PART A PHYSICS

1.

An experiment is performed to obtain the 1.

value of acceleration due to gravity g by
using a simple pendulum of length L. In
this experiment time for 100 oscillations is
measured by using a watch of 1 second
least count and the value is 90.0 seconds.
The length L is measured by using a meter
scale of least count 1 mm and the value is
20.0 cm. The error in the determination
of g would be :

2.

(1)

1.7%

(2)

2.7%

(3)

4.4%

(4)

2.27%

2.

The position of a projectile launched from

the

origin

at

r 5(40 i 1 50 j ) m

t50

is

given

at t52s.

by

If the

projectile was launched at an angle u from

the horizontal, then u is (take g510 ms22).

A
L U U L
U g
100 1 UU
U
90.0 U L 1 mm
UU U
20.0 cm g U U
(1)

1.7%

(2)

2.7%

(3)

4.4%

(4)

2.27%

t50 U

(1)

tan21 2 3

tan21 2 3

(2)

tan21 3 2

(2)

tan21 3 2

(3)

tan21 7 4

(3)

tan21 7 4

(4)

tan21 4 5

(4)

tan21 4 5

Set : 01

U r 5(40 i 1 50 j ) m
u U
, u (g510 ms22 ).
t52s

(1)

English : 1

Hindi : 1

Set : 01

3.

Water is flowing at a speed of 1.5 ms21 3.

through

horizontal

cross-sectional area

1022

m2

tube

of

and you are

trying to stop the flow by your palm.

Assuming

that

the

water

stops

immediately after hitting the palm, the

minimum force that you must exert should
be (density of water5103 kgm23).

4.

1022 m2

S U
1.5 ms21 U U
U U
U UU
L ,
(
5103 kgm23).

(1)

15 N

(1)

15 N

(2)

22.5 N

(2)

22.5 N

(3)

33.7 N

(3)

33.7 N

(4)

45 N

(4)

45 N

A block A of mass 4 kg is placed on 4.

another block B of mass 5 kg, and the block
B rests on a smooth horizontal table. If
the minimum force that can be applied on
A so that both the blocks move together is
12 N, the maximum force that can be
applied on B for the blocks to move

4 kg A U
5 kg B U U U B
U S U
A U ,
, 12 N
B U ,
,

together will be :
(1)

30 N

(1)

30 N

(2)

25 N

(2)

25 N

(3)

27 N

(3)

27 N

(4)

48 N

(4)

48 N

English : 2

Set : 01

Hindi : 2

Set : 01

5.

Two bodies of masses 1 kg and 4 kg are 5.

connected to a vertical spring, as shown
in the figure. The smaller mass executes
simple harmonic motion of angular
frequency 25 rad/s, and amplitude 1.6 cm
while the bigger mass remains stationary
on the ground. The maximum force

1 kg 4 kg S U
mU U U U
25 rad/s
1.6 cm U U U
U SU U mU U

(g510 ms22 ).

exerted by the system on the floor is

(take g510 ms22).

(1)

20 N

(2)

10 N

(3)

60 N

(4)

40 N

English : 3

Set : 01

(1)

20 N

(2)

10 N

(3)

60 N

(4)

40 N

Hindi : 3

Set : 01

6.

A cylinder of mass Mc and sphere of mass 6.

Ms are placed at points A and B of two

inclines, respectively. (See Figure). If they

roll on the incline without slipping such
that their accelerations are the same, then
sin uc
the ratio
is :
sin us

8
7

(1)

15
14

(2)
(3)
(4)

8
7

15
14

English : 4

Set : 01

Mc Ms
A B
U U ( )
U U U
,

(1)

8
7

(2)

15
14

(3)

8
7

(4)

15
14

Hindi : 4

sin uc
sin us

Set : 01

7.

Indias Mangalyan was sent to the Mars 7.

by launching it into a transfer orbit EOM
around the sun. It leaves the earth at E
and meets Mars at M. If the semi-major
axis of Earths orbit is ae51.531011 m,
that of Mars orbit a m 52.28310 11 m,
taken Keplers laws give the estimate of
time for Mangalyan to reach Mars from

U U
U SU EOM
E U U U M
U h-
ae51.531011 m U h-
am52.2831011 m , U
U

Earth to be close to :

(1)

500 days

(1)

500

(2)

320 days

(2)

320

(3)

260 days

(3)

260

(4)

220 days

(4)

220

English : 5

Set : 01

Hindi : 5

Set : 01

8.

In materials like aluminium and copper, 8.

the correct order of magnitude of various

S U

elastic modulii is :
(1)

Youngs modulii < shear modulii

(1)

< bulk modulii.

(2)

Bulk modulii < shear modulii

(2)

< Youngs modulii.

(3)

Shear modulii < Youngs modulii

(3)

< bulk modulii.

(4)

Bulk modulii < Youngs modulii

(4)

< shear modulii.

9.

S < M S
< S .
S < M
S < S .
M S < S
< S .
S < S
< M S .

which amplitude of this pendulum will

U U U
40 U 10 cm 8 cm
U SU
U U
1.3 , U U
10 cm 5 cm
U

reduce from 10 cm to 5 cm in

(ln 551.601, ln 250.693).

The amplitude of a simple pendulum, 9.

oscillating in air with a small spherical bob,
decreases from 10 cm to 8 cm in 40 seconds.
Assuming that Stokes law is valid, and
ratio of the coefficient of viscosity of air to
that of carbon dioxide is 1.3, the time in

carbondioxide will be close to (ln 551.601,

ln 250.693).
(1)

231 s

(1)

231 s

(2)

208 s

(2)

208 s

(3)

161 s

(3)

161 s

(4)

142 s

(4)

142 s

English : 6

Set : 01

Hindi : 6

Set : 01

10.

