Answ Er Key: Hints & Solutions (Practice Paper-1)

1
Pre-foundation Career Care Programmes (PCCP) Division

1
PART-I (1 Mark)
MATHEMATICS
1.
7
3
2
2
1
x x
|
|
.
|
\
|
General term = ( 1)
r

7
C
r

r 7
2
1
x
|
|
.
|
\
|

r
3
2
x
|
|
.
|
\
|
T
r + 1
= ( 1)
r

7
C
r

3
r 2
2
r 7
x x
= ( 1)
r

7
C
r

3
r 2
2
r 7
x
+
= ( 1)
r

7
C
r

6
r 4 r 3 21
x
+
= ( 1)
r

7
C
r

6
r 21
x
+
For the coefficient of x
4
,
6
r 21+
= 4
21 + r = 24
r = 24 21
r = 3
T
3 + 1
= ( 1)
3

7
C
3
= 1
2 3
5 6 7

= 35.
ANSWER KEY
HINTS & SOLUTIONS (PRACTICE PAPER-1)
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans.
D B C C D D A B B A
C D D D B
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. A B B D B B D A B B
A D B A A
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans.
B B B D D C D B B A D C A D
Ques. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans.
B C B C B A B A A B C A A C B
Ques. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans.
C B A B C D D D C C C D B B C
Ques. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans.
B A B C A B B C A A B A C B B
Ques. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. A D D A C D A A C D B D A B D
Ques. 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. D C D B B A A A D D B A B A B
id3573687 pdfMachine by Broadgun Software - a great PDF writer! - a great PDF creator! - http://www.pdfmachine.com http://www.broadgun.com
2
2
2.
z
z
z
z
+
= 1 and | z | = 1
Let z = x + iy
Then, z = x iy
| z | =
2 2
y x + = 1
or x
2
+ y
2
= 1
iy x
iy x
iy x
iy x
+
+
= 1
2 2
2 2 2 2
y x
ixy 2 y x ixy 2 y x
+
+ +
= 1
2 2
2 2
y x
) y x ( 2
+
= 1
2x
2
2y
2
= x
2
+ y
2
x
2
= 3y
2
x = y 3
Now, x
2
+ y
2
= 1
3y
2
+ y
2
= 1
4y
2
= 1
y
2
=
4
1
y =
2
1
Then, x =
2
3
Different complex number are : z =
2
3
+ i
2
1
, z =
2
3
i
2
1
, z =
2
3
+ i
2
1
and z =
2
3
i
2
1
.
3. Let A
1
= B
Therefore AB = I
A
43 41
37 35
=
1 0
0 1
35
R
R
1
1

A
43 41
35
37
1
=
1 0
0
35
1
1 2 2
R 41 R R
A
35
12
0
35
37
1
=
1
35
41
0
35
1
2 2
R
12
35
R
3
3
A
1 0
35
37
1
=
12
35
12
41
0
35
1
2 1 1
R
35
37
R R
A
1 0
0 1
=
12
35
12
41
12
37
12
43
A =
12
35
12
41
12
37
12
43
12 A =
35 41
37 43
det (12A) = | 43 35 4137|
= 1505 1517
= 12.
4. Given :
=1 n
2
n
1
=
6
2
t
=
+ + + +
+ + + +
1 n
3 3 3 3
n ..... 3 2 1
) 1 n 2 ( ... 5 3 1
=
+
1 n
2 2
2
4
) 1 n ( n
n
=
+
1 n
2
) 1 n (
4
4
|
.
|
\
|
+ + +
1 n
2 2
1 .........
3
1
2
1
1
4

1 n
2
1
n
1
4
|
|
.
|
\
|
t
1
6
2
.
4
4
5. 4ax
2
+ xy + 4y
2
= 0
m
1
+ m
2
=
b
h 2
m
1
+ m
2
=
4
1
m
1
m
2
=
b
a

m
1
m
2
=
4
a 4
= a
Given : m
2
= m
1
2
m
1
+ m
1
2
=
4
1
4m
1
2
+ 4m
1
= 1
4m
1
2
+ 4m
1
+ 1 = 0
(2m
1
+ 1)
2
= 0
m
1
=
2
1
m
1
m
2
= a
m
1
m
1
2
= a
m
1
3
= a

