Hempathane Topcoat
Hempathane Topcoat
Hempathane Topcoat
Product identity :
5521900010
Product type :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
Ready-for-use mixture :
55210 = 55219 7 vol. / 95370 1 vol. 55212 = 55219 7 vol. / 95370 1 vol.
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
8 October 2014
8 October 2014.
Mixture
R10
Xn; R20/21
Xi; R36/37/38
R52/53
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Warning
Hazard statements :
Precautionary statements :
Prevention :
Version: 0.1
-
Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Page: 1/12
5521900010
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If skin irritation occurs: Get medical attention.
Storage :
Keep cool.
Hazardous ingredients :
Not applicable.
Not applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
xylene
ethylbenzene
12-hydroxyoctadecanoic acid,
reaction products with 1,
3-benzenedimethanamine and
hexamethylenediamine
bis (1,2,2,6,6-pentamethyl4-piperidyl) sebacate
CAS: 100-41-4
Index: 601-023-00-4
EC: 432-840-2
CAS: 220926-97-6
Index: 616-201-00-7
>=1 - <3
Classification
Regulation (EC) No.
1272/2008 [CLP]
Type
[1] [2]
[1] [2]
[1] [2]
[1]
[1]
[1] [2]
[1]
EC: 255-437-1
CAS: 41556-26-7
>=0.25 - <1
R43
N; R50/53
n-butyl acrylate
EC: 205-480-7
CAS: 141-32-2
Index: 607-062-00-3
<1
R10
Xi; R36/37/38
R43
hydroxypropylmethacrylate
EC: 248-666-3
CAS: 27813-02-1
<1
Xi; R36
R43
See Section 16 for the
full text of the Rphrases declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
Version: 0.1
-
Page: 2/12
5521900010
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact :
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
Skin contact :
Ingestion :
Over-exposure signs/symptoms
Eye contact :
Inhalation :
Skin contact :
Ingestion :
No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments :
No specific treatment.
Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway, sewer or drain.
Decomposition products may include the following materials: carbon oxides metal oxide/oxides
Version: 0.1
-
Page: 3/12
5521900010
Version: 0.1
-
Page: 4/12
5521900010
ethylbenzene
n-butyl acrylate
Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection :
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Version: 0.1
-
Page: 5/12
5521900010
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. When the product is applied by spraying and for
continuous or prolonged work always wear an air-fed respirator e.g. hood with supply of fresh or
compressed air or a full face, powered air purifying filter. Be sure to use an approved/certified
respirator or equivalent.
Liquid.
Color :
White.
Odor :
Solvent-like
pH :
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Vapor pressure :
Vapor density :
Relative density :
1.186 g/cm
Solubility(ies) :
Very slightly soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Lowest known value: 280 to 470C (536 to 878F) (solvent naphtha (petroleum), light arom.).
Decomposition temperature :
Viscosity :
Explosive properties :
Highly explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Oxidizing properties :
Weighted average: 39 %
Water % by weight :
Weighted average: 0 %
VOC content :
459.1 g/l
435.8 g/l
TOC Content :
Version: 0.1
-
Page: 6/12
5521900010
ethylbenzene
12-hydroxyoctadecanoic acid,
reaction products with 1,
3-benzenedimethanamine and
hexamethylenediamine
bis (1,2,2,6,6-pentamethyl4-piperidyl) sebacate
n-butyl acrylate
hydroxypropylmethacrylate
Result
Species
Dose
Exposure
Rat
>5 mg/l
4 hours
LD50 Dermal
LD50 Oral
LC50 Inhalation Gas.
LC50 Inhalation Vapor
LD50 Dermal
LD50 Oral
LD50 Dermal
LD50 Oral
LC50 Inhalation Dusts and mists
Rabbit
Rat
Rat
Rat
Rabbit
Rat
Rabbit
Rat
Rat
>2000 mg/kg
3592 mg/kg
5000 ppm
6350 ppm
>2000 mg/kg
4300 mg/kg
>5000 mg/kg
3500 mg/kg
3650 mg/m
4 hours
4 hours
4 hours
LD50 Dermal
LD50 Oral
LD50 Dermal
Rat
Rat
Rat
2000 mg/kg
2000 mg/kg
>2000 mg/kg
LD50 Oral
LC50 Inhalation Gas.
LD50 Dermal
LD50 Oral
LD50 Oral
Rat
Rat
Rabbit
Rat
Rat
>2000 mg/kg
2730 ppm
2 mL/kg
900 mg/kg
11200 mg/kg
4 hours
-
Version: 0.1
-
Page: 7/12
5521900010
ATE value
Dermal
Inhalation (gases)
Inhalation (vapors)
Inhalation (dusts and mists)
7921.9 mg/kg
36008.6 ppm
46.47 mg/l
306.9 mg/l
Irritation/Corrosion
Product/ingredient name
solvent naphtha (petroleum), light
arom.
xylene
ethylbenzene
n-butyl acrylate
Result
Species
Score
Exposure
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
Rabbit
24 hours 5 milligrams
24 hours 500 milligrams
24 hours 15 milligrams
24 hours 500 milligrams
24 hours 10 milligrams
Sensitizer
Product/ingredient name
bis (1,2,2,6,6-pentamethyl4-piperidyl) sebacate
Route of exposure
Species
skin
Result
Guinea pig
Sensitizing
Category
Category 3
Category 3
Route of exposure
Target organs
Not applicable.
Not applicable.
Category
ethylbenzene
Category 2
Route of exposure
Target organs
Not determined
ears
Aspiration hazard
Product/ingredient name
Result
Other information :
Result
Acute EC50 2.6 mg/l
Version: 0.1
-
Exposure
96 hours
Daphnia
48 hours
Species
Page: 8/12
48 hours
96 hours
96 hours
72 hours
5521900010
Fish
Aquatic plants
Aquatic plants
96 hours
72 hours
72 hours
96 hours
Test
-
Dose
Inoculum
Product/ingredient name
solvent naphtha (petroleum), light
arom.
xylene
ethylbenzene
12-hydroxyoctadecanoic acid,
reaction products with 1,
3-benzenedimethanamine and
hexamethylenediamine
Result
Aquatic half-life
Photolysis
Biodegradability
Readily
Readily
Readily
Not readily
LogPow
BCF
Potential
3.12
3.6
6.01
10 to 2500
8.1 to 25.9
-
high
low
low
high
2.38
0.97
17.27
-
low
low
Mobility :
Not applicable.
vPvB :
Not applicable.
Version: 0.1
-
Page: 9/12
5521900010
ADR/RID
Class
14.1
UN no.
14.2
Proper shipping name
UN1263
PAINT
14.3
Transport hazard class(es)
3
14.4
PG*
14.5
Env* Additional information
III
No.
Special provisions
640 (E)
Tunnel code
(D/E)
IMDG
Class
UN1263
IATA
Class
UN1263
PAINT
III
No.
Emergency schedules
(EmS)
F-E, S-E
III
No.
PAINT
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
C6: Flammable (R10)
Version: 0.1
-
Page: 10/12
5521900010
F - Highly flammable
Xn - Harmful
Xi - Irritant
N - Dangerous for the environment
H225
H226
H304
H312 (dermal)
H315
H317
H319
H332
H332 (inhalation)
H335 (Respiratory
tract irritation)
H373 (ears)
H400
H410
H411
H412
H413
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Version: 0.1
-
Page: 11/12
5521900010
Justification
On basis of test data
Calculation method
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
Version: 0.1
-
Page: 12/12