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    14.1 Born Haber Cycle NaCl

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    lianchen251110
    This document describes the Born-Haber cycle process for calculating the lattice energy of sodium chloride. It shows the step-by-step reactions involved in atomizing the elements, ionizing them, and forming the ionic solid. By applying Hess's law to the cycle, the lattice energy can be determined by subtracting the sum of other enthalpy changes from the enthalpy of formation.

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    14.1 Born Haber Cycle NaCl

    Uploaded by

    lianchen251110
    83 views3 pages
    This document describes the Born-Haber cycle process for calculating the lattice energy of sodium chloride. It shows the step-by-step reactions involved in atomizing the elements, ionizing them, and forming the ionic solid. By applying Hess's law to the cycle, the lattice energy can be determined by subtracting the sum of other enthalpy changes from the enthalpy of formation.

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    This document describes the Born-Haber cycle process for calculating the lattice energy of sodium chloride. It shows the step-by-step reactions involved in atomizing the elements, ionizing them, and forming the ionic solid. By applying Hess's law to the cycle, the lattice energy can be determined by subtracting the sum of other enthalpy changes from the enthalpy of formation.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    83 views3 pages

    14.1 Born Haber Cycle NaCl

    Uploaded by

    lianchen251110
    This document describes the Born-Haber cycle process for calculating the lattice energy of sodium chloride. It shows the step-by-step reactions involved in atomizing the elements, ionizing them, and forming the ionic solid. By applying Hess's law to the cycle, the lattice energy can be determined by subtracting the sum of other enthalpy changes from the enthalpy of formation.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPT, PDF, TXT or read online from Scribd
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    Born-Haber Cycles

    eg for sodium chloride: enthalpy H Na+(g)+ Cl(g) + eH H


    first ionisation energy

    first electron affinity

    Na (g) + Cl (g)
    atomisation

    Na+ (g) + Cl- (g)

    Na (g) + Cl2 (g) H atomisation Na (s) + Cl2 (g) H


    formation

    H lattice association

    NaCl (s)

    Born-Haber Cycles : applying Hesss Law


    There are two routes from elements to ionic compound enthalpy H Na+ (g) + Cl (g) H H
    first ionisation energy

    first electron affinity

    Na (g) + Cl (g)
    atomisation

    Na+ (g) + Cl- (g)

    Na (g) + Cl2 (g) H atomisation Na (s) + Cl2 (g) H


    formation

    H lattice association

    Apply Hesss Law:

    NaCl (s)

    HatmNa + HatmCl + H1st IE + H1st EA + Hlattice = Hformation

    Born-Haber Cycles: applying Hesss Law


    HatmNa + HatmCl + H1st IE + H1st EA + Hlattice = Hformation Rearrange to find the lattice energy: Hlattice = Hformation - (HatmNa + HatmCl + H1st IE + H1st EA) So Born-Haber cycles can be used to calculate a measure of ionic bond strength based on experimental data.

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