s h /s lu % g / s l 4 g s v itr i 8 i / % th / r m 4 l p l 4 s m 4 . In % . E n g . C h / m , 1 0 (2 ), 2 3 4 -2 3 8 . K im , S .M o o n , S ., H . u s in g 4n% E nh4 n3/% K im , K . W . (2 0 0 1 ). R / m o v 4 l o 8 H / 4 v y M / t 4 ls E l / 3 tr o k in / ti 3 S o il P r o 3 / s s in g . W 4 t/ r, A ir , 8 ro m 4n% S o ils S o il P o llu tio n , 1 2 5 (1 ), 2 5 9 -2 7 2 . K im u r 4 , T .T 4 k 4 s / , K . EDTA 3om 4n% p l/ x T 4 n 4 k 4 , S. (2 0 0 7 ). C o n 3 / n tr 4 tio n o 8 3 o p p / r 4t th / p H j u n 3 t i o n 8 o rm / % in s o il 6y 4n% 4n 4 3opp/ r- / l / 3 tr o k in / ti 3 r / m / % i 4 tio n p ro 3 / s s . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 4 3 (3 ), 6 6 8 -6 7 2 . K o 6 y 4 , M .E r % / m , N . g 4 lv 4 n i 3 / l / 3 tr o % / s . 4n% r in s in g D / m ir 6 4 s , E . (2 0 1 5 ). T r / 4 tm / n t o 8 C r, N i w 4 s t/ w 4 t/ r D / s 4 lin 4 tio n 4n% 6y / l / 3 tr o 3 o 4 g u l 4 tio n p ro 3 / ss 4n% u s in g Zn 8 ro m ir o n W 4 t / r T r / 4 tm / n t, 5 6 (5 ), 1 1 9 1 -1 2 0 1 . K o g / ls 3 h 4 tz , U . (2 0 0 4 ) . A tm o s p h / r i 3 - p r / s s u r / p l 4 s m 4 t / 3 h n o lo g y . P l 4 s m 4 P h y s . C o n tr o ll / % F u s io n , 4 6 , B 6 3 - B 7 5 . K u n io , K .H ir o s h i, K .T o r u , S. 4n% K o i 3 h i, S. (1 9 7 5 ). M / th o % 8or in 3 in / r 4 tin g in % u s tr i 4 l w 4 s t 4 g / : G o o g l / P 4 t / n ts . K uo, Y .C h 4 n g , J .C h 4 n g , K .C h 4 o , C .T u 4 n , S t 4 6 iliz 4 tio n o 8 r / s i % u / s o 6 t 4 in / % 1 - T r / 4 tm / n t p 4 th o 8 m / t 4 ls in 4 8 ro m Y. 4n% C h 4 n g -C h i/ n , G. (2 0 1 0 ). th / tr / 4 tm / n t o 8 l 4 6 o r 4 to r y w 4 s t / . p 4 r t p l 4 s m 4 m / ltin g s y s t / m . J o u r n 4 l o 8 th / A ir & W 4 s t / M 4 n 4 g / m / n t A s s o 3 i 4 tio n , 6 0 (4 ), 4 2 9 -4 3 8 . K w 4 k , T .L / / , S .M 4 k / n , S .S h in , H .P 4 r k , J. 4n% Y o o , Y . D . (2 0 0 5 ) . A s tu % y o 8 g 4 s i 8 i 3 4 tio n o 8 m u n i 3 ip 4 l s o li % w 4 s t / u s in g 6 u rn / r. 4 % o u 6 l / in v / r s / % i 8 8 u s io n 8 l4 m / E n / r g y & F u / ls , 1 9 (6 ), 2 2 6 8 - 2 2 7 2 . K w 4 k , T .L / / , S .P 4 rk , J .M 4 k / n , S .Y o o , Y . D . m u n i 3 ip 4 l s o li % w 4 s t / in 4 p ilo t p l 4 n t 4n% 4n% L / / , S. (2 0 0 6 4 ). G 4 s i 8 i 3 4 tio n o 8 its im p 4 3 t o n / n v ir o n m / n t. K o r / 4 n J o u r n 4 l o 8 C h / m i 3 4 l E n g in / / r in g , 2 3 ( 6 ) , 9 5 4 -9 6 0 . 141 K w 4 k , T .M 4 k / n , S .L / / , S .P 4 rk , J .M in , B . 4 s p / 3 ts 4n% Y o o , Y . D . (2 0 0 6 6 ) . E n v ir o n m / n t 4 l o 8 g 4 s i 8 i 3 4 tio n o 8 k o r / 4 n m u n i 3 ip 4 l s o li % w 4 s t / in 4 p ilo t p l 4 n t. F u / l,, 8 5 (1 4 -1 5 ), 2 0 1 2 -2 0 1 7 . L / 4 l- Q u ir o s , E . (2 0 0 4 ) . P l 4 s m 4 p r o 3 / s s in g o 8 m u n i 3 ip 4 l s o li % w 4 s t / . B r 4 z il i 4 n J. o 8 P h y s ., 3 4 (4 B ), 1 5 8 7 -1 5 9 3 . L / s t 4 n , D .L u o , C . 4n% L i, X . (2 0 0 8 ) . T h / u s / o 8 3 h / l 4 tin g 4 g / n ts in th / r / m / % i 4 tio n o 8 m / t 4 l- 3 o n t 4 m in 4 t / % s o ils : A r / v i / w . E n v ir o n m / n t 4 l P o llu tio n , 1 5 3 (1 ), 3 ­ 13. L i, C .- T .L / / , W .- J .H u 4 n g , K .- L .F u , S .-F . 4n% L 4 i, Y .-C . (2 0 0 7 ) . V itr i 8 i 3 4 tio n o 8 C h r o m iu m E l / 3 tr o p l 4 tin g S lu % g / . E n v ir o n m / n t 4 l S 3 i / n 3 / & T / 3 h n o lo g y , L i, J .L iu , K .Y 4 n , S .L i, Y . t / 3 h n o lo g y 8or 4n% H 4 n , D . (2 0 1 6 ). A p p li 3 4 tio n o 8 th / r m 4 l p l 4 s m 4 th / tr / 4 tm / n t o 8 s o li % w 4 s t / s in C h in 4 : A n o v / r v i / w . W 4 s t / M 4 n 4 g / m / n t, 5 8 , 2 6 0 -2 6 9 . L i, O .G u o , Y .C h 4 n g , J .U r 4 s h im 4 , K . so u r3/ s 6y 4 S 4 ito , N . (2 0 1 2 ) . T r / 4 tm / n t o 8 n o n - p o in t th / r m 4 l p l 4 s m 4 s y s t / m u n % / r J P l4 s m 4 E n v iro n 3  s to r m w 4 t / r s / % im / n ts : 4 r3 4 D C p 4 rti 4 l tr 4 n s 8 / r r / % m o % / . In t T / 3 h n o l, 6 (1 ), 6 3 -6 7 . L i, O . L .G u o , Y .C h 4 n g , J. S. tr4 n s 8 / rr/ % 4n% 4n% 3om S 4 ito , N . (2 0 1 5 4 ). T h / r m 4 l p l 4 s m 4 tr / 4 tm / n t o 8 p 4 r is o n 6 / tw / / n D C n o n - tr 4 n s 8 / r r / % 4n% p 4 r ti 4 lly p l 4 s m 4 . E n v ir o n m / n t 4 l T / 3 h n o lo g y , 3 6 (1 3 ) , 1 6 7 2 -1 6 7 9 . L i, O . L .G u o , Y .C h 4 n g , J. S .U r 4 s h im 4 , K . n o n p o in t s o u r 3 / 4n% S 4 ito , N . (2 0 1 5 6 ) . A n / w p o llu tio n / s to r m w 4 t / r s lu % g / tr / 4 tm / n t 6y 4n 4 p p ro 4 3h o8 in t / g r 4 t / % th / r m 4 l p l 4 s m 4 s y s t / m . I n t / r n 4 tio n 4 l J o u r n 4 l o 8 E n v ir o n m / n t 4 l S 3 i / n 3 / 4n% T / 3 h n o lo g y , 12, 1 7 6 9 -1 7 7 8 . L in , K .