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(2 E )-2-Hydroxyimino- N ′-[( E )-2-pyridylmethylene]propanohydrazide

2009, Acta Crystallographica Section E Structure Reports Online

In the title compound, C(9)H(10)N(4)O(2), the pyridine ring is twisted by 16.5 (1)° from the mean plane defined by the remaining non-H atoms. An intra-molecular N-H⋯N inter-action is present. In the crystal, inter-molecular O-H⋯N and N-H⋯O hydrogen bonds link mol-ecules into layers parallel to the bc plane. The crystal packing exhibits π-π inter-actions indicated by the short distance of 3.649 (1) Å between the centroids of the pyridine rings of neighbouring mol-ecules.

# # h,k,l, Fc-squared, Fo-squared, sigma(Fo-squared) and status flag # data_I _shelx_title ' in P2(1)/c' _shelx_refln_list_code 4 _shelx_F_calc_maximum 144.52 _exptl_crystal_F_000 432.00 _reflns_d_resolution_high 0.7109 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 10.2740 _cell_length_b 9.7170 _cell_length_c 10.1360 _cell_angle_alpha 90.000 _cell_angle_beta 109.280 _cell_angle_gamma 90.000 _shelx_F_squared_multiplier 1.000 loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 450.25 428.92 9.44 o 3 0 0 2390.71 2541.30 40.93 o 4 0 0 1087.87 1144.84 44.23 o 5 0 0 454.57 489.23 7.51 o 6 0 0 1866.39 2122.05 11.55 o 7 0 0 264.96 275.53 6.56 o 8 0 0 0.86 1.84 0.87 o 9 0 0 1148.65 1200.85 49.31 o 10 0 0 585.29 537.07 5.99 o 11 0 0 154.31 150.61 3.92 o 12 0 0 6.74 3.50 2.25 o 2 1 0 1159.28 1220.25 15.04 o 3 1 0 1510.61 1541.12 34.97 o 4 1 0 54.34 38.01 0.62 o 5 1 0 1195.58 1336.70 28.00 o 6 1 0 277.10 288.52 5.83 o 7 1 0 11.40 7.10 0.70 o 8 1 0 1.54 2.00 0.70 o 9 1 0 1254.16 1236.12 16.65 o 10 1 0 130.95 125.24 2.63 o 11 1 0 20.21 15.83 1.63 o 12 1 0 98.04 86.92 2.42 o 0 2 0 3999.28 4187.13 15.97 o 1 2 0 623.01 644.71 6.42 o 2 2 0 6546.66 6975.90 40.62 o 3 2 0 74.23 67.50 0.88 o 4 2 0 1430.02 1540.22 9.26 o 5 2 0 857.96 934.69 21.73 o 6 2 0 407.94 397.71 9.47 o 7 2 0 11.22 10.60 0.74 o 8 2 0 203.31 202.83 3.94 o 9 2 0 5.54 4.76 0.78 o 10 2 0 19.00 17.86 1.24 o 11 2 0 84.39 77.86 2.05 o 12 2 0 2.93 3.73 1.58 o 1 3 0 2073.37 2220.51 3.54 o 2 3 0 188.98 162.95 1.55 o 3 3 0 2052.32 2380.34 25.17 o 4 3 0 1352.23 1444.44 22.31 o 5 3 