Polystone
Polystone
Polystone
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Table of Contents
Chapter One: Introduction to Poly Stone................1 Poly Stone Uses Colors (Cross Reference Charts) Custom Colors Spray Equipment and Instructions.....3
Chapter Two:
Chapter Three: Matrix..................................................11 Chapter Four: Molds..................................................12 In-mold Post Mold Seaming Gel Coat and Resins...........................14 Back Coats and Back Fills.................. 15
Chapter Seven: Care and Maintenance.......................16 Chapter Eight: Appendix: Trouble Shooting................................17 Supplemental Information................. 23 Catalyst Chart Material Safety Data Sheet Glossary of Terms Poly Stone to Acrybond Color Cross Reference Chart
4775 S. Third Avenue, Tucson, AZ 85714 Tel: 520-889-1933 or 800-669-9214 Fax: 520-889-6782 Web: www.acstone.com E-mail: sales@acstone.com
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Poly Stone Custom Colors Custom colors are available by special order. Please contact ACS directly at 520-889-1933 or toll free 800669-9214.
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Example: To spray one 60 by 60 panel and two panels that are 30 by 60, all at 50 mils. How much Poly Stone would be needed and how much gel coat is needed? Answer: 60 inches = 5 ft; 5 ft. x 5 ft. = 25 square feet 30 inches = 2.5 ft; 2.5 ft. x 5 ft. = 12.5 ft. square ft. x 2 panels = 25 ft2 Now go to the chart at 50 mils. 0.45 lbs per sq. ft. are needed. 0.45 lbs. x 50 ft2 (25 + 25) = 22.5 lbs. of mix, 5.63 pounds of Poly Stone, and 16.87 pounds of gel coat
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Spraying without Gel Coat Using Poly Stone in applications without a clear gel coat is preferred by many fabricators. In such cases, proper care must be taken to ensure that a quality gel coat or resin that is designed for use as a spray solid surface be used. For more information on spray-able resins and gel coats, see chapter ve. Supplemental Equipment A mil gauge is an inexpensive (often times obtained from manufacturers free of charge) tool that allows for quick, easy measuring of gel coat and Poly Stone thickness (see gure 2d).
For a variety of spray systems and accessories, Troescher Company offers sales and service (contact information below). Systems offered by Troescher include a Binks 7N with unique modications, allowing for the ability to spray granite. The Binks 7N system is based on a liquid pressure pot tank containing the Poly Stone and gel coat mixture on one intake line going to the gun. A catalyst (initiator) tank is attached on another intake line going to the gun. The functional aspect of the Binks pot system is that components can be added or subtracted, resulting in either a simple hot pot system, to a complex air-assist system. Using a 10 gallon system that allows placing a mixed matrix 5 gallon bucket inside the pressure pot is recommended. For more information contact Craig Troescher at 513-271-5700 or craigt@fuse.net. Wet Spray Systems Large capacity wet spray pump systems deliver high volumes of Poly Stone mixed with gel coat and catalyst (see gure 2d). These systems are designed with either an internal static catalyst mixing system or external fans (catalyst and gel coat) mixing system. Such systems allow for high part volume as on a production line or large custom shop. A higher skill level and understanding are necessary to operate these systems to ensure speed and quality. In order to function properly, wet spray systems require routine cleaning and maintenance. Manufacturers for these spray systems include Venus Magnum at www.venusmagnum.com/ products-b.htm, RimCraft Technologies at www. rimcraft.com (offers large chip spray systems). This level of spray equipment cost ranges from USD$4,500 to $6,500.
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STEP 1
Mold Assembly Measure and number mold bars to ensure proper placement. See the proceeding chapter for other examples of molds that can be used with Poly Stone. Image to the left is an example of mold bar assembly.
STEP 2
Secure Mold Once mold sections are in order, use double sided tape and tempered glass to set-up mold bars. Apply mold release and make sure the glass is level and on a stable platform. Image shown, illustrates mold on tempered glass surface.
STEP 3
External Mold Bar Taping To secure mold form, tape corners of mold bars to avoid bar separation caused by weight of matrix. Images to the left illustrate tape location on mold bars.
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STEP 4
Measurement Resin: Measure by weight, pouring resin rst, ller second. Typical ratio is 25% Poly Stone, 75% Gel Coat PLEASE NOTE: Gel coat properties (viscosity and shop temperature) or chip size may affect mix ratio.