3
2
1
|
.
|
\
|
= a
a =
8
1
.
6. y = 2x
2
+ x 2
B
A
Let point A is (t
1
, 2t
1
2
+ t
1
2 ) and point B is (t
2
, 2t
2
2
+ t
2
2)
Given : Mid point of AB is (0, 0)
So,
2
t t
2 1
+
= 0 t
1
+ t
2
= 0
2
2 t t 2 2 t t 2
2
2
2 1
2
1
+ + +
= 0
2(t
1
2
+ t
2
2
) + (t
1
+ t
2
) 4 = 0
2[(t
1
+ t
2
)
2

2t
1
t
2
] + 0 4 = 0
2[0 2t
1
t
2
] = 4
4t
1
t
2
= 4
t
1
t
2
= 1
(t
1
t
2
)
2
= (t
1
+ t
2
)
2
4t
1
t
2
= 0 4( 1)
= 4
t
1
t
2
= 2.
Distance AB :
AB =
2
2
2
2 1
2
1
2
2 1
) 2 t t 2 2 t t 2 ( ) t t ( + + +
AB =
| |
2
2 1
2
2
2
1
2
2 1
) t t ( ) t t ( 2 ) t t ( + +
5
5
AB =
| |
2
2 1 2 1 2 1
2
) t t ( ) t t )( t t ( 2 ) 2 ( + + +
AB =
| |
2
) 2 ( ) 0 ( 2 4 + +
AB =
4 4 +
=
8
= 2 2 .
7.
(1, 1)
1
1
1
1
0,
c
4
, 0
c
3
3
x

+

4
y

+

c

=

0
Perperndicular from (1, 1) on line 3x + 4y + c = 0
16 9
c 4 3
+
+ +
= 1
| 7 + c | = 5
7 + c = 5
c = 5 7
c = 12
| c | = 12.
8. p cos
2

|
.
|
\
|
2
R
+ r cos
2
|
.
|
\
|
2
P
p
pq
) r s ( s
+ r
qr
) p s ( s
=
q
s
[s r + s p]
=
q
s
[2s r p]
=
q
s
[p + q + r r p]
= s
=
2
r q p + +
.
9. 3cos
2
x sin
2
x sin
4
x cos
2
x = 0
3(1 sin
2
x) sin
2
x sin
4
x (1 sin
2
x) = 0
3 sin
2
x 3sin
4
x sin
4
x 1 + sin
2
x = 0
4sin
4
x + 4sin
2
x 1 = 0
4sin
4
4sin
2
x + 1 = 0
(2 sin
2
x 1)
2
= 0
2sin
2
x = 1
6
6
sin
2
x =
2
1
sinx =
2
1
sin x has 4 solution in the interval [0, 2t].
10. u =
2
1
sin
1

|
.
|
\
|
4
1
sin2u =
4
1
2sinu cosu =
4
1
sinu cosu =
8
1
Value of : 64sinu + 64cosu 8secu 8cosecu + tanu + cotu
= 64(sinu + cosu) 8 (secu + cosecu)+
|
.
|
\
|
u
u
+
u
u
sin
cos
cos
sin
= 64(sinu + cosu) 8
|
.
|
\
|
u
+
u sin
1
cos
1
+
|
|
.
|
\
|
u u
u + u
cos sin
cos sin
2 2
= 64(sinu + cosu) 8
|
.
|
\
|
u u
u + u
cos sin
cos sin
+
u ucos sin
1
= 64(sinu + cosu) 8
8 / 1
) cos (sin u + u
+ 8
= 64(sinu + cosu) 64 (sinu + cosu) + 8
= 8.
11. L =
n
lim
\
|
|
.
|
\
|
+ + |
.
|
\
|
+ |
.
|
\
|
n
n
2
2 lim
0 x
x
1
sin x ....
x
1
sin x
x
1
sin x
L =
n
lim
)
`
|
.
|
\
|
+ + |
.
|
\
|
+