- H .H s u , H .- T .K o , Y .- W .S h i / h , Z .- X . p ro % u 3t 3 h 4 r 4 3 t / r is ti 3 s o 8 6 io s lu % g / 4n% 8 ro m C h i 4 n g , H .-L . (2 0 0 9 ) . P y r o ly ti 3 th / w 4 s t / w 4 t / r tr / 4 tm / n t p l 4 n t o 8 4 p / tr o 3 h / m i 3 4 l in % u s tr y . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 7 1 (1 ), 2 0 8 -2 1 4 . L u n % s t / % t, T .S / i 8 / r t, E .A 6 r 4 m o , L .T h / lin , B .N y s tr o m , A .P / tt / r s / n , J. R. (1 9 9 8 ) . E x p / r im / n t 4 l % / s ig n 4n% o p tim iz 4 tio n . 4n% B / rg m 4 n , C h / m o m / tr i 3 s 4 n% in t / llig / n t l 4 6 o r 4 to r y s y s t / m s , 4 2 (1 ) , 3 -4 0 . M 4, W .F 4 n g , Y .C h / n , V o l 4 tiliz 4 tio n 4 sh in 4 DC 4n% 4 r3 D .C h / n , l / 4 3 h in g p l4 s m 4 G .X u , Y .S h / n g , 6 / h 4 v io r 8 u rn 4 3/ . H. 4n% Zhou, Z. (2 0 1 7 ). o 8 h / 4 v y m / t 4 ls in M S W in 3 in / r 4 tio n F u / l, 2 1 0 , 1 4 5 -1 5 3 . 1 42 8 y M 4 h m o o % , T. 4n% t / 3 h n o lo g i / s 2 1 1 2 E llio tt, A . (2 0 0 6 ). A r / v i / w o 8 s / 3 o n % 4 r y s lu % g / r / % u 3 tio n 8or th / p u lp 4n% . M 4 l4 k 4 h m 4 % , A. 4n% Chu4n, m / th o % o lo g y to o p tim iz / % p 4 p / r in % u s tr y . W 4 t / r R / s / 4 r 3 h , 4 0 ( 1 1 ) , 2 0 9 3 ­ ig / s t / % p 4 lm o il S. Y . (2 0 1 3 ) . A p p li 3 4 tio n 3 o 4 g u l 4 tio n - 8 lo 3 3 u l 4 tio n m ill / 8 8 lu / n t u s in g 4 lu m o 8 r/ sp o n s/ tr / 4 tm / n t o 8 . su r8 4 3/ 4 n 4 / r o 6 i 3 4 lly D / s 4 lin 4 tio n 4n% W 4 t/ r T r / 4 tm / n t, 5 1 ( 3 4 - 3 6 ) , 6 7 2 9 -6 7 3 5 . M 4 r 4 n i, D .B r 4 g u g li 4 , C . M .M in in n i, G . C r, M n , N i, P 6 , 8 u rn 4 3/ . 4n% 4n% M 4 3 3 io n i, F . (2 0 0 3 ). B / h 4 v io u r o 8 Z n in s / w 4 g / s lu % g / in 3 in / r 4 tio n 6y 8 lu i % is / % %  6/% W 4 s t / M 4 n 4 g , 2 3 , 1 1 7 -1 2 4 . M 4 r i 4 , E . D . B . R . (2 0 1 1 ) . C o s t- 6 / n / 8 it m o n t/ v i% / o ; 4n% w 4 s t / to / n / rg y 4 n 4 ly s is o8 4 w 4 s t / to / n / rg y p l4 n t 8or in s m 4 ll is l 4 n % s . (M S 3 ), u n iv / r s ity o8 3 o lu m 6 i 4 , 3 o lu m 6 i 4 . M / i, D .H / , Y . L .L iu , S .Y 4 n , J. in 4n% T u , X . (2 0 1 6 ) . O p tim iz 4 tio n o 8 C O 2 C o n v / r s io n C y lin % r i 3 4 l D i / l / 3 tr i 3 B 4 r r i / r D is 3 h 4 r g / 4 E x p / r im / n ts . P l 4 s m 4 P r o 3 / s s / s 4n% % ry in g , p y r o ly s is D / s ig n o8 P o ly m / r s , 1 3 (5 ), 5 4 4 -5 5 6 . M / n / n % / z , J. A .D o m in g u / z , A .I n g u 4 n z o , M . in % u 3 / % R / 4 3 to r U s in g 4n% 4n% P is , J. J. (2 0 0 5 ) . M i 3 r o w 4 v / - g 4 s i 8 i 3 4 tio n ( M W D P G ) o 8 s / w 4 g / s lu % g / : V itr i 8 i 3 4 tio n o 8 th / s o li % r / s i % u / . J o u r n 4 l o 8 A n 4 ly ti 3 4 l 4n% A p p li / % P y r o ly s is , 7 4 ( 1 - 2 ) , 4 0 6 -4 1 2 . M itr 4 s in o v i 3 , A .P / r s h in , L .W / n , J. Z . 4n% v 4 lu 4 6 l / m / t 4 ls 8 ro m 4n% M o s t 4 g h im i, J. (2 0 1 1 ) . R / 3 o v / r y o 8 C u E - w 4 s t / u s in g th / r m 4 l p l 4 s m 4 tr / 4 tm / n t. J. m 4 t / r., 6 3 (8 ) , 2 4 -2 8 . M o h 4 i, I. 4n% S z / p v o lg y i, J. (2 0 0 5 ) . T r / 4 tm / n t o 8 p 4 r ti 3 u l 4 t / m / t 4 llu r g i 3 4 l w 4 s t / s in th / r m 4 l p l4 s m 4 s . C h / m i3 4 l E n g i n / / r in g 4n% P r o 3 / s s in g : P ro 3/ ss I n t / n s i 8 i 3 4 tio n , 4 4 (2 ) , 2 2 5 -2 2 9 . M o h 4 i, I .S z / p v o lg y i, J. W 4 s t / s in 4n 4n% K 4 r o ly , Z . /. 