A capillary tube is immersed vertically in 10.

water and the height of the water column
is x. When this arrangement is taken into
a mine of depth d, the height of the water
column is y. If R is the radius of earth, the
x
ratio
is :
y
d

(1) 12

11.

U U
U S x
U d
, S y
R , x
y

(1)

12
R

(2)

2d

12
R

(2)

2d

12
R

(3)

R 2d
R 1d

(3)

R 2d
R 1d

(4)

R 1d
R 2d

(4)

R 1d
R 2d

Water of volume 2 L in a closed container 11.

is heated with a coil of 1 kW. While water
is heated, the container loses energy at a
rate of 160 J/s. In how much time will the
temperature of water rise from 278C to
778C ?

(Specific heat of water is

2 L 1 kW
U U
, 160 J/s U U U
278C
778C ? ( cU c
4.2 kJ/kg U cU c )

4.2 kJ/kg and that of the container is

negligible).
(1)

8 min 20 s

(1)

(2)

6 min 2 s

(2)

(3)

7 min

(3)

(4)

14 min

(4)

English : 7

Set : 01

U 20 U
6 U 2 UU
7 U
14 U
8

Hindi : 7

Set : 01

12.

The equation of state for a gas is given by 12.

PV5nRT1aV, where n is the number of
moles and a is a positive constant. The
initial temperature and pressure of one
mole of the gas contained in a cylinder are
To and Po respectively. The work done by

S U PV5nRT1aV
, n U a
SU U
U To
Po U
, mU

the gas when its temperature doubles

isobarically will be :

13.

(1)

Po To R
Po 2a

(1)

Po To R
Po 2a

(2)

Po To R
Po 1a

(2)

Po To R
Po 1a

(3)

Po To R ln 2

(3)

(4)

P o To R

(4)

Po To R ln 2
Po To R

evacuated vessel will be of the order of :

U (300 K) U
4.0310215 UUSU
U R58.3 JK21 21,
1 USU5105 S U U
5631023 21
U

(1)

0.2 mm

(1)

0.2 mm

(2)

0.2 mm

(2)

0.2 mm

(3)

0.2 cm

(3)

0.2 cm

(4)

0.2 nm

(4)

0.2 nm

Modern vacuum pumps can evacuate a 13.

vessel down to a pressure of 4.0310215 atm.
at room temperature (300 K). Taking
R58.3 JK21 mole21, 1 atm5105 Pa and
N Avogadro 56310 23 mole 21 , the mean
distance between molecules of gas in an

English : 8

Set : 01

Hindi : 8

Set : 01

14.

A particle which is simultaneously 14.

subjected to two perpendicular simple
harmonic motions represented by ;
x5a1 cos vt and y5a2 cos 2vt traces a
curve given by :

, U U
x5a1 cos vt U y5a2 cos 2vt U
,

(1)
(1)

(2)
(2)

(3)
(3)

(4)
(4)

English : 9

Set : 01

Hindi : 9

Set : 01

15.

A transverse wave is represented by :

y5

15.

10
2p
2p
sin
x
t2
T
p
l

S U
y5

10
2p
2p
sin
x
t2
T
p
l

U U
?

For what value of the wavelength the

wave velocity is twice the maximum
particle velocity ?

16.

(1)

40 cm

(1)

40 cm

(2)

20 cm

(2)

20 cm

(3)

10 cm

(3)

10 cm

(4)

60 cm

(4)

60 cm

The magnitude of the average electric field 16.

normally present in the atmosphere just
above the surface of the Earth is about
150 N/C, directed inward towards the
center of the Earth. This gives the total
net surface charge carried by the Earth to
be :
[Given

e o 58.85310 212

C 2 /N-m 2 ,

cU U U U U
S l U
150 N/C
U U mU U
cU
[ e o 58.85310 212 C 2 /N-m 2 ,
RE56.373106 m]

RE56.373106 m]
(1)

1670 kC

(1)

1670 kC

(2)

2670 kC

(2)

2670 kC

(3)

2680 kC

(3)

2680 kC

(4)

1680 kC

(4)

1680 kC

English : 10

Set : 01

Hindi : 10

Set : 01

17.

provide the resultant capacitance of :

3 mF U
U
U U ?

(1)

1 mF

(1)

1 mF

(2)

2 mF

(2)

2 mF

(3)

4.5 mF

(3)

4.5 mF

(4)

6 mF

(4)

6 mF

Three capacitances, each of 3 mF, are 17.

provided. These cannot be combined to

18.

A d.c. main supply of e.m.f. 220 V is 18.

connected across a storage battery of
e.m.f. 200 V through a resistance of 1 V.
The battery terminals are connected to an
external resistance R. The minimum
value of R, so that a current passes

l 220 V cU U
1 V U mU l
200 V U U
UU U U R
R , UU
U U U,

through the battery to charge it is :

(1)

7V

(1)

7V

(2)

9V

(2)

9V

(3)

11 V

(3)

11 V

(4)

Zero

(4)

English : 11

Set : 01

Hindi : 11

Set : 01

19.

The mid points of two small magnetic 19.

dipoles of length d in end-on positions, are
separated by a distance x, (x >> d). The

S d m
x U U U (x >>d)
x2n , n :

force between them is proportional to

x2n where n is :

20.

