While it's tempting to write this show off as a lame-o Charlie's Angles rip-off, you really shouldn't do that. She Spies is a variation on that theme that actually is better than the original. Three misfit women are pulled out of prison and forced to work for the FBI putting bad guys in jail. What makes this series much better than the original is: 1. The cast acts better, 2. The humor actually works, and 3. You can really sympathize with the women of She Spies more than you could the women of Charlie's Angels. About the only complaint I have about it is that being a syndicated show, it's on at a very inconvenient hour in most markets (many places show it around midnight on Saturday as of this writing.)
It's worth checking out.