4. (2 0 0 1 ) . R / % u 3 tio n o 8 M / t 4 llu r g i 3 4 l R F T h / r m 4 l P l 4 s m 4 R / 4 3 to r . P l 4 s m 4 C h / m is tr y 4n% P l4 s m 4 P r o 3 / s s in g , 2 1 , 5 4 7 -5 6 3 . M o h 4 m m 4 % i, T .R 4 z m i, A . S o u th M s / p 4 r 4 tio n /% 4n% S 4 % r z 4 % / h , M . (2 0 0 4 ). D / s 4 lin 4 tio n S tr 4 t / g i / s in it / r r 4 n / 4 n C o u n tr i / s . E 8 8 / 3 t o 8 o p / r 4 tin g p 4 r 4 m / t / r s o n P 6 2 + 8 ro m w 4 s t / w 4 t / r u s in g / l / 3 tr o % i 4 ly s is . D / s 4 lin 4 tio n , 1 6 7 , 3 7 9 -3 8 5 . 143 M o u n to u r is , A .V o u ts 4 s , E . s lu % g / : P r o 3 / s s 4n% 4n% T 4 s s io s , D . (2 0 0 8 ). P l 4 s m 4 g 4 s i 8 i 3 4 tio n o 8 s / w 4 g / % / v / lo p m / n t 4n% / n / rg y o p tim iz 4 tio n . E n / r g y C o n v / r s io n M 4 n 4 g / m / n t, 4 9 ( 8 ) , 2 2 6 4 - 2 2 7 1 . M o u s t 4 k 4 s , K .F 4 tt 4 , D .M 4 l 4 m is , D / m o n s tr 4 ti o n p l4 s m 4 S .H 4 r 4 l 4 m 6 o u s , K . 4n% L o iz i % o u , M . (2 0 0 5 ). g 4 s i 8 i 3 4 tio n /v itr i 8 i 3 4 tio n s y s t/ m 8or / 8 8 / 3 tiv / h 4 z 4 r % o u s w 4 s t / tr / 4 tm / n t. J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls B 1 2 3 (2 0 0 5 ) 1 2 0 - 1 2 6 , B 1 2 3 , 1 2 0 -1 2 6 . M o u s t 4 k 4 s , K .P 4 p 4 % o p o u lo s , A .F 4 tt 4 , D .H 4 r 4 l 4 m 6 o u s , K . J. (2 0 0 3 ) . D / s ig n 4n% 3 o n s tr u 3 tio n g 4 s i 8 i 3 4 tio n /v itr i 8 i 3 4 tio n u n i t in t / r n 4 tio n 4 l 3o n 8 / r/ n 3 / on 8or o8 4n% % /m 4 L o iz i % o u , M . o n s tr 4 tio n w 4 s t / tr / 4 tm / n t. P 4 p / r p r / s / n t / % / n v ir o n m / n t 4 l s 3 i/ n 3 / 4n% 4t p l4 s m 4 th / 8 th t / 3 h n o lo g y , L / m n o s is l 4 n % g r / / 3 / . M o u s t 4 k 4 s , K .X y % is , G .M 4 l 4 m is , S .H 4 r 4 l 4 m 6 o u s , K . J. A n 4 ly s is o8 r / s u lts g 4 s i 8 i 3 4 tio n /v itr i 8 i 3 4 tio n 8 ro m u n it th / 8or 4n% o p / r 4 tio n o p tim iz in g L o iz i % o u , M . (2 0 0 8 4 ). o8 its p ilo t 4 p / r8 o rm 4 n 3/ . p l4 s m 4 Jo u rn 4 l o8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 5 1 (2 ), 4 7 3 -4 8 0 . M o u s t 4 k 4 s , K .X y % is , G .M 4 l 4 m is , S .H 4 r 4 l 4 m 6 o u s , K . J. A n 4 ly s is o8 r / s u lts g 4 s i 8 i 3 4 tio n /v itr i 8 i 3 4 tio n 8 ro m u n it th / 8or o p / r 4 tio n o p tim iz in g 4n% L o iz i % o u , M . (2 0 0 8 6 ) . o8 its p ilo t 4 p l4 s m 4 p / r8 o rm 4 n 3/ . J. o8 H 4 z 4 r % .M 4 t / r . R / s , 1 5 1 , 4 7 3 -4 8 0 . M u k h / r j / / , P . S .B h o i, B .M is h r 4 , C . R .D 4 s h , R . R .S 4 t 4 p 4 th y , B . K . K . (2 0 1 2 ). P r o % u 3 tio n o 8 P ig ir o n 8 ro m p l 4 s m 4 s m / ltin g t / 3 h n o lo g y S y m p o s iu m M / / tin g 4 n % N 4 l3 o r/ % m u % 6y J4 y 4 s4 n k 4 r, 4 p p li 3 4 tio n E x h i 6 itio n (p p . 9 9 -1 0 3 ). (2 0 0 6 ) . C o - g 4 s i 8 i 3 4 tio n o 8 S / w 4 g / S lu % g / 4n% 4n% 4n% H u4ng, W . P l 4 s ti 3 W 4 s t / s : E v 4 lu 4 tio n o 8 A p p li 3 4 tio n . J o u r n 4 l o 8 th / J 4 p 4 n I n s titu t / o 8 E n / r g y , 8 5 , 9 6 4 -9 7 0 . M u r 4 k 4 m i, o8 o n L i g h t M / t 4 ls / T M S A n n u 4 l M u r 4 k 4 m i, T .S u % 4 , T .M o u r i, S .S h ig / t 4 , J .H ir 4 t 4 , T .F u jim o r i, T . E x p / r im / n t 4n% T .S u z u k i, Y .N 4 g 4 s 4 w 4 , H .Y 4 m 4 m o to , O k 4 m o to , S. (2 0 0 9 ). C o m 6 u s tio n T .K o s / k i, 3 h 4 r 4 3 t / r is ti 3 s T .H ir o s / , H. o 8 s / w 4 g / s lu % g / in 4n% 4 in 3 in / r 4 tio n p l 4 n t 8 o r / n / r g y r / 3 o v / r y . F u / l P r o 3 / s s in g T / 3 h n o lo g y , 9 0 , 7 7 8 783. 1 44 N 4 o u m , C .F 4 tt 4 , D .H 4 r 4 l 4 m 6 o u s , K . J. m / t 4 ls 8 ro m S 3 i/ n 3 / 4n% N / m 4 , S. 4n% s / w 4 g / s lu % g / 6y 4n% L o iz i % o u , M . (2 0 0 1 ). R / m o v 4 l o 8 h / 4 v y 4 3 i% tr / 4 tm / n t. J o u r n 4 l o 8 E n v ir o n m / n t 4 l H / 4 lth , P 4 r t A , 3 6 (5 ), 8 7 3 -8 8 1 . G 4 n / s h p r 4 s 4 % , K . (2 0 0 2 4 ). P l 4 s m 4 p y r o ly s is o 8 m / % i 3 4 l w 4 s t / . C u r r / n t S 3 i / n 3 / , 8 3 (3 ), 2 7 1 -2 7 8 . N / m 4 , S. K . 4n% G 4 n / s h p r 4 s 4 % , K . S. (2 0 0 2 6 ) . P l 4 s m 4 p y r o ly s is o 8 m / % i 3 4 l w 4 s t / . C u r r / n t S 3 i / n 3 / , 8 3 (3 ), 2 7 1 -2 7 8 . N ik o l 4 y , M . 4n% M 4 r i 4 , Y . (2 0 1 7 4 ). M / th o % s tr / 4 tm / n t. P 4 p / r p r / s / n t / % N ik o l 4 y , M . 