STEP 5
Mixing Equipment First image shows a very basic system of mixing equipment. Second image shows another system for mixing resin and ller.
Hand drill mixer. Motor driven mixer.
STEP 6
Poly Stone Spray Methods First image to the left shows the beginning spray application using a cup gun. Second image illustrates spraying Poly Stone using a different spray system (not shown in these steps).
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STEP 7
Cup Gun Preparation Hold cup gun at a 45 degree angle Trigger air to the gun prior to angling the gun towards the moldthis avoids drips.
STEP 8
Poly Stone Spray Application Apply several spray passes, instead of one overlapping pass as done with gel coat. Use a gel coat thickness gauge to measure depth of material (gure 2f). For use behind recommended. gel coat 30-40 80 mils mils are are
applying,
STEP 9
Poly Stone Technique Tip Use a paint brush and some of the Poly Stone mixture to completely cover the over hangs which could have been missed during spray application.
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STEP 10
Poly Stone Technique Tip For best results, allow Poly Stone and gel coat mix to become tacky to touch before proceeding to next step (back ll pour).
STEP 11
Back Coat Mixture When mixing the back coat, use a pigment that matches the Poly Stone spray color. See chapter on back coats and back lls for more information on color selection. Cultured marble or Featherlite may be used if the nished part does not require fabrication (see chapter six for more information on Featherlite). If fabrication is required, Alumina tri-hydrate must be used for backlls.
STEP 12
Matrix Mix Image to the left show the pigment mixing into matrix.
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STEP 13
Poly Stone Technique Tip For improved catalyst dispersal, premix catalyst into a small portion of resin. Mix thoroughly and then add to matrix mix.
STEP 14
Catalyst to Matrix Add premixed catalyst to pigmented matrix. Introduce catalyst as matrix is mixing
STEP 15
Back Coat Mixture Pour back ll mixture into mold immediately after catalyst is mixed thoroughly into matrix.
Matrix mixture
35 mils
Poly Stone
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STEP 16
Poly Stone Technique Tip Cure temperature Fahrenheit. should not exceed 180o
STEP 17
Completion After cure is complete, remove part from mold. Image to the right illustrates a nished Poly Stone product.
Tips for Spraying Liquid Granite Material 1. Liquid granite lines must always be wet out by pressurizing un-catalyzed gel coat through the line and the gun. This prevents clogging of the lines and the gun. 2. Liquid granite must have a viscosity of less than 10,000 centipoise (cps). To ensure less than 10,000 cps, do not add Poly Stone in greater concentrations than one part by weight Poly Stone to three parts by weight solid surface spray-able resin. 3. It is not necessary to ush granite lines with acetone when changing granite colors. Instead, ush with clear gel coat, then proceed to next color. Poly Stone colors do not use pigment, making color changes simple. 4. To reuse a bucket of mixed liquid material that has been sitting around for more than 24 hours, simply remix the materials together. 5. When spray system is not in use for an extended time period, pressurize non catalyzed clear gel coat through system.