0 145.80 147.64 2.63 o 6 3 0 144.76 142.16 1.67 o 7 3 0 215.47 225.88 2.79 o 8 3 0 0.09 0.86 0.59 o 9 3 0 88.04 78.59 2.66 o 10 3 0 0.09 1.54 1.04 o 11 3 0 160.68 169.80 3.43 o 12 3 0 100.84 103.77 2.84 o 0 4 0 35.27 41.54 0.68 o 1 4 0 62.14 62.66 0.55 o 2 4 0 2053.71 2137.43 17.94 o 3 4 0 128.07 153.53 0.93 o 4 4 0 0.94 2.53 0.43 o 5 4 0 71.83 71.06 0.86 o 6 4 0 24.73 25.34 1.30 o 7 4 0 34.44 39.27 1.02 o 8 4 0 47.02 56.97 1.16 o 9 4 0 19.25 16.73 1.09 o 10 4 0 7.06 4.75 0.93 o 11 4 0 29.34 28.52 1.53 o 12 4 0 46.74 47.11 3.84 o 1 5 0 246.94 243.92 0.90 o 2 5 0 692.51 741.07 3.92 o 3 5 0 7.53 8.74 0.37 o 4 5 0 881.40 894.20 6.66 o 5 5 0 12.21 11.27 0.44 o 6 5 0 288.70 290.13 2.62 o 7 5 0 241.53 226.60 2.18 o 8 5 0 8.26 2.90 0.95 o 9 5 0 62.44 63.18 1.45 o 10 5 0 4.02 4.88 1.26 o 11 5 0 6.82 6.75 1.33 o 0 6 0 212.29 217.94 2.47 o 1 6 0 107.72 113.84 0.74 o 2 6 0 20.77 23.55 0.63 o 3 6 0 65.34 83.71 0.93 o 4 6 0 432.49 442.14 2.52 o 5 6 0 63.29 55.29 0.66 o 6 6 0 0.23 1.02 0.50 o 7 6 0 13.94 8.81 0.60 o 8 6 0 48.69 37.96 1.26 o 9 6 0 2.96 2.93 1.17 o 10 6 0 47.30 46.41 1.58 o 11 6 0 2.01 1.76 1.39 o 1 7 0 137.97 140.59 1.12 o 2 7 0 121.91 112.92 0.78 o 3 7 0 730.97 727.35 4.77 o 4 7 0 0.67 1.55 0.37 o 5 7 0 318.85 288.27 2.66 o 6 7 0 10.20 6.73 0.72 o 7 7 0 93.99 100.67 2.69 o 8 7 0 2.71 2.63 1.02 o 9 7 0 2.49 2.51 1.13 o 10 7 0 61.83 60.63 2.14 o 0 8 0 0.35 0.50 0.46 o 1 8 0 17.90 16.84 0.52 o 2 8 0 5.53 6.12 0.63 o 3 8 0 0.06 0.88 0.39 o 4 8 0 739.41 744.72 5.53 o 5 8 0 125.56 109.27 1.17 o 6 8 0 324.65 311.38 5.18 o 7 8 0 1.30 0.96 0.75 o 8 8 0 172.67 171.93 2.86 o 9 8 0 3.36 4.17 1.36 o 1 9 0 184.83 178.63 1.28 o 2 9 0 49.62 44.22 0.80 o 3 9 0 21.04 22.47 0.85 o 4 9 0 26.12 28.69 0.71 o 5 9 0 6.89 5.01 0.62 o 6 9 0 5.49 6.68 0.94 o 7 9 0 2.21 3.14 1.00 o 8 9 0 43.44 49.17 2.35 o 9 9 0 99.46 90.37 3.76 o 0 10 0 349.56 354.46 4.08 o 1 10 0 131.36 129.43 1.51 o 2 10 0 735.67 753.35 4.13 o 3 10 0 0.00 0.36 0.66 o 4 10 0 93.73 96.73 1.20 o 5 10 0 38.07 34.18 0.86 o 6 10 0 13.53 15.73 1.24 o 7 10 0 56.15 55.66 1.49 o 8 10 0 138.99 141.85 2.49 o 1 11 0 139.17 142.56 1.46 o 2 11 0 2.60 2.26 0.74 o 3 11 0 1.64 2.14 0.75 o 4 11 0 0.01 1.05 0.82 o 5 11 0 85.66 93.62 3.09 o 6 11 0 8.54 9.17 