4n% th / M A T E C W M 4 r i 4 , Y . (2 0 1 7 6 ) . M / th o % s tr / 4 tm / n t. P 4 p / r p r / s / n t / % P 4 n , X .J i 4 n h u 4 , Y . m / t 4 ls in 4t 4n% 8 ly 4 sh 4t 4n% s o lu tio n s th / M A T E C W g 4 lv 4 n i 3 w 4 s t / w 4 t / r o 8 C o n 8 / r/ n 3/ s. /6 4n% 8or s o lu tio n s 8or g 4 lv 4 n i 3 w 4 s t / w 4 t / r o 8 C o n 8 / r/ n 3/ s. /6 Z h / n g m i 4 o , X . (2 0 1 3 ). D / to x i 8 y in g P C D D /F s 4n% 8 ro m o u 6 l/ m / % i 3 4 l w 4 s t / in 3 in / r 4 to r s w ith DC 4 % h/4vy 4 3 p l 4 s m 4 to r 3 h . J o u r n 4 l o 8 E n v ir o n m / n t 4 l S 3 i / n 3 / s , 2 5 (7 ) , 1 3 6 2 - 1 3 6 7 . P4n, X. 4n% X i / , Z . (2 0 1 4 ) . C h 4 r 4 3 t / r is ti 3 s o 8 M / lt in g I n 3 in / r 4 to r A s h / s U s in g D ir / 3 t C u r r / n t P l 4 s m 4 T o r 3 h . E n v ir o n m / n t 4 l P 4 r k , H . S .L / / , B . J. 4n% 4n% 4 n 4 ly ti 3 4 l 4 to x i 3 o o g y , 4 (3 ). K im , S. J. (2 0 0 5 ). M / % i 3 4 l w 4 s t / tr / 4 tm / n t u s in g p l 4 s m 4 . J. In % . E n g . C h / m , 11, 3 5 3 -3 6 0 . P 4 t / l, M . L . 8or 4n% C h 4 u h 4 n , J. S. (2 0 1 2 ). P l 4 s m 4 G 4 s i 8 i 3 4 tio n : A S u s t 4 in 4 6 l / S o lu tio n th / M u n i 3 ip 4 l S o li % W 4 s t / M 4 n 4 g / m / n t in th / S t 4 t / o 8 M 4% h y 4 P r4 % / sh , In % i 4 . I n t / r n 4 tio n 4 l J o u r n 4 l o 8 E n v ir o n m / n t 4 l S 3 i / n 3 / s , 3 (1 ). P / r / z - V ill 4 r / jo , L .M 4 r tin / z - M 4 r tin / z , D .U r / n 4 - N i / to , C. 4n% S .C 4 r r 4 s 3 o - H u r t 4 % o , S 4 n 3 h / z - S o to , in / r tiz 4 tio n o 8 g 4 lv 4 n i 3 s lu % g / w 4 s t / in P. 3 l4 y J. B .E li 3 h / - Q u / s 4 % 4 , (2 0 1 5 ). 6 ri 3 k s . V 4 lo r iz 4 tio n 4n% A p p li / % C l 4 y S 3 !/ n 3 / , 1 0 5 ( S u p p l / m / n t C ), 8 9 -9 9 . P / t / r , M . (2 0 1 1 ). H is to r i 3 4 l D / v / lo p m / n t o 8 H o t - % ip G 4 lv 4 n iz in g . H 4 n % 6 o o k o 8 H o t D ip G 4 lv 4 n iz in g : W I L E Y - V C H V / r l 4 g G m 6 H & C o. P o ir o u x , R . 4n% R o llin , M . (1 9 9 6 ). H ig h t / m p / r 4 tu r / tr / 4 tm / n t o 8 w 4 s t / : l 4 6 o r 4 to r i / s to t h / in % u s tr i 4 l s $4 g / . P u r / A p p l. C h / m , 6 8 8 ro m , 1 0 3 5 -1 0 4 0 . P o u r 4 li, M . (2 0 1 0 ). A p p li 3 4 tio n o 8 P l 4 s m 4 G 4 s i 8 i 3 4 tio n T / 3 h n o lo g y in W 4 s t / to E n / r g y - C h 4 ll / n g / s 4n% O p p o r tu n iti / s . I E E E E n / r g y , 1 (3 ), 125 -1 3 0 . 145 T r 4 n s 4 3 tio n s o n S u s t 4 in 4 6 l / R 4 is s i, S. (2 0 0 9 ). D / v / lo p in g n / w p r o 3 / s s / s 4n% o p tim iz in g p / r 8 o r m 4 n 3 / u s in g r / s p o n s / s u r 8 4 3 / m / th o % o lo g y . W o r l % A 3 4 % / m y o 8 S 3 i / n 3 / , E n g i n / / r in g 4n% T / 3 h n o lo g y , 4 9 , 1 0 3 9 -1 0 4 2 . R 4 m 4 3h 4 n % r4 n , K. 4n% / l / 3 tr o p l 4 tin g R 4 m 4 3h 4 n % r4 n , K . (2 0 0 0 ). P l4 s m 4 in - 8 lig h t tr / 4 tm / n t o 8 s lu % g / . V 4 3 u u m , 5 9 , 2 4 4 -2 5 1 . 4n% / l / 3 tr o p l 4 tin g R 4 o , L .C 4 r 4 6 in , P . K ik u k 4 w 4 , N . K ik u k 4 w 4 , N . (2 0 0 2 ). T h / r m 4 l p l 4 s m 4 in - 8 lig h t tr / 4 tm / n t o 8 s lu % g / . I E E E T r 4 n s . P l 4 s m 4 4n% &3 () 3 0 , 3 1 0 -3 1 7 . H o l 3 r o 8 t, G . ( 2 0 1 0 , 5 -8 O 3 to 6 / r , 2 0 1 0 ). P l 4 s m 4 W 4 s t / G 4 s i 8 i 3 4 tio n : D / 3 / n tr 4 liz / % A p p r o 4 3 h to P r o % u 3 tio n o 8 E n / r g y F r o m W 4 s t / . P 4 p / r p r/ s / n t/ % 4t th / 2n% I n t / r n 4 tio n 4 l C o n 8 / r / n 3 / o n H 4 z 4 r% o u s 4 n% I n % u s tr i 4 l W 4 s t / M 4 n 4 g / m / n t, C h 4 n i 4 , C r / t / , G r / / 3 / . R 4 s h i % , K .S in h 4 , K . 4n% P .C ., S. (2 0 1 3 ). A n u p % 4 t / o n o x i % 4 tiv / s tr / s s - m / % i 4 t / % o r g 4 n p 4 th o p h y s io lo g y . F o o % C h / m T o x i 3 o l, 6 2 , 5 8 4 -6 0 0 . R 4 th , S. S .J 4 y 4 s 4 n k 4 r , K .S 4 t 4 p 4 th y , B . K .M is h r 4 , B . K . K in / ti 3 s 4n% 4 r3 8 u rn 4 3 / . s t 4 tis ti 3 4 l 6 / h 4 v io u r 4n% o 8 ir o n r / 3 o v / r y M u k h / r j / / , P . S. (2 0 1 1 ). 