Quiz 5
Quiz 5
Quiz 5
Due: 11:50pm on Monday, October 29, 2012 Note: You will receive no credit for late submissions. To learn more, read your instructor's Grading Policy
Question 1
Part A
Complete and balance the following molecular equation.
Express your answer as a balanced chemical equation. Identify all of the phases in your answer. ANSWER:
Correct
Part B
Write the net ionic equation for it. Express your answer as a balanced net ionic equation. Identify all of the phases in your answer. ANSWER:
Correct
Part C
Complete and balance the following molecular equation.
Express your answer as a balanced chemical equation. Identify all of the phases in your answer. ANSWER:
Correct
Part D
Write the net ionic equation for it. Express your answer as a balanced net ionic equation. Identify all of the phases in your answer. ANSWER:
Correct
Part E
Complete and balance the following molecular equation.
Express your answer as a balanced chemical equation. Identify all of the phases in your answer. ANSWER:
Correct
Part F
Write the net ionic equation for it. Express your answer as a balanced net ionic equation. Identify all of the phases in your answer. ANSWER:
Correct
Question 2
Designate the Bronsted-Lowry acid and the Bronsted-Lowry base on the left side of each equation, and also designate the conjugate acid and conjugate base on the right side.
Part A
ANSWER: is the B-L acid; conj. base. is the B-L acid; conj. base. is the B-L acid; conj. base. is the B-L acid; conj. base. is the B-L base. is the conj. acid; is the is the B-L base. is the conj. acid; is the is the B-L base. is the conj. acid; is the is the B-L base. is the conj. acid; is the
Correct
Part B
ANSWER: is the B-L acid; the conj. base. is the B-L acid; the conj. base. is the B-L acid; the conj. base. is the B-L acid; the conj. base. is the B-L base. is the conj. acid; is is the B-L base. is the conj. acid; is is the B-L base. is the conj. acid; is is the B-L base. is the conj. acid; is
Correct
Part C
ANSWER: is the B-L acid; conj. base. is the B-L acid; conj. base. is the B-L acid; conj. base. is the B-L acid; conj. base. is the B-L base. is the conj. acid; is the is the B-L base. is the conj. acid; is the is the B-L base. is the conj. acid; is the is the B-L base. is the conj. acid; is the
Correct
Question 3
Complete the following table by calculating the missing entries. In each case indicate whether the solution is acidic or basic. Acidic or basic? 7.5!10"3 3.5!10"10 8.25 5.73
Part A
Complete the first row. Express your answer using two significant figures.
ANSWER: = 1.3!10"12
Correct
Part B
Complete the first row. Express your answer using two decimal places. ANSWER: = 2.12
Correct
Part C
Complete the first row. Express your answer using two decimal places. ANSWER: = 11.88
Correct
Part D
Complete the first row. Indicate whether the solution is acidic or basic. ANSWER: acidic basic
Correct
Part E
Complete the second row. Express your answer using two significant figures. ANSWER: = 2.9!10"5
Correct
Part F
Complete the second row. Express your answer using two decimal places. ANSWER: = 4.54
Correct
Part G
Complete the second row. Express your answer using two decimal places. ANSWER: = 9.46
Correct
Part H
Complete the second row. Indicate whether the solution is acidic or basic. ANSWER: acidic basic
Correct
Part I
Complete the third row. Express your answer using two significant figures. ANSWER: = 5.6!10"9
Correct
Part J
Complete the third row. Express your answer using two significant figures. ANSWER: = 1.8!10"6
Correct
Part K
Complete the third row. Express your answer using two decimal places. ANSWER: = 5.75
Correct
Part L
Complete the third row. Indicate whether the solution is acidic or basic. ANSWER: acidic basic
Correct
Part M
Complete the fourth row. Express your answer using two significant figures. ANSWER: = 5.4!10"9
Correct
Part N
Complete the fourth row. Express your answer using two significant figures. ANSWER: = 1.9!10"6
Correct
Part O
Complete the fourth row. Express your answer using two decimal places. ANSWER: = 8.27
Correct
Part P
Complete the fourth row. Indicate whether the solution is acidic or basic. ANSWER: acidic basic
Correct
Question 4
Calculate the of each of the following strong acid solutions.