1.58 o 7 11 0 4.91 4.97 1.63 o 8 11 0 354.91 403.39 4.89 o 0 12 0 416.56 426.77 23.71 o 1 12 0 9.65 7.79 0.97 o 2 12 0 45.71 44.33 1.92 o 3 12 0 9.31 10.49 1.35 o 4 12 0 41.38 41.52 1.84 o 5 12 0 0.05 0.00 2.02 o 6 12 0 7.04 6.84 1.97 o 1 13 0 32.15 28.89 2.35 o 2 13 0 19.08 22.74 1.75 o 3 13 0 6.17 7.93 1.57 o 4 13 0 20.21 22.94 1.94 o -12 1 1 32.05 29.77 2.77 o -11 1 1 191.60 176.54 2.75 o -10 1 1 9.33 9.06 0.92 o -9 1 1 151.64 143.17 2.53 o -8 1 1 224.16 233.25 2.03 o -7 1 1 129.54 140.75 2.97 o -6 1 1 10.47 10.64 0.52 o -5 1 1 209.10 240.63 5.02 o -4 1 1 27.84 26.19 0.42 o -3 1 1 1173.97 1278.58 8.97 o -2 1 1 22.14 25.21 0.44 o -1 1 1 1933.68 2055.32 13.35 o 1 1 1 1092.08 1172.12 15.24 o 2 1 1 875.40 861.14 12.34 o 3 1 1 49.55 45.86 0.95 o 4 1 1 284.44 298.20 5.53 o 5 1 1 757.67 777.85 16.90 o 6 1 1 52.71 53.11 1.97 o 7 1 1 1322.50 1302.39 30.65 o 8 1 1 3.32 2.32 0.85 o 9 1 1 195.39 188.73 4.26 o 10 1 1 1.89 2.45 1.25 o 11 1 1 2.75 2.88 1.42 o 12 1 1 0.02 0.94 1.36 o -12 2 1 68.96 69.84 1.76 o -11 2 1 33.71 33.71 1.23 o -10 2 1 8.90 9.52 1.09 o -9 2 1 62.15 56.51 1.92 o -8 2 1 255.65 264.25 2.15 o -7 2 1 97.87 91.90 1.63 o -6 2 1 160.87 171.27 3.14 o -5 2 1 559.94 645.85 9.55 o -4 2 1 1099.28 1121.51 17.85 o -3 2 1 34.76 36.43 0.70 o -2 2 1 20886.21 19961.14 180.86 o -1 2 1 839.96 831.59 9.84 o 0 2 1 2.94 3.21 0.26 o 1 2 1 4010.35 4154.41 35.14 o 2 2 1 932.79 924.75 7.92 o 3 2 1 86.57 98.19 0.68 o 4 2 1 23.45 23.87 0.46 o 5 2 1 724.17 826.03 12.05 o 6 2 1 180.78 190.81 4.28 o 7 2 1 603.52 594.20 14.16 o 8 2 1 145.26 127.16 2.31 o 9 2 1 287.89 286.93 3.50 o 10 2 1 18.21 18.05 1.56 o 11 2 1 0.00 0.95 1.48 o 12 2 1 25.30 20.56 2.13 o -12 3 1 13.79 12.36 1.39 o -11 3 1 171.48 169.99 7.02 o -10 3 1 0.40 2.06 0.67 o -9 3 1 75.18 73.15 1.64 o -8 3 1 42.09 42.04 1.14 o -7 3 1 29.02 31.62 0.59 o -6 3 1 470.68 478.07 7.15 o -5 3 1 6.09 5.73 0.38 o -4 3 1 130.20 126.84 1.83 o -3 3 1 16.86 24.07 0.49 o -2 3 1 123.04 120.57 0.64 o -1 3 1 1758.16 1893.10 10.31 o 0 3 1 153.13 149.69 0.71 o 1 3 1 599.28 556.95 1.71 o 2 3 1 0.68 1.37 0.36 o 3 3 1 1439.60 1611.57 6.42 o 4 3 1 433.97 438.70 2.10 o 5 3 1 46.72 55.00 1.12 o 6 3 1 44.35 50.03 0.98 o 7 3 1 75.21 76.89 1.65 o 8 3 1 5.78 7.17 0.89 o 9 3 1 