Humidity

Humidity and hygrometry
Specific concepts
Absolute / Specific / Relative Dew point (depression) Psychrometrics
General concepts
Air Concentration Density Dew Evaporation Humidity buffering (Atm.) Pressure Liquid water Avogadro's law Nucleation Thermodynamic equilibrium
Measures and Instruments
Heat index Sat. vap. density Mixing ratio Water activity H. indicator card Hygrometer Dry/Wet-bulb temperature

Humidity is the amount of water vapor in the air. Water vapor is the gaseous state of water and is invisible. Humidity indicates the likelihood of precipitation, dew, or fog. Higher humidity reduces the effectiveness of sweating in cooling the body by reducing the rate of evaporation of moisture from the skin. This effect is calculated in a heat index table or humidex.

There are three main measurements of humidity: absolute, relative and specific. Absolute humidity is the water content of air at a given temperature expressed in gram per cubic metre. Relative humidity, expressed as a percent, measures the current absolute humidity relative to the maximum (highest point) for that temperature. Specific humidity is a ratio of the water vapor content of the mixture to the total air content on a mass basis.

Types

Paranal Observatory on Cerro Paranal in the Atacama Desert is one of the driest places on earth.

Absolute humidity

Absolute humidity is the total mass of water vapor present in a given volume of air. It does not take temperature into consideration. Absolute humidity in the atmosphere ranges from near zero to roughly 30 grams per cubic meter when the air is saturated at 30 °C.

Absolute humidity is the mass of the water vapor $(m_{H_2O})$, divided by the volume of the air and water vapor mixture $(V_{net} )$, which can be expressed as:

$AH = {m_{H_2O} \over V_{net}}.$

The absolute humidity changes as air temperature or pressure changes. This makes it unsuitable for chemical engineering calculations, e.g. for clothes dryers, where temperature can vary considerably. As a result, absolute humidity in chemical engineering may refer to mass of water vapor per unit mass of dry air, also known as the mass mixing ratio (see "specific humidity" below), which is better suited for heat and mass balance calculations. Mass of water per unit volume as in the equation above is also defined as volumetric humidity. Because of the potential confusion, British Standard BS 1339 (revised 2002) suggests avoiding the term "absolute humidity". Units should always be carefully checked. Many humidity charts are given in g/kg or kg/kg, but any mass units may be used.

The field concerned with the study of physical and thermodynamic properties of gas–vapor mixtures is named psychrometrics.

Relative humidity

Main article: Relative humidity

The relative humidity $(RH$ or $\phi)$ of an air-water mixture is defined as the ratio of the partial pressure of water vapor $(p_{H_2O})$ in the mixture to the equilibrium vapor pressure of water $(p^*_{H_2O})$ at a given temperature:

$\phi = {p_{H_2O} \over p^*_{H_2O}}$

Relative humidity is normally expressed as a percentage; a higher percentage means that the air-water mixture is more humid.

Relative humidity is an important metric used in weather forecasts and reports, as it is an indicator of the likelihood of precipitation, dew, or fog. In hot summer weather, a rise in relative humidity increases the apparent temperature to humans (and other animals) by hindering the evaporation of perspiration from the skin. For example, according to the Heat Index, a relative humidity of 75% at 80.0 °F (26.7 °C) would feel like 83.6 °F ±1.3 °F (28.7 °C ±0.7 °C) at ~44% relative humidity.

Specific humidity

Specific humidity (or moisture content) is the ratio of water vapor mass ($m_v$) to the air parcel's total (i.e., including dry) mass ($m_a$) and is sometimes referred to as the humidity ratio. Specific humidity is approximately equal to the "mixing ratio", which is defined as the ratio of the mass of water vapor in an air parcel to the mass of dry air for the same parcel.

