Nuclear Energy (Radioactivity, Nuclear Fission and Fusion)
Nuclear Energy (Radioactivity, Nuclear Fission and Fusion)
Nuclear Energy (Radioactivity, Nuclear Fission and Fusion)
7.1
7.2
Introduction
Radioactive decay
7.3
7.4
7.5
Half life
7.6
7.7
7.8
7.9
7.10
7.11
7.12
7.13
7.14
7.1
Introduction
The difference between the masses before and after the nuclear reactions representing the above
three nuclear processes corresponds to the reaction energy or nuclear energy, according to
the mass-energy relation E=mc2.
Nuclear energy was first discovered by French physicist Henri Becquerel in 1896, when he found
that photographic plates stored in the dark near uranium were blackened like X-ray plates, which
had been just recently discovered at the time 1895.
Example-1: Find the energy equivalent of 1gm of matter.
Solution:
m= 0.001 kg
Page 1 of 14
9 x1013
= 2.5x107 kWh
1000 x3600
7.2
Radioactive decay
For a nucleus to be stable, the number of neutrons should in most cases be little higher than the
number
of
protons.
For
example,
oxygen
has
three
stable
isotopes
16
8
13
8
O,
17
8
O,
14
8
O,
O,
18
8
O [ N 8,9,10]
15
8
O,
19
8
O and
20
8
and
five
known
unstable
19
8
O,
13
8
(i.e.
O,
20
8
14
8
O,
radioactive)
15
8
isotopes
[ N 5,6,7] there
neutrons.
7.3
15
8
O which are lacking in neutrons, undergo +-decay. In this process one of the
protons in the nucleus is transformed into a neutron and a positron and a neutrino are emitted.
This transformation is written as
15
8
O 157 N
where + signifies the emitted positron which in this context is called a -ray and denotes the
neutrino.
By contrast, nuclei like
19
8
process one of the neutron in the nucleus is transformed into a proton and an electron and an
antineutrino are emitted. This transformation is written as
19 O 19 F
8
9
It should be noted that in both +-decay and decay the atomic mass number remains the
same.
49
Ti
22
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238 U234 Th 4 He
92
90
2
Decay by -emission is comparatively rare in nuclides lighter than lead, but it is common for the
heavier nuclei.
(iv) Gamma Radiation:
The nucleus formed as the result of -decay (+ or -), electron capture or -decay is often left in an
excited state following the transformation. The excited nucleus then decays by the emission of
one or more -rays (photons).
Then the nickel-60 drops down to the ground state by emitting a gamma ray:
Gamma rays of 1.17 MeV and 1.33 MeV are produced.
7.4
There is only one law which governs all decay processes. This law states that the probability
per unit time that a nucleus will decay is a constant, independent of time. This constant is
called the decay constant and is denoted by .
Let us suppose that at time t the number of radioactive nuclei which have not yet decayed is N(t).
The rate at which these nuclei decay is therefore N (t ) disintegrations per unit time. This decay
rate is called the activity of the sample. Activity is measured in Becquerel (Bq) which is one
disintegration per second.
Let us suppose that at the beginning of disintegrations i.e. at t=o, the number of radioactive nuclei
present in the sample is N0.
Since N (t ) dt nuclei decay in the time interval dt, it follows that the decrease in the number of
undecayed nuclei in the sample in time dt is
dN (t ) N (t )dt ,
[1]
dN (t )
N (t ), [ 2]
dt
From [2] we can write
dN
dt
N
N
N0
dN
dt
N
0
log e [ N / N 0 ] t
N (t ) N 0 e t ,
[3]
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N (t ) N 0 e t
A (t ) A e
0
or
[ 4]
where A(t) is the activity at time t and A0 is the activity at time t=o.
7.5
Half life
It is defined as the time interval during which one half of the total number of nuclei that were
present at the beginning of the time interval have decayed .