n
n
0 x
2
2
0 x 0 x
x
1
sin x lim .........
x
1
sin x lim
x
1
sin x lim
L =
n
lim
{ } 0 . .......... 0 0 0 + + + +
L = 0
12. f(x) =
< + +
>
1 x for c bx ax
1 x for x
2
3
f(x) = 3x
2
= 2ax + b
[f(x)]
x = 1
= 6x = 2a
6 = 2a
a = 3.
13. f(x) = x
3
3ax
2
+ b
f(x) = 3x
2
6ax
For the f(x) to be increasing f(x) > 0.
3x
2
6ax > 0
3x (x 2a) > 0
(x 2a) > 0 [ x > 0]
x > 2a
So, a > 0.
7
7
14. | | | | ( ) dx x x
2
cos x
3
1
|
.
|
\
|

t
=
( )
|
.
|
\
|

t
2
1
dx 1 x
2
cos
+
( )
|
.
|
\
|

t
3
2
dx 2 x
2
cos 2
=
( )
t
|
.
|
\
|

t
2
1 x
2
sin
2
1
+ 2
( )
t
|
.
|
\
|

t
2
2 x
2
sin
3
2
=
] 0 1 [
4
] 0 1 [
2
t
+
t
=
t
6
.
15. Let A =
n
1
{(2n + 1) (2n + 2) ------- (2n + n)}
1/n
log A =
n
1
n
lim
log
+ + + +
n
) n n 2 (
.....
n
) 3 n 2 (
n
) 2 n 2 (
n
) 1 n 2 (
log A =
n
1
n
lim
log
|
.
|
\
|
+ |
.
|
\
|
+ |
.
|
\
|
+ |
.
|
\
|
+
n
n
2 .....
n
2
2
n
2
2
n
1
2
log A =
+
1
0
dx ) x 2 log(
log A = ) x 2 log( 2 x ) x 2 log( x
1
0
+ + +
log A = [log 3 1 + 2 log 3 2 log2]
log A = [log 3 loge + log 9 log4]
log A = [log (27/4e)]
A = (27/4e).
16.
1
V
+
2
V
+
3
V
= 0
2 1
V V
= ?
2 1
V V +
=
3
V
2 1
V V +
.
2 1
V V +
=
( )
3
V
.
( )
3
V
2
1
V +
2
2
V +
2 2
V . V 2
=
2
3
V
1 + 1 +
2 2
V . V 2
= 1
2 2
V . V 2
= 1
2 2
V . V
=
2
1
8
8
2
2 1
V V =
2
1
V +
2
2
V
2 1
V . V 2
= 1 + 1 2
2
1
= 1 + 1 + 1 = 3
2
2 1
V V = 3
2 1
V V
=
3
.
17. Total number of possible cases = 4 + 3 + 2 + 1 = 10
Favourable cases = {(H T T H T),(T H T H T ), (T T H H T ), (T T T H H)}
Total number of favourable cases = 4
p(4
th
toss is a head) =
10
4
=
5
2
.
18. a + b + c = even
Case 1 : All taken are even :
3
C
5
= 10
Case 2 : One even + 2 odd :
1
C
5

2
C
5
= 50
Total = 10 + 50 = 60.
19. 2log(x 2y) = logx + logy
log(x 2y)
2
= log(xy)
(x 2y)
2
= xy
x
2
+ 4y
2
4xy = xy
x
2
+ 4y
2
5xy = 0
x
2
4xy xy + 4y
2
= 0
x(x 4y) y (x 4y) = 0
(x y)(x 4y) = 0
x = y (N.P.), x = 4y
y
x
= 4.
20. Let x, y and z are 2n, n
2
1 & n
2
+1.
Let x = 2n, y = n
2
1 and z = n
2
+1.
Option (A) : 2 does not divide x .
Clearly 2 divides x. So option (A) is not true.
Ex : 8, 15 and 17 are pythogorean triplet. 2 divides 8.
Option (B) : 2 does not divide z(x + y)
(n
2
+ 1)(2n + n
2
1) which is an odd number so, 2 does not divides z(x + y).
So, option (B) is true.
Option (C) : 4 divides x + y + z
Ex : 5, 12, 13 are the pythogorean triplet.
Clearly 5 + 12 + 13 = 30, and 4 does not divides 30.
So, option (C) is not true.
Option (D) : 8 divides x + y + z
Ex : 8, 15, 17 are the pythogorean triplet.
Clearly 8 + 15 + 17 = 40, and 8 divides 40.
So, option (B) is true.
9
9
PHYSICS
21. By work energy theorem, W = AK
mgh w
f