(1)

(2)

(3)

(4)

20.

The magnetic field of earth at the equator

is approximately 431025 T. The radius
of earth is 6.43106 m. Then the dipole
moment of the earth will be nearly of the
order of :
(1)

1023

(2)

1020

(3)

1016

(4)

1010 A m2

English : 12

m2

m2

m2

Set : 01

(1)

(2)

(3)

(4)

U U
431025 T
6.43106 m m
U
(1)

1023 A m2

(2)

1020 A m2

(3)

1016 A m2

(4)

1010 A m2

Hindi : 12

Set : 01

21.

VL : VC : VR51 : 2 : 3. If the rms voltage

of the AC source is 100 V, then VR is close

U LCR
U U L U C U U R U
- - U
VL, VC VR ,
VL : VC : VR51 : 2 : 3 U o
-- U 100 V , VR

(1)

50 V

(1)

50 V

(2)

70 V

(2)

70 V

(3)

90 V

(3)

90 V

(4)

100 V

(4)

100 V

When the rms voltages VL, VC and VR are 21.

measured respectively across the inductor
L, the capacitor C and the resistor R in a
series LCR circuit connected to an
AC source, it is found that the ratio

to :

English : 13

Set : 01

Hindi : 13

Set : 01

22.

Match

List I (Wavelength range of 22.

electromagnetic spectrum) with List II.

(Method of production of these waves)
and select the correct option from the

I (l SU U U)
II ( U )
U

options given below the lists.

List I

List II

Vibration of atoms
700 nm to
(i)
(a)
and molecules.
1 mm

1 nm to
(b)
400 nm

Inner shell electrons

in atoms moving from
(ii)
one energy level to a
lower level.

(c) < 10 23 nm (iii)

1 mm to
(d)
0.1 m

Radioactive decay of
the nucleus.

(a)

700 nm

(b)

1 nm

1 mm

400 nm

(i)

(ii)

(c) < 1023 nm (iii)

(d)

(iv) Magnetron valve.

1 mm
0.1 m

II
U

U U
U SU
SU
UU

(iv) U

(1)

(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

(1)

(a)-(iv), (b)-(iii), (c)-(ii), (d)-(i)

(2)

(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)

(2)

(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)

(3)

(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)

(3)

(a)-(ii), (b)-(iii), (c)-(iv), (d)-(i)

(4)

(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

(4)

(a)-(i), (b)-(ii), (c)-(iii), (d)-(iv)

English : 14

Set : 01

Hindi : 14

Set : 01

23.

A diver looking up through the water sees 23.

the outside world contained in a circular
horizon. The refractive index of water is
4
, and the divers eyes are 15 cm below
3
the surface of water. Then the radius of

U U U

4 U U
3
cU 15 cm

the circle is :
(1)

15333 5 cm

(1)

15333 5 cm

(2)

1533 7 cm

(2)

1533 7 cm

(3)

153 7
cm
3

(3)

153 7
cm
3

(4)

153 3
cm
7

(4)

153 3
cm
7

English : 15

Set : 01

Hindi : 15

Set : 01

24.

Using monochromatic light of wavelength 24.

l, an experimentalist sets up the Youngs
double slit experiment in three ways as
shown.
If she observes that y5b9, the wavelength

U l
mU U
S U
y5b9,
U

of light used is :

English : 16

Set : 01

Hindi : 16

Set : 01

25.

(1)

520 nm

(1)

520 nm

(2)

540 nm

(2)

540 nm

(3)

560 nm

(3)

560 nm

(4)

580 nm

(4)

580 nm

The focal lengths of objective lens and eye

lens of a Gallelian Telescope are 25.
respectively 30 cm and 3.0 cm. Telescope
produces virtual, erect image of an object
situated far away from it at least distance
of distinct vision from the eye lens. In this
condition, the Magnifying Power of the
Gallelian Telescope should be :

26.

U
$ 30 cm
3.0 cm U ScU
U U U S
, S ,
U

(1)

111.2

(2)

211.2

(1)

111.2

(3)

28.8

(2)

211.2

(4)

18.8

(3)

28.8

(4)

18.8

For which of the following particles will it

be most difficult to experimentally verify 26.
the de-Broglie relationship ?
(1)

an electron

(2)

a proton

(3)

an a-particle

(4)

a dust particle

English : 17

Set : 01

U-
?
(1) U$
(2) U
(3) a-
(4)

Hindi : 17

Set : 01

27.

28.

29.

If the binding energy of the electron in a 27.

hydrogen atom is 13.6 eV, the energy
required to remove the electron from the
first excited state of Li11 is :

U U U
13.6 eV , Li11 S
U U

(1)

122.4 eV

(1)

122.4 eV

(2)

30.6 eV

(2)

30.6 eV

(3)

13.6 eV

(4)

3.4 eV

(3)

13.6 eV

(4)

3.4 eV

Identify the gate and match A, B, Y in

28.
bracket to check.

U U cU A, B, Y
U

(1)

AND (A51, B51, Y51)

(2)

OR (A51, B51, Y50)

(1)

AND (A51, B51, Y51)

(3)

NOT (A51, B51, Y51)

(2)

OR (A51, B51, Y50)

(4)

XOR (A50, B50, Y50)

(3)

NOT (A51, B51, Y51)

(4)

XOR (A50, B50, Y50)

A transmitting antenna at the top of a

tower has a height 32 m and the height of
29.
the receiving antenna is 50 m. What is the
maximum distance between them for
satisfactory communication in line of sight
(LOS) mode ?