8 ro m r / % m u % u s in g p l 4 s m 4 H ig h T / m p . M 4 t / r . P r o 3 / s s , 3 0 (3 ), 2 1 1 . R 4 th , S. S .P 4 n y , A .J 4 y 4 s 4 n k 4 r , K .M itr 4 , A . K .K u m 4 r , C . S. ( 2 0 1 3 ) . S t 4 tis ti 3 4 l m o % / lin g s tu % i / s o 8 ir o n r / 3 o v / r y 4n% 8 ro m M u k j / r j / / , P . S. r/ % m u% u s in g th / r m 4 l p l 4 s m 4 . P l 4 s m 4 S 3 (* T / 3 h n o l, 1 5 (5 ), 4 5 9 -4 6 4 . R /% % y, K. R. 4n% C h in th 4 m r / % % y , S. (1 9 9 9 ). E l / 3 tr o k in / ti 3 r / m / % i 4 tio n o 8 h / 4 v y m / t 4 l- 3 o n t 4 m in 4 t / % s o ils u n % / r r / % u 3 in g / n v ir o n m / n ts . W 4 s t / M 4 n 4 g / m / n t, 1 9 (4 ), 2 6 9 -2 8 2 . R o % r ig u / s , R . C .K / n / 4 ly , W . R .D i / tr i 3 h , D . s u r 8 4 3 / m / th o % o lo g y ( R S M ) to r / 3 o v / r in g x y lo s / R o s s in i, G . 4n% 6y 4n% / v 4 lu 4 t / J / 8 8 r i / s , T . W . (2 0 1 2 ). R / s p o n s / m o is tu r / / 8 8 / 3 ts on 3o rn s to v / r in D E O h y % r o ly s is . B io r / s o u r T / 3 h n o l, 1 0 8 , 1 3 4 -1 3 9 . B / r n 4 r % / s , A . M . (2 0 0 6 ). G 4 lv 4 n i 3 s lu % g / m / t 4 ls r / 3 o v / r y p y r o m / t 4 llu r g i 3 4 l 4n% 6y h y % r o m / t 4 llu r g i 3 4 l tr / 4 tm / n t. J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 3 1 ( 1 - 3 ) , 2 1 0 -2 1 6 . R o u s s / 4 u , C .B 4 r 4 u % , F .L / l / y t / r , L . s 4 3 ri8 i3 i4 l 4 no% / s: Im p 4 3 t 4n% on G il, O . (2 0 0 9 ) . C 4 th o % i 3 p r o t / 3 tio n m 4 r in / s / % im / n t m / t 4 lli 3 3 o n t4 m 6y z in 3 in 4 tio n . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 6 7 (1 ), 9 5 3 -9 5 8 . R u j, B . 4n% G h o s h , S. (2 0 1 4 ). T / 3 h n o lo g i 3 4 l 4 s p / 3 ts 8 o r th / r m 4 l p l 4 s m 4 tr / 4 tm / n t o 8 m u n i 3 ip 4 l s o li % w 4 s t / — A r / v i / w . F u / l P r o 3 / s s in g T / 3 h n o lo g y , 1 2 6 , 2 9 8 ­ 308. 1 46 R u t 6 / r g , P . G .B r 4 ts / v , A . N .S 4 8 r o n o v , A . A .S u r o v , A . V . ( 2 0 0 2 ) . T h / t / 3 h n o lo g y 4n% / x / 3 u tio n 4n% S 3 h / g o l/ v , V . V . o 8 p l4 s m 4 3 h / m i3 4 l % is in 8 / 3 tio n o 8 h 4 z 4 r % o u s m / % i 3 4 l w 4 s t / . I E E E T R A N S A C T I O N S O N P L A S M A S C IE N C E , 3 0 (4 ) , 1 4 4 5 -1 4 4 8 . 1 0 .1 1 0 9 /T P S .2 0 0 2 .8 0 4 2 1 8 % +,- S 4 8 8 4 r z 4 % / h , A .S h im 4 o k 4 , T .M o to m u r 4 , Y . m in / r 4 lo g i 3 4 l / v 4 lu 4 tio n 4n% W 4 t 4 n 4 6 / , K . (2 0 0 6 ). C h / m i 3 4 l o 8 s l 4 g p r o % u 3 ts % / r iv / % 8 ro m 4 n% th / p y r o ly s is /m / ltin g tr / 4 tm / n t o 8 M S W . W 4 s t / M 4 n 4 g / m / n t, 2 6 ( 1 2 ) , 1 4 4 3 -1 4 5 2 . S 4 8 8 4 rz 4 % / h , A .S h im 4 o k 4 , T .M o to m u r 4 , Y. 4n% W 4 t4 n 4 6 / , K. ./4 0 . C h 4 r 4 3 t / r iz 4 tio n s tu % y o 8 h / 4 v y m / t 4 l- 6 / 4 r in g p h 4 s / s in M S W (2 0 0 9 ). J o u rn 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 6 4 (2 -3 ), 8 2 9 -8 3 4 . S 4 h / r, S. 4n% A 6 % / l H 4 m i % , Z . (2 0 0 3 ) . E 8 8 / 3 t o 8 s tr u 3 tu r / 4n% % ro ss 8 o r m 4 tio n 4 lu m in iu m 3 o n t/ n t o n th / 3 o 4 tin g in th / h o t- % ip g 4 lv 4 n iz in g p ro 3 / s s . S u r 8 4 3 / 4 n% I n t / r 8 4 3 / A n 4 ly s is . W il / y I n t / r S 3 i / n 3 / (w w w .in t / r s 3 i / n 3 / .w il / y . 3 o m ), 3 5 , 9 3 4 -9 4 7 . S 4 // m , H . M .E w / i % 4 , E . A . th / ir / n v ir o n m / n t 4n% F 4 r 4 g , A . (2 0 0 0 ) . H / 4 v y m / t 4 ls in im p 4 3 t I n t / r n 4 tio n 4 l C o n 8 / r / n 3 / on 8or hum 4n h / 4 lth . . P4p/r % r in k in g w 4 t / r & p r/ s / n t/ % 4t th / E n v ir o n m / n t 4 l H 4 z 4 r % s M itig 4 tio n . I C E H M , C 4 ir o U n iv / r s ity ,G iz 4 , E g y p t. S 4 m 4 l, S. (2 0 1 7 ). T h / r m 4 l p l 4 s m 4 t / 3 h n o lo g y : T h / p r o s p / 3 tiv / 8 u tu r / in m 4 t / ri 4 l p r o 3 / s s in g . J o u r n 4 l o 8 C l / 4 n / r P r o % u 3 tio n , 1 4 2 (P 4 r t 4 ), 3 1 3 1 -3 1 5 0 . S 4 m 4 l, S. K .S in % h o o r 4 , L . P .M is h r 4 , S. C . p r o 3 / s s in g o 8 P r o 3 / s s in g S 3 i/ n 3 / 6 lu / 4n% 4n% % u s t. P 4 p / r p r / s / n t / % M is h r 4 , B . (2 0 1 5 ) . S tu % i / s o n p l 4 s m 4 4t th / 4 th N 4 tio n 4 l C o n 8 / r / n 3 / o n C h 4 r 4 3 t / r iz 4 tio n o 8 M 4 t / r i 4 ls . I O P C o n 8 . S / ri / s . M 4 t / r i 4 ls E n g in / / r in g . S 4 n k 4 r 4 m m 4 l, M .T h 4 th / y u s , A . u s in g p s / u % o m o n 4 s S 4 n t4 n u , P . 