= 0
w
f
= mgh
22. E = 13.6
2
2
n
z
= 13.6
1
4
= 54.4eV Ans (D)
23.
2E
E
V | F
B
|
deflected in x direction (Ans.B)
25. 90
I
45
P
2
I
P
1
P
By Malus's law, I'= I
0
cos
2
45
initensity after P
1
I = Icos
2
45 =
2
I
initensity after P
2
I
2
=
2
I
1
cos
2
45 =
4
I
Ans : B
26. Due to inertia ballon displace in the direction of motion of the bus.
27. (D) As for hydrogen like atom
|
|
.
|
\
|
=
2
2
2
1
2
n
1
n
1
z . R
1
(Here z = 1, same for deuterium and hydrogen)
So,
1
will be same for deuterium as that for hydrogen.
28. Bulk modulus, B =
|
.
|
\
| A
A
V
V
P
As in isothermal process, PV = K
On differentiating, PdV + VdP = 0
P
P
V
V A
=
A
Hence B =
|
.
|
\
| A
A
P
P
P
= P
10
10
29. From brewsters law tanI =
1
2
u
u
30. Cheaking dimensionally all the formula
] T L [
T
L
] L [
2
g
2 2
2
=
t
and
2 / 1
3
2 1 2
] ML [
] T L [
] L [
] MLT [ g
=
p
o

= [L
2
T
2
] (dimension of v
2
)
] ML ][ L [
] L ][ T L M [ 2
3
1 2 1 1

=
p
to
= [L
2
T
2
]
Only (A) option is correct dimensionally
33. As v & d depends on frame of referance but change in KE and hence heat does not depend.
34. V>> gr 2
V
B
36.
A 2v
C
2v
x
v
v
B
v
B
= v
0

c
v 2
1
v
C
= v
o

c
v
1
V
A
= V
0

u
+
c
cos v 2
1
V
A
> V
C
> V
B
(Answer : C)
37. By dalton's law of partion pressure. (Ans : D)
38. E
in
= 0 E
out
=
2
r
KQ
V
in
=
R
KQ
= const. V
out
=
r
KQ
X is for electric field versus distance graph
Y is for potential versus distance graph
Ans. is (B)
39. E
net
= 2
] x [
) y x (
kq
2 / 3 2 2
+
E
net
=
2
x
kq 2
11
11
CHEMISTRY
41. For weak acid [H
+
] = Co
[H
+
] = 0.1 0.1
[H
+
] = 10
2
pH = log[H
+
]
pH = log[10
2
]
pH = 2
42.
N
O
O
it has two donor side [O & N]

43. H
3
O
+
sp
3
hybridisation, due to presence of 1 lp
structure is trigonal pyramidal.
45. (D) Ba > Ca > Mg > Be
Solubility increases down the group due to increase of size of cation.
46. C > Be > B > Li
Z
eff
| I E |
47. Dipole moment = e d
F Be F
= 0
48. [NiCl
4
]
2
is tetrahedral.
50. mvr =
t 2
nh
where n = 1, 2, 3 -------
51. (A) both valencies occupy by the same group.
52. p-nitrophenol -o-nitrophenol m-nitrophenol
I & M I & M ( intramolecular H-bond) I
54. (A)
CH O COR
2
CH O COR + 3NaOH
CH O COR
3RCOONa +
Salt of fatty acid

