Instruction Manual Innov-X Systems Alpha Series™ X-Ray Fluorescence Spectrometers

INSTRUCTION MANUAL
INNOV-X SYSTEMS
ALPHA SERIES
X-RAY FLUORESCENCE
SPECTROMETERS
August 2005
Version 2.1
Innov-X Systems, Inc.

10 Gill Street, Suite Q
Woburn, MA 01801
Toll Free 866-446-6689 FAX 781-938-0128
Web-Site: www.innov-xsys.com
2003 Innov-X Systems, Inc. All rights reserved.
Copyright Innov-X Systems, Inc. 2003

All rights reserved
No part of this publication may be reproduced, read or stored in a retrieval system,
or transmitted, in any form or by any means, electronic, mechanical, by
photocopying, recording or otherwise, without the prior permission of Innov-X
Systems, Inc.
THE INFORMATION IN THIS INSTRUCTION MANUAL IS FURNISHED AS
IS WITHOUT WARRANTY AND FOR INFORMATIONAL PURPOSES ONLY.
THIS DOCUMENT, IS SUBJECT TO CHANGE WITHOUT NOTICE, AND
SHOULD NOT BE CONSTRUED AS A COMMITMENT BY INNOV-X
SYSTEMS, INC. INNOV-X SYSTEMS, INC. ASSUMES NO LIABILITY FOR
ANY ERRORS, INACCURACIES OR OMISSIONS THAT MAY APPEAR IN
THIS MANUAL; NOR FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES
RESULTING FROM THE FURNISHING, PERFORMANCE, OR USE OF THIS
MATERIAL. Please report any errors to Innov-X Systems, Inc.; in order that
corrections can be made in future publications.
10 Gill Street, Suite Q
Woburn, MA 01801
Toll Free 866-446-6689 FAX 781-938-0128
Web-Site: www.innov-xsys.com
2003 Innov-X Systems, Inc. All rights reserved.
TABLE OF CONTENTS
Topic
Page
Chapter 1: INTRODUCTION
1.0 Inspecting the Analyzer
1.1 Components Included with the Analyzer
1.2 Quick Start Instructions
1.3 Introduction to XRF
1-1
1-1
1-2
1-3
Chapter 2: USAGE AND ASSEMBLY OF ACCESSORIES

2.0 Accessories
2.1 Analyzer Battery
2.2 Changing a Battery
2.3 Battery Charger
2.4 HP iPAQ Battery
2.5 Removing the iPAQ from Analyzer
2.6 Standardization Cap and/or Weld Analysis Mask
2.7 Testing Stand (optional accessory)
2-1
2-1
2-1
2-2
2-3
2-3
2-4
2-5
Chapter 3: RADIATION SAFETY

3.0 Important Safety Information
3.1 General Safety Precautions
3.2 Recommended Radiation Safety Training Components
3.3 Innov-X Safety Features
3.4 Performing a Test Following Appropriate Radiation Safety Procedures
3.5 Correct and Incorrect Instrument Usage
3.6 Radiation Warning Lights and Labeling
3.6.1 Main Power Switch and Indicator Light
3.6.2 Probe Light and Probe Label
3.6.3 Testing Light on Back of Analyzer
3.6.4 Label Behind iPAQ
3.7 Radiation Levels from Analyzer
3.8 Radiation Doses for Several Scenarios
3.9 Common Questions and Answers Regarding Radiation Safety
3.10 Safeguards and Emergency Response
3.11 Dosimeter Badges
3.12 Typical Registration Requirements
Chapter 4: OPERATION
4.0 Operation - General
4.1 Working with HP iPAQ Pocket PC
4.2 Operation - Main Software Screens
4.2.1 Innov-X Main Menu
4.2.2 The Analysis Screen
4.2.3 The Results Screen
4.3 Passwords
4.4 Standardization
4.4.1 Standardization Procedure
4.4.2 Standardization Errors
4.4.3 Battery Replacement and Initialization/Standardization
4.5 Software Trigger Lock
4.6 Test InformationLabel Input
4.6.1 Modifying the Test Info Template
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3-1
3-2
3-3
3-3
3-4
3-7
3-8
3-9
3-12
3-13
3-14
3-14
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4-1
4-1
4-3
4-3
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4-8
4.6.2 Entering Test Information

4.6.3 Editing Test Info from the Results Screen
4.7 Exporting and Erasing Data
4.7.1 Installing ActiveSync
4.7.2 Exporting Results
4.7.3 Customizing Results Export
4.7.4 Exporting Spectra
4.7.5 Erasing Readings
Chapter 5S: SOIL ANALYSIS
5.0 Check Standards
5.1 Sample Presentation
5.2 Testing in Soil Mode
5.3 Soil Results Screen
5.3.1 Results View Menu
5.3.2 Spectrum Screen
5.3.3 Test Info Screen
5.4 Soil Mode Options
5.4.1 Set Testing Times
5.4.2 Soil Mode Test End Condition
5.5 LEAP Mode (Light Element Analysis Program)
5.5.1 LEAP Settings
5.5.2 Testing Times
Appendix 1S: Troubleshooting GuideSoil Analysis
Appendix 2S Metals in Soil Analysis Using Field Portable X-Ray Fluorescence
Appendix 3S: X-ray Registration Information
General Appendices:
Technical Specifications
Certificate of ConformityCE
Innov-X Standard Warranty
4-14
5S-1
5S-1
5S-1
5S-2
5S-3
5S-6
Chapter 1 Introduction
1.0 INSPECTING YOUR INNOV-X ANALYZER
Upon receipt:
1.
2.
Locate and remove the shipping papers and documentation from under the lids foam padding.
Remove the Innov-X Analyzer and all of the components from the protective carrying case and
identify each on the enclosed shipping list.
3. Connect the battery charger to an 110V-240V AC power source. Place one Li-ion battery on the
charger and charge it for at least 2 hours. Charge the second battery.
4. Charge the HP iPAQ using the attached AC adaptor for at least hour.
5. Read and review the Quick Start section of the Users Manual. Innov-X recommends that you read
the entire manual.
6. Install the fully charged battery into the analyzer.
7. Press the ON/OFF button on the back of the analyzer and the power button on the iPAQ.
8. Select Innov-X from the start menu located in the upper left hand corner of iPAQ screen.
9. Select the desired analysis mode (i.e., Analytical, FastID, Pass/Fail or Soil). The instrument will
undergo a one minute hardware initialization period.
10. Standardize the instrument with the 316 Stainless Steel mask. Standardize the instrument every 4
hours or as directed by the display.
11. Release the software trigger lock and analyze a sample of known composition, in order to verify the
correct operation of the analyzer.
12. Analyze samples of unknown composition.
1.1 COMPONENTS INCLUDED WITH THE ANALYZER

Shown here are the various items which are included with the Innov-X portable XRF analyzer. Unless
otherwise noted, all items are standard accessories.
Analyzer, with iPAQ attached.
Two, Li-ion batteries (one shown).
Standardization cap and weld mask (optional)

The standard standardization cap has no weld slit.
Battery charger and an AC adaptor. Battery shown

mounted in charging system.
iPAQ cradle and AC adaptor. The cradle is used to

connect the iPAQ to a PC for downloading data and
reports.
Testing stand. This is the benchtop docking

station for the analyzer. It is an optional accessory
1.2 QUICK START INSTRUCTIONS

The following section provides a quick overview to using the Innov-X portable XRF analyzer. This is
intended to provide the basic startup and operational instruction needed to perform simple analyses. It is
highly recommended that the user read the sections on Radiation Safety (Chapter 3) and the detailed
description on operation (Chapter 4). The following Quick Start information is also provided as a separate,
bound, laminated publication for quick reference.
1.
2.
3.
4.
5.
6.
7.
8.
9.
Place a battery in the analyzer.

Power on the Analyzer (On/Off switch located on back of analyzer)
Power on the iPAQ (Button located in upper right hand corner of iPAQ)
Select Innov-X from the start menu located in the upper left hand corner of iPAQ screen.
Read the radiation safety notice and acknowledge that you are a certified user by pressing Start.
Select Desired Mode.
The analyzer will undergo a 60 second hardware initialization.
Place a standardization clip on the nose of the analyzer. Tap the button on the screen to
standardize. (Manual section 4.4 Standardization)
When standardization is complete, remove the standardization clip.
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Innov-X User Manual Version 2.1
10. Release the software trigger lock by tapping the locked icon on the iPAQ screen and tapping yes
in response to the software prompt.
11. Test standard to verify instrument performance.
12. Results will display on screen. Subsequent tests may be started from either the Results or
Analysis screens.
1.3 INTRODUCTION TO XRF: X-RAY FLUORESCENCE

SPECTROMETRY OVERVIEW
Basic Theory
Although most commonly known for diagnostic use in the medical field, the use of x-rays forms the basis
of many powerful analytical measurement techniques, including X-ray Fluorescence (XRF) Spectrometry.
XRF Spectrometry is used to identify elements in a substance and quantify the amount of those elements
present. An element is identified by its characteristic X-ray emission wavelength () or energy (E). The
amount of an element present is quantified by measuring the intensity of its characteristic line. XRF
Spectrometry ultimately determines the elemental composition of a material.
All atoms have a fixed number of electrons (negatively charged particles) arranged in orbitals around the
nucleus. The number of electrons in a given atom is equal to the number of protons (positively charged
particles) in the nucleus; and, the number of protons is indicated by the Atomic Number in the Periodic
Table of Elements. Each Atomic Number is assigned an elemental name, such as Iron (Fe), with Atomic
Number 26. Energy Dispersive (ED) XRF and Wavelength Dispersive (WD) XRF Spectrometry typically
utilize activity in the first three electron orbitals, the K, L, and M lines, where K is closest to the nucleus.
Each electron orbital corresponds to a specific and different energy level for a given element.
Emitted Electron
Detector
Electron
Secondary X-ray Photon Fluorescence