91.12 70.80 2.54 o 10 3 1 126.41 114.08 2.40 o 11 3 1 4.65 4.25 1.23 o 12 3 1 14.72 18.03 3.63 o -12 4 1 124.76 127.48 3.69 o -11 4 1 0.88 1.90 1.11 o -10 4 1 1.21 1.50 0.91 o -9 4 1 68.81 60.03 2.01 o -8 4 1 238.61 216.08 2.08 o -7 4 1 83.90 71.90 1.13 o -6 4 1 1552.68 1666.23 24.77 o -5 4 1 70.68 88.81 1.63 o -4 4 1 997.15 1035.00 11.98 o -3 4 1 2579.66 2856.36 22.31 o -2 4 1 131.76 126.74 1.14 o -1 4 1 11.17 12.42 0.41 o 0 4 1 47.97 47.68 0.59 o 1 4 1 114.81 118.53 1.12 o 2 4 1 276.78 271.97 1.37 o 3 4 1 988.27 1146.97 8.78 o 4 4 1 27.99 28.69 0.61 o 5 4 1 9.97 12.16 0.56 o 6 4 1 2.21 5.19 0.85 o 7 4 1 25.34 24.90 0.95 o 8 4 1 2.14 1.43 0.86 o 9 4 1 20.32 18.33 1.48 o 10 4 1 225.22 223.61 3.25 o 11 4 1 6.70 6.71 1.57 o -12 5 1 128.83 121.27 4.17 o -11 5 1 11.70 9.05 1.29 o -10 5 1 12.87 9.80 1.22 o -9 5 1 5.69 4.05 0.91 o -8 5 1 171.34 143.81 2.57 o -7 5 1 101.88 81.33 2.17 o -6 5 1 277.31 298.81 3.02 o -5 5 1 38.00 32.98 0.68 o -4 5 1 56.74 50.22 0.54 o -3 5 1 89.01 94.09 0.68 o -2 5 1 621.82 641.96 2.03 o -1 5 1 5.90 10.36 0.66 o 0 5 1 2.10 2.56 0.32 o 1 5 1 72.03 82.44 0.94 o 2 5 1 70.62 62.01 0.87 o 3 5 1 769.69 747.09 7.02 o 4 5 1 8.90 7.11 0.57 o 5 5 1 444.86 470.44 3.59 o 6 5 1 175.20 202.75 2.77 o 7 5 1 10.24 10.34 0.76 o 8 5 1 17.05 9.28 0.93 o 9 5 1 4.92 7.74 0.99 o 10 5 1 7.70 11.99 1.32 o 11 5 1 74.03 67.44 1.67 o 12 5 1 116.66 124.06 3.23 o -11 6 1 22.47 24.62 2.23 o -10 6 1 7.12 4.00 1.38 o -9 6 1 25.60 31.92 1.62 o -8 6 1 40.23 29.71 0.86 o -7 6 1 140.55 118.74 2.01 o -6 6 1 251.53 241.96 2.13 o -5 6 1 208.63 183.63 1.31 o -4 6 1 34.64 37.81 0.79 o -3 6 1 1.49 1.25 0.33 o -2 6 1 82.21 85.38 0.79 o -1 6 1 62.49 55.23 0.58 o 0 6 1 530.46 528.72 2.57 o 1 6 1 76.84 80.54 0.62 o 2 6 1 443.37 429.46 2.71 o 3 6 1 54.99 47.96 0.52 o 4 6 1 77.47 83.20 0.92 o 5 6 1 4.02 4.47 0.52 o 6 6 1 24.74 15.47 0.96 o 7 6 1 13.85 11.26 0.83 o 8 6 1 6.48 8.71 0.89 o 9 6 1 4.07 4.36 1.00 o 10 6 1 44.90 53.47 1.69 o 11 6 1 1.49 2.54 1.38 o -10 7 1 83.20 90.72 2.02 o -9 7 1 23.97 22.32 1.93 o -8 7 1 5.12 6.63 1.05 o -7 7 1 3.83 4.65 0.78 o -6 7 1 60.61 64.82 0.82 o -5 7 1 49.60 46.78 0.73 o -4 7 1 524.01 529.01 2.61 o -3 7 1 65.71 56.47 0.61 o -2 7 1 200.46 193.69 1.62 o -1 7 1 31.64 30.09 