CH OH
2
CH OH
2
CH OH
glycerol
55. (B) Branching | surface area |
vanderwaals forces | b.p. |
12
12
56. (C) Zn/NaOH
NO
2
2
Zn/NaOH
N = N
58. CH CH CH(OH) COOH
3 2
59. (C)
OH
COOH
[contains phenolic group]
60. (B) stability of carbanions o
M &
M &
+ I +
I
PART-II (2 Mark)
MATHEMATICS
81. ab = 2 (a + b)
2
1
ab
b a
=
+
2
1
b
1
a
1
= +
...... (i)
bc = 3( b + c)
3
1
bc
c b
=
+
3
1
c
1
b
1
= +
...... (ii)
ca = 4( c + a)
4
1
ca
a c
=
+
4
1
a
1
c
1
= +
...... (iii)
Add (i), (ii) and (iii)
4
1
3
1
2
1
c
1
b
1
a
1
2 + + = |
.
|
\
|
+ +
24
3 4 6
c
1
b
1
a
1 + +
= + +
24
13
c
1
b
1
a
1
= + +
...... (iv)
From (i) and (iv)
c = 24
13
13
From (ii) and (iv)
a =
5
24
From (iii) and (iv)
b =
7
24
So, value of 5a + 7b + c
= 24 + 24 + 24 = 72.
82. x
2
+ ax + b = 0
o + | = a, o| = b
x
4
+ ax
3
+ cx
2
+ dx + e = 0
Roots are o + |, o |, o + | and o |
Sum of roots = a
o + | + o | o + | o | = a
a = 0 o + | = 0
Sum of roots taken two at a time = + c
(o + |) (o |) + (o |) ( o + |) + ( o + |)( o |) + ( o |) (o + |) + (o + |) ( o + |) + (o |)
( o + |) = c
0 ( o + |)
2
+ 0 + 0 + 0 (o + |)
2
= c
2(o |)
2
= c
2[o
2
+ |
2
2o|] = c
2[(o + |)
2
2o| 2o|] = c
2[ 4o|] = c
c = 8o|
c = 8b = 0
Product of roots taken three at a time = d
(o + |) (o |) ( o + |) + (o + |) ( o + |)( o |) + ( o |) (o + |) + (o + |) ( o + |) ( o + |) ( o +
|) = d
0 + 0 + 0 + 0 = d
d = 0
Product of roots = e
(o + |)(o |)( o + |)( o |) = e
e = 0
So, c = 0 is the false statement
83.
Q
P
O
y = 3x
y = 2x
PQ = 5
Let point Q is (x, 3x)
14
14
Given QP = 5 and QP line 2x y = 0
1 4
x 3 x 2
+
= 5
x =
5 5
Therefore point Q is (
5 5
,
5 15
)
OQ =
( ) ( )
2 2
5 15 5 5 +
=
1125 125 +
=
1250
=
2 25
In AOPQ
OQ
2
= OP
2
+ PQ
2
( )
2
2 25
= OP
2
+ (5)
2
1250 25 = OP
2
OP
2
= 1225
OP = 35 cm.
84. cot
2
B
=
) c s )( c s (
) b s ( s

cot
2
C
=
) b s )( a s (
) b s ( s

cot
2
B
cot
2
C
=
) c s )( a s (
) b s ( s

) b s )( a s (
) c s ( s

cot
2
B
cot
2
C
=
) c s )( b s ( ) a s (
) c s )( b s ( s
2
2

cot
2
B
cot
2
C
=
2
2
) a s (
s
cot
2
B
cot
2
C
=
a s
s
Given : b + c = 3a
s =
2
c b a + +
=
2
a 3 a +
= 2a.
cot
2
B
cot
2
C
=
a a 2
a 2
=
a
a 2
= 2.
15
15
85.
E
F
C
B
A
D
Given : AE = EF = FC =
3
AC
Let, AB = BC = CD = DA = x
Then, AC =
2
x
Let BE = a
In AAEB
cos 45 =
x .
3
x 2
2
a x
9
x 2
2 2
2
+
2
1
=
3
x 2 2
a
9
x 11
2
2
2
3
x 2
2
=
9
x 11
2
a
2
a
2
=
9
x 11
2