K
K
Primary X-ray Photons
X-ray Tube
In XRF Spectrometry, high-energy primary X-ray photons are emitted from a source (X-ray tube) and
strike the sample. The primary photons from the X-ray tube have enough energy to knock electrons out of
the innermost, K or L, orbitals. When this occurs, the atoms become ions, which are unstable. Electrons
seek stability; therefore, an electron from an outer orbital, L or M, will move into the newly vacant space at
the inner orbital. As the electron from the outer orbital moves into the inner orbital space, it emits an
energy known as a secondary X-ray photon. This phenomenon is called fluorescence. The secondary Xray produced is characteristic of a specific element. The energy (E) of the emitted fluorescent X-ray
photon is determined by the difference in energies between the initial and final orbitals of the individual
transitions.
1-3
This is described by the formula

E=hc/
where h is Planck's constant; c is the velocity of light; and is the characteristic wavelength of the photon.
Wavelengths are inversely proportional to the energies; they are characteristic for each element. For
example the K energy for Iron (Fe) is about 6.4keV. The number of element-specific characteristic Xrays produced in a sample over a given period of time, or the intensity, can be measured to determine the
quantity of a given element in a sample. Typical spectra for EDXRF Spectrometry appear as a plot of
Energy (E) versus the Intensity (I).
1400
X-ray Intensity
1200
1000
800
600
400
200
0
0
10
15
20
25
Energy (keV)
History
Wilhelm Roentgen discovered X-rays in 1895. Methods for identifying and quantifying elements using
XRF were first published by Henry Moseley in 1913. Much research and development of XRF continued
after Moseley's pioneering work, especially during WWII when rapid developments in the aircraft,
automotive, steel and other metals industries heightened the need to identify alloys quickly and reliably.
However, the first commercial XRF Spectrometers weren't available until the early 1950's. Those systems
were based on WDXRF technology and measured the characteristic wavelength of an element, one element
at a time. Although the use of these systems was critical for elemental analyses, they were large,
expensive, and required highly skilled operators to use and maintain them.
In the late 1960's, EDXRF technology, which measures the characteristic energy of an element, began to
rival the use of WDXRF due to the development of Si (Li) solid state detectors, which offered better energy
resolution of the signal. EDXRF systems offered the potential of collecting and displaying information on
all of the elements in a sample at the same time, as opposed to one at a time with typical WDXRF systems.
Many of the early EDXRF systems used radioisotopes for excitation instead of X-ray tubes, which could
require changing sources to determine all the elements of interest. Some of those early EDXRF systems
did not easily resolve multiple elements in a single analytical run.
As can be imagined, the equipment and applications of XRF Spectrometers have developed tremendously
since the 1960's. Advancements in technology, electronics, computers, software and the use and
modification of them for XRF Spectrometers by instrument manufacturers, research scientists & engineers,
and industrial users alike have led to the current state of the art in XRF Spectrometers. Now a mature
technology, XRF Spectrometry is routinely used for R&D, QC and analytical services in support of
production.
Elemental Analysis
1-4
XRF Spectrometry is the choice of many analysts for elemental analysis when compared to the other
techniques available. Wet chemistry instrument techniques for elemental analysis require destructive and
time-consuming specimen preparation, often using concentrated acids or other hazardous materials. Not
only is the sample destroyed, waste streams are generated during the analytical process that need to be
disposed of, many of which are hazardous. These wet chemistry elemental analysis techniques often take
twenty minutes to several hours for specimen preparation and analysis time. All of these factors lead to a
relatively high cost per sample. However, if PPB and lower elemental concentrations are the primary
measurement need, wet chemistry instrument elemental analysis techniques are necessary.
XRF Spectrometry easily and quickly identifies and quantifies elements over a wide dynamic concentration
range, from PPM levels up to virtually 100% by weight. XRF Spectrometry does not destroy the sample
and requires little, if any, specimen preparation. It has a very fast overall sample turnaround time. These
factors lead to a significant reduction in the per sample analytical cost when compared to other elemental
analysis techniques.
All elemental analysis techniques experience interferences, both chemical and physical in nature, and must
be corrected or compensated for in order to achieve adequate analytical results. Most wet chemistry
instrument techniques for elemental analysis suffer from interferences that are corrected for by both
extensive and complex specimen preparation techniques, instrumentation advancements, and by
mathematical corrections in the system's software. In XRF Spectrometry, the primary interference is from
other specific elements in a substance that can influence (matrix effects) the analysis of the element(s) of
interest. However, these interferences are well known and documented; and, instrumentation
advancements and mathematical corrections in the system's software easily and quickly correct for them.
In certain cases, the geometry of the sample can effect XRF analysis, but this is easily compensated for by
grinding or polishing the sample, or by pressing a pellet or making glass beads.
Quantitative analysis for XRF Spectrometry is typically performed using Empirical Methods (calibration
curves using standards similar in property to the unknown) or Fundamental Parameters (FP). FP is
frequently preferred because it allows elemental analysis to be performed with no standards or calibration
curves. This enables the analyst to use the system immediately, without having to spend additional time
setting up individual calibration curves for the various elements and materials of interest. The capabilities
of modern computers allow the use of this no-standard mathematical analysis, FP, accompanied by stored
libraries of known materials, to determine not only the elemental composition of an unknown material
quickly and easily, but even to identify the unknown material itself.
EDXRF Spectrometers
EDXRF Spectrometer systems are mechanically very simple; essentially there are no moving parts. An
EDXRF system typically has three major components: an excitation source, a spectrometer/detector, and a
data collection/processing unit. The ease of use, rapid analysis time, lower initial purchase price and
substantially lower long-term maintenance costs of EDXRF Spectrometers have led to having more
systems in use today worldwide than WDXRF Spectrometer systems.
Sample/Specimen
Excitation
Source
Data Collection/
Processing Unit
Spectrometer/
Detector
EDXRF has been found most useful for scrap alloy sorting, forensic science, environmental analysis,
archaeometry and a myriad of other elemental field-oriented analyses.
1-5
Handheld EDXRF Spectrometers for Field Analyses

It is clear that a future trend for elemental analysis is in rapid site investigation using techniques that are
fast, inexpensive, reliable, and long-term cost effective. There is a need for immediate decisions to be
made during the delivery of materials, industrial processing, and in the field for positive materials
identification or environmental site assessment and remediation. It is also clear that EDXRF Spectrometry
is the most suitable elemental analysis technique available for field analysis due to its simplicity, speed,
precision, accuracy, reliability, and overall cost effectiveness.
Recent technological developments in cell phones, pocket PC's and other portable consumer electronics
have led to the advancement of many high-performance, miniature components. X-ray equipment
manufacturers began to take advantage of these developments in the late 1990's and developed Handheld
EDXRF systems. An obvious advantage of Handheld EDXRF systems is that the analyzer is taken to the
sample as opposed to bringing the sample to the analyzer and configuring it to fit in an analysis chamber. In
addition to the per sample analytical cost savings, a key factor in using non-destructive EDXRF analysis,
especially in the field, is the overall project cost savings due to improved and more timely decision making.
The use of EDXRF for immediate positive materials identification or to guide an environmental site
characterization will generally reduce the overall time required in the field due to the quick turnaround for
the sample analysis; this invariably reduces the overall costs of analytical field work.
Of course, Handheld EDXRF technology has continued to evolve in concert with portable consumer
electronic developments. Just like the early Benchtop EDXRF systems, early Handheld EDXRF systems
used radioisotopes for excitation. There are several practical problems with the use of radioactive isotopes
for handheld systems. The source decays and loses its testing speed over time. In addition to the loss in
analytical capabilities, the sources have to be replaced incurring a cost. The use of radioactive isotopes also
requires licensing (state-to-state in the US) and a radioactive materials control program; they are difficult to
ship and transport, as they require hazardous materials declarations and/or permits. Consequently, the
newest and most exciting development in Handheld EDXRF technology is the use of battery operated,
miniature X-ray tubes, which was pioneered by the staff at Innov-X Systems.
Innov-X Systems Handheld EDXRF Spectrometers
Innov-X Systems specializes in Handheld EDXRF technology with the most advanced miniature
components available for X-ray Tube sources, detectors, and PC 's. Innov-X Systems Handheld EDXRF
Spectrometers are ideally suited for field analysis of alloys, lead-based paint, environmental soils, filters,
dust wipes, forensics, archaeometry, and a variety of other elemental analyses in the field or around the
plant. Innov-X Systems EDXRF Spectrometers are affordable, easy to use, reliable, and overall cost
effective. The Innov-X Systems Handheld EDXRF units incorporate state-of the art components including
a battery operated miniature X-ray tube, a high-resolution silicon pin detector, high speed data acquisition
circuitry, and a Compaq IPAQ Pocket PC handheld computer for calculations, results and operator
interface.
Innov-X Systems EDXRF Spectrometers offer the following invaluable features:
Portable
Battery operated, rechargeable
X-ray Tube-based (Ag or W anode, 10-40kV, 10-100uA)
Si PiN diode detector.
Integrated pocket PC
Pistol-shaped design for difficult testing locations and welds
Auto-compensation for irregular or small samples
Fundamental Parameters for no-standard analyses
Stored Grade Libraries for rapid Grade ID's
Stored Fingerprint Libraries for rapid material ID's
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Docking station available for use as standard benchtop unit