0.50 o 0 7 1 1.60 2.11 0.39 o 1 7 1 17.27 19.73 0.53 o 2 7 1 340.30 353.85 1.71 o 3 7 1 10.00 8.91 0.45 o 4 7 1 87.55 75.22 0.95 o 5 7 1 37.43 31.47 0.70 o 7 7 1 259.17 261.32 2.03 o 8 7 1 13.56 15.43 1.01 o 9 7 1 12.60 11.11 1.33 o 10 7 1 10.29 9.25 1.64 o -10 8 1 0.04 0.68 2.89 o -9 8 1 0.12 2.13 1.44 o -8 8 1 2.81 3.48 0.98 o -7 8 1 0.03 1.46 0.75 o -6 8 1 72.89 66.80 1.51 o -5 8 1 211.09 206.73 1.36 o -4 8 1 390.56 382.12 1.50 o -3 8 1 30.30 33.87 0.61 o -2 8 1 19.80 16.80 0.56 o -1 8 1 93.23 91.80 0.83 o 0 8 1 27.61 25.59 0.57 o 1 8 1 133.15 126.57 1.20 o 2 8 1 353.95 354.90 2.36 o 3 8 1 348.44 337.63 1.82 o 4 8 1 4.01 4.99 0.44 o 5 8 1 9.03 13.37 0.75 o 6 8 1 12.56 17.40 1.03 o 7 8 1 114.14 121.61 1.47 o 8 8 1 13.72 15.75 1.37 o 9 8 1 32.85 34.15 2.08 o -9 9 1 32.18 32.14 2.39 o -8 9 1 19.31 18.11 1.38 o -7 9 1 74.44 78.49 1.99 o -6 9 1 24.17 25.89 0.84 o -5 9 1 52.63 51.01 1.03 o -4 9 1 97.46 96.72 1.73 o -3 9 1 414.46 414.60 2.99 o -2 9 1 265.67 269.04 1.86 o -1 9 1 74.37 76.17 0.91 o 0 9 1 52.72 50.11 0.78 o 1 9 1 513.77 515.67 3.98 o 2 9 1 0.00 0.43 0.61 o 3 9 1 111.19 114.10 1.54 o 4 9 1 28.52 26.14 0.80 o 5 9 1 77.03 74.87 1.39 o 6 9 1 49.04 47.76 1.48 o 7 9 1 0.11 0.76 0.88 o 8 9 1 0.99 0.00 1.91 o 9 9 1 19.51 15.76 3.12 o -9 10 1 85.97 96.11 2.74 o -8 10 1 77.68 77.68 2.71 o -7 10 1 0.47 1.22 0.91 o -6 10 1 38.80 40.64 2.65 o -5 10 1 31.00 29.59 0.88 o -4 10 1 135.71 135.55 1.43 o -3 10 1 105.02 100.45 2.10 o -2 10 1 322.52 314.22 2.57 o -1 10 1 244.65 245.83 2.41 o 0 10 1 30.67 27.73 1.58 o 1 10 1 14.51 13.79 0.88 o 2 10 1 541.62 552.85 7.58 o 3 10 1 136.48 131.60 2.70 o 4 10 1 3.63 2.75 0.72 o 5 10 1 3.71 7.40 1.31 o 6 10 1 86.00 88.34 2.05 o 7 10 1 30.47 32.26 1.75 o -8 11 1 33.57 41.48 2.96 o -7 11 1 90.67 110.77 2.13 o -6 11 1 14.42 12.89 1.04 o -5 11 1 10.35 6.94 0.88 o -4 11 1 5.18 6.41 0.94 o -3 11 1 45.96 42.96 1.10 o -2 11 1 30.92 27.06 1.39 o -1 11 1 11.00 10.31 0.91 o 0 11 1 159.00 164.82 2.99 o 1 11 1 23.98 22.90 1.01 o 2 11 1 0.89 1.60 0.83 o 3 11 1 2.01 1.67 0.81 o 4 11 1 51.62 52.02 2.88 o 5 11 1 19.95 18.75 1.50 o 6 11 1 51.30 55.51 2.32 o 7 11 1 95.39 95.20 2.71 o -6 12 1 163.35 187.82 3.75 o -5 12 1 43.41 42.92 2.40 o -4 12 1 2.96 3.80 1.28 o -3 12 1 