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Figure: 4a In-Mold In-mold granite refers to the process of spraying the liquid granite into a mold. Then, marble or solid surface matrix is cast behind the sprayed granite product. Figure 4a is an example of spraying liquid Poly Stone into bar molds (also seen in chapter three). Figure 4b is an example of a sprayed granite mold. Post Mold Post mold granite refers to the process of spraying the liquid granite onto a core product, that may be wood, Medium Density Fiberboard (MDF) or foam board. In post mold granite spraying, it is necessary to Poly Vinyl Acetate (PVA) spray the entire product to seal the product after completion of spraying the granite material. Sealing the product stops the inhibition of the cure caused by polyester being in contact with the air. This is most important when sanding the product. Sanding a product that is not PVA will cause sandpaper to block up and become useless. Methods of Seaming Poly Stone Parts The following procedure will replicate the process of seaming solid surface sheet goods as in Poly Stone products. The most important part of the seam is making sure that a perfect dry t seam is achieved. If the seam is visible when the pieces are dry t together, it will also be seen when the pieces are wet seamed together. Therefore, it is very important that the seam is routed cleanly after the cut. Procedure 1. Cut the nished product to be seamed with a sharp triple chip blade. A diamond tip granite blade is recommended. 2. Clean edges of the cuts made with the circular saw. There will be some minor chips/cracks or chatter marks that will need to be removed in order to make a dry t seam that is inconspicuous. This
Figure: 4b is done by mirror cutting/trimming both pieces, using a high speed three horsepower router with a straight cut carbide tip router bit and using a straight edge for the exactness. The bit cut width is 1/2, so gap the pieces to be cut uniformly about 3/8 apart. Between 1/32 to 1/16 from each cut piece will be removed. Make sure that the alignment is correct on the pieces, so that the straight lip of the front edge of the counter does not have a slight angle. After trimming the cut, align the pieces and visually check the cut. If gaps or uneven spots are visible, re-trim pieces. When sanding, be careful not to round out the face edges of the cut, which could create unsatisfactory results. Once the seam dry ts well, for post mold applications, screw and hot melt in an 18 wooden seam block to the larger, less mobile piece to be joined. Split the dimensions so that 9 inches is on one side of the cut and 9 inches are on the other side of the cut. Use Acrybond color matched adhesive. A color reference chart is provided. See appendix. Wipe the seam and the deck area (at least 4 inches from the seam on both pieces) with denatured alcohol, removing dust and oils that may prevent a smooth seam. Take 2 by 2 sample blocks of solid surface samples, or other appropriate material, and hot melt them down in three to four locations along the seam. Blocks should be equally spaced, and no closer than 1/2 to the seam. Many fabricators nd that taking the blocks and drilling out 1/4 holes approximately 6 to 10 per block in advance helps adhesion of the hot melt to the block and the seaming surface. Do this before hot melting the block to the deck. For another method see gure 4a. Take three or four more blocks and repeat the process by placing these blocks on the other piece, exactly opposite of the pieces which were
3.
4.
5. 6.
7.
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hot melted down in step 10. 8. Prepare clamps (either Jorgeson or bar clamps) by having them set to the proper lengths ready to seam. 9. Place both pieces together, and gap them approximately 1/8 of an inch. For the front piece of the counter top, be prepared to place some masking tape to prevent the adhesive from running out. 10. Apply the Acrybond adhesive using two parallel beads along the length of the seam. 11. Gently tighten clamps. Tightening the closest clamp while ensuring that the top edges of the counter top are exactly level. The more level these surfaces are, the less sanding that will be required, and the higher likelihood that youll have two matching sides of the seamed area. A popsicle stick may be used to move back and forth across the seam to ensure the top edges are level. If readjustment is necessary, simply loosen the clamp and readjust to level the seam. Repeat this process for each clamped area. Tighten all four clamps uniformly nger tight. Caution: Overtightened clamps will cause a seam failure. Remove extra adhesive by using a one sided razor blade, sharp wood chisel, or putty knife. Then, tighten the clamps 1/16 of a turn, which will cause a little bit of adhesive to come out. For post-mold applications, screw in the underneath side that has not yet been screwed in. After the adhesive has gelled, remove clamps. Gel time is between 15 to 25 minutes. Using denatured alcohol, gently remove the blocks from the surface of the counter top. If excessive force is used part of the surface of the counter top will be pulled off. If necessary, use a sharp putty knife will help in removing the blocks. Once the adhesive is hard (dry) and ready to sand/work, use a 60 micron pad on a dual action orbital sander to create a matte nish. Less sanding will result in a better match. Finish job with a Scotchbrite 7447 pad (purple) for a matte nish. For a satin nish, use 60 micron, then 30 micron, then use a 7448 pad (white or grey).
Seam Block
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Figure 4c.
15.
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Problem: Bleedinga color that shows in another color Problem that arises when one color shows Color Striping Cause on another color.
Solution Gel coat sagging over gel coat................. Assess sag resistance, striping gel coat Immediately spray strip coat. Over wet base coast, spray thin lm of strip. Laminate Bleed Cause Solution Monomer in laminating resin.................. Excessive monomer in resin used in laminating. Backside of gel coat cure......................... Change the gel coat.
Problem: Blistersbubble-like defect in appearance Problem appears like bubbles on the surface.
After Part is Pulled, Heat Exposure Cause Solution Under-cure of un-reacted catalyst........... Catalyst over-spray, % of catalyst, mixing issue, leaks. Oil, solvent, water..................................... Dirty air lines, material or rollers. Air pockets................................................ Review rollout. After Part in Field Solution Cause Un-reacted catalyst................................... Review catalyst levels, distribution, and lm thickness (18 mils).