Results shown after a few seconds of testing time.
For more information on how to utilize your Innov-X Systems Handheld EDXRF Spectrometer optimally,
please review this Instruction Manual or contact us directly.
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Chapter 2. Usage and Assembly of

Accessories
2.0 ACCESSORIES
This chapter describes the various accessories that are provided with an Innov-X XRF analysis system.
Included are:
Batteries
Battery Charger
iPAQ cradle and charger
Testing Stand Assembly (not standard with all units)
Standardization Clip or Standardization Clip/Welding mask.
2.1 ANALYZER BATTERY

The Innov-X Systems XRF Analyzer is powered by a replaceable, rechargeable Lithium ion battery. In
addition, the iPAQ has its own internal battery.
Innov-X Systems Main Battery
The Innov-X Analyzer uses a rechargeable Lithium Ion Smart Battery. A picture
of the battery is shown in Fig. 2.1. Two batteries are included with each
analyzer. The batteries are charged an external battery charger. Batteries
typically function for 4 to 8 hours, depending on usage patterns. Heavier duty
cycles deplete the battery more quickly. Therefore, users who do longer and
more frequent tests will need to replace their batteries more often than users who
take shorter or fewer tests.
Replacement batteries can be purchased directly by calling Innov-X Systems at
781-938-5005. (P/N A003)
Figure 2.1. Li-ion

Battery for analyzer
Battery power indicators:

There are two ways of determining the charge remaining on a battery: the LED indicator on the battery and
the battery status icon on the analyzer screen. The battery icon, when tapped, will indicate the percent
charge remaining on a battery inside the analyzer. Additionally, the battery icon will change from green to
yellow when the battery gets low, indicating it has about 15 minutes left of charge.
To use the battery LED, push the button below the indicator. The lighting will indicate the % of charge. If
possible, try to use batteries with at least 50% of their full charge, according to the indicator.
2.2 CHANGING A BATTERY

To change a battery, perform the following steps:
1.
2.
3.
Hold the instrument by the handle, upside down, so the bottom of the instrument base is pointing
upward. Please refer to Fig. 2.2.
Hold the instrument so that the nose is pointing away from the operator.
Open the battery door on the bottom of the handle. The batteries have a small tab attached for
ease of removal.
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4.
5.
Pull out the existing battery, and replace with a new battery.
Insert the charged battery into the analyzer such that the connectors on the top of the battery are
facing to the right. Note that the battery slot is keyed so that the battery can only be inserted one
way.
Figure 2.2a. Instrument handle. Pull the rubber latch and lift
door. Reach into opening and remove battery.
Figure 2.2b Insert new battery

into opening.
2.3 BATTERY CHARGER

The battery charger is shown in Fig. 2.3. It takes about 2 hours to completely charge a battery. The status
of the charger is shown by two lights on the power adaptor. Table 2.1 lists the information conveyed by the
lights.
Figure 2.3. Battery charger.

Left Light
On
On
Off
Blink
Right light
Off
On
On
Blink
Off
Off
Status
Battery is charging
Battery is 80% charged
Battery is completely charged
Error. Remove battery and replace on charger. If error persists, call
Innov-X Systems Technical support.
No battery is on charger
Table 2.1 Battery charger status lights
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2.4 HP IPAQ POCKET PC BATTERY

The iPAQ has an internal rechargeable battery, which can be recharged by using the power adaptor that is
included with the unit. This adaptor can be connected either to the iPAQ itself, or to the cradle. If it is
connected to the cradle, and plugged in, the iPAQ will recharge whenever it is placed in the cradle. In
addition, the iPAQ Battery will recharge whenever the iPAQ is mounted in an Innov-X analyzer which is
powered, but not actively taking a test. The amber light on the top of the iPAQ will blink whenever the
battery is charging. It will remain solid when the battery is completely charged.
Since the iPAQ will be recharged whenever the Innov-X Systems Analyzer is in use, it may never be
necessary to use the iPAQ power adaptor. However, care should be taken when the analyzer is not used for
a period of several days, as the iPAQ uses some power even when it is powered off. It is therefore possible
to completely discharge the battery simply by not using the iPAQ for several days, or by using it for several
hours without recharging it.
If you do not use your Innov-X Analyzer on a daily basis, or if you will have a down period of more than
several days, it is recommended that you remove the iPAQ from the Analyzer when it is not in use and plug
in the iPAQ to a power outlet to recharge it. This will ensure that your iPAQ is always charged and ready
for use. You should also always plug in the power cord whenever the iPAQ is removed from the analyzer
for data transfer.
If you do allow the iPAQ battery to discharge significantly, either by allowing it to sit too long unused, or
by using it for a period of time without it being connected to a power source, it may not be possible to
operate your analyzer. If this happens, the Innov-X software will provide an error message indicating that
the iPAQ battery is too low. Recharge the iPAQ for at least a half an hour before attempting another
measurement.
If the iPAQ battery is completely discharged, it will not be possible to turn on the iPAQ until it is
recharged. A complete power failure will erase anything that is stored in the Main Memory of the iPAQ.
All Innov-X program and data files are stored on the storage card, rather than in Main Memory, so you will
not lose any data or have to reinstall the Innov-X software.
1.
2.
3.
4.
5.
If the battery on the iPAQ is completely discharged, charge it for at least one half hour.
You will be required to follow the prompts on the iPAQ screen before you can use the iPAQ. This
procedure involves realigning the screen by tapping in several spots, and going through a quick
tutorial.
The iPAQ will reinitialize the Innov-X Systems software. A message will appear indicating that
this is going to happen. You must tap ok to initialize.
The software will open automatically; a message will appear indicating that several registries have
been restored. Tap ok to dismiss this message.
Set the clock to the current time. Note, this is very important, as your data is indexed by date. If
the date in the iPAQ is incorrect, you may not be able to locate your results. The instrument will
not allow you to take a reading until the date has been changed.
a. From the Start Menu, tap Settings.
b. Select the System tab, and tap clock.
c. Set the proper date. Further details about this procedure can be found in the HP iPAQ
users manual.
2.5 REMOVING THE IPAQ FROM THE ANALYZER

It is very important to properly remove the iPAQ Pocket PC from the analyzer to avoid damaging the
connector on the back of the iPAQ.
In order to remove the iPAQ, push the iPAQ retainer shown in Fig. 2.4 towards the front of the analyzer.
Holding the retainer forward, grab the iPAQ from the sides, slide the iPAQ forward until it is clear of its
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connector, then tilt the front end up enough so it clears the front holder allowing the iPAQ to be lifted out
of the instrument.
Note: Never grab the iPAQ and twist it side-to-side to remove it from the analyzer. Always move
the iPAQ retainer forward as instructed above, slide the iPAQ forward and remove from the
analyzer.
Figure 2.4. Removing the iPAQ from the analyzer.
2.6 STANDARDIZATION CAP and/or WELD TESTING MASK

All analyzers are supplied with either a standardization cap or a combination standardization cap welding
mask. The standardization mask is the standard accessory. Welding masks can be purchased as an
additional accessory, or in lieu of the standardization mask.
Standardization Cap
The cap clips on the front end of the analyzer and is used to standardize the system as described in Chapter
4. To attach the cap, snap it onto the nose of the analyzer over the Kapton window.
Combination Standardization Cap/Welding Mask
The standardization/welding mask is shown in Fig. 2.5. The cap clips onto the front end of the analyzer
and is used to standardize the system as described in Chapter 4. To attach the cap, snap it onto the nose of
the analyzer over the Kapton window. Be sure that when attaching the cap, that the solid end (as opposed
to the end with the wide slit) is covering the window. To remove the mask, slide it off to either side.
The opposite end of the standardization cap serves as a welding mask. This mask is used to shield the base
metal from analysis, when analyzing a weld. It is important to use this mask since failure to do so will
produce an alloy chemistry that is a mixture of the base metal and the actual weld. For best results:
a.
b.
c.
d.
Use the welding mask only for welds that are larger than the opening in the mask;
Make solid contact between the surface of the mask and the material to test;
Use the mask only in the Analytical Mode not with the standard Fast ID library;
Consider using longer test periods to compensate for the smaller testing area especially
with more difficult separations.
If it is desirable to use the welding mask in FastID mode, a user can create a special Welding Mask
Library. Teach all relevant alloys with the welding mask is in position. Make sure these fingerprints are
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saved in library that contains ONLY fingerprints taught with a welding mask. When measuring a weld,
make sure the Weld library is the only one selected. By creating a special finger print library using the
welding mask, a user can get good results in the Fast ID Mode as well.
Figure 2.5 Standardization cap and welding mask. (Optional accessory)

The standard standardization cap does not have the welding slit.
2.7 TESTING STAND (optional accessory)

The testing stand is designed as a docking station
for the handheld analyzer. It can be used as a
bench-top system, or to test small samples. A list of
components and an assembled stand is shown in
Figure 2.6:
Components of the testing stand:

1
2.
3.
4.
5.
6.
7.
8.
Three (3) short legs

Three (3) long legs
Lower Stand
Upper Stand
Four (4) knobs for top plate
Test stand cradle
Clip for cradle.
Adaptor cable (connects serial connector
on iPAQ cradle to auxiliary port on
analyzer)
Figure 2.6. Assembled Testing Stand
Assembly of Testing Stand

1. Insert the three Short Legs through the holes in the
Lower Stand by inserting the threaded screw through the
holes. This will balance the Lower Stand on the table
top. (Fig. 2.7).
Figure 2.7. Mounting Lower Stand onto Short