4.13 3.59 0.93 o -2 12 1 0.16 1.23 0.78 o -1 12 1 91.78 87.70 1.50 o 0 12 1 533.60 560.79 8.67 o 1 12 1 236.43 238.18 2.48 o 2 12 1 39.11 36.28 1.76 o 3 12 1 99.85 102.96 1.64 o 4 12 1 6.23 8.09 1.52 o 5 12 1 0.07 1.39 1.89 o 6 12 1 0.44 0.37 1.49 o -4 13 1 22.75 22.88 1.87 o -3 13 1 5.59 6.86 1.44 o -2 13 1 76.98 84.36 2.10 o -1 13 1 73.46 71.32 2.05 o 0 13 1 24.01 23.84 1.64 o 1 13 1 41.00 39.76 1.59 o 2 13 1 23.87 20.09 1.63 o 3 13 1 98.22 107.79 2.24 o -13 0 2 40.91 40.91 4.08 o -12 0 2 49.76 49.65 3.40 o -11 0 2 153.36 152.98 1.87 o -10 0 2 82.68 87.36 2.70 o -9 0 2 451.94 451.36 6.77 o -8 0 2 1.02 1.44 0.72 o -7 0 2 1243.21 1349.22 7.84 o -6 0 2 599.77 659.52 8.90 o -5 0 2 682.27 655.04 29.62 o -4 0 2 7.64 7.95 0.54 o -3 0 2 1010.16 1009.67 2.14 o -2 0 2 733.60 712.97 12.70 o -1 0 2 1567.48 1577.22 80.16 o 0 0 2 5290.90 5270.21 76.92 o 1 0 2 295.17 313.01 7.63 o 2 0 2 2279.29 2466.71 35.38 o 3 0 2 1404.91 1463.61 25.23 o 4 0 2 525.29 534.23 2.08 o 5 0 2 126.69 127.63 2.42 o 6 0 2 1.08 0.84 1.36 o 7 0 2 626.90 574.40 5.60 o 8 0 2 31.66 25.64 2.18 o 9 0 2 14.75 11.88 1.57 o 10 0 2 8.10 6.73 1.75 o 11 0 2 49.63 44.03 3.33 o -13 1 2 4.35 3.61 1.54 o -12 1 2 0.04 1.68 1.02 o -11 1 2 2.58 1.38 0.73 o -10 1 2 23.04 22.59 0.82 o -9 1 2 7.12 6.80 0.61 o -8 1 2 503.05 500.95 3.78 o -7 1 2 944.20 965.02 13.03 o -6 1 2 4.68 5.27 0.44 o -5 1 2 258.06 251.61 4.49 o -4 1 2 9.17 16.07 0.39 o -3 1 2 5808.70 6549.32 20.73 o -2 1 2 73.44 78.85 1.30 o -1 1 2 4773.02 5108.47 26.47 o 0 1 2 0.09 0.69 0.37 o 1 1 2 409.00 358.28 6.97 o 2 1 2 464.66 402.74 4.28 o 3 1 2 836.52 798.80 2.09 o 4 1 2 50.94 46.80 0.66 o 5 1 2 54.90 55.72 2.47 o 6 1 2 380.17 359.00 2.94 o 7 1 2 759.86 719.35 4.28 o 8 1 2 68.43 65.72 1.41 o 9 1 2 74.91 79.14 1.87 o 10 1 2 114.80 102.38 2.91 o 11 1 2 28.34 26.11 2.18 o -13 2 2 8.93 7.30 2.17 o -12 2 2 279.24 285.48 6.49 o -11 2 2 210.42 204.26 3.70 o -10 2 2 12.08 14.08 0.83 o -9 2 2 7.60 8.38 0.68 o -8 2 2 67.39 68.38 1.32 o -7 2 2 16.10 12.00 0.44 o -6 2 2 82.60 78.72 0.67 o -5 2 2 777.26 888.39 7.90 o -4 2 2 994.00 1123.92 5.50 o -3 2 2 17.29 15.09 0.37 o -2 2 2 13468.60 13999.19 86.98 o -1 2 2 586.14 658.96 3.16 o 0 2 2 96.41 80.27 1.11 o 1 2 2 438.51 425.58 3.85 o 2 2 2 