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3.2.3.

1 APCI propane precooled mixed refrigerant process


The Propane Precooled Mixed Refrigerant (C3-MR) process, developed by Air Products & Chemicals
Inc. (APCI), is the most widely used liquefaction process to date. This process has dominated
the base load LNG technology since the late 1970s with about 75% of the natural gas liquefaction
market.
The C3-MR process, as shown in Figure 3-3, is composed of a multistage propane precooling
system followed by liquefaction using a mixed refrigerant system (made up of nitrogen, methane,
ethane, and propane). The natural gas feed is initially cooled by a separate propane chiller package to
an intermediate temperature, approximately 35_C (31_F). The natural gas is then liquefied and
subcooled in the main cryogenic heat exchanger (MCHE), composed of a large number of small
diameter spiral-wound tube bundles (i.e., spiral-wound or spool-wound heat exchanger). The mixed
refrigerant is partially condensed by the propane chiller before entering the heat exchanger.

The separate liquid and vapor streams are then chilled further before being flashed across Joule-
Thomson valves, which provide the cooling for the final gas liquefaction.
The heart of the APCI C3-MR process is its proprietary spiral wound heat exchangers (SWHE).
Large capacity trains over 5 MTPA can be designed using the split MR compressor/driver
arrangement, where the available power of each gas turbine driver and its helper motor/turbine is fully
utilized for LNG production with a minimum number of refrigerant compressor casings.
A modification by APCI made in the past decade has increased the size of LNG plants (over 6
MTPA; e.g., several liquefaction trains commissioned in Qatar 2008 to 2011 are over 7.8 MTPA).
The AP-X_ process adds a third refrigerant cycle (nitrogen expander) to provide the LNG subcooling
duties outside the main cryogenic heat exchanger -MCHE (Roberts et al., 2002). With the nitrogen
cycle, the size of the main exchanger can be kept the same, with the subcooling duty shared by the

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