Bunker Oil
Bunker Oil
Bunker Oil
DEFINITION :
A dark viscous residual fuel obtained by blending mainly heavier components from crude distillation unit,
short residue and clarified oil from fluidized catalytic cracker unit.
NOMENCLATURE
Bunker fuel, furnace oil , Fuel oil are other names for the same product. Though Fuel oil is a general term
applied to any oil used for generation of power or heat, Fuel oil can included distillates and blends of
distillates and residue such as Light Diesel Oil.
SPECIFICATION
Furnace oil in the current marketing range meets Bureau of Indian Standards Specification IS : 1593 1982 for fuel oils, grade MV2.
VISCOSITY
Viscosity is the most important characteristic in the furnace oil specification. It influences the degree of
pre-heat required for handling, storage and satisfactory atomization. If the oil is too viscous it may
become difficult to pump, burner may be hard to light and operation may be erratic. Poor atomization may
result in the carbon deposits on the burner tips or on the walls. The upper viscosity limit for furnace oil is
such that it can be handled without heating in the storage tank is excepting under server cold conditions.
Pre-heating is necessary for proper atomization.
FLASH POINT
As per the Controller of Explosives classification, Furnace oil falls in the class "C" category with minimum
flash point standard of 66 deg. C. Since Penskey Martens Closed Cup method is used, it is apparent that
a small quantity of low boiling point hydrocarbons is sufficient to lower the flash point drastically.
POUR POINT
It is a very rough indication of the lowest temperature at which Furnace Oil is readily pumpable. In the
specification the pour point of Furnace oil is not stipulated. However, for Furnace oil manufactured
indigenously and for imported parcels, the pour point is such that current supplies normally can be
handled without heating the fuel oil handling installation.
WATER
Water may be present in free or emulsified form and can on combustion cause damage to the inside
furnace surfaces especially if it contains dissolved salts. It can also cause sputtering of the flame at the
burner tip. Water content of furnace oil when supplied is normally very low as the product at refinery site is
handled hot and maximum limit of 1% is specified in the standard.
SEDIMENT
Furnace oil being a blend of residues contains some quantity of sediments. These have adverse effect on
the burners and cause blockage of filters etc. However, the typical values are normally much lower than
the stipulated value of maximum 0.25 percent, by mass.
ASH
Ash is incombustible component of the furnace oil and is expressed as a percentage mass of the furnace
oil sample. Ash consists of extraneous solids, residues of organometallic compounds in solution and salts
dissolved in water present in the fuel. These salts may be compounds of sodium, vanadium, calcium
magnesium, silicon, iron etc.
Ash has erosive effect on the burner tips, causes damage to the refractories at high temperatures and
gives rise to high temperature corrosion and fouling of equipments.
SULPHUR
Sulphur determination includes burning of known quantiy of oil, treating the sulphur oxidation products
formed during combustion and weighing of sulphur in the form of sulphate.
The sulphur di oxide may come in direct contact with the product during the combustion process and may
create adverse quality effects in the product.
CALORIFIC VALUE
Calorific value of a fuel is the quantity of heat generated in kilocalories by complete burning of one
kilogram weight of fuel. Gross calorific value is higher than net calorific value to the extent of heat
required to change water formed by combustion into water vapours.
CHARACTERISTICS
Test
methods
Grade
LV
Grade
MV1
Grade
MV2
Grade
HV
Acidity, inorganic
P-2
NIL
NIL
NIL
NIL
P-4
0.1
0.1
0.1
0.1
P-6 or 7
P-21
66
66
66
66
Kinematic viscosity in
centistokes at 50 0C
P-25
80
125
180
378
P-30
0.25
0.25
0.25
0.25
Sulphur, total, % by
wt., max.
P-33 or P35
3.5
4.0
4.0
4.5
Water Content, % by
vol., max.
P-40
1.0
1.0
1.0
1.0
Furnace oil is a Dark, viscous residual fuel oil which is obtained by blending residual products from various
refining processes with suitable diluent usually middle distillates to obtain the required fuel oil grades.
These fuel oil grades are similar in nature and have been marketed under different specifications in various
countries. In India it is sold under BIS specification under IS 1593-1982, Medium Grade 2 .
Uses of Furnace Oil are :
Furnace oil is a class C product having Flash Point above 66 OC. Since this is a residual fuel, there has to be
gradual filtration system to prevent the filter choking and fuel nozzles choking. Due to its viscous nature, it
has to be heated to improve its flowability and to a proper temperature for proper atomisation. Normally
gear pumps are preferred to avoid cavitation problems.
Form of
Licence
XVI
Fee
For each class of
petroleum Rs. 1000
for the first 50 Kl plus
Rs. 15 for every
additional KL or part
thereof, for every
calendar year subject
to a maximum of Rs.
15,000 per calendar
year or part thereof.
Safety Information :
Reactivity Data - Chemically stable and incompatible with strong oxidizers. Does not React
vigorously with common materials but can react with oxidizing agents
Health Hazard Data - Routes of entry may be through inhalation/ ingestion/ skin/ eye.
Sr.No
Requirements
Grade MV2
Characteristics
Inorganic acidity
Nil
Test Method
[P:] of IS:1448
[P:2]
[P:4] Method A
0.1
3
(typical 10000)
[P:6 or 7]
Density at 15 C
To be reported
[P:32]
66
[P:21]
5
Flash point (PMCC) C. Min
O
125-180
[P:25]
0.25
[P:30]
4.0
[P:33 or 35]
1.0
[P:40]
27
[P:10]
10
Sources:
http://www.petroleumbazaar.com/fo/Fospec.htm
http://www.bharatpetroleum.com/business/indFuelsSolvents_furnace_oil.asp?
from=bus