Part A
8.5!10"3 ,
Correct
Part B
1.34 of in 560 of solution,
Correct
Part C
6.90 of 0.250 diluted to 54.0 ,
Correct
Part D
A solution formed by mixing 15.0 of 0.130 with 17.0 of 0.200 .
Correct
Question 5
Part A
Calculate
for 1.4!10"3
Part B
Calculate for 1.4!10"3 .
Correct
Part C
Calculate for 2.460 of in 300.0 of solution.
Answer Requested
Part D
Calculate for 2.460 of in 300.0 of solution.
= 13.5345
Answer Requested
Part E
Calculate for 1.30 of 0.250 diluted to 1.50 .
Answer Requested
Part F
Calculate for 1.30 of 0.250 diluted to 1.50 .
Correct
Part G
Calculate . Express your answer using two significant figures. ANSWER: = 0.18 for a solution formed by adding 4.00 of 0.180 to 10.0 of 8.8!10"2
Correct
Part H
Calculate for a solution formed by adding 4.00 of 0.180 to 10.0 of 8.8!10"2 .
Correct
Question 6
Write the chemical equation and the expression for the acid dissociation of each of the following acids in as a product and then with the hydronium ion. aqueous solution. First show the reaction with
Part A
. Show the reaction with as a product.
Express your answer as a chemical equation. Identify all of the phases in your answer. ANSWER:
Answer Requested
Part B
Write the ANSWER: expression for the acid dissociation from the previous part.
Correct
Part C
. Show the reaction with the hydronium ion as a product. Express your answer as a chemical equation. Identify all of the phases in your answer. ANSWER:
Answer Requested
Part D
Write the ANSWER: expression for the acid dissociation from the previous part.
Correct
Part E
. Show the reaction with as a product.
Express your answer as a chemical equation. Identify all of the phases in your answer. ANSWER:
Correct
Part F
Write the ANSWER: expression for the acid dissociation from the previous part.
Correct
Part G
. Show the reaction with the hydronium ion as a product. Express your answer as a chemical equation. Identify all of the phases in your answer. ANSWER:
Correct
Part H
Write the ANSWER: expression for the acid dissociation from the previous part.
Correct
Question 7
Calculate the of each of the following solutions ( and values are given in Appendix D in the textbook).
Part A
9.8!10"2 propionic acid .
Correct
Part B
0.100 hydrogen chromate ion .
Correct
Part C
0.119 pyridine .
Correct
Question 8
Write the chemical equation and the expression for the reaction of each of the following bases with water.
Part A
Write the chemical equation for the reaction of propylamine, ANSWER: with water.
Correct
Part B
Write the ANSWER: expression for the reaction of propylamine, with water.
Correct
Part C
Write the chemical equation for the reaction of monohydrogen phosphate ion, ANSWER: with water.
Answer Requested
Part D
Write the ANSWER: expression for the reaction of phosphate ion, with water.
Correct
Part E
Write the chemical equation for the reaction of benzoate ion, ANSWER: with water.
Correct
Part F
Write the ANSWER: expression for the reaction of benzoate ion, with water.
Correct
Question 9
Part A
Calculate the molar concentration of . Express your answer using two significant figures. ANSWER: = 1.5!10"3 ions in a 0.540 solution of hypobromite ion
Correct
Part B
What is the of this solution?
Correct
Question 10
The strength of an acid, , is often determined by the strength and polarity of the bond. In general, a weaker and more polar bond leads to a stronger acid. For binary acids of elements in the same group of the periodic table, the bond strength decreases down the bond increases from left
group, so acidity increases. For binary acids of elements in the same row of the periodic table, the polarity of the
For oxoacids, acid strength increases with the oxidation number of the central atom. If the oxidation number is the same, acid strength increases with the electronegativity of the central atom.
Part A
Rank the following compounds in order of decreasing acid strength using periodic trends. Rank the acids from strongest to weakest. To rank items as equivalent, overlap them.