*Source: Cook Composites & Polymers Co., 2000 Application Manual. For more detailed application information contact CCP at 800-821-3590. Please note that the information has been altered as required as it applies to the application of Poly Stone.
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Problem: Chalkinggel coat oxidation Problem appears chalk-like or deposit on surface of gel coat (premature). Gel coats can oxidize over a long period of time. Related to environmental conditions.
Cause Solution Cure......................................................... Incomplete cure from under/over catalyzing. Check air lines, material, rollers. Also catalyst level, lm thickness and water/solvent contamination. Contamination........................................ Particles from atmosphere. Insufcient bufng.................................. Wipe buffed area with solvent rag. If gloss remains, are is alright. If gloss dulls, more bufng is required. Poor mold condition............................... Reduce sanding/bufng requirement on parts by keeping mold in good condition.
Problem: Checkingmud cracking Problem appears as crescent shaped cracks Cause Solution Poor integrity of the gel coat lm........... Could be trapped vapor or incompatible either separately or in groups.
liquid that blows through the gel coat lm upon aging. Check catalyst level, asses if there is water, solvent or some other liquid in area. Chemical damage or extremes in temperature.
Problem: Cracks Web-like cracks radiating from a centerpoint. Also cracks in circles. Frontal impact occurs. Stress cracks appearing in parallel lines.
Cause Solution Impact from laminate side..................... Handling and de-molding procedures. Parts should be handled with care. Mark on mold..........................................Defect in mold. Impact mark............................................ Handle with care. Stress from exing.................................. Too high gel coat thickness. Laminate too thin or under cured. De-molding or handling procedure causing problem to occur. Mold mark............................................... Mold defect.
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Problem: Fading
Reference water spotting later in chapter. Cause Solution Poorly cured gel coat.............................. Check catalyst levels and lm thickness18 mils (+ 2 mils). Improper cleaners or chemicals............. Do not use strong alkaline or acidic cleaners.
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Problem: Pre-release Problem occurring in the gel coat during cure, with visible surface distortion and low gloss.
Cause Incorrect catalyst.................................... High catalyst level.................................. Low catalyst level................................... Uneven and/or too thick lm................ Gel coat cured too long......................... Solution Contact vendor for correct catalyst. Check equipment and decrease catalyst. Check equipment and increase catalyst. Check thickness, not to exceed 24 mils, wet. Film thickness should be consistent Do not leave gel coat in mold for more than 3 hours without laminating the skin coat. Laminate same day if there are variations in temperature. Contact manufacturer. Do not add styrene without their approval. Catalyst not dispersed correctly. Possible water, oil or solvent contamination. Type and amount on the mold. Some may cause and oily residue and pre-release. Change clay, dust with ne powder or over-spray with PVA. Laminate sooner Check for correct catalyst level. Build laminate in stages. Too high in exotherm. Low resin solids. Uneven laminate thickness. Check resin to glass ratio.
Gel coat resin solids too low.................. Uneven cure........................................... Trapped solvent...................................... Mold release........................................... Clay......................................................... Extended cure time................................ Laminate curing too fast........................ Incorrect type of resin............................ Laminate curing uneven........................
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Problem: Softness
Problem resulting in the gel coat being easily marked or damaged. Cause Solution Soft gel coat........................................... Cure of gel coat in not complete. Also, check catalyst levels, lm thickness and possible contaminants.
Problem: Splotches
After sanding and bufng, splotches appear on parts. Problem also referred to as leathery, pebbly and chicken skin. Cause Over-spray.............................................. Line not maintained wet....................... Cure........................................................ Solution Over-spray should not accumulate. Spray laps within ve minutes. Film must cure as a total homogenous lm instead of individually cured thin lms.
Improperly cured gel coat..................... Chemical treatments such as chlorine Incorrect use of these chemicals. or cleaners.............................................. Parts exposed to moisture too quickly Allow for one week ambient cure before after fabrication...................................... service.