U U U 32 m
U U 50 m
cUU (LOS) U U
U U ?

(1)

55.4 km

(1)

55.4 km

(2)

45.5 km

(2)

45.5 km

(3)

54.5 km

(3)

54.5 km

(4)

455 km

(4)

455 km

English : 18

Set : 01

Hindi : 18

Set : 01

30.

An n-p-n transistor has three leads 30.

A, B and C. Connecting B and C by moist
fingers, A to the positive lead of an
ammeter, and C to the negative lead of the
ammeter, one finds large deflection. Then,
A, B and C refer respectively to :
(1)

Emitter, base and collector

(2)

Base, emitter and collector

(3)

Base, collector and emitter

(4)

Collector, emitter and base.

English : 19

Set : 01

U SUU U
A, B C B C
U, U U
A U U U
U C U
A, B C

(1) , U
(2) U,
(3) U,
(4) , U
n-p-n

Hindi : 19

Set : 01

PART B CHEMISTRY
31.

In a face centered cubic lattice atoms A 31.

are at the corner points and atoms B at
the face centered points. If atom B is
missing from one of the face centered

B U
U A U
U U B U
U B U U

points, the formula of the ionic compound

is :

AB2

(1)

AB 2

(2)

(2)

A 5B2

A 5B 2

(3)

(3)

A 2B3

A 2B 3

(4)

(4)

A 2B5

A 2B 5

32.
32.

(1)

Van der Waals equation for a gas is stated

as,

p5

2
nRT
n
2a .
V
V 2 nb

(1)

nRT
when ,
V

temperature is sufficiently high and

pressure is low.

(2)

temperature is sufficiently low and

pressure is high.

(3)

both temperature and pressure are

very high.

(4)

2
nRT
n
p5
2a .
V
V 2 nb

U U

This equation reduces to the perfect gas

equation, p 5

UU U

both temperature and pressure are

M,

p5

nRT
V

U U

(1)

(2)

(3)

(4)

very low.

English : 20

Set : 01

Hindi : 20

Set : 01

33.

The

standard

electrode

potentials 33.

(E ) of four metals A, B, C and D are

o

M /M

A, B, C

U U

SUUU ()

(E )
o

M /M

21.2 V, 0.6 V, 0.85 V U 20.76 V

21.2 V , 0.6 V, 0.85 V and 20.76 V,

U U

respectively. The sequence of deposition

of metals on applying potential is :

34.

(1)

A, C, B, D

(1)

A, C, B, D

(2)

B, D, C, A

(2)

B, D, C, A

(3)

C, B, D, A

(3)

C, B, D, A

(4)

D, A, B, C

(4)

D, A, B, C

At a certain temperature, only 50% HI is 34.

dissociated into H2 and I2 at equilibrium.
The equilibrium constant is :

35.

U 50% HI, H2 U
I2 SU

(1)

1.0

(1)

1.0

(2)

3.0

(2)

3.0

(3)

0.5

(3)

0.5

(4)

0.25

(4)

0.25

molarity of the solution is :

(U 60) 120
1000 U
1.12 UU
UU

(1)

1.00 M

(1)

1.00 M

(2)

2.00 M

(2)

2.00 M

(3)

2.50 M

(3)

2.50 M

(4)

4.00 M

(4)

4.00 M

Dissolving 120 g of a compound of 35.

(mol. wt. 60) in 1000 g of water gave a
solution of density 1.12 g/mL.

English : 21

The

Set : 01

Hindi : 21

Set : 01

36.

The half-life period of a first order reaction 36.

is 15 minutes. The amount of substance
left after one hour will be :

37.

U -
15 U U U

(1)

4 of the original amount

(1)

(2)

8 of the original amount

(2)

(3)

16 of the original amount

(3)

(4)

32 of the original amount

(4)

A current of 10.0 A flows for 2.00 h 37.

through an electrolytic cell containing a
molten salt of metal X. This results in the
decomposition of 0.250 mol of metal X at
the cathode. The oxidation state of X in

16

32

X U UU
2.00 U 10.0 A l
U U 0.250 X
X S
( F596,500 C)

the molten salt is : (F596,500 C)

(1)

11

(1)

11

(2)

21

(2)

21

(3)

31

(3)

31

(4)

41

(4)

41

English : 22

Set : 01

Hindi : 22

Set : 01

38.

of electron in the excited state of Li21 is :

U U U
213.6 eV Li 21 S
U

(1)

227.2 eV

(1)

227.2 eV

(2)

30.6 eV

(2)

30.6 eV

(3)

230.6 eV

(3)

230.6 eV

(4)

27.2 eV

(4)

27.2 eV

The energy of an electron in first Bohr orbit 38.

of H - atom is 213.6 eV. The energy value

39.

The temperature at which oxygen 39.

molecules have the same root mean square
speed as helium atoms have at 300 K is :
(Atomic masses : He54 u, O516 u)

40.

H-U

, U
SU U
300 K U ,
(U He54 , O516 )

(1)

300 K

(1)

300 K

(2)

600 K

(2)

600 K

(3)

1200 K

(3)

1200 K

(4)

2400 K

(4)

2400 K

The standard enthalpy of formation of 40.

NH3 is 246.0 kJ/mol. If the enthalpy of

formation of H 2 from its atoms is

2436 kJ/mol and that of N 2 is
2712 kJ/mol, the average bond enthalpy

246.0 kJ/
U H 2
2436 kJ/ U N2 2712 kJ/
N2H NH3 U
NH3

of N2H bond in NH3 is :

(1)

21102 kJ/mol

(1)

21102 kJ/

(2)

2964 kJ/mol

(2)

2964 kJ/

(3)

1352 kJ/mol

(3)

1352 kJ/

(4)

11056 kJ/mol

(4)

11056 kJ/

English : 23

Set : 01

Hindi : 23

Set : 01

41.

