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    Cheat Sheet 1

    Uploaded by

    iabureid7460
    The document provides steps and equations for calculating the pH of monoprotic acids and bases of varying concentrations. It also includes the pH calculation methods and common strong/weak acids and bases with their pKa/pKb values.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Cheat Sheet 1

    Uploaded by

    iabureid7460
    23 views2 pages
    The document provides steps and equations for calculating the pH of monoprotic acids and bases of varying concentrations. It also includes the pH calculation methods and common strong/weak acids and bases with their pKa/pKb values.

    Original Description:

    pH Cheat sheet 1

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    © © All Rights Reserved

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    The document provides steps and equations for calculating the pH of monoprotic acids and bases of varying concentrations. It also includes the pH calculation methods and common strong/weak acids and bases with their pKa/pKb values.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    23 views2 pages

    Cheat Sheet 1

    Uploaded by

    iabureid7460
    The document provides steps and equations for calculating the pH of monoprotic acids and bases of varying concentrations. It also includes the pH calculation methods and common strong/weak acids and bases with their pKa/pKb values.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    Monoprotic acid of concentration C

    1. Strong acid assume K a =1000


    2. K a / C0.01 ? Yes 5, No 3
    3. K a / C20 ? Yes 4, No 6
    4. pH =logC 7
    5. pH =log C K a 7
    K a K a 4CK a 7
    6. pH =log
    2
    7. pH 6.30 ? Yes End, No 8
    8. K a /C20 ? Yes 9, No 10

    Monoprotic base of concentration C


    1. Strong base assume K b=1000
    2. K b /C0.01 ? Yes 5, No 3
    3. K b /C20 ? Yes 4, No 6
    4. pH =14logC 7
    5. pH =14log C K b 7
    K b K b 4CK b 7
    6. pH =14 log
    2
    7. pH 7.70 ? Yes End, No 8
    8. K b /C20 ? Yes 9, No 10

    C C 2 4Kw
    End
    2
    8
    10. C10 ? Yes 11, No use BATE
    11. pH =7.00 End

    C C 2 4Kw
    End
    2
    8
    10. C10 ? Yes 11, No use BATE
    11. pH =7.00 End

    Weak monoprotic acid salt


    of concentration C

    Weak monoprotic base salt


    of concentration C

    9. pH =log

    1. pK b =14 pK a
    2. Continue as for monoprotic base.

    9. pH =14log

    1. pK a =14 pK b
    2. Continue as for monoprotic acid.
    2006 ChemBuddy http://www.chembuddy.com

    pH & pOH definition

    pH =log [ H ]

    pOH =log [ OH ]
    water ionization constant

    14
    K w=[OH ][ H ]=10
    pH pOH =pK w=14
    acid dissociation constant
    [ H ] [ A ]
    K a=
    HA H A
    [ HA]
    base dissociation constant
    [ OH ] [B ]
    K b=
    [ BOH ]
    pK a pK b =14

    BOH B OH

    Dissociation percentage

    f p=[ A ]/ C
    Henderson-Hasselbalch equation
    [A ]
    pH = pK a log

    [ HA ]
    [ B ]
    pOH = pK b log

    [ BOH ]

    Strong acids
    HCl, HBr, HI, HClO4,
    H2SO4 (first proton only), HNO3
    Strong bases
    KOH, NaOH, RbOH, CsOH
    Weak acids/bases
    pKax
    acetic C2H4O2 4.75
    H2SO4
    HF
    3.45
    H2CO3
    6.37 oxalic C2O4H2
    10.25
    citric C6H8O7 3.13
    4.76
    6.40
    NH4OH
    H3PO4
    2.15 aniline C6H7N
    7.20
    12.35

    pKax
    -3
    1.99
    1.25
    4.27
    pKb
    9.25
    9.4

    BATE pH calculator
    Program for fast, easy and accurate
    calculation of pH of solutions containing
    mixtures of strong/weak acid/bases up to
    four dissociation steps.
    2006 ChemBuddy http://www.chembuddy.com

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