If N1 nuclei are present at time t1 and one half that number N 2 N 1 / 2 have survived at time t2,
we can write
N1 N 0e t1
N 2 N 0e t 2
N1
N2
[ t2 t1]
[ t2 t1] ln 2
ln 2 0.693
T1/ 2 half life [ t2 t1]
7.6
If there are N0 radioactive nuclei at time =0, the number that decay in some time interval dt at t is
dN N [t ]dt N 0 e t dt
If we multiply this number by the life time t of these nuclei, sum over all the possible lifetimes from
t=0 to t= , and divide by the total number of nuclei, we get the average or mean lifetime :
1
t dN te t dt te t
N0 0
0
0
{[te
e t dt
0
1
/ ] e t dt}
0
Now, we know
t
A(t ) A0 e t A0 e
In can be seen from this equation that in one mean (average) life, the activity falls to (1/e) of its
initial value.
Example-2: Find the half-lives of a radioactive material if its activity drops to (1/16) th of its initial value
in 30 years.
Page 4 of 14
Solution:
We know that N N 0 (1 / 2) .
n
N
1
1
1
( )4 ( )n
N 0 16
2
2
or
n4
Therefore, Half-life = Total time of disintegration / No. of half-lives = 30 years / 4 = 7.5 years.
Example-3: What percentage of initial amount of a radioactive material decays during the time, equal
to mean lifetime of this material?
Solution:
Percentage of decay
7.7
N 0 e N 0 / e, 1 /
N0 N
1
1
x100 (1 ) x100 (1
) x100 63 %
N0
e
2.7
A nucleus consists of proton and neutrons. However, the total mass of a nucleus is always less
than the sum of the masses of its constituents e.g. the mass of helium nucleus is 4.00388 amu
(atomic mass unit) whereas the mass of 2 protons and 2 neutrons totals 4.03312 amu.
Thus, the mass of a helium nucleus is 0.02924 amu less than the sum of the masses of its
constituents. This difference is known as mass defect. The mass defect of a given nucleus can be
calculated by using the equation:
The energy equivalent of mass defect is called binding energy. An amount of mass equal to mass
defect has been converted into potential energy which holds the nucleus together.
Example-4: Show that a mass defect of 1amu is equivalent to about 931 Mev of energy.
Solution:
1 amu = 1.66054x10-27kg
Energy = mc2 = 1.66x10-27x(3.0x108)2 = 1.49x10-10J =
1.49 x10 10
1.6 x1019
931MeV .
The binding energy per nucleon of different elements is different. In Figure below, we show the
binding energy per nucleon as a function of mass number for different elements. It is seen from
this figure that binding energy is highest at the centre of the periodic table. This means that if
lighter elements are fused together or heavier elements split, release of energy would take place.
This gives two fundamental ways of obtaining nuclear energy:
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(i)
(ii)
The nuclear fission process is used in nuclear power plants for generation of energy. The nuclear
fusion process has still not been exploited commercially.
4
2
particle. The binding energy per nucleon is a maximum for nuclei of mass number A =56.
This figure suggests that we can liberate energy from the nucleus in two different ways. If we
split a heavy nucleus into two lighter nuclei, energy is released because the binding energy
per nucleon is greater for the two lighter fragments than it is for the original nucleus. This
process is known as nuclear fission. For example, if the uranium nucleus is broken into two
smaller nuclei, the binding energy difference per nucleon as about 0.8 MeV. The total energy
given off is therefore
[0.8 MeV/nucleon][235 nucleons]=188 MeV
Alternatively when we combine two light nuclei into a heavier nucleus, again, energy is
released when the binding energy per nucleon is greater in the final nucleus than it is in the
two original nuclei. The process is known as nuclear fusion. For instance, if two deuterium[
2
1
4
2
nuclear fusion is the main energy source of the sun and other stars.
Example-5: Find the average binding energy per nucleon for (a) heavy hydrogen
Uranium
Solution:
2H
1
, (b)
235 U
92 .
(a)
For
2H
1
MeV
(b)
For
235 U
92 ,
7.8
U + n = 148La + 85Br + 3n
MeV
MeV
MeV
MeV
MeV
MeV
200 MeV
1 MeV (million electron volts) = 1.609 x 10 -13 joules
If all the atoms of 1 kg of pure 235U (25.64x1023 atoms) were fissioned, the energy released would
be equivalent to that contained 3x10 6 kg of coal. Natural uranium contains only 0.7% 235U. If
fission efficiency is 50% fission of 1 kg of natural uranium would give energy equivalent to 10500
kg of coal.