The amount of oxygen in 3.6 moles of water 41.

3.6

is :

42.

(1)

115.2 g

(1)

(2)

57.6 g

(2)

(3)

28.8 g

(3)

(4)

18.4 g

(4)

The gas evolved on heating CaF2 and SiO2 42.

with concentrated H2SO4, on hydrolysis
gives a white gelatinous precipitate. The

57.6
28.8
18.4

115.2

U SiO2 H2SO4 U
U U U $

CaF2

precipitate is :

43.

(1)

hydrofluosilicic acid

(1)

(2)

silica gel

(2)

(3)

silicic acid

(3)

(4)

calciumfluorosilicate

(4)

U U


UU

(at. no. of V523)

U U 1.73 BM
S U U U
(V U 523) U UU

(1)

VCl2

(1)

VCl2

(2)

VCl4

(2)

VCl4

(3)

VCl3

(3)

VCl3

(4)

VCl5

(4)

VCl5

Chloro compound of Vanadium has only 43.

spin magnetic moment of 1.73 BM. This
Vanadium chloride has the formula :

English : 24

Set : 01

Hindi : 24

Set : 01

44.

An octahedral complex of Co 31 is 44.

diamagnetic. The hybridisation involved
in the formation of the complex is :

45.

(1)

sp3d2

(1)

sp3d2

(2)

dsp2

(2)

dsp2

(3)

d2sp3

(3)

d2sp3

(4)

dsp3d

(4)

dsp3d

Which of the following is not formed when 45.

H 2S

reacts

with

solution ?

acidic

K 2 Cr 2 O 7

K2Cr2O7 H2S
U ?
(1)

CrSO 4

(1)

CrSO 4

(2)

(2)

Cr2(SO4)

Cr2(SO4)

(3)

(3)

K2SO 4

K2SO 4

(4)

(4)

Which of the following has unpaired

U
?

electron(s) ?

(1)

N2

(2)

O2
2

(3)

N 221

(4)

O 222

46.
46.

c U
U U

Co31

(1)

N2

(2)

O2
2

(3)

N 221

(4)

O 222

English : 25

Set : 01

Hindi : 25

Set : 01

47.

In the following sets of reactants which 47.

two sets best exhibit the amphoteric
character of Al2O3 . xH2O ?
2
Set 1 : Al2O3 . xH2O (s) and OH (aq)
Set 2 : Al2O3 . xH2O (s) and H2O (l)
1
Set 3 : Al2O3 . xH2O (s) and H (aq)
Set 4 : Al2O3 . xH2O (s) and NH3 (aq)
(1) 1 and 2

48.

49.

(2)

1 and 3

(3)

2 and 4

(4)

3 and 4

The number and type of bonds in C 222 ion 48.

in CaC2 are :
(1)

One s bond and one p2bond

(2)

One s bond and two p2bonds

(3)

Two s bonds and two p2bonds

(4)

Two s bonds and one p2bond

The form of iron obtained from blast 49.

U U
Al2O3 . xH2O U
?
2
Set 1 : Al2O3 . xH2O (s) U OH ()
Set 2 : Al2O3 . xH2O (s) U H2O ()
1
Set 3 : Al2O3 . xH2O (s) U H ()
Set 4 : Al2O3 . xH2O (s) U NH3 ()
(1) 1 U 2
(2) 1 U 3
(3) 2 U 4
(4) 3 U 4
C 222
U ?
(1) s U p2
(2) s U p2
(3) s U p2
(4) s U p2

CaC2

^ M

furnace is :
(1)

Steel

(1)

(2)

Cast Iron

(2)

(3)

Pig Iron

(3)

(4)

Wrought Iron

(4)

English : 26

Set : 01

S (Steel)
U (Cast Iron)
(Pig Iron)
U (Wrought Iron)

Hindi : 26

Set : 01

50.

The correct statement about the magnetic 50.

properties of [Fe(CN)6]32 and [FeF6]32

U [FeF6]32
U (Z526).

[Fe(CN)6]32

is : (Z526).
(1)

both are paramagnetic.

(1)

(2)

both are diamagnetic.

(2)

(3)

[Fe(CN) 6 ] 32

(3)

is

diamagnetic,

[FeF6]32 is paramagnetic.
(4)

[Fe(CN) 6 ] 32 is

paramagnetic,

(4)

[FeF6]32 is diamagnetic.
51.

Which one of the following reactions will 51.

not result in the formation of carbon-

[Fe(CN)6]32 U
[FeF6]32
[Fe (CN)6]32 U [FeF6]32

-
?

carbon bond ?

52.

(1)

Reimer-Tieman reaction

(1)

(2)

Friedel Crafts acylation

(2)

(3)

Wurtz reaction

(3)

(4)

Cannizzaro reaction

(4)

UU - U
U U
U$
$U

of propene with diborane, H 2 O 2 and

NaOH, the organic compound formed is :

UU, H2O2 U NaOH

UU-U

(1)

CH3CH2OH

(1)

CH3CH2OH

(2)

CH3CHOHCH3

(2)

CH3CHOHCH3

(3)

CH3CH2CH2OH

(3)

CH3CH2CH2OH

(4)

(CH3) COH

(4)

(CH3) COH

In the hydroboration - oxidation reaction 52.