Specific Humidity is defined as:

$SH = {m_v \over m_a}.$

Specific humidity can be expressed in other ways including:

$SH = {0.622 \times {p_{H_2O}} \over {p_{(dry\, air)}}}$

$0.622 = {{MM_{H_2O}} \over {MM_{(dry\, air)}}}$

or:

$SH = {{0.622 \times p_{H_2O}}\over {p-0.378 \times p_{H_2O}}}.$

Using this definition of specific humidity, the relative humidity can be expressed as

$\phi = {{SH \times p}\over {(0.622+0.378 \times SH) p^*_{H_2O}}}$

However, specific humidity is also defined as the ratio of water vapor to the total mass of the system (dry air plus water vapor). For example, the ASHRAE 2009 Handbook, Ch1,1.2, (9a) defines specific humidity as "the ratio of the mass of water vapor to total mass of the moist air sample".

Measurement

A hygrometer

There are various devices used to measure and regulate humidity. A device used to measure humidity is called a psychrometer or hygrometer. A humidistat is a humidity-triggered switch, often used to control a dehumidifier.

Humidity is also measured on a global scale using remotely placed satellites. These satellites are able to detect the concentration of water in the troposphere at altitudes between 4 and 12 kilometers. Satellites that can measure water vapor have sensors that are sensitive to infrared radiation. Water vapor specifically absorbs and re-radiates radiation in this spectral band. Satellite water vapor imagery plays an important role in monitoring climate conditions (like the formation of thunderstorms) and in the development of future weather forecasts.

Climate

See also: Greenhouse Effect, Precipitation (meteorology), and Humid subtropical climate

While humidity itself is a climate variable, it also interacts strongly with other climate variables. The humidity is affected by winds and by rainfall. At the same time, humidity affects the energy budget and thereby influences temperatures in two major ways. First, water vapor in the atmosphere contains "latent" energy. During transpiration or evaporation, this latent heat is removed from surface liquid, cooling the earth's surface. This is the biggest non-radiative cooling effect at the surface. It compensates for roughly 70% of the average net radiative warming at the surface.

Second, water vapor is the most abundant of all greenhouse gases. Water vapor, like a green lens that allows green light to pass through it but absorbs red light, is a "selective absorber". Along with other greenhouse gases, water vapor is transparent to most solar energy, as you can literally see. But it absorbs the infrared energy emitted (radiated) upward by the earth's surface, which is the reason that humid areas experience very little nocturnal cooling but dry desert regions cool considerably at night. This selective absorption causes the greenhouse effect. It raises the surface temperature substantially above its theoretical radiative equilibrium temperature with the sun, and water vapor is the cause of more of this warming than any other greenhouse gas.

Unlike most other greenhouse gases, however, water is not merely below its boiling point in all regions of the Earth, but below its freezing point at many altitudes. As a condensible greenhouse gas, it precipitates, with a much lower scale height and shorter atmospheric lifetime- weeks instead of decades. Without other greenhouse gases, Earth's blackbody temperature, below the freezing point of water, would cause water vapor to be removed from the atmosphere. Water vapor is thus a "slave" to the non-condensible greenhouse gases.

The most humid cities on earth are generally located closer to the equator, near coastal regions. Cities in South and Southeast Asia are among the most humid. Kuala Lumpur, Jakarta, and Singapore have very high humidity all year round because of their proximity to water bodies and the equator and often overcast weather. Some places experience extreme humidity during their rainy seasons combined with warmth giving the feel of a lukewarm sauna, such as Kolkata, Chennai and Cochin in India, and Lahore in Pakistan. Sukkur city located on the Indus River in Pakistan has some of the highest and most uncomfortable dew point in the country frequently exceeding 30 °C (86 °F) in the Monsoon season. High temperatures couple up with bizarre dew point to create heat index in excess of 65 °C (149 °F). Darwin, Australia experiences an extremely humid wet season from December to April. Shanghai and Hong Kong in China also have an extreme humid period in their summer months. During the South-west and North-east Monsoon seasons (respectively, late May to September and November to March), expect heavy rains and a relatively high humidity post-rainfall. Outside the monsoon seasons, humidity is high (in comparison to countries North of the Equator), but completely sunny days abound. In cooler places such as Northern Tasmania, Australia, high humidity is experienced all year due to the ocean between mainland Australia and Tasmania. In the summer the hot dry air is absorbed by this ocean and the temperature rarely climbs above 35 °C (95 °F).

