Sulfurated Potash

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SULFURATED POTASH

GROUP 7:
LEAO
LUCAS
MIKE
NAYUSAN
OGOC
QUIAMBAO

SULFURATED POTASH
Synonyms:

Liver of Sulfur
Potassa sulfurata
Sulfurated potassa
Hepar sulfuris

not a true chemical compound


Composed chiefly of Potassium polysulfides and
Potassium thiosulfate
Contains not less than 12.8% of sulfur in combination as sulfide

Physical Properties
Occurs as irregular, liver-brown pieces when
freshly made, changing to a greenish brown
yellow color through absorption o moisture,
oxygen and carbon dioxide.
Has a bitter, acrid, alkaline taste
Decomposes on exposure to air

Solubility
1 Gram of sulfurated potash is soluble in
about 2mL of water (usually leaving a slight
residue), forming a brown solution which is
strongly alkaline.
Freely soluble in water

Preparation
1. Mix 2 Grams sublimed sulfur and 4 Grams potassium
carbonate and gradually heat them together in a crucible
until effervescence ceases.
3K2CO3 + 8S 185C
2K2S3 + K2S2O3 + 3CO2
2. Increase the heat to dull redness or until perfect fusion
results.
3. Pour the melt upon a stone slab, covered to prevent
access of air, and allow it to cool.
4. Break the solid into pieces and bottle immediately.

Preparation (continued)
The mixture actually consists of potassium
polysulfides:

Dipotassium trisulfide (K2S3)


Dipotassium tetrasulfide (K2S4)
Dipotassium pentasulfide (K2S5)
Potassium thiosulfate (K2S2O3 )
If the temperature is not carefully controlled,
potassium sulfate (K2SO4) may be formed due to the
decomposition of the thiosulfate.
4K2S2O3 3K2SO4 + K2S3

Uses
*Rarely used internally
Due to the liberation of hydrogen sulfide on
contact with the skin, and the alkaline
medium which it creates, the compound is
used to treat parasitic diseases of the skin.
10% ointment used for acne, scabies,
ringworm, psoriasis and tinea versicolor
parasiticide
scabicide

White Lotion N.F. VIII


Synonym: Lotio Alba, Lotio Sulfurata

Sulfurated potash + Zinc Sulfate Zinc


Sulfide
Use: topically as astringent and protective

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