English : 27

Set : 01

Hindi : 27

Set : 01

53.

The major product of the reaction

53.

NaNO /H SO

NaNO /H SO

2
2
4

2
2
4

is :

(1)

(1)

(2)

(2)

(3)

(3)

(4)

54.

(4)

For the compounds

CH3Cl, CH3Br, CH3I and CH3F,
54.
the correct order of increasing C-halogen
bond length is :

(3)

CH3F < CH3Cl < CH3Br < CH3I

CH3F < CH3Br < CH3Cl < CH3I
CH3F < CH3I < CH3Br < CH3Cl

(4)

CH3Cl < CH3Br < CH3F < CH3I

(1)
(2)

English : 28

Set : 01

U CH3F
- U U

CH3Cl,CH3Br,CH3I

(1)
(3)

CH3F < CH3Cl < CH3Br < CH3I

CH3F < CH3Br < CH3Cl < CH3I
CH3F < CH3I < CH3Br < CH3Cl

(4)

CH3Cl < CH3Br < CH3F < CH3I

(2)

Hindi : 28

Set : 01

55.

56.

heating :

U U U

(1)

C6H5Br1CH25CH2CH22ONa

(1)

C6H5Br1CH25CH2CH22ONa

(2)

CH25CH2CH22Br1C6H5ONa

(2)

CH25CH2CH22Br1C6H5ONa

(3)

C6H52CH5CH2Br1CH32ONa

(3)

C6H52CH5CH2Br1CH32ONa

(4)

CH25CH2Br1C6H52CH22ONa

(4)

CH25CH2Br1C6H52CH22ONa

Allyl phenyl ether can be prepared by 55.

In a nucleophilic substitution reaction :

DMF

56.

DMF

R2Br1Cl2 R_Cl1Br2,

R2Br1Cl2 R_Cl1Br2,

which one of the following undergoes

Z S U U
?

complete inversion of configuration ?

(1)

C6H5CHC6H5Br

(1)

C6H5CHC6H5Br

(2)

C6H5CH2Br

(2)

C6H5CH2Br

(3)

C6H5CH CH3Br
C6H5CCH3C6H5Br

(3)

C6H5CH CH3Br
C6H5CCH3C6H5Br

(4)
57.

(4)

In which of the following pairs A is more 57.

A, S B ?

stable than B ?
A

(1)

(1)

(2)

(2)

(3)

(3)

(4)

Ph3C , (CH3) C
3

English : 29

(4)
Set : 01

Ph3C , (CH3) C
3

Hindi : 29

Set : 01

58.

59.

given. Which one represents Buna-S ?

U h U
-S ?

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Which is the major product formed when 59.

U U U U UU
U ?
(1) UU
(2) U U
(3) U$
(4) U

Structure of some important polymers are 58.

acetone is heated with iodine and

potassium hydroxide ?

60.

(1)

Iodoacetone

(2)

Acetic acid

(3)

Iodoform

(4)

Acetophenone

Which one of the following class of 60.

compounds is obtained by polymerization

U U U
?

of acetylene ?
(1)

Poly-yne

(1)

(2)

Poly-ene

(2)

(3)

Poly-ester

(3)

(4)

Poly-amide

(4)

English : 30

Set : 01

-
-
-SUU
-U

Hindi : 30

Set : 01

PART C MATHEMATICS
61.

Let P be the relation defined on the set of 61.

all real numbers such that
P5{(a, b) : sec2 a2tan2 b51}. Then P is :
(1)

reflexive and symmetric but not

transitive.

(2)

reflexive and transitive but not

symmetric.

(3)

symmetric and transitive but not

reflexive.

(4)
62.

an equivalence relation.

for some real number k, is :

w(Im w 0) ,
z , S
k , U w2 w z5k (12z)
cU U ,

(1)

{z : ?z?51}

(1)

{z : ?z?51}

(2)

{z : z5 z }

(2)

{z : z5 z }

(3)

{z : z 1}

(3)

{z : z 1}

(4)

{z : ?z?51, z 1}

(4)

{z : ?z?51, z 1}

If

equations

Let w(Im w 0) be a complex number. 62.

Then the set of all complex numbers z
satisfying the equation w2 w z5k (12z),

63.

C
P S U U

P5{(a, b) : sec2 a2tan2 b51} , P
(1) S U

(2) S U

(3) U S

(4)

a common root, then a : b : c equals :

U
ax 2 1bx1c50,
(a, b, c R, a 0) 2x213x1450
cU , a : b : c UU

(1)

1:2:3

(1)

1:2:3

(2)

2:3:4

(2)

2:3:4

(3)

4:3:2

(3)

4:3:2

(4)

3:2:1

(4)

3:2:1

ax 2 1bx1c50, 63.

(a, b, c R, a 0) and 2x213x1450 have

English : 31

Set : 01

Hindi : 31

Set : 01

64.

then

x(x1b3)1(a323abx)50

the

x(x1b3)1(a323abx)50

a 2 and b 2

(2)

a b 2 and a 2 b

(4)

equation,

a b and a b
223

has roots :

(1)

(3)

65.