In the United States the most humid cities, strictly in terms of relative humidity, are Forks and Olympia, Washington. This fact may come as a surprise to many, as the climate in this region rarely exhibits the discomfort usually associated with high humidity. This is because high dew points play a more significant role than relative humidity in discomfort, and so the air in these western cities usually does not feel "humid" as a result. In general, dew points are much lower in the Western U.S. than those in the Eastern U.S.

The highest dew points in the US are found in coastal Florida and Texas. When comparing Key West and Houston, two of the most humid cities from those states, coastal Florida seems to have the higher dew points on average. However, Houston lacks the coastal breeze present in Key West, and, as a much larger city, it suffers from the urban heat island effect. A dew point of 88 °F (31 °C) was recorded in Moorhead Minnesota on July 19, 2011, with a heat index of 133.5, although dew points over 80 °F (27 °C) are rare there. The US city with the lowest annual humidity is Las Vegas, Nevada, averaging 39% for a high and 21% as a low. Appleton, Wisconsin registered a dew point of 90 degrees F on 13 July 1995 with an air temperature of 104 degrees resulting in a heat index of 149 degrees; this record has apparently held and in fact the highest dew point measured in the country bounced amongst or was tied by locations in Wisconsin, Minnesota, and Iowa during the preceding 70 years or more with locations in northern Illinois also coming close. Dew points of 95 degrees are found on the Red Sea coast of Saudi Arabia at certain times.

Air density and volume

Main articles: Volume (thermodynamics) and Density of air

Humidity depends on water vaporization and condensation, which, in turn, mainly depends on temperature. Therefore, when applying more pressure to a gas saturated with water, all components will initially decrease in volume approximately according to the ideal gas law. However, some of the water will condense until returning to almost the same humidity as before, giving the resulting total volume deviating from what the ideal gas law predicted. Conversely, decreasing temperature would also make some water condense, again making the final volume deviate from predicted by the ideal gas law. Therefore, gas volume may alternatively be expressed as the dry volume, excluding the humidity content. This fraction more accurately follows the ideal gas law. On the contrary the saturated volume is the volume a gas mixture would have if humidity was added to it until saturation (or 100% relative humidity).

Humid air is less dense than dry air because a molecule of water (M ≈ 18 u) is less massive than either a molecule of nitrogen (M ≈ 28) or a molecule of oxygen (M ≈ 32). About 78% of the molecules in dry air are nitrogen (N₂). Another 21% of the molecules in dry air are oxygen (O₂). The final 1% of dry air is a mixture of other gases.

For any gas, at a given temperature and pressure, the number of molecules present in a particular volume is constant – see ideal gas law. So when water molecules (vapor) are introduced into that volume of dry air, the number of air molecules in the volume must decrease by the same number, if the temperature and pressure remain constant. (The addition of water molecules, or any other molecules, to a gas, without removal of an equal number of other molecules, will necessarily require a change in temperature, pressure, or total volume; that is, a change in at least one of these three parameters. If temperature and pressure remain constant, the volume increases, and the dry air molecules that were displaced will initially move out into the additional volume, after which the mixture will eventually become uniform through diffusion.) Hence the mass per unit volume of the gas—its density—decreases. Isaac Newton discovered this phenomenon and wrote about it in his book Opticks.

Effects

Animals and plants

Humidity is one of the fundamental abiotic factors that defines any habitat, and is a determinant of which animals and plants can thrive in a given environment.

The human body dissipates heat through perspiration and its evaporation. Heat convection to the surrounding air, and thermal radiation are the primary modes of heat transport from the body. Under conditions of high humidity, the rate of evaporation of sweat from the skin decreases. Also, if the atmosphere is as warm as or warmer than the skin during times of high humidity, blood brought to the body surface cannot dissipate heat by conduction to the air, and a condition called hyperthermia results. With so much blood going to the external surface of the body, less goes to the active muscles, the brain, and other internal organs. Physical strength declines, and fatigue occurs sooner than it would otherwise. Alertness and mental capacity also may be affected, resulting in heat stroke or hyperthermia.