3
x 2
2
a
2
=
9
x 6 x 11
2 2
=
9
x 5
2
a =
3
5
x
Similarily BF = a =
3
x 5
.
In ABEF
BE = BF =
3
x 5
and EF =
3
x 2
16
16
cosu =
BF BE 2
EF BF BE
2 2 2
+
cosu =
3
x 5
3
x 5
2
9
x 2
9
x 5
9
x 5
2 2 2

+
cosu =
9
x 10
9
x 8
2
2
=
10
8
=
5
4
.
tanu =
4
3
.
86.
C
B
A
D
x x
2007
v = Volume of box = (2007 2x)
2
x
dx
dv
= 2(2007 2x)( 2x) + (2007 2x)
2
= (2007 2x)[ 4x + 2007 2x]
= (2007 2x) (2007 6x)
For the maximum volume
dx
dv
= 0
(2007 2x)(2007 6x) = 0
x =
2
2007
or x =
6
2007
2
2
dx
v d
= (2007 6x) ( 2) + (2007 2x) ( 6)
= 4014 + 12x 12042 + 12x
= 24x 16056
6
2007
x
2
2
dx
v d
=
|
|
.
|
\
|
= 24
6
2007
16056
= 8028 16056 < 0
Volume is maximum when x =
6
2007
=
2
669
cm.
17
17
87. S = y
2
4x
S (0, 2) = 4, S (1/2, 5/2) = 25/4 2 = 17/4, S (5/2, 9/2) = 81/4 20/2 = 41/4 and S (1, 3) = 9 4 = 5
It is clear that (0, 2) is closest to parabola y
2
= 4x.
88.
I < 0
J > 0
or
2
e 2
e
or
I < 0
J < 0
2
e
J < 0
So, I and J can be both negative but not both positive.
89. |z
1
z
2
+ z
2
z
3
+ z
3
z
1
| = |z
1
z
2
z
3
|
3 2 1
z
1
z
1
z
1
+ +
=
3 2 1
z z z + + [ |z
1
| = |z
2
| = |z
3
| ]
= |z
1
+ z
2
+ z
3
|.
90. So, the angles will be 99, 108, ....., 153, 162
Sum of largest two angles = 153 + 162 = 315.
PHYSICS
91. Rotational inertia does not depend on speed so rotational inertia of the cylinder about its axis will be
2
1
MR
2
.
92. Air column is closed at one end, so fundamental frequency
n =
2
10 66 4
330
4
v
= 125 Hz
n
1
: n
2
: n
3
....... = 1 : 3 : 5 ...........
So, possible frequencies are
125, 375, 675, 875, 1125 (> 1kHz)
So only possible frequenceies are 3.
93. Time period of pendulum on the surface of the earth
T
0
= 2p
g
2

t
........(i)
At a depth d, g' = g
|
.
|
\
|

R
d
1
and ' = ( ) ou + 1
So new time period,
T =
'
'
t
g
2

=
) R / d 1 ( g
) 1 (
2
ou +
t

= (1+ ou)

(1 d/R)

=
|
.
|
\
|
ou +
2
1
1

|
.
|
\
|
+
R 2
d
1
18
18
94. For first darkness,
d sinu = sinu =
3 . 0
10 2
10 6
6
7
=
u = 17
95. In LC

circuit time period, T = 2t
Lc
t =
4
T
= LC
2
t
96. For insulated material capacity,
C =
) / a a d (
A
r
0
c +
c
But of metal, c
r
=
So, C =
) a d (
A
0
c
97. A
max
= g (block and piston remains together)
Ae
2
= g
A
max
=
2
g
e
=
2 2
f 4
g
t
98. z = 0, as
P
and
E
in same direction
5
10
dZ
dE
= F =
dZ
dE
P = 10
7
10
5
= 10
2
N
99. Inside the atom,
Electric field due to +v charge , E(r) =
2
e
r
kz
Due to ve charge, E(r) = K
3
r
r ze
So, E(r) =
|
.
|
\
|

tc
3 2
0
R
r
r
1
4
ze
r < R
For out side atom
Q
net
= 0
E(r) = 0 r > R
100. AQ = c
P
AT
=
T R 1
2
f
A |
.
|
\
|
+
=
V P 1
2
f
A |
.
|
\
|
+
|
.
|
\
|
+1
2
f
=
5 5
10 3 10 01 . 1
61 . 10
PdV
Q