4n% 4n% 4n% 8 lu o r / s 3 / n s . R 4 m y 4 , D . (2 0 1 4 ) . B io r / m o v 4 l o 8 34% m iu m O p / n J. W 4 t / r P o llu t. T r / 4 t( 1 ) , 9 2 -1 0 0 . P 4 k , K . Y . (2 0 0 6 ) . S o li % i 8 i 3 4 t io n - s t 4 6 il iz 4 tio n o 8 o r g 4 n i 3 in o r g 4 n i 3 3 o n t4 m in 4 n ts u s in g p o r tl 4 n % 3 / m / n t: 4 4n% lit / r 4 tu r / r / v i / w . E n v ir o n . R / v ., 14. S 3 h u lz , W . D . 4n% 8 o r m 4 tio n T h i / l / , M . (E % s .). (2 0 1 1 ). H o t T / 3 h n o lo g y . H 4 n % 6ook V / rl4 g G m 6 H . 1 47 on hot % % ip G 4 lv 4 n iz in g 4n% L4y/r ip g 4 lv 4 n is in g .: W il / y - V C H S / 6 4 g , M . G .K o r z / n o w s k i, C .B / r n 4 r % / s , A . M . o 8 / n v ir o n m / n t 4 l 3om 4n% V il / l 4 , A . C . (2 0 0 9 ). E v 4 lu 4 tio n p 4 ti 6 ility o 8 E A F D u s in g % i 8 8 / r / n t l / 4 3 h in g s t 4 n % 4 r % s . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 1 6 6 (2 ), 6 7 0 -6 7 5 . 1/ 2 , J .- H . 4n% H o n g , B .-G . (2 0 1 2 ). p o w % / r s . N u 3 l / 4 r / n g in / / r in g Sh/n, L. 4n% 4n% T h / rm 4 l p l4 s m 4 t / 3 h n o lo g y , 4 4 (1 ) , 9 -2 0 . Z h 4 n g , D . (2 0 0 5 ) . L o w - t / m p / r 4 tu r / p y r o ly s is o 8 s / w 4 g / s lu % g / p u tr / s 3 i 6 l / g 4 r 6 4 g / 8or 8u/l S h i / , J .Y i- R u , L .K 4 / - L o n g , L . 4n% C h in g - Y u 4 n , C . ( 2 0 1 4 4 ). T h / r m 4 l T r / 4 tm / n t o 8 C o n 8 / r / n 3 / o n F u tu r / E n v i r o n m / n t S h i / , J. L .L i 4 u , Y . R .L in , K . L . 4n% 4n% o rg 4 n i3 Jo u rn 4 l S 3 i/ n 3 / 4n% 4t th / 4 th I n t / r n 4 tio n 4 l E n / r g y , S in g 4 p o r / . 64 s/ % s t 4 6 i liz 4 tio n /s o li % i 8 i 3 4 tio n o 8 in 4 t / % h 4 z 4 r % o u s w 4 s t / s u s in g N 4 - 6 / n t o n it / o 8 E n v ir o n m / n t 4 l 4n% 4n% J u n , K . S. (1 9 9 5 ) . C / m / n t 3 o n t4 m th / 4 th I n t / r n 4 tio n 4 l C h 4 n g , C . Y . (2 0 1 4 6 ) . T h / r m 4 l T r / 4 tm / n t o 8 C o n 8 / r / n 3 / o n F u tu r / E n v i r o n m / n t 4n% 4t E n / r g y .I P C B E E , S in g 4 p o r / P 4 p / r S lu % g / U s i n g T o r 3 h P l 4 s m 4 . P 4 p / r p r / s / n t / % S h in , H . S. E n g i n / / r in g 4n% o il p r o % u 3 tio n . F u / l, 8 4 ( 7 - 8 ) , 8 0 9 -8 1 5 . P 4 p / r S lu % g / U s i n g T o r 3 h P l 4 s m 4 . P 4 p / r p r / s / n t / % S h ir o , Y . s y n th / s is o 8 n 4 n o - s iz / % 4n% S 3 i/ n 3 / 4n% H / 4 lth . P 4 rt A: 4n% s ili 3 4 -8 u m / . E n v ir o n m / n t 4 l T o x i 3 o lo g y , 3 0 (3 ), 6 5 1 -6 6 8 . T 4 h / i, T. (2 0 0 0 ). P r in 3 ip l / 4n% P r o 3 / s s o 8 H / 4 v y M / t4 l R / m o v 4 l 8 ro m S / w 4 g / S lu % g / . E n v i r o n S 3 3 T / 3 h n o l, 3 4 , 1 5 7 2 -1 5 7 5 . S m ith , W . J. S o 6 i/ 3 k 4 , E . 4n% 4n% / 8 8 / 3 tiv / G o o % w in , F . E . (2 0 1 0 ) . H o t D ip C o 4 tin g s . R / t r i / v / % S z y m 4 n s k i, L . (2 0 1 4 ). T h / r m 4 l p l 4 s m 4 v itr i 8 i 3 4 ti o n p r o 3 / s s t / 3 h n o lo g y 8 o r 8 ly 4 s h 4 n % J o u r n 4 l o 8 C h / m i 3 4 l T / 3 h n o lo g y S to i 3 4 , A .S 4 n % 8 ro m 6 / rg , M. 4n% 3 h ro m 4n% iu m - r i 3 h s / w 4 g / s lu % g / u tiliz 4 tio n . B io t / 3 h n o lo g y , 8 9 (7 ), 1 1 1 5 -1 1 1 7 . H o l 6 y , O . (2 0 0 9 ). E n / r g y U s / w ith in W 4 s t / w 4 t / r T r / 4 tm / n t 4n% 4s 44 S lu % g / H 4 n % lin g 4n% 4t R / 3 o v / r y S tr 4 t / g i / s P u lp 4n% P 4 p / r M ills . B io r / s o u r T / 3 h n o l, 1 0 0 (1 4 ), 3 4 9 7 - 3 5 0 5 . S ty li 4 n o u , M . A .K o lli 4 , D .H 4 r 4 l 4 m 6 o u s , K .- J .I n g l / z 4 k is , V . J .M o u s t 4 k 4 s , K . G . L o iz i % o u , M . D . (2 0 0 7 ). E 8 8 / 3 t o 8 m / t 4 ls 8 ro m 4 3 i% 4 n% tr / 4 tm / n t o n th / r / m o v 4 l o 8 h / 4 v y s / w 4 g / s lu % g / . D / s 4 lin 4 tio n , 2 1 5 (1 ) , 7 3 -8 1 . S u lliv 4 n , C .T y r / r , M .C h / / s / m 4 n , C . R . w 4 t / r tr / 4 tm / n t w 4 s t / s 4n% 3 o n t 4 in in g G r 4 h 4 m , N . J. D . (2 0 1 0 ) . D is p o s 4 l o 8 4 rs / n i 3 . 1778. 