1
1
b U ax21bx1150
a
(a 0, a, b R) , U

1
1
and
are the roots of the 64.
a
b
equation, ax21bx1150 (a 0, a, b R),
If

223

and b

(1)

a 2

(2)

ab 2

(3)

ab

(4)

223

a 2 b

a b

223

the system of equations

a, b, c U S
U

(a21)x5y1z,

(a21)x5y1z,

(b21)y5z1x,

(b21)y5z1x,

(c21)z5x1y,

(c21)z5x1y,

If a, b, c are non - zero real numbers and if 65.

has

non-trivial

solution,

then

U , ab1bc1ca UU

ab1bc1ca equals :
(1)

a1b1c

(1)

a1b1c

(2)

abc

(2)

abc

(3)

(3)

(4)

21

(4)

21

English : 32

Set : 01

Hindi : 32

Set : 01

66.

If B is a 333 matrix such that B250, then 66.

det. [(I1B)50250B] is equal to :

67.

det. [(I1B)50250B] UU

(1)

(1)

(2)

(2)

(3)

(3)

(4)

50

(4)

50

The number of terms in the expansion of 67.

(11x)101

68.

(11x22x)100

in powers of x is :

302

(1)

302

(2)

301

(2)

301

(3)

202

(3)

202

(4)

101

(4)

101

all the 4-digit numbers formed by using the

numbers 3, 4, 5 and 6, without repetition,

333

(11x)101 (11x22x)100

(1)

The sum of the digits in the units place of 68.

B250

x U

3, 4, 5 6 ,
U, U
S U

is :
(1)

432

(1)

432

(2)

108

(2)

108

(3)

36

(3)

36

(4)

18

(4)

18

English : 33

Set : 01

Hindi : 33

Set : 01

69.

Given an A.P. whose terms are all positive 69.

integers. The sum of its first nine terms is
greater than 200 and less than 220. If the
second term in it is 12, then its 4th term

U Z
200
220 U 12 ,

is :

70.

(1)

(1)

(2)

16

(2)

16

(3)

20

(3)

20

(4)

24

(4)

24

If the sum

70.

5
7
1 2
1 2
1.......1 u p t o
2
1
1 12
1 1 2 2 1 32

5
7
1 2
1 2
1.......1
2
1
1 12
1 1 2 2 1 32

20 terms is equal to

71.

k
, then k is equal to :
21

(1)

120

(1)

120

(2)

180

(2)

180

(3)

240

(3)

240

(4)

60

(4)

60

( )

k
21

UU , k UU

If f(x) is continuous and f 9 2 5 2 9 , then 71.

f(x)

12 cos 3x
lim f
is equal to :
x0
x2

12 cos 3x
lim f

x0
x2

(1)

9/2

(1)

9/2

(2)

2/9

(2)

2/9

(3)

(3)

(4)

8/9

(4)

8/9

English : 34

Set : 01

Hindi : 34

20

( )

f 9 2 52 9

UU

Set : 01

72.

73.

If

y5enx,

d2 y d2 x
then 2 2 is equal to : 72.
dx dy

d2 y d2 x
2 2
dx dy

(1)

n enx

(1)

n enx

(2)

n e2nx

(2)

n e2nx

(3)

(3)

(4)

2n e2nx

(4)

2n e2nx

If the Rolles theorem holds for the 73.

function f(x)52x31ax21bx in the interval
1
[21, 1] for the point c5 , then the value
2
of 2a1b is :

74.

y5enx ,

f(x)52x31ax21bx U
1

[21, 1]

c5 U U ,
2
2a1b

(1)

(1)

(2)

21

(2)

21

(3)

(3)

(4)

22

(4)

22

3 x
4 x
If f (x )5 1 2 1 , x R, then the 74.
5
5

f (x )5 3

equation f(x)50 has :

U f(x)50 /
(1)
(2)
(3)
(4)

(1)

no solution

(2)

one solution

(3)

two solutions

(4)

more than two solutions

English : 35

Set : 01

UU

Hindi : 35

4
1 2 1 , x R ,
5

Set : 01

75.

76.

77.

sin 8 x 2 cos8 x
(12 2 sin 2 x cos 2 x )

(1)

1
sin 2x1c
2

(2)

(3)

(4)

2sin2 x1c

dx is equal to :

75.

sin 8 x 2 cos8 x
(12 2 sin 2 x cos 2 x )

(1)

1
sin 2x1c
2

1
sin 2x1c
2

(2)

1
sin 2x1c
2

1
sin x1c
2

(3)

1
sin x1c
2

(4)

2sin2 x1c

The integral

1
2

l n (11 2 x )
11 4 x

d x , equals :

76.

1
2

l n (11 2 x )
11 4 x 2

(1)

p
ln 2
4

(1)

p
ln 2
4

(2)

p
ln 2
8

(2)

p
ln 2
8

(3)

p
ln 2
16

(3)

p
ln 2
16

(4)

p
ln 2
32

(4)

p
ln 2
32

dx

UU

d x , UU

area (in square units) of the region A is :

A5{(x, y) : y2 [ 4x, y22x/24}

A ( )

(1)

(1)

(2)

(2)

(3)

10

(3)

10

(4)

11

(4)

11

Let A5{(x, y) : y2 [ 4x, y22x/24}. The 77.

English : 36

Set : 01

Hindi : 36

Set : 01

78.

If the differential equation representing the 78.

family of all circles touching x-axis at the
origin is (x 22y 2)

dy
5g(x) y, then g(x)
dx

, x-
U S U , U
(x22y2)

dy
5g(x) y, ,
dx

g(x)

UU

equals :

79.

(1)

1
x
2

(1)

1
x
2

(2)

2x 2

(2)

2x 2

(3)

2x

(3)

2x

(4)

1 2
x
2

(4)

1 2
x
2

Let a and b be any two numbers satisfying

1
1
1 2 5 . Then, the foot of
4
a
b
perpendicular from the origin on the
2

variable line,
(1)

hyperbola
semi-axis5 2 .