=
A
f = 4.3
So, gas is a mixture of mono and diatomic molecules.
19
19
CHEMISTRY
101.
CH = CH CH CH CH
2 2 3
Br
Br
2
CH CH CH CH CH
2 2 3
Br Br Br
* *
CH Br
2
H C Br
H C Br
CH CH
2 3
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
CH Br
2
Br C H
CH CH
2 3
Br C H
CH Br
2
H C Br
Br C H
CH CH
2 3
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
/
CH Br
2
Br C H
CH CH
2 3
H C Br
102.
P
V
according to above graph P o V
This contradict the Boyles law
103. Molarity of acetic acid = 0.1 M [Suppose volume of acetic acid = x]
no. of millimoles present in x ml of acetic acid = 0.1x
Molarity of sodium acetate = 0.2
no. of millimoles present in 10 ml of sodium acetate = 0.2 10 = 2
pH = pKa + log
] Acid [
] Salt [
4.91 = 4.76 + log
x 10
x 1 . 0
x 10
2
+
+
[ total volume = (10 + x) ml]
0.15 = log
x 1 . 0
2
0.15 = log20 logx
0.15 = 1.3010 logx
logx = 1.151
x = antilog (1.151)
x = 14.16 ml
x ~ 14.2 ml
20
20
104. Ba(OH)
2
+ SO
2

BaSO
3
+ H
2
O
(White ppt.)
Ba(OH)
2
+ SO
3

BaSO
4
+ H
2
O
(White ppt.)
BaSO
3
is soluble in dil HCl but BaSO
4
is not soluble in dil HCl . After filteration , filtrate contains BaSO
3
Br
2
+ H
2
O

2HBr + O
(Bromine water)
BaSO
3
+ O

BaSO
4
White ppt
105. o
V
1
according to question given potential energy = kinetic energy
eV =
2
1
mv
2
----- (1)
eV =
m 2
P
2
[ P = mv]
eV =
m 2
h
2
2
[ p =
h
]
2
=
meV 2
h
2
=
meV 2
h
e, m, h are constants
so
V
1
106. K
b
= 0.52 k Kg mol
1
(given)
AT
b
= 0.052 K (given)
m = given
AT
b
=
mW
w K 1000
0 b
It means we can calculate
W
w
0
=
b
b
K 1000
m T A
---------------- (i)
Relative lowering of vapour pressure of water

o
s o
P
P P
=
W
w
0

m
M
------(ii)
M = molecular mass of water = 18
m = given
W
w
0
= by equation (i)
so we can calculate relative lowering of V.P. of water by equation (ii)
osmotic pressure t =
V
n
ST
But V is unknown, so we cant find out the value of osmotic pressure.
freezing point depression AT
f
=
mW
w K 1000
o f
But value of K
f
is not given so we cant calculate the magnitude of freezing point depression.
21
21
107. Test of Nitrogen
Organic compound no ppt. Nitrogen
Fused with Na + FeSO
4
observed absent
+ FeCl
3
Test of sulphur
Organic compound fused violet S present
with Na + sodium nitroprusside colour
observed
Thus according to question organic compound contains sulphur only.
108.
CH
3
NH
2
(CH CO) O
3 2
CH
3
NHCOCH
3
Br /CH COOH
2 3
CH
3
NH COCH
3
Br
( ) I
( ) II
H O/H
2
+
NH
2
CH
3
Br
( ) III

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Pre-foundation Career Care Programmes (PCCP) Division

it has two donor side [O & N]

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