There are two classes of fissionable materials.
Fissile Material: A fissile material is one that will undergo fission when bombarded by
neutrons of any energy. Fissile materials are 235U, 233U, 239Pu and 241Pu
Page 7 of 14
235
92 U
94
1
01n 139
56 Ba 36 Kr 3 0 n
Fertile Material: A fertile material is one that will capture a neutron, and transmute by
radioactive decay into a fissile material. Fertile isotopes may also undergo fission directly, but
only if impacted by a high energy neutron, typically in the MeV range. Fertile materials are
232
Th, 238U, 240Pu,
238
1
92 U 0 n
239
239
239
92 u 93 Np 94 Pu
Thus fissile and fertile materials together are defined as fissionable materials.
7.9
7.10
Materials used:
Nuclear reactions are controlled by a neutron-absorbing material, such as silver, indium and
cadmium. Other elements that can be used include boron, cobalt, hafnium, dysprosium,
gadolinium, samarium, erbium, and europium, or their alloys and compounds, e.g. high-boron
steel, silver-indium-cadmium alloy, boron carbide, zirconium diboride, titanium diboride, hafnium
diboride, gadolinium titanate, and dysprosium titanate.
7.11
the emission of a neutron is often considered its "birth," and the subsequent absorption is
considered its "death." For thermal (slow-neutron) fission reactors, the typical prompt neutron
lifetime is on the order of 10 4 seconds, and for fast fission reactors, the prompt neutron lifetime is
on the order of 107 seconds. These extremely short lifetimes mean that in 1 second, 10,000 to
10,000,000 neutron lifetimes can pass.
7.12
The ratio of neutrons available for fissioning in any one generation to the number available in the
preceding generation is called the effective multiplication factor, keff, and is calculated by:
keff =
keff < 1 (subcriticality): The system cannot sustain a chain reaction, and any beginning
of a chain reaction dies out over time.
keff = 1 (criticality): Every fission causes an average of one more fission, leading to a
fission (and power) level that is constant. Nuclear power plants operate with keff = 1
unless the power level is being increased or decreased.
keff > 1 (supercriticality): For every fission in the material, it is likely that there will be "
keff " fissions after the next mean generation time. The result is that the number of
fission reactions increases exponentially. Nuclear weapons are designed to operate
under this state.
In a nuclear reactor, keff will actually oscillate from slightly less than 1 to slightly more than 1, due
primarily to thermal effects (as more power is produced, the fuel rods warm and thus expand,
lowering their capture ratio, and thus driving k lower). This leaves the average value of k at
exactly 1. Delayed neutrons play an important role in the timing of these oscillations.
Page 9 of 14
7.13
Page 10 of 14
7.14
H 11H 12 H e
This process involves converting a proton to a neutron and is analogous to the beta-decay
processes discussed earlier. Once we have obtained 2H (deuterium), the next reaction that can
occur is
2
1
followed by
3
2
H 11H 23He
Note that the first two reactions must occur twice in order to produce the two 3He we need for the
third reaction. We can write the net process as
31
H 3
He
1
2
61
H 3
He 3
He 4
He 21
H 2 2 2
1
2
2
2
1
41
H 4
He 2e 2 2
1
2
The net result is the fusion of four protons into one alpha particle, with the release of two
electrons, two neutrinos, and energy, but several individual reactions are involved, depending on
the mass of the star. Since the two positrons disappear in this process, the only masses
remaining are four hydrogen atoms and the one helium atom, and so
Q ( m i m f )c 2 ( 4 x1.007825 u 4.002603 u ) (931.5 MeV / u ) 26.7 MeV
Each fusion reaction liberates about 26.7 MeV of energy. Let us now try to calculate the rate at
which these fusion reactions occur in the sun. The power output from the sun may be shown to
be about 4x1026 W, which corresponds to about 10 38 MeV/s. Thus there must be about 10 38 fusion
reactions per second, consuming around 4x10 38 protons per second. For stars the size of the sun
or smaller, the proton-proton chain dominates.