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Appendix
Catalyst Chart
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MATERIAL SAFETY DATA SHEET* Safety and Handling Information The following is general ingredient information for Poly Stone. SECTION IPRODUCT INFORMATION Chemical Name/Synonyms: Poly Stone, Textures RTECS NO: None Trade Names: This MSDS pertains to all Dura Stone, Poly Stone and Textures colors. Chemical Formula: Mixture - See Section II SECTION IIHAZARDOUS INGREDIENTS INGREDIENT CAS# WEIGHT % Aluminum Tri-hydrate 21645-51-2 50-97 (As Aluminum hydroxide) 5 mg/M3 (Resp) Titanium Dioxide 13463-67-7 < 1.0% (Pigments) 5 mg/M3 (Resp) Filler N/A 3-20 (Filler is a proprietary, trade secret ingredient and is considered non-hazardous under OSHA 29 CFR 1910.1200) NOTE: None of the ingredients are shown to be carcinogenic EXPOSURE LIMITS 15 mg/M3 (Total) 10 mg/M3 (Total) 15 mg/M3 (Total)
SECTION IIIHEALTH INFORMATION Permissible Exposure Limits: See Section II Eye Contact: May be mildly irritating to eyes Skin Contact: Not a skin irritant Inhalation: May be mildly irritating to the upper respiratory tract. This material is considered a nuisance particulate. Ingestion: No signicant health problems are expected SECTION IVEMERGENCY FIRST AID PROCEDURES Eye Contact: Flush eyes immediately with large amounts of water for at least 10 minutes. Seek medical attention if irritation persists. Skin Contact: Wash off with water. Inhalation: Remove from area of exposure to fresh air area. Ingestion: Low toxicity; should not cause any signicant health problems. SECTION VPHYSICAL DATA Appearance and Odor: Granular solid material, various colors. No odor. Molecular Weight: Not applicable Boiling Point: Not Applicable Melting Point: Not Applicable Specic Gravity: Not Applicable Solubility: Soluble in strong acids and alkalies SECTION VIFIRE AND EXPLOSION HAZARDS Flash Point: 680oF for ller material. Base material presents no re or explosion hazard. Unusual Fire and Explosion Hazard: Filler material will burn with a dark smoke once ignited but will not present an explosive hazard. Special Fire Fighting Procedures: Use a self contained breathing apparatus approved by NIOSH for all res. Use dry chemical, carbon dioxide, foam or water spray extinguishing media. SECTION VIIPHYSICAL HAZARDS AND REACTIVITY DATA Stability: Stable. Hazardous Polymerization: Will not occur Incompatibility (Materials to avoid): Strong oxidizing agents Hazardous Decomposition Products: In a sustained re, product components may degrade to form carbon monoxide, hydrogen cyanide, and other hazardous by products. SECTION VIIIEMPLOYEE PROTECTION Respiratory Protection: If PEL/TLV of any constituent in the mixture is exceeded, use a NIOSH approved half mask, air purifying respirator with particulate lters in atmospheres to 10X the PEL. Ventilation: Provide sufcient mechanical (general and/or local exhaust) ventilation to maintain exposures
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below the PEL/TLV(s) Other protective Equipment: Eye protection as goggles, and gloves and protective clothing (particulate impermeable) as needed to prevent irritation. SECTION IXENVIRONMENTAL PROTECTION Spill and Leak Procedures: Use dry cleanup procedures; avoid dusting. Collect in containers or bags. Waste Disposal: If reuse or recycling is not possible, material may be disposed of in a sanitary landll if codes permit. RCRA Hazardous Waste No.: Not federally regulated SECTION XSPECIAL PRECAUTIONS Prolonged storage and exposure to moisture will lead to eventual caking of the product. This is a detriment only to handling the material. No hazard entailed. Some or all of the reportable chemical substances in this product are regulated by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. None of the substances in this product are classied as toxic chemicals subject to reporting requirements of Section 313 of SARA Title III. DOT Classication: Not hazardous by DOT regulations. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE AND IS BELIEVED TO BE CORRECT. HOWEVER, ACS MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. ACS ASSUMES NO RESPONSIBILITY FOR INJURY OR ILLNESS FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. *The above data sheet is also available separate from the spray guidelines upon request. Poly Stone Product Description COLOR NAMES : PS000 - PS999 WE CERTIFY THAT POLY STONE IS COMPOSED OF THE FOLLOWING INGREDIENTS: CHEMICAL COMPOSITION: CHEMICAL NAME CAS NUMBER % POLYESTER 26062-94-2 47-53 ALUMINA TRI-HYDRATE 21645-51-2 47-53
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