148 S 3 i. T o t 4 l E n v ir o n , 4 0 8 , 1 7 7 0 ­ S z / n t / , R . N .B / n % / r , O . W .S 3 h r o / t / r , R . A .G r 4 3 i 4 , M . G . T r / 4 tin g E l / 3 tr o p l 4 tin g R / s i % u / s 6 y P l 4 s m 4 - L 4 6 0 5 5 0 8 -9 0 1 ) C i% T 4 n % / ro , C .T ix i / r , 4% / 4n% 4n% B 4 r 6 o s 4 , L . (1 9 9 8 ). P il o t S 3 4 l / T / s ts ., (C E P U n iv / r s it 4 r i 4 , S 4 o P 4 u lo , B r 4 z il. C .T r is 4 n t, P .D / s m 4 is o n , A to m o s p h / r i 3 p r / s s u r / p l 4 s m 4 : A J. R / v i/ w . 4n% L / p r in 3 / , P. (2 0 0 6 ). s p / 3 tr o 3 h im i 3 4 A 3 t 4 P 4 r t B . A to m i 3 s p / 3 tr o s 3 o p y , 6 1 (1 ), 2 -3 0 . T4ng, L. 4n% H u 4 n g , H . (2 0 0 5 ). T r / 4 tm / n t o 8 W 4 s t / T y r / P o w % / r U s in g 8 r/ q u / n 3y C 4 p 4 3 itiv / ly C o u p l / % 4 H ig h - P l 4 s m 4 R / 4 3 to r . T h / C h in / s / J o u r n 4 l o 8 P r o 3 / s s E n g in / / r in g , 5 (3 ). T 4 n g , L .H u 4 n g , H .Z h 4 o , Z . L .W u , C . Z . p o ly p r o p y l / n / in 4n% C h / n , Y . (2 0 0 3 ). P y r o ly s is o 8 n itr o g / n p l 4 s m 4 r / 4 3 to r . I n % E n g C h / m R / s , 4 2 (6 ) , 1 1 4 5 ­ 4 1150. T 4 n ig 4 k i, N .M 4 n 4 k o , K . w 4 s t/ 4n% 4n% O s 4 % 4 , M . (2 0 1 2 ). C o - g 4 s i 8 i 3 4 tio n o 8 m u n i 3 ip 4 l s o li % m 4 t / r i 4 l r / 3 o v / r y in l 4 r g / - s 3 4 l / g 4 s i 8 i 3 4 tio n 4 4n% m / ltin g s y s 6/ m . W 4 s t / M 4 n 4 g / m / n t, 3 2 (4 ) , 6 6 7 -6 7 5 . T 3 h o u n w o u , P . B .Y / % jo u , C . G .P 4 tlo ll 4 , A . K . M / t 4 l T o x i 3 ity 4n% 4n% 4n% S u tto n , D . J. (2 0 1 2 ) . H / 4 v y th / E n v ir o n m / n t. I n L u 3 h , A . (E % .), M o l / 3 u l 4 r , C lin i 3 4 l E n v ir o n m / n t 4 l T o x i 3 o lo g y : V o lu m / 3: E n v ir o n m / n t 4 l T o x i 3 o lo g y (p p . 1 3 3 -1 6 4 ). B 4 s / l: S p r in g / r B 4 s / l. T i 4 n , M .P 4 r k , H . 4n% R o w , K . H . (2 0 1 4 ) . O p tim iz 4 tio n o 8 S y n th / s is A m o u n ts o 8 P o ly m / r s w ith T w o M o n o m / r s 6y D i 8 8 / r / n t M / th o % s B 4 s / % on R / sp o n s/ S u r 8 4 3 / M / th o % o lo g y . A % v 4 n 3 / s in P o ly m / r T / 3 h n o lo g y , 3 3 (2 ). T ip p 4 y 4 w o n g , N . 4 ir 4n% K h o n g k r 4 p 4 n , P . (2 0 0 9 ) . D / v / lo p m / n t o 8 p l4 s m 4 to r3 h 4n% its 4 p p li 3 4 tio n to / l / 3 tr o n i 3 4 l 4 6 o r 4 to r y s 3 4 l / w 4 s t / tr / 4 tm / n t. In t. J. E n v ir o n . S 3 78 T / 3 h ., 6 (3 ), 4 0 7 -4 1 4 . T o l / % o , J. M .C o r / ll 4 , J. in in 3 in / r 4 tio n 4n% o8 C o r / ll 4 , L . M . (2 0 0 5 ). T h / p 4 r titio n in g o 8 h / 4 v y m / t 4 ls s lu % g / s I n t / r p r / t 4 tio n o 8 r / s u lts w ith 4n% w 4 s t/ in 4 3 o n 3 / p tu 4 l 4 6 u 6 6 lin g 8 lu i % iz / % 6/ % : 2 . m o % / l. J H 4 z 4 r % M 4 t / r , 1 2 6 ( 1 - 3 ) , 1 5 8 -1 6 8 . T o r o p o v , V . V .v 4 n K / u l / n , F .M 4 r k in / , V . th / m u lti- p o in t 4 p p r o x im 4 tio n r/ s p o n s/ s . P 4 p / r p r/ s / n t/ % 4t 4n% D / D o / r , H . (1 9 9 6 ). R / 8 in / m / n ts in m / th o % to r / % u 3 / th / th / P r o 3 / / % in g s I S S M O s y m p o s iu m o n m u lti % is 3 ip lin 4 r y 1 49 / 8 8 / 3 ts 6 th 4 n 4 ly s is 4 n % o 8 n o is y s tru 3 tu r 4 l A I A A /U S A F / N A S A / o p tim iz 4 tio n . T u 4 n , Y . J .W 4 n g , H . P . 3 o - m / ltin g o8 4n% 8 9y C h 4 n g , J. E . (2 0 1 2 ) . T r 4 3 k in g o 8 4 sh / s 4n% 3h ro m iu m in p l 4 s m 4 s lu % g / s . W 4 t / r, A ir, & S o il P o llu tio n , 2 2 3 (8 ) , 5 2 8 3 -5 2 8 8 . T z / n g , C ., C .K u o , Y . Y .H u 4 n g , T . F .L in , D . L . r 4 % io 4 3 tiv / w 4 s t / s 6y p l 4 s m 4 in 3 in / r 4 tio n 4n% Y u , Y . J. (1 9 9 8 ) . T r / 4 tm / n t o 8 4n% v itr i 8 i 3 4 ti o n 8 o r 8 in 4 l % is p o s 4 l. J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 5 8 (1 ), 2 0 7 -2 2 0 . V 4 n O o s t, G .H r 4 6 o v s k y K o p / 3 k y , M . V .K o n r 4 % , M .H lin 4 , M . P y r o ly s is /g 4 s i 8 i 3 4 ti o n o 8 6 io m 4 s s 8or s y n th / ti 3 8u/l 4n% K 4 v k 4 , T . (2 0 0 9 ). p r o % u 3 tio n u s in g h y 6 ri% 4 g 4 s - w 4 t / r s t 4 6 iliz / % p l 4 s m 4 to r 3 h . V 4 3 u u m , 8 3 , 2 0 9 -2 1 2 . W 4 n g , J .F / n g , X .A n % / r s o n , C . W . N .X in g , Y . m / r3u ry 2 2 2 3 o n t4 m 4n% S h 4 n g , L . (2 0 1 2 ). R / m / % i 4 tio n o 8 in 4 t / % s it / s - A r / v i / w . J o u r n 4 l o 8 H 4 z 4 r % o u s M 4 t / r i 4 ls , 2 2 1 ­ , 1 -1 8. W 4 n g , Q .Y 4 n , J. H .T u .X .C h i, Y .L i, X . D . o 8 m u n i 3 ip 4 l s o li % 4n% w 4 s t / in 3 in / r 4 to r L u , S. Y . (2 0 0 9 ) . T h / r m 4 l tr / 4 tm / n t 8 ly 4 sh u s in g D C o u 6 l/ % 4 r3 4 rg o n p l 4 s m 4 . F u / l, 8 8 (5 ) , 9 5 5 -9 5 8 . W 4 n g , S. B .C h / n g , C . M .L 4 n , W .Z h 4 n g , X . H .L iu , D . P . 