Hint 2. Describe how the acidity changes in a group of the periodic table
Complete the following statement about the trend observed for binary acids of elements in the same group of the periodic table. ANSWER: decreases Acid strength increases stays the same as you move down a group.
Correct
The strength of the bond decreases with increasing size of element down a group. The weaker the bond, the easier it is to break it. Therefore the acidity increases.
Hint 3. Describe how the acidity changes in a period of the periodic table
Complete the following statement about the trend observed for binary acids of elements in the same row of the periodic table. ANSWER: decreases Acid strength increases stays the same from left to right across a period.
Correct
In a periodic row, the polarity of the element bond increases with the increase in electronegativity of (from left to right). The more polar the bond, the easier it is to remove the proton.
ANSWER:
Part B
Without consulting the table of acid-dissociation constants, match the following acids to the given Drag the appropriate items to their respective bins. values.
same central atom, sulfur. The polarity of the proton bond increases with the increase in the oxidation number of the central atom. We can compare the oxidation numbers of in these compounds and rank the acids.
-2 -1 0 +1 +2 +3 +4 +5 +6 +7
ANSWER:
Correct
Notice that oxidation number and acid strength both increase with the number of oxygen atoms.
Question 11
Part A
Calculate the of a buffer that is 0.115 in and 0.195 in .
Correct
Part B
Calculate the of a solution formed by mixing 65 of 0.33 with 75 of 0.27 .
Correct
Question 12
Part A
How many milliliters of 0.120 solution? ANSWER: = 88.2 are needed to completely neutralize 49.0 of 0.108
Correct
Part B
How many milliliters of 0.129 ANSWER: = 15.5 are needed to neutralize 0.160 of ?
Correct
Part C
If 55.2 of solution is needed to precipitate all the sulfate ion in a 746 sample of , what is the molarity of the solution? ANSWER: = 9.51!10"2
Correct
Part D
If 42.6 of 0.214 solution is needed to neutralize a solution of , how many grams of
Correct
Question 13
Tartaric acid, requires 25.65 solution. , has two acidic hydrogens. The acid is often present in wines and precipitates from . It of 0.1500 solution to titrate both acidic protons in 50.00 of the tartaric acid solution as the wine ages. A solution containing an unknown concentration of the acid is titrated with
Part A
Write a balanced net ionic equation for the neutralization reaction. ANSWER:
Answer Requested
Part B
Calculate the molarity of the tartaric acid solution. Express your answer using four significant figures. ANSWER: 3.848!10"2
Correct
Question 14
A sample of 0.2140 of an unknown monoprotic acid was dissolved in 25.0 of water and titrated with . The acid required 27.4 of base to reach the equivalence point.
Part A
What is the molar mass of the acid? ANSWER: = 82.2
Correct
Question 15
By the Brnsted-Lowry definition, acids are proton donors and bases are proton acceptors. By the Lewis definition, acids are electron-pair acceptors, and bases are electron-pair donors. For bases, the two definitions are equivalent such that all Lewis bases are Brnsted-Lowry bases and vice versa. However, it is possible to have a Lewis acid that is not a Brnsted-Lowry acid. This is because Lewis acids include molecules and cations that have a vacant valence orbital, regardless of whether they have a proton to donate. Common examples of Lewis acids (that are not Brnsted-Lowry acids) are metal ions, such as and . The following is an example of a Lewis acid-base reaction:
. Therefore,
is a Lewis acid.
Part A
Identify the Lewis acid in the following reaction:
ANSWER:
Correct
Each of six anions donates a pair of electrons to , which has six vacant valence orbitals.
Part B
Classify each of the following as a Lewis acid or a Lewis base. Drag the appropriate items to their respective bins.
ANSWER:
Correct
Part C
In the following pair, which species would you expect to be the stronger Lewis acid?
greater the positive charge on the cation, the greater its ability to attract negatively charged electrons.
ANSWER:
Correct
Score Summary:
Your score on this assignment is 84.8%. You received 12.72 out of a possible total of 15 points.