(2)

a hyperbola with each semi-axis52.

(3)

a circle of radius52

(4)

a circle of radius5 2

English : 37

with

a U b,
,

1
1
1 2 5 cU U
4
a
b
x y
UU, 1 51
a b
2

U , S

x y
1 51 , lies on :
a b

79.

each

(1)
(2)
(3)
(4)

Set : 01

U U ,
5 2
U U U ,
52
U, 52
U, 5 2

Hindi : 37

Set : 01

80.

81.

82.

Given three points P, Q, R with P(5, 3) and 80.

R lies on the x-axis. If equation of RQ is
x22y52 and PQ is parallel to the x-axis,
then the centroid of DPQR lies on the
line :
(1) 2x1y2950
(2) x22y1150
(3) 5x22y50
(4) 2x25y50
If the point (1, 4) lies inside the circle
x 2 1y 2 26x210y1p50 and the circle 81.
does not touch or intersect the coordinate
axes, then the set of all possible values of p
is the interval :
(1) (0, 25)
(2) (25, 39)
(3) (9, 25)
(4) (25, 29)
If OB is the semi-minor axis of an ellipse,
82.
F1 and F2 are its foci and the angle between
F 1 B and F 2B is a right angle, then the
square of the eccentricity of the ellipse is :
(1)
(2)
(3)
(4)

1
2

(1)
(2)
(3)
(4)

2x1y2950
x22y1150
5x22y50
2x25y50

(1, 4) x21y226x210y1p50
S ,
S U , U U , p
U
(1)
(2)
(3)
(4)

(0, 25)
(25, 39)
(9, 25)
(25, 29)

OB, , F1
F2 F1B F2B
,

(1)

1
2

(2)

1
2 2

(3)

1
4

English : 38

P, Q, R P(5, 3) R,
x- U S RQ U
x22y52 PQ, x- U ,
DPQR U U S ,

(4)
Set : 01

Hindi : 38

1
2

1
2

1
2 2
1
4

Set : 01

83.

Equation of the plane which passes 83.

U, U

through the point of intersection of lines

x 21 y 2 2 z2 3
5
5
3
1
2

x 21 y 2 2 z2 3
5
5
and
3
1
2

x 2 3 y 21 z2 2
5
5
1
2
3

x 2 3 y 21 z2 2
5
5
1
2
3

U U ,
U U ,

and has the largest distance from the origin

is :

84.

(1)

7x12y14z554

(1)

7x12y14z554

(2)

3x14y15z549

(2)

3x14y15z549

(3)

4x13y15z550

(3)

4x13y15z550

(4)

5x14y13z557

(4)

5x14y13z557

A line in the 3-dimensional space makes 84.

p
an angle u 0 < u [ with both the

u 0 < u [

x and y axes. Then the set of all values of

u U

u is the interval :

(1)

p
0 ,
4

(1)

p
0 ,
4

(2)

p p
6 , 3

(2)

p p
6 , 3

(3)

p p
4 , 2

(3)

p p
4 , 2

(4)

p p
,
3 2

(4)

p p
,
3 2

English : 39

Set : 01

(space)

Hindi : 39

U
p

y,

Set : 01

85.

86.

If ? a ?5 2, ? b ?5 3 and ?2 a 2 b ?5 5 , then 85.

? a ?5 2, ? b ?5 3

?2 a 1 b ? equals :

?2 a 1 b ?

(1)

17

(1)

17

(2)

(2)

(3)

(3)

(4)

(4)

In a set of 2n distinct observations, each of 86.

the observation below the median of all the
observations is increased by 5 and each of
the remaining observations is decreased by
3. Then the mean of the new set of

?2 a 2 b ?5 5

UU

, ,
, 5
3
U ,

2n

observations :

87.

(1)

increases by 1.

(1)

(2)

decreases by 1.

(2)

(3)

decreases by 2.

(3)

(4)

increases by 2.

(4)

If A and B are two events such that 87.

P(AB)5P(AB), then the incorrect
statement

amongst

the

1 U
2 U
2

A B U P(AB)5P(AB)

, ?

following

statements is :

(1)

A B

(1)

A and B are equally likely

(2)

P(AB9)50

(2)

P(AB9)50

(3)

P(A9B)50

(3)

P(A9B)50

(4)

P(A)1P(B)51

(4)

P(A)1P(B)51

English : 40

Set : 01

Hindi : 40

Set : 01

88.

The number of values of a in [0, 2p] for 88.

which 2 sin3 a27 sin2 a17 sin a52, is :

89.

,
2 sin3 a27 sin2 a17 sin a52 ,

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

If

cosec u5

cosec u5

p1q
p2q

(pq0),

then 89.

p u
cot 1 is equal to :
4 2

p u
cot 1
4 2

(1)

p
q

(1)

p
q

(2)

q
p

(2)

q
p

(3)

pq

(3)

pq

(4)
90.

[0, 2p] a

pq

(4)

The contrapositive of the statement I go 90.

to school if it does not rain is :
(1)

If it rains, I do not go to school.

(2)

If I do not go to school, it rains.

(3)

If it rains, I go to school.

(4)

If I go to school, it rains.

(pq0)

UU

pq

S
(Contrapositive)
(1) , S
(2) S ,
(3) , S
(4) S ,

-o0oEnglish : 41

p1q
p2q

-o0oSet : 01

Hindi : 41

Set : 01