Page 11 of 14
C 1H
13
13
C H
14
14
15
15
15
13
13
C e
N H
15
O
1
N e
N H
N
O
12
He
Notice that the 12C plays the role of catalyst; we neither produce nor consume any 12C in these
reactions, but the presence of the carbon permits this sequence of reactions to take place at a
much greater rate than the previously discussed proton-proton cycle. The net process is still
described by 41H 4He, and of course the Q value is the same. Since the coulomb repulsion
between H and C is larger than the Coulomb repulsion between two H nuclei, more thermal
energy and a correspondingly higher temperature are needed for the carbon cycle. The carbon
cycle probably becomes important at a temperature of about 20 X 10 6 K, while the Suns interior
temperature is only 15 X 106 K.
When all of the hydrogen has been converted to helium, the Sun will contract and its temperature
will increase until helium burning occurs, by processes such as
3 4He 12C
Two He nuclei have a larger mutual Coulomb repulsion than two H nuclei, so helium fusion needs
more thermal energy than hydrogen fusion.
When the helium is used up, a still higher temperature will allow carbon fusion to make even
heavier elements, for example, 24Mg. Such processes will continue until 56Fe is reached; beyond
this point no further energy is gained by fusion.
SOLVED EXAMPLES
Problem No. 1: Show that after 10 half-lives a radioactive material is reduced to 1/1000 part
approximately.
Solution: From radioactive decay law, one can show that a radioactive material, after n half-lives, will
decay to N N 0 (1 / 2) .
n
N N 0 (1 / 2) 10 N 0 / 1024 N 0 / 1000
Problem No. 2: The half-life of radium is 1600 years. After how much time (1/16) th part of radium will
remain un-disintegrated in the sample?
4
n
Solution: Given N N 0 / 16 , therefore, N / N 0 (1 / 16) (1 / 2) (1 / 2)
Page 12 of 14
n4
We
1
K .E mv 2
2
2 xK .E
know
that
fraction
decayed 1
N
6.53 x10 6
N0
234
92
U,
235
92
U and
238
92
U , present
in the ratio 0.006%, 0.71% and 99.284% respectively. The half-lives of these isotopes are 2.5x10 5
years, 7.1x108 years and 4.5x109 years respectively. Calculate the contribution to activity (%) of each
isotope in sample.
Solution: No. of
234
92
0
U nuclei in the mixture = N 24
=
100gm)
0.71x6.02 x10 23
235
No. of
235
92
0
U nuclei in the mixture = N 25
=
No. of
238
92
0
U nuclei in the mixture = N 28
=
N 24 :
or
0
25
N 25 :
0
28
N 28
0.006 x6.02 x10 23 x 0.693 0.71x6.02 x10 23 x0.693 99.284 x6.02 x10 23 x
:
:
234 x 2.5 x10 5
235 x 7.1x10 8
238 x 4.5 x10 9
: 0.926 x10 10 1.02 : 0.0425 : 0.926 51.41% : 2.13% : 46.45%
235
92
U and
235
92
238
92
U and
238
92
Page 13 of 14
that initially these isotopes were in equal abundance and no isotopic separation has occurred,
calculate the age of these elements on the earth.
Solution:
N 25 N e
0
25
25 t
N 28 N 280 e 28t
0
0
In the beginning, N 25 N 28 .
e 28t 99.28
137.88
0.72
e 25t
or [ 28 25 ]t ln 137.88 4.927
or
Now
t 4.927 /[ 25 28 ]
8
10
25 0.693 / T125
per year
/ 2 0.693 / 7.1x10 9.76 x10
9
10
28 0.693 / T128
per year
/ 2 0.693 / 4.5 x10 1.54 x10
Problem No. 6: Calculate the amount of energy required to remove a neutron from
40
20
Ca=39.962589 amu,
39
20
Solution:
Ca
Ca n
39
20
Mass defect = (mass of Ca-39 +n) mass of Ca-40 = 38.970691 + 1.008665 39.962589
Page 14 of 14
Ca
amu.
40
20
40
20