Human comfort

Humans are sensitive to humid air because the human body uses evaporative cooling as the primary mechanism to regulate temperature. Under humid conditions, the rate at which perspiration evaporates on the skin is lower than it would be under arid conditions. Because humans perceive the rate of heat transfer from the body rather than temperature itself, we feel warmer when the relative humidity is high than when it is low.

Some people experience difficulty breathing in humid environments. Some cases may possibly be related to respiratory conditions such as asthma, while others may be the product of anxiety. Sufferers will often hyperventilate in response, causing sensations of numbness, faintness, and loss of concentration, among others.

Air conditioning reduces discomfort in the summer not only by reducing temperature, but also by reducing humidity. In winter, heating cold outdoor air can decrease relative humidity levels indoor to below 30%, leading to discomfort such as dry skin, cracked lips and excessive thirst.

Electronics

Many electronic devices have humidity specifications, for example, 5% to 45%. At the top end of the range, moisture may increase the conductivity of permeable insulators leading to malfunction. Too low humidity may make materials brittle. A particular danger to electronic items, regardless of the stated operating humidity range, is condensation. When an electronic item is moved from a cold place (e.g. garage, car, shed, an air conditioned space in the tropics) to a warm humid place (house, outside tropics), condensation may coat circuit boards and other insulators, leading to short circuit inside the equipment. Such short circuits may cause substantial permanent damage if the equipment is powered on before the condensation has evaporated. A similar condensation effect can often be observed when a person wearing glasses comes in from the cold (i.e. the glasses become foggy). It is advisable to allow electronic equipment to acclimatise for several hours, after being brought in from the cold, before powering on. Some electronic devices can detect such a change and indicate, when plugged in and usually with a small droplet symbol, that they cannot be used until the risk from condensation has passed. In situations where time is critical, increasing air flow through the device's internals, such as removing the side panel from a PC case and directing a fan to blow into the case, will reduce significantly the time needed to acclimatise to the new environment.

In contrast, a very low humidity level favors the build-up of static electricity, which may result in spontaneous shutdown of computers when discharges occur. Apart from spurious erratic function, electrostatic discharges can cause dielectric breakdown in solid state devices, resulting in irreversible damage. Data centers often monitor relative humidity levels for these reasons.

Building construction

Common construction methods often produce building enclosures with a poor thermal boundary, requiring an insulation and air barrier system designed to retain indoor environmental conditions while resisting external environmental conditions. The energy-efficient, heavily-sealed architecture introduced in the 20th century also sealed off the movement of moisture, and this has resulted in a secondary problem of condensation forming in and around walls, which encourages the development of mold and mildew. Additionally, buildings with foundations not properly sealed will allow water to flow through the walls due to capillary action of pores found in masonry products. Solutions for energy-efficient buildings that avoid condensation are a current topic of architecture.

Industry

High humidity can often have a negative effect on the capacity of chemical plants and refineries that use furnaces as part of the process (e.g. steam reforming, wet sulfuric acid process). The humidity will reduce the oxygen concentration, and the flue gas fans have to pull more air through the system to get the same firing rate (dry air is 20.9% Oxygen, at 100% relative humidity, the air is 20.4% oxygen).

See also

• Dew point depression
• Humidity indicator
• Savory brittleness scale

References

• United States Environmental Protection Agency, "IAQ in Large Buildings". Retrieved Jan. 9, 2006.

External links

• Glossary definition of absolute humidity – National Science Digital Library
• Glossary definition of psychrometric tables – National Snow and Ice Data Center
• Glossary definition of specific humidity – National Snow and Ice Data Center
• FREE Humidity & Dewpoint Calculator – Vaisala
• Free Windows Program, Dewpoint Units Conversion Calculator – PhyMetrix
• Free Online Humidity Calculator – Calculate about 16 parameters online with the Rotronic Humidity Calculator
• Calculator for humidity sensor and ebook – Calculator for humidity sensor for rapid conversion of humidity measurements. Uniquely, includes measurement uncertainties and ebook: Principles of Humidity Measurement