760.65 786.62 4.01 o 3 2 2 62.83 72.66 0.94 o 4 2 2 445.11 476.92 3.75 o 5 2 2 86.30 91.52 2.16 o 6 2 2 14.14 13.60 1.39 o 7 2 2 169.93 169.72 2.37 o 8 2 2 413.13 375.07 5.89 o 9 2 2 91.98 92.72 1.77 o 10 2 2 107.64 107.63 2.67 o 11 2 2 0.37 0.54 1.30 o -13 3 2 20.38 19.32 2.99 o -12 3 2 6.37 6.02 0.95 o -11 3 2 234.44 232.57 6.06 o -10 3 2 285.98 260.30 3.40 o -9 3 2 16.68 18.89 0.84 o -8 3 2 60.57 58.75 1.34 o -7 3 2 208.97 203.11 2.06 o -6 3 2 549.68 511.45 5.08 o -5 3 2 130.15 153.16 1.32 o -4 3 2 108.65 94.31 1.25 o -3 3 2 485.68 497.72 4.66 o -2 3 2 1413.89 1565.01 4.84 o -1 3 2 300.89 275.37 1.06 o 0 3 2 142.76 133.97 1.92 o 1 3 2 891.51 903.28 8.91 o 2 3 2 120.24 120.83 1.20 o 3 3 2 906.26 981.56 6.46 o 4 3 2 1254.28 1362.70 20.68 o 5 3 2 889.95 884.83 3.84 o 6 3 2 7.68 3.82 0.84 o 7 3 2 21.59 23.33 1.08 o 8 3 2 194.58 172.72 5.25 o 9 3 2 37.14 41.40 1.60 o 10 3 2 89.56 99.58 2.68 o 11 3 2 0.01 1.38 1.42 o -12 4 2 25.27 26.66 1.82 o -11 4 2 50.10 49.87 1.63 o -10 4 2 378.97 349.84 5.62 o -9 4 2 4.60 3.26 1.04 o -8 4 2 15.35 13.33 0.73 o -7 4 2 750.28 738.35 7.20 o -6 4 2 7.80 8.73 0.50 o -5 4 2 105.66 87.54 0.90 o -4 4 2 3553.83 3959.41 9.11 o -3 4 2 314.20 279.71 2.81 o -2 4 2 29.48 25.77 0.49 o -1 4 2 3726.03 4058.94 15.71 o 0 4 2 10.14 11.85 0.41 o 1 4 2 94.91 113.07 1.46 o 2 4 2 68.83 80.01 1.74 o 3 4 2 864.97 962.38 4.20 o 4 4 2 49.81 53.38 1.17 o 5 4 2 448.52 421.22 6.76 o 6 4 2 60.02 49.89 1.19 o 7 4 2 56.29 56.93 1.35 o 8 4 2 6.76 5.58 1.08 o 9 4 2 2.44 0.57 1.03 o 10 4 2 117.18 104.94 2.04 o 11 4 2 74.27 80.00 2.09 o -12 5 2 23.72 21.77 2.97 o -11 5 2 58.13 56.08 1.96 o -10 5 2 96.14 94.66 1.90 o -9 5 2 79.59 78.50 1.29 o -8 5 2 4.27 5.96 0.69 o -7 5 2 113.72 103.34 1.39 o -6 5 2 15.88 18.45 0.78 o -5 5 2 79.41 77.12 1.63 o -4 5 2 119.22 124.63 0.80 o -3 5 2 39.37 43.98 1.37 o -2 5 2 95.57 81.00 0.89 o -1 5 2 724.07 730.40 2.55 o 0 5 2 0.30 1.32 0.45 o 1 5 2 1069.96 1186.48 6.04 o 2 5 2 198.78 170.40 1.32 o 3 5 2 102.24 84.56 0.87 o 4 5 2 123.87 120.58 1.55 o 5 5 2 2.16 2.53 0.47 o 6 5 2 71.68 68.53 1.09 o 7 5 2 178.07 154.14 2.23 o 8 5 2 139.25 112.40 2.31 o 9 5 2 62.48 67.82 2.23 o 10 5 2 22.98 25.49 1.33 o 11 5 2 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