4n% Y 4 n g , S. Z . (2 0 1 3 ). E x p / r im / n t 4 l S tu % y o 8 T h / r m 4 l P l 4 s m 4 P r o 3 / s s in g W 4 s t / C ir 3 u it B o 4 r % s . A % v 4 n 3 / % M 4 t / r i 4 ls R / s / 4 r 3 h , 6 5 2 - 6 5 4 , 1 5 5 3 -1 5 6 1 . W 4ng, Z .G u o , Q .L iu , X. 4n% C 4o, C. (2 0 0 7 ). Low T / m p / r 4 tu r / P y r o ly s is C h 4 r 4 3 t / r is ti 3 s o 8 O il S lu % g / u n % / r V 4 r io u s H / 4 tin g C o n % itio n s . E n / r g y & F u / ls , 2 1 , 9 5 7 -9 6 2 . w 4 t4 n 4 6 / , N. T. (2 0 1 3 ). D / 3 o m p o s itio n A tm o s p h / r i 3 P r / s s u r / . P l 4 s m 4 S 3 i / n 3 / W 4 t 4 n 4 6 / , T. 4n% o8 G ly 3 / r in / 6y W 4 t/ r 4n% T / 3 h n o lo g y , 1 5 (4 ), 1-6. S h im 6 4 r 4 , S. (2 0 0 3 ). H 4 lo g / n 4 t / % h y % r o 3 4 r 6 o n P l4 s m 4 s % /3om 4t p o s itio n 6y s t / 4 m th / r m 4 l p l 4 s m 4 s . H ig h T / m p . M 4 t / r . P r o 3 / s s , 7, 4 5 5 -4 7 4 . W / i4 , Y . L . 4n% W u 4 , C . H . (1 9 9 7 ). P A H E m is s io n s I n 3 in / r 4 tio n o 8 4n 8 ro m th / F lu i % iz / % - B / % I n % u s tr i 4 l S lu % g / . J o u r n 4 l o 8 th / A ir & W 4 s t / M 4 n 4 g / m / n t A s s o 3 i 4 tio n , 4 7 (9 ) , 9 5 3 -9 6 0 . W / r l / , S. (2 0 1 5 4 ). G 4 s i 8 i 3 4 tio n o 8 F ix / % B / % R / 4 3 to r . E n / r g i / s , 4 D ri/ % 8 S / w 4 g / S lu % g / in 4 L 4 6 o r 4 to r y S 3 4 9/ , 8 5 6 2 -8 5 7 2 . W / r l / , S. (2 0 1 5 6 ) . N itr o g / n O x i % / s E m is s io n R / % u 3 tio n U s in g S/w 4g/ S lu % g / G 4 s i 8 i 3 4 tio n G 4 s R / 6 u r n in g P r o 3 / s s . E 3 o l C h / m E n g S ., 2 2 (1 ) , 8 3 -9 4 . W / s tin g h o u s / - p l 4 s m 4 . (2 0 1 5 ). R / tri/ v / % h t t p : // w w w .w / s t in g h o u s / - p l 4 s m 4 . 3 o m . 1 50 23 o 3 to 6 / r , 2015, 8 ro m Y / u n g , A . T .H s u , C . N . / x tr 4 3 tio n o8 :/ 4 % 4n% M / n o n , R . M . (1 9 9 6 ) . E D T A - / n h 4 n 3 / % / l / 3 tr o k in / ti 3 . J G / o t / 3 h E n g , 1 2 2 (8 ), 6 6 6 -6 7 3 . Y i- M in g , K .K u o - L in , H . 4n% o 8 M u n i 3 ip 4 l S o li % C h its 4 n , L . (2 0 1 2 ). M / t 4 l B / h 4 v io r % W 4 s t / I n 3 in / r 4 to r F ly A s h . A / r o s o l u r in g V itr i 8 i 3 4 tio n 4n% A ir Q u 4 lity R / s / 4 r 3 h , 12, 1 3 7 9 -1 3 8 5 . Z 4 i % o n , A . K .P 4 r i % 4 h , G . H .B 4 k 4 r , M . T . T h / P r o 3 / s s in g V 4 r i 4 6 l / s 8or 4n% R u s h % 4 n , I. (2 0 1 2 ) . O p tim is 4 tio n o 8 H ig h P o ly m / r L o 4 % in g in C o m p r / s s / % W o o % U s i n g R / s p o n s / S u r 8 4 3 / M / th o % o lo g y . J o u r n 4 l o 8 T r o p i 3 4 l F o r / s t S 3 i / n 3 / , 2 4 ( 2 ) , 2 4 1 -2 4 8 . Zh4ng, Q. (2 0 1 1 ). M 4 th / m 4 ti 3 4 l g 4 s i 8 i 3 4 tio n in 4 8 ix / % m o % / lin g o8 m u n i 3 ip 4 l s o li % w 4 s t/ p l4 s m 4 - 6 / % m / ltin g r / 4 3 to r . ( D o 3 to r 4 l D is s / r t 4 tio n ) , S E -1 0 0 4 4 S to 3 k h o lm , S w / % / n . Z h 4 n g , Q .D o r, L .F / n ig s h t / in , D .Y 4 n g , W . m u n i 3 ip 4 l s o li % 4n% B l 4 s i 4 k , W . (2 0 1 2 ). G 4 s i 8 i 3 4 tio n o 8 w 4 s t / in th / p l 4 s m 4 g 4 s i 8 i 3 4 tio n m / ltin g p ro 3 / s s . A p p l. E n / r g , 9 0 , 1 0 6 -1 1 2 . Z h / n , H .X u - t 4 o , Z . 4n% G u i- q in g , X . (2 0 1 3 ). P r o % u 3 t Q u 4 lity I m p r o v / m / n t T h r o u g h R / s p o n s / S u r 8 4 3 / M / th o % o lo g y : A C 4 s / S tu % y . . P 4 p / r p r / s / n t / % I n t / r n 4 tio n 4 l C o n 8 / r/ n 3/ on T / 3 h n o lo g y I n n o v 4 tio n 4n% 4t th / I n % u s tr i 4 l M 4 n 4 g / m / n t. Z l / 6 / k , Z .H o % u l, J. w 4 s t/ 4n% 4n% 3 o n t 4 in in g D r o 3 h y tk 4 , R . (2 0 1 8 ). R / p 4 ir i n g h / 4 v y m / t 4 ls . I O P C o n 8 / r / n 3 / E n g in / / r in g , 3 8 5 ( 3 8 5 ) , 1-6. 151 3om p o s it / u s in g h 4 z 4 r % o u s ;/ ri / s : M 4 t / r i 4 ls S 3 i / n 3 /