Legs.
2-5
2. Mount the three Long Legs onto the Lower Stand by

inserting the threaded screws from the Short Legs into
the holes on the Long Legs and turning until snug.
Remove iPAQ from analyzer by following the
instructions in Figure 2.4. Place the analyzer into the
gap in the Lower Stand as shown. (Fig. 2.8).
Figure 2.8. Mounting Long Legs onto Lower

Stand and inserting analyzer.
3. Mount the Upper Stand onto the Long Legs. The

Upper Stand has holes for the screws at the end of each
of the Long Legs. The Upper Stand will also fit snugly
over the front end of the analyzer. Be sure that the
Upper Stand is mounted so that all three screws are
inserted through the holes, and the front end of the
analyzer is flush with the top surface of the upper stand.
(Fig. 2.9).
Figure 2.9. Mounting Upper Stand onto

Testing Stand.
5. Put three knobs to secure testing stand onto analyzer. The iPAQ clip can be secured with any of the
knobs. This clip grabs the base of the iPAQ cradle to hold the iPAQ securely in place.
6. Place the iPAQ in the cradle and connect it to the
Auxiliary Port on the analyzer using the serial cable
adaptor.
Figure 2.10. Connecting iPAQ to Auxiliary

Port on analyzer.
2-6
Chapter 3 Safety Information

3.0 IMPORTANT SAFETY INFORMATION
THE XRF SHOULD NOT BE POINTED AT ANYONE OR ANY BODY PART, ENERGIZED OR
DE-ENERGIZED! The safe and proper operation of the Innov-X XRF instruments is the highest priority.
These instruments produce ionizing radiation and should ONLY be operated by individuals, who have been
trained by Innov-X Systems, Inc. and received a manufacturers training certificate. Innov-X recommends
that operators and companies implement a written Radiation Safety Program, with safety components
specific to the site and application of use of the instrument. The Radiation Safety Program should be
reviewed annually and revised appropriately by a competent individual.
Innov-X analyzers must be used by trained operators, according to the instructions presented in this
manual. Improper usage may circumvent safety protections and could potentially cause harm to the user.
Pay attention to all warning labels and messages.
Important Notice for all Canadian Users:

Canadian Federal Regulations (Radiation Emitting Devices Act) require that all Canadian users must be
certified according to NRC Standard CAN/CGSB-48.97/2-2000 in order to use this device.
For this certification contact: Natural Resources Canada, Manager Nondestructive Testing Certification,
CANMET, 568 Booth St., Ottawa, ON, K1A 0G1; Tele: (613) 943-0583; Fax(613) 943-8297.
Users are advised to contact their appropriate federal/provincial./territorial radiation protection agency for
applicable rules of operation.
The Innov-X analyzer is a very safe instrument when used according to manufacturers recommended
safety procedures as detailed in this chapter.
Radiation levels during testing are < 0.1 mR/hr on all surfaces of the analyzer except at or near the exit port
for the radiation. This means that if an operator follows standard operating procedures, they will not obtain
any detectable radiation dose above naturally occurring background radiation, on their hand while holding
the analyzer, or on any area of their body.
This chapter details specifics of the radiation levels. It covers both standard (safe) and un-safe methods of
operation, it provides radiation emission information, and also provides dose estimates for unsafe
operations.
3.1 GENERAL SAFETY PRECAUTIONS AND INFORMATION:

Retain and follow all product safety and operating instructions. Observe all warnings on the product and in
the operating instructions. To reduce the risk of bodily injury, electric shock, fire and damage to the
equipment, observe the following precautions:
Heed service markings. Except as explained in this documentation, do not service any Innov-X product
yourself. Opening or removing covers may expose you to electric shock. Service needed on components
inside these compartments should be done only by Innov-X Systems, INC.
Damage requiring service:
The power cord, plug or battery contacts for the battery charger are damaged.
3-1
Liquid has been spilled or an object has fallen onto the instrument.
The instrument has been exposed to rain or water.
The instrument has been dropped or damaged.
There are noticeable signs of overheating.
The instrument does not operate normally when you follow operating instructions.
Safety Precautions:
Use the correct external power source: Ensure that the voltage is appropriate (100V-240 V/ 50-60 Hz) for
charging the battery packs. Do not overload an electrical outlet, power strip, or convenience receptacle.
The overall load should not exceed 80% of the branch circuit rating.
Use cables and power cords properly:
Plug the battery charger into a grounded electrical outlet that is easily accessible at all times. Do not pull
on cords and cables. When unplugging the cord form the electrical outlet, grasp and pull the cord by the
plug.
Handle battery packs properly; do not: disassemble, crush, puncture, short external contacts, dispose of in
fire or water, or expose a battery pack to temperatures higher than 60 oC (140 oF).Do not attempt to open or
service a battery pack.
WARNING: Danger of explosion if battery is incorrectly substituted. Replace only with Innov-X
specified batteries. Used batteries may be returned to Innov-X Systems for disposal.
3.2 INNOV-X SYSTEMS RECOMMENDED RADIATION SAFETY

TRAINING COMPONENTS
Individual Companies and States have specific regulations and guidelines for the use of X-ray tube
generated ionizing radiation. The purpose of the recommendations below is to provide generic guidance
for an ALARA - best practice - approach to radiation safety. These recommendations do not replace the
requirement to understand and comply with the specific policies of any state or organization.
1.
2.
3.
4.
5.
6.
Proper Usage. Never point the instrument at another person. Never point the instrument into the air
and perform a test. Never hold a sample in your hand and test that part of the sample.
Establish Controlled Areas. The location of storage and use should be of restricted access to limit
potential exposure to ionizing radiation. In use, the target should not be hand held and the area at least
three paces beyond the target should be unoccupied.
Specific Controls. The instrument should be stored, in a locked case, or locked cabinets when not in
use. When in use, it must remain in the direct control of a factory trained, certified operator.
Time - Distance - Shielding Policies. Operators should minimize the time around the energized
instrument, maximize the distance from the instrument window, and shoot into high density materials
whenever possible. Under no circumstances should the operator point the instrument at themselves or
others.
Prevent Exposure to Ionizing Radiation. - All reasonable measures, including labeling, operator
training and certification, and the concepts of time, distance, & shielding, should be implemented to
limit radiation exposure to as low as reasonably achievable (ALARA).
Personal Monitoring. Radiation control regulations may require implementation of a radiation
monitoring program, where each instrument operator wears a film badge or TLD detector for an initial
period of 1 year to establish a baseline exposure record. Continuing radiation monitoring after this
3-2
period is recommended, but may be discontinued if accepted by radiation control regulators. Please
refer to Sect. 3.10 for a list of providers of film badges.
3.3 INNOV-X SAFETY FEATURES

The Innov-X analyzer is very safe when used correctly, however the analyzer does emit radiation through
the analyzer window, and all precautions must be taken to reduce exposure to this radiation. In order to
minimize the possibility of accidental exposure, the following safety features are standard in all Innov-X
analyzers.
1. Deadman trigger. The trigger must be held for the duration of the test. This requires that the
user consciously depress the trigger whenever x-rays are emitted, and ensures that the analyzer is
attended at all times while x-rays are emitted.
Upon completion of safety training, an INNOV-X certified trainer may deactivate this feature
upon request. The deactivation of the trigger is recommended only if long tests are required (such
as for soil mode) and if the unit is used primarily by only 1 or 2 users who utilize it frequently, in a
very controlled environment. In situations where multiple users are sharing the unit, it is
recommended that the deadman trigger remain active.
Note: Canadian Regulations require that the deadman trigger be used at all times. This
feature will not be disabled for usage in Canada.
2.
Software Trigger lock. Before using the trigger, the user must tap on a lock icon located in the
lower right hand corner of the iPAQ screen. The user must then confirm that they wish to unlock
the trigger. If the instrument is used continuously, the software trigger lock will remain off. If
five minutes elapse between tests, the trigger will lock automatically.
3.
Software Proximity sensor. The software requires that a sample be present in front of the
analyzing window. This prevents the accidental exposure of bystanders to an open beam. If the
analyzer detects that a sample is not present, it will abort the test and shut off x-rays two seconds
after the test is started.
3.4 PERFORMING A TEST FOLLOWING APPROPRIATE

RADIATION SAFETY PROCEDURES
Starting the Analyzer:
When an operator opens the Innov-X software on
the iPAQ, he or she will be presented with one of
the displays shown to the right. Provided an
operator has received training from an authorized
Innov-X trainer, he/she should tap the START
button to begin using the analyzer.
In Canada, INNOV-X ANALYZERS MUST BE
OPERATED BY CERTIFIED USERS ONLY!
From this point the operator is presented with the
main menu of the analyzer to choose an operating
mode and begin testing (described in Chapter 4).
The remainder of this section is dedicated to
operational and safety aspects that pertain to safe
use and storage of the analyzer.
3-3
Starting a test using the trigger.

When the trigger is depressed, the analyzer supplies power to the x-ray tube
and opens the shutter to emit x-rays.
If deadman trigger is enabled, the trigger must be depressed for the duration
of the test. Releasing the trigger will close the shutter and immediately end
the test. If deadman trigger is disabled, pulling the trigger once will start a
test, pulling it again will stop it.
Figure 3.1 Handle of

analyzer. Trigger is located
at top of handle.
Starting a Test Using the Start Icon on the iPAQ Screen

This feature is disabled in all units shipped. It will become active only
if the deadman trigger is disabled.
An operator may also begin a test by pressing the Start button on the
touch screen, as shown at the right. The Start button, rather than the
trigger, is generally used when the analyzer is docked into the testing
stand.
This Feature is not available in Canada. All tests must be started via
the trigger.
3.5 CORRECT AND INCORRECT INSTRUMENT USAGE:

The Innov-X XRF analyzer can be used in several different testing configurations. Safety guidelines are
described for each configuration.
Configuration 1: Usage as a Handheld Alloy Analyzer:

In this configuration the analyzer is held in the hand, placed on various types of samples and a test is
performed. Samples include pipes, valves, large pieces of scrap metal, basically any sample large enough
to be tested in place, rather than held in the operators hand. Point the instrument at a metal sample such
that no part of your body including hands and/or fingers is near the aperture of the analyzer where x-rays
are emitted.
Using the analyzer in this manner assures that the operator will not obtain a radiation dose to any body part
or extremity in excess of naturally occurring background radiation. The radiation at any surface of the
analyzer is < 0.1 mR/hr except at the exit port and the immediate area around the exit port.
The user should take care that personnel are not located within 3 (1 m) of the front end of the analyzer
during testing, in the direction of the x-ray beam. Provided the analysis window is completely covered,
there is virtually no radiation being emitted around the area of the sample. However, if a small component
or curved surface is being analyzed, some radiation will be detectable.
3-4
Configuration 2: Usage in the Testing Stand

Innov-X strongly recommends that testing small pieces or small samples (rod, fasteners, turnings, XRF
sample cups, bagged samples, etc.) be analyzed using the Innov-X Testing Stand. This allows the sample to
be placed onto the analysis window of the analyzer without requiring the sample to be held by the operator.
See figure below titled Testing Stand Operation.
Note for Canadian Usage: The testing stand is not available for use in Canada at this time because it has
not received regulatory approval yet. When an interlocked version of the testing stand has received
regulatory approval, it will be available for sale into Canada. Please contact Innov-X Systems for an
update on this process at 781-938-5005.
Figure 3.2 Testing Stand Operation. Please refer to Section 2.7:
Testing Stand for assembly instructions.
Warning: Innov-X strongly recommends that operators do NOT
hold samples in their hand for testing. Never hold a small sample
in your hand, and test that sample, such that your hand is exposed
to the x-ray beam being emitted from the analyzer. This type of
testing produces a small but non-negligible radiation dose to the
operators hand. Please see Section 3.7: Radiation Doses for
Several Scenarios for dose levels. Also, see Figure 3.4 for an
example of incorrect usage.
Figure 3.2.
Testing of Small Components:

Operators often are required to test small components, particularly in the field of alloy analysis. Examples
of small samples include turnings, weld rod, wires, fasteners, nuts and/or bolts.
There are specific procedures to test small components. These procedures should be followed at all times.
Never hold a small part with your fingers or in the palm of your hand and perform a test. Doing so
may deliver a significant dose of radiation to your fingers or hand. Please refer to the Examples of
Mis-use below.
Method 1: Testing a sample lying on a flat surface.
3-5
Figures 3.2.: Performing a testing for a sample lying on the surface of a table. This is a good way to test
small samples, rather than holding them in your hand.
To analyzer small sample:
Place the sample onto a flat surface.
Place the window of the analyzer onto the sample and begin the test.
Safety Precautions:
Do not test samples in this manner at a desk or table where the operator is sitting. If the desk is made of
wood or another non-metallic material, some radiation will penetrate the desk and may provide exposure to
legs or feet if the operator is sitting at the desk or table.
Analytical Precautions:
If the sample does not completely cover the window, be sure the surface used does not contain metals or
even trace levels of metals, as this may affect the accuracy of the XRF result. The XRF may report the
presence of additional metals in the surface material. For this type of testing, it is good to place the sample
onto a piece of 1100series aluminum alloy and perform the analysis. The operator should disable the
aluminum analysis capability (See Section 8.3.3 in the manual for instructions).
Method 2: Use the testing stand as described above (see also Fig. 3.2).
Examples of Incorrect and Possible

Unsafe Operation:
Improper Operation, DO NOT
TEST SAMPLES LIKE THIS:
Exposure to the operators hand/fingers will likely
be minimal for this type of a testing, because the
operators hands and fingers are not in the primary
beam. However, Innov-X believes that this type of
the analyzer sets a poor safety precedent in that any
operation where the operator places their fingers or
hands near the window should not be permitted.
Figure 3.3. Incorrect Usage. While the dose to

the operators fingers/hand is negligible, testing
this way sets a poor safety example for other
operators, possibly encouraging other unsafe
usage. Innov-X strongly recommends against this
type of testing.
3-6
DO NOT TEST SAMPLES LIKE THIS:

Never hold a sample in your hand such that any part
of your body or appendages are exposed to the x-ray
beam. Testing samples in this way may generate
significant radiation exposure (up to 27 R/hr) to the
operators fingers.
Figure 4.4 Extreme example of incorrect usage.

An operator should NEVER hold small samples by
hand
3.6 RADIATION WARNING LIGHTS AND LABELING:

3.6.1 Main Power switch and Indicator Light:
The main power switch is found on the rear of the unit and is shown in the
figure to the left. Pressing the switch for several seconds will turn on the main
power. A green LED indicates the main power is on. The main power must be
turned on in order to operate the unit however, this switch DOES NOT turn on
the x-ray tube. No power will be supplied to the x-ray tube unit the Innov-X
software is started.
3.6.2 Probe Light and Probe Label:

The Innov-X analyzer is equipped with warning lights that alert the operator when the tube is receiving
power, and when x-rays are being emitted from the analyzer. Please see Fig. 3.5.
When the red light on the front nose of the analyzer is ON continuously (not blinking), this indicates the xray tube is receiving a low level of electrical power and the shutter is closed. The system is producing a
low level of x-rays internally in this condition, but the shutter is providing adequate shielding to keep x-ray
levels below levels of detection. The instrument is safe to be carried around or set down in this
configuration.
When the red light is blinking, this indicates the tube is powered, the shutter is open and the analyzer is
emitting x-ray radiation out of the analysis window. The analyzer should only be pointed at a sample, or be
in the testing stand with a sample resting on the window, in this configuration.
3.6.3 Display on Back of Analyzer:

The display on the back of the analyzer, shown in Fig. 3.6, provides a testing message to indicate that the
x-ray tube is energized and the shutter is open. This display is for testing conditions (i.e. overhead) where
the operator cannot see the Probe Light or the iPAQ display.
3.6.4 Label Behind iPAQ:

3-7
The analyzer also has a label just below the iPAQ indicating, as shown in Figure 3.7:
CAUTION: Radiation. This Equipment Produces Radiation When Energized.
This label is required by most regulatory agencies. The term When Energized refers to the condition
where the tube is fully energized and the shutter is open. This condition is also indicated by the red
blinking light on the probe.
Figure 3.5. Probe light and labeling.

When the light is on continuously, the xray tube is receiving minimal power and
it is producing a minimum level of xrays. The shutter is also closed so there
is no radiation exposure to the operator
or bystanders.
Figure 3.6. Back light on

analyzer.
Figure 3.7. Label behind iPAQ.

Top version is used in Canada
3.7 RADIATION LEVELS FROM ANALYZER

Two pictures of the analyzer are shown below. In the first picture, all the relevant components referenced
in this radiation safety section are displayed and labeled. The second picture shows a close-up of the front
end of the window. The four sides A, B, C and D are indicated on this picture because they are referenced
in terms of radiation levels output by the analyzer. The measured radiation levels for standard operating
conditions are shown in the figures and tables below. Standard operating conditions are tube voltage
operating at 35 kV, tube current of 5 uA, and 2 mm aluminum filtration.
Figure 3.8 Innov-X Analyzer, Side View
3-8
Figure 3.9 Innov-X Analyzer, Front View

Radiation Levels (mrem/hr) for Alloy Analysis, Standard Beam Conditions: 35kV, 5 uA, 2mm aluminum
filtering:
Sample at
Window
Blank (Air)
Metal
Trigger
<0.1
Location A
(Top)
<0.1
Location B
(Right Side)
<0.1
Location C
(Bottom)
<0.1
Location D
(Left Side)
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
Table 3.1. Dose rates (units of mrem/hr) at various locations with a metal sample covering the window and
with no sample present. For no sample the analyzer is shooting the x-ray beam into air.
As shown in the Table 3-1, the dose to the operators hand is negligible. The radiation levels at the side
surfaces of the instrument snout (aluminum housing) are all <0.1 mrem/hour. Despite these low levels of
radiation, there is no reason for any body part to be in the locations denoted A, B, C and D!
Table 3-2 shows the radiation levels directly in the x-ray beam that is emitted from the analyzer. Radiation
levels at the exit aperture (or port) are substantial. There is no reason for the operator or any personnel to
be exposed by the direct beam. Operators should never hold samples in their fingers or cupped in their
hands, as this may generate a significant radiation exposure.
Operations should never point the analyzer at another person and start a test, as this may also provide
significant exposure to the person if they are within a few inches of the port of the instrument.
Radiation Levels in the Primary Beam Versus Distance from Port:
For Alloy Analysis, Standard Beam Conditions: 35kV, 5 uA, 2mm aluminum filtering:
Tube
Conditions
At Trigger,
or any part
of operators
body.
<0.05
At Window
4 inches
12 inches
36 inches
48 inches
35 kV, 5 uA,
28,160
2,080
186
24
14
2 mm Al
filtering
15 kV, 25
< 0.05
27,780
1,620
145
19
11
uA, thinner
filter
material
Table 3.2. Dose rates (units of mrem/hr) in the direct x-ray beam being emitted from the analyzer
3.8 RADIATION DOSES FOR SEVERAL SCENARIOS

In this section we provide data, concrete examples of use and misuse of the analyzer and common
questions and answers we encounter when training personnel on the safe use of the Innov-X analyzer. The
goal is to explain scenarios of safe versus improper usage of the analyzer.
The table below presents radiation doses for normal operating conditions and also for examples of misuse
of the analyzer and even extreme misuse. Innov-X provides installation training that includes detailed
radiation safety training and documentation designed to prevent misuse of the analyzer
3-9
Example of Instrument Usage

Normal Operation - Dose to
Hand:
User analyzes samples
according to standard operating
procedures described in this
manual. Assumption:
Operator using system with xray tube ON for 8 hours/day, 5
days/week, 50 weeks/year.
(Practically constant usage).
Normal Operation Dose to

Torso:
Analyzer is used under the
same operating conditions
described above.
Radiation Exposure and Comments
Maximum exposure is to operators hand, at the trigger. Exposure is <

0.1 mrem/hr. Annual exposure to hand is then < 200 mrem (2mSv).
US: Maximum exposure under OSHA regulations is 50,000 mrem
annually. Thus continuous operation provides a dose that is at least 250
times lower than maximum allowed by OSHA.
Canada: Maximum exposure under ICRP regulations is 500 mSv for
radiation workers and 50 mSv for the general public. Thus continuous
operation provides a dosage 250 times lower for a radiation worker and
and 25 times lower for the general public.
Exposure to Torso is so low it cannot be measured. To be conservative
we use the same figure as the trigger, <0.1 mrem hr. Annual exposure
using operating conditions above is < 40 mrem. (0.4 mSv)
Maximum allowed is 5,000 mrem under OSHA
and 20 mSv under ICRP for radiation workers (1 mSv for general
public).
For the x-ray energy emitted by portable XRF analyzers (10-60 keV region), the bone in the
fingers will absorb radiation about 3-5 times more than soft tissue, so the bone would be at an
elevated radiation risk compared to soft tissue. For this reason no person shall hold a test
specimen in front of the window with the fingers in the direct beam, or direct the beam at any part
of the human body. Reference: Health Physics 66(4):463-471;1994.
Misuse Example 1:
Operator holds samples in front
of window with fingers, such
that fingers are directly in the
primary beam. Do not do this!.
For fingers at the port, in the primary beam, the maximum dose to the
fingers is 28,160 mrem/hr. Assume an operator performs a 10 sec test
(typical). The dose to the operators fingers or hand is 28,160 x
(10/3600) = 78 mrem. If the operator did this 641 times/year they
would exceed the allowable annual dose of 50,000 mrem to an
extremity. In Canada, the maximum allowed dose is 500 mSv/year
(Canada ICRP radiation worker) or 50 mSv/year (Canada ICRP general
public).
If the test time was 30 seconds instead of 10 seconds, the operator would
receive a dose of 234 mrem for each exposure, and thus would
exceed the annual safe limit of 50,000 mrem after 213 tests.
Even though it is unlikely to make this mistake so many times in a year,
do not even do it once. Take the extra time to test a sample on a surface
or use a testing stand. Note: If the operator takes an average of
only two shortcuts per week and places his/her fingers within
the primary x-ray beam at the window, they will exceed the
annual dose rate.
3-10
Misuse Example 2:
Operator places analyzer
against body and pulls the
trigger to start a test. Analyzer
tests to preset testing time
(usually 10 seconds) unless
operator pulls trigger again to
stop test. This applies to
analyzer being in contact with
operator or with bystander.
Dose at exit of sampling window is 28,160 mrem/hr.
Dose for a 10 second exposure with analyzer in contact with

Torso: 78 mrem (.78 mSv).
US: If an operator did this act 64 times in a year, the operator
would exceed the annual safe dosage to the torso of 5,000
mrem/year. The maximum dose of 5,000 mrem/year is a whole
body limit, which does not truly apply in this case because the xray beam size is small (about 2 cm2 area 1.5 cm x 1 .3 cm at
the port). Applying correction factors for the beam size is
complex and beyond the scope of this manual. The important
point is that for proper operation there is no reason to ever
exposure any part of the human body directly to the x-ray source.
This example serves to provide estimated exposure in the event
this occurs.
If the testing time was 30 seconds instead of 10 seconds, thus the
operator placed the port against his body or that of a bystander and
performed a 30 second test, the dose would be 234 mrem. This is about
the same as a mammogram. Repeating this gross mis-use 22 times
would exceed the annual allowable limits.
Canada: Radiation worker would have to repeat this example (234
mrem exposure) of gross misuse 8 times to achieve the ICRP level of
20 mSv. (general public 1.3 times to achieve limit of 1mSv)
Misuse Example 3:
Operator manages to initiate a
test for 10 seconds and exposes
a bystander that is standing 12
away from analyzer port. What
is exposure to bystander?
Dose to bystander at 1 foot is 350 mrem/hr. For a 10 second exposure

dose is 1 mrem. This is 5,000 times lower than the allowable dose to a
worker in a year. This would have to happen 5,000 times to for that
worker or bystander to obtain the maximum allowable dose.
Formula for calculating other scenarios:
Note: The proximity sensor

would automatically shut down
the x-ray tube after 2 seconds,
so this is an extremely
improbable occurrence.
Note 2: Equations to scale
these to other scenarios
involving longer or shorter
tests, and bystander being at
distances other than 12 are
provided at right.
13.25 t
Dose = 1 mrem
x
D + 1.25 10
D = distance from port in inches
T = testing time
Example: Bystander is 3 away from port for a 30 second test. In this
case the dose is calculated as:
2
13.25 30
Dose = 1 mr
x = 0.38mrem
36 + 1.25 10
US OSHA: Maximum allowable level is 5,000 mrem assuming
bystanders torso is exposed. Thus, this misuse would have to occur
12,500 times in a year to the same bystander before that bystander
achieved his maximum allowed dose.
ICRP: 5000 times for rad worker, 250 for general public
3-11
Comparative: Radiation Doses from Typical Exposures to Ionizing Radiation

Common medical and/or dental x-rays:
20-30 mrem each.
Mammogram:
100-200 mrem
Flying in a commercial jet coast to coast (6 hrs.):
1-2 mrem.
Daily exposure from background radiation:

0.3 to 0.5 mrem/day
* depends on geographic location
Table 3.3 Radiation Doses from Typical Exposures to Ionizing Radiation
From the above table, a single case of analyzer misuse, thus producing a one-time exposure of 70250 mrem, is comparable with single-event common medical x-ray procedures such as an annual
chest x-ray or mammogram, or 25-50 airline flights in a year, and thus is not considered harmful.
Regular misuse, such as taking safety shortcuts twice weekly, produces radiation exposure that
greatly exceeds these typical levels and should be avoided entirely.
3.9 COMMON QUESTIONS AND ANSWERS REGARDING

RADIATION SAFETY
Question: When Im shooting a piece of pipe or valve on a rack or on a table top, is there any exposure to
people standing in other locations, or standing several feet away from the analyzer?
Answer: Even a thin amount of metal sample (1-2 mm thickness) is enough to completely
attenuate the x-ray beam emitted from the Innov-X analyzer. Shooting a piece of material that
covers the sampling window on the analyzer will completely shield any bystanders from radiation
exposure. However, good practice recommends that the area for at least 4-5 feet in front of the
analyzer is clear of people.
Question: If I forgot to switch the safety on the trigger to ON, I pick up the analyzer and accidentally
pull the trigger, is that dangerous to nearby personnel?
Answer: No, this example of misuse is not dangerous, but it may produce a non-negligible
radiation exposure to nearby personnel. For an exposure to occur, the following things must
happen. First, you must be holding the analyzer so that a bystander is actually standing in the xray beam being emitted. Just being near the analyzer is totally safe otherwise. Second, the
bystander must be within 1-3 feet from the nose of the analyzer in addition to being in the beam
path, to receive any appreciable dose. If all of these conditions are true, the dose received by a
bystander is still extremely low. It ranges between 0.1 to 0.5 mrem depending on the exact
location of the bystander. This dose is 10,000 to 50,000 times less than the allowed dose. Please
see Misuse Example 4 in the table above.
Question: Do I need to create restricted areas where I am using the analyzer?
Answer: No, provided you are following normal operating procedures there is no reason to restrict
access to an area where the analyzer is in use. The operator should take precautions to keep any
personnel more than 3 feet away from the sampling window of the analyzer in the event of
accidental misuse as detailed above. Should the operator also elect to test small components like
weld rod as shown in Figure 3.3, the operator should also be sure that no personnel are standing
within about 4-5 feet of the sampling window.
Question: How does the x-ray tube in the Innov-X system compare to a radiography system used for
taking images of metal parts.
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Answer: The x-ray tube used in the Innov-X system produces between 1,000 and 10,000 times
lower power than most radiography systems (0.5-1 watt for Innov-X versus kW for radiography
systems). This is because a portable XRF is designed to perform surface analysis of alloys and
other samples, whereas radiography systems are designed to shoot x-rays entirely through metal
components in order to obtain an image on the other side of the object being bombarded with xrays. For example, many tube-based radiography systems use a 300-400 kV tube and currents in
the tens or hundreds of milliamps (mA). The Innov-X analyzer uses a tube operating at 35 kV and
5-30 micro-amps. The radiation levels produced are therefore thousands or tens of thousands
times lower with the Innov-X system.
Question: Should we use dosimeter badges with the Innov-X analyzer.
Answer: Dosimeter badges are required by some states, and optional by other states. Innov-X
recommends that operators wear badges, at least for the first year of operation, as a general
precaution to flag any misuse of the analyzer. Dosimeter badges are available for the torso
(generally worn on the belt loop or shirt pocket) and are available as ring badges. The best
single badge to obtain is a ring badge that is worn on a finger, on the opposite hand used to hold
the analyzer. This will record accidental exposure for the most likely case an operator grabbing
a small sample and holding it in one hand while analyzing it. Note: these badges generally have a
threshold of 10 mrem, and are renewed monthly. So it will take several cases of misuse even to
obtain a reading on a typical badge. When purchasing a badge, obtain the type used for x-ray and
low energy gamma ray radiation.
3.10 SAFE GUARDS AND EMERGENCY RESPONSE

The main safeguards to use as an owner of an Innov-X portable XRF are really intended to restrict access to
properly trained operators:. Note: Canadian regulations require certified personnel to use the
device, refer to section 3.0 in this chapter.

1.
2.
Keep the system in a controlled location, where only authorized users are likely to have access to
the analyzer at any given time.
Make a simple sign that is kept with the analyzer indicating that an operator must have completed
a training class provided by your company or must have attended an Innov-X training course in
order to use the analyzer. Note that when the Innov-X system is turned on, the screen displays a
message indicating that the system should only be used by authorized personnel.
Emergency Response:
Because the Innov-X system is a battery operated, x-ray tube based analyzer, the emergency response plan
is very simple. If the operator believes the analyzer is locked up in an OPEN position, they should do
two things:
1.
2.
Press the On/Off switch on the base to power the analyzer off. The green LED indicator will turn
off, indicating system power is off. At this point it is not possible for the analyzer to be producing
x-rays.
As an additional precaution, the operator may remove the battery trap door at the bottom of the
analyzer (have the nose pointing away from personnel), and pull out the battery. Even if the
operator has failed to properly power the system off in Step #1, removing the battery guarantees
that no x-rays can be produced. There is no electrical power being provided to the x-ray tube.
Note: It would be highly unusual for an operator to somehow lock up the analyzer with the x-ray tube
powered on. This would require the operator to crash the iPAQ during an analysis. If this happens the
analyzer will shut off the x-ray tube 10 seconds after the last communication with the iPAQ. However, if at
any time the operator believes the x-ray tube is on and no test is in progress, powering off the analyzer and
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restarting will automatically shut down the x-ray tube and close the shutter. It will no longer be possible to
produce x-rays at this point.
3.11 DOSIMETER BADGES

Dosimeter badges are provided as a monthly service by several companies, listed in this section (see
below). The badges are generally provided monthly, and the operator returns the previous month badges to
the company for analysis. The operator receives a monthly report showing any personnel with readings
higher than typical background radiation.
Dosimeter badges are required by some states, and optional by other states. Innov-X recommends that
operators wear badges, at least for the first year of operation, as a general precaution to flag any misuse of
the analyzer. Dosimeter badges are available for the torso (generally worn on the belt loop or shirt pocket)
and are available as ring badges. The best single badge to obtain is a ring badge that is worn on a finger,
on the opposite hand used to hold the analyzer. This will record accidental exposure for the most likely
case an operator grabbing a small sample and holding it in one hand while analyzing it. Note: these
badges generally have a threshold of 10 mrem, and are renewed monthly. So it will take several cases of
misuse even to obtain a reading on a typical badge. When purchasing a badge, obtain the type used for xray and low energy gamma ray radiation.
Dosimeter Companies:
Here are two companies that provide badges as a regular service. There are certainly many more.
Landauer Inc.
Glenwood, IL
708-755-7000
AEIL
Houston, TX
713-790-9719
3.12 TYPICAL REGISTRATION REQUIREMENTS

Innov-X maintains a database of the registration requirements for every state, including sample registration
forms. Most states require some form of registration, and generally they require the registration to be
received within 30 days of receipt of the instrument. Some states require no registration, while a few
require notification in advance. Please contact Innov-X for specific questions regarding the state where the
instrument will be used, or for copies of registration forms.
In general a company will have to provide the following information regarding the device:
1.
2.
3.
4.
5.
6.
7.
8.
Purpose of device. Generally this is Analytical or Industrial. Be sure to inform the state
registration office that the device will NOT be used for radiography or for medical uses.
Radiation Safety Officer Monitors training, safe use, and controls access to the instrument.
Authorized Users Trained by Innov-X Factory Authorized Representatives in the safe and proper
use of the XRF.
Operating parameters of the analyzer 35 kV, 5-30 micro-amps.
Type of system, either fixed, mobile or portable. Generally the correct choice is Portable.
User Training Specified Indicate that only individuals receiving manufacturer training,
documented by a manufacturers training certificate will operate the instrument.
Personal Monitoring. This may be required by radiation control authorities. Many registration
forms will ask that you indicate whether or not you intend to perform dosimeter monitoring.
Copy of Registration & Manual at the Job Site
If you have any questions regarding the type of registration form or filling out the form, please contact
Innov-X Systems. Many states may confuse a portable XRF system that uses a tube with medical or
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industrial radiography systems. This is because of the relative newness of portable tube-based systems. In
all likelihood, Innov-X personnel have experience providing the necessary documentation to the state in
question, and can readily assist the customer in this process.
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Chapter 4 Operation
4.0 OPERATION - GENERAL
Power to the instrument is controlled by the ON/OFF button located at the rear of the analyzer. The green
LED next to this button will illuminate when the analyzer power is on. The iPAQ operates on the Microsoft
Windows CE operating system and is activated separately by the power button on the right top face, just
over the display. The trigger is locked via the software.
4.1 WORKING WITH THE HP iPAQ Pocket PC

The Microsoft Windows CE operating system and Innov-X software provided on the iPAQ handheld
computer are operated by user input through the touch screen. For comprehensive details on the iPAQs
operation, please refer to the iPAQ reference materials included with your unit.
General tips
The Start Menu is found in the upper left corner of the iPAQ screen. This is used to launch all
applications, including the Innov-X Systems Analyzer software.
The instrument is designed as a point and shoot system that requires little, if any, entry of
information for most operations. In the event the user modifies the grade library, enters testing
information data, or performs other functions, it will be necessary to enter data via the virtual
keyboard, which can be accessed by tapping the keyboard icon in the lower right corner. The
iPAQ also includes character recognition software. This can be selected from the drop-down
menu to the right of the keyboard icon.
The File toolbar which will be used to Change Functions, Screens and Options is located at the
bottom of the screen.
It is possible to cut, copy, rename and delete files from within Windows File Explorer by selecting
the file to be modified and holding the stylus on the screen for 2 seconds.
Pressing buttons on the bottom of the iPAQ will perform various functions that are described in
the iPAQ documentation. The button on the right hand size of the analyzer is the iPAQ task
manager. Pressing this button will show all programs that are currently open. Open files can be
closed from this menu. Simply hold the stylus on the file for a few seconds. The option to close
the file will appear.
4.2 OPERATION - MAIN SOFTWARE SCREENS

The Innov-X Software consists of three main screens:
Main Menu screen: Used to select the analysis mode, open the results screen, and change the
administrator password.
Analysis Screen: Used to change settings, edit libraries, and perform tests.
Results Screen: Displays results from current reading, allows scrolling back to previous test
results. Allows recorded data to be exported to a comma delimited file which is directly
compatible with Microsoft Excel.
4.2.1 Innov-X Main Menu

The main menu below appears upon startup. The Main Menu allows you to choose an analysis mode, as
well as perform certain administrative functions such as changing your login password. The modes which
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are available on the analyzer are shown in blue. For information on adding additional analysis modes to an
analyzer, please contact the Innov-X Sales Department at 781-938-5005.
Use the Main Menu to select the desired analysis mode.
The analysis mode can be selected by either tapping on the
name of the method (shown in blue) or by selecting the
appropriate mode from the Modes menu.
The administrative password can be changed by selecting
Options Change Password.
It is possible to go directly to the Results Screen by selecting
ViewResults. If the results screen is opened in this
manner, it is possible to view results when the iPAQ is not
connected to the analyzer.
4.2.2 The Analysis Screen

Selecting a mode opens the analysis window for that mode. All data acquisition and analyzer control are
done from this window. This window allows the user to start or stop an analysis, change testing
parameters, and modify the fingerprint and grade libraries (Alloy Analysis only).
The analysis screen runs continually while during normal instrument operation. From the results menu, it
is always possible to go back to the Analysis screen by selecting FileExit or by tapping the X in the
upper right hand corner of the screen.
The analysis screen for Analytical mode is shown to the right.
Screens from other modes are similar and will be described in later in
this manual. The analysis screen shows the name of the mode that is
currently active, a start/stop button (which is inactive in most cases),
an info button that is used to enter descriptive information for any
given test, a trigger lock and a battery indicator. In addition, a
message appears directly below the name of the mode which will
indicate the current state of the analyzer. Typically it reads Ready to
Test, but also provides other information in certain circumstances.
Any mode specific information will be displayed at the bottom of the
screen above the menu choices.
4.2.3 The Results Screen

The Results screen displays the current reading and old data. All data handling functions such as exporting
and deleting readings are carried out from this screen. Once the Results Screen is open, the user may start
new tests without going back to the analysis screen by pulling and holding the trigger. Tapping the X in the
upper right hand corner will return the user to the analysis screen without starting a test. If no analysis
mode is running, an Exit button will appear which will close the Results screen.
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The Results screen is automatically shown at the completion of any

analysis. It can also be accessed from the analysis screen for any
mode or the Main Menu, by selecting ViewResults. Once the
Results screen has been opened, the information which is displayed
can be changed by selecting options from the View menu. The
various viewing options will be described in detail in later chapters.
4.3 PASSWORDS - ABOUT PASSWORD PROTECTION

Certain functions such as adding and deleting fingerprints from the libraries, and Pass/Fail setup have been
specified as Administrative Level Functions. These functions are described in detail in later sections of the
manual. In order to use these functions, a password must be entered. The default password is set as the
lowercase letter z. This password can be entered whenever the system prompts for a password.
Changing the Administrator Password.
The Administrator password may be changed at any time from the
Innov-X Main Menu by choosing OptionsChange Password.
When the change password option is selected, this screen will appear.
If you are changing the password for the first time, enter the letter z;
otherwise enter the current system password. Then, choose a
password and enter it twice, once in the New Password box and
again in the Confirm Password box. Passwords may be any
combination of letters or numbers.
4.4 STANDARDIZATION
4.4.1 Standardization Procedure
Before performing tests, it is necessary to standardize the instrument. This automated procedure involves
collecting a spectrum on a known standard (Alloy 316) and comparing a variety of parameters to values
stored when the instrument was calibrated at the factory. If there are any problems with the instrument,
they will be indicated by an error message.
The standardization procedure takes about 1 minute. Standardization must be done any time the analyzer
hardware is initiated or restarted and must be repeated if the instrument is operating for more than 4 hours.
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It is possible to re-standardize the instrument at any point while the software is running. Standardization is
always initiated from the Analysis Screen of any Mode.
If the analyzer is restarted, you will be required to standardize the
instrument before performing any measurements. This is indicated by
the message Standardization Required. Please place a
standardization clip over the analyzer window. Then tap here to
standardize. on the analysis screen
It is not possible to start a test before standardization. If the trigger is

pulled before the standardization procedure is completed, a message
box will appear. Press ok to acknowledge and clear the message.
To initiate the standardization procedure, snap the standardization

piece on the front of the instrument. Verify that it completely covers
the analyzer window. When using a standardization mask with a weld
collimator, be sure that the solid portion of the mask covers the
analyzer window. Tap the grey box in the center of the screen or
select FileStandardize to begin.
4-4
When standardization is in progress, the red light on the top of the

instrument will blink, indicating that the X-ray tube is energized and
the shutter is open. In addition, a status bar will appear, tracking the
progress of the measurement.
When standardization is complete, the message Successful

Standardization will appear, along with the resolution of the
instrument. Tap ok to acknowledge and clear the message. The
instrument is ready for testing.
4.4.2 Standardization Errors

The analyzer performs several diagnostic checks during the standardization process. If the standardization
fails, the instrument will prompt the user regarding the next step. Several errors could occur while
standardizing: Wrong Standardization Material, Error in Resolution or Error in Count Rate
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After closing the Standardization Failed message, two additional screens will appear. The first is a picture
of the spectrum generated during the standardization. The second is a summary comparing factory set
values for resolution, count rate, and peak positions to values calculated during the standardization.
When standardization fails, verify that the standardization mask is in place, and attempt standardization
again. To restandardize after a failure, tap the grey box in the center of the display, or choose
FileStandardize. If you are using a weld collimator, make sure that the solid part of the mask is
covering the window.
If standardization fails again, exit the analysis screen and power off the instrument. Restart and
restandardize. If the standardization fails a 3rd time, you will be prompted to perform a soft reset of the
iPAQ. Selecting Yes on this screen will automatically soft reset the IPAQ. You should also power cycle the
instrument. Restart and restandardize. If the standardization fails again, replace the battery in the instrument
and attempt another standardization. If this fails, please contact the Innov-X Systems service center at 781-
938-5005.
4-6
4.4.3 Battery Replacement and Initialization/Standardization

When the battery is too low to take a measurement, an error message will
appear:
In order to continue testing, replace the battery immediately, and then tap
OK. The analysis screen will remain open, and the instrument will
reinitialize. This process will take 1 minute. It is not necessary to restandardize, provided that less than 4 hours has elapsed since the last
standardization and the battery swap is completed within 10 minutes.
After re-initialization is completed, testing can continue.
If the battery is not replaced, and cancel is selected, the Analysis screen
will close. When the software is restarted, the instrument will go through
a complete 1 minute initialization and will require standardization.
4.5 THE SOFTWARE TRIGGER LOCK

Innov-X analyzers are equipped with a software trigger lock which prevents the trigger from being actuated
unintentionally. The lock is released by tapping an icon on the iPAQ screen. Once the lock is released, it
will remain unlocked for subsequent tests, until more than five minutes has elapsed between tests. At that
point, the trigger lock will be activated and will need to be disabled before additional testing can
commence.
Tap the lock icon located directly

above the battery indicator.
Select yes to disable the trigger

lock
4-7
The open lock icon indicates

when the trigger is disabled.
4.6 TEST INFORMATION - LABEL INPUT

Information such as sample name, and identifying characteristics can be stored with each measurement.
This is done from the test information (Test Info) screen which can be accessed from the Analysis Screen
of any mode by tapping the Info button, or selecting EditEdit Test Information.
The Test Info screen consists of eight fields. The name and format of each field can be changed by using
the Modify Test Info Template feature described in section 4.6.1 Modifying the Test Info Template.
The process of entering test information prior to each analysis is described in section 4.6.2 Entering Test
Information. Finally, the process of entering or changing test information after the analysis has been
completed is described in section 4.6.3 Editing Test Info from the Results Screen.
4.6.1 Modifying the Test Info Template

Test Info fields are modified via the Modify Test Info Template option found in the edit menu on the
analysis screen in every software mode. Each field can be designated to be Direct Entry, Drop-down, or
Tree. Direct entry fields allow users to enter characters directly from the virtual keyboard, or a bar code
reader. Drop down menus provide a list of options to choose from. Trees are more complicated dropdowns; which allow users to subdivide large numbers of choices for ease in quickly locating the correct
label. For example, a user may set up a tree with several parts for a main assembly. Subassemblies for the
parts can be linked to their parent parts.
To make any changes to the Test Info format, select Edit Modify
Test Info Template from the analysis screen of any Mode.
Modifications of Test Info screens are specific to each mode, and will
need to be made to each mode if more than one is used.
4.6.1a Changing Field Names

Field names can be edited by tapping on the current name. This will
open an editable text box. A new name can be entered with the virtual
keyboard. Selecting another cell or tapping ok will save this info.
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4.6.1b Selecting Field Type

From the Modify Test Info screen, the type of field can be selected
from a drop-down menu. Simply tap the arrow in the Field Type box
for the field being modified.
Select Direct Edit for a text field which will accept data
from the virtual keyboard, or a bar code scanner.
Select Drop-down for a drop-down list
Select Tree for a Drop-down menu with many choices, some

of which may be grouped into categories and subcategories.
Select Unused to eliminate the field from the Test Info screen.
4.6.1c Changing Drop-down Menu Entries

Once a field has been designated a drop-down menu, entries can be
added or deleted by clicking the +/- symbol to the right of the field.
Two choices will appear; Remove Entry and Add.
To delete a drop-down entry, first select the label to be deleted, then
press +/- and tap Remove Entry.
To add an entry from a drop-down list, tap the +/- symbol next to
appropriate field, and select Add. Type the new info into the blank
text box that appears. Select OK and the entry will be added to the
drop-down menu.
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Repeat the process above to complete the complete drop-down list.

If it is anticipated that a drop-down field will not be used for all
samples, enter an empty field as a choice so you can choose to leave
the field blank.
4.6.1d Changing Tree lists.

Once a field has been designated a tree, modifications to the contents
of the tree can be made by tapping the +/- symbol to the right of the
tree.
All modifications to trees are made from the menu shown on the right.
It is possible to add, edit, delete or rename trees. Select the
appropriate choice from the menu to perform any of these functions.
When you have finished creating/editing your tree, highlight it and
select Done.
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The following is an example of how a user might create a tree:

A manufacturer of tubes and valves tests all parts to ensure that
theyre made of the proper material. The companys QC procedure
involves labeling each test with the part number of the item. Rather
than forcing operators to look through a long list of part numbers, a
tree is created in order to subdivide the parts number into groups
based on part type.
The procedure for creating the tree is as follows:
Select: Add New Tree:
Enter the Name of the Tree in the text box and select OK.
Tap Add to add the first item
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Enter the name of the item
Once the tree is started, continue to Tap Add Item to add a top level
menu item, or select an item and tap Add SubItem to link a
subcategory to the item. Continue until all items have been added.
In this example, the part numbers for pipes and valves are separated
into categories. The pipes are further subdivided by material type.
4.6.2 Entering Test Information
1.
To enter the Test Info screen, you must be in the Analysis

Screen. If the Results Screen is open, tap the 9 in the upper
right hand corner to return to the Analysis Screen. From the
Analysis Screen, select EditEdit Test Information, or tap
the Info icon.
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2.
To enter a unique sample name or number, select a direct

entry field by tapping anywhere within the field. Use the
virtual keyboard to enter the information.
3.
To select information from one of the drop-down menus, tap

the arrow to the right of the box. Select the desired entry.
4.
Some drop-down fields are formatted as trees. To select

information from these fields, tap the arrow to the right of the
box. A screen will appear showing options. The plus (+)
symbol will appear before some choices indicating the
presence of sub-items. Tap on the + symbol to expand the
menu. Tap on any item or sub-item to select it, then press
Select.
5.
6.
When all the necessary data have been entered. select OK

The information entered in the test info screen will be saved with each reading until the test info
screen is modified again.
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4.6.3 Editing Test Info from the results screen

Test information can be edited, or added to a test after its completion.
From the results screen, scroll to the reading to be modified.
Select View Test Info to see in the information which is
already stored.
Select Edit Edit Test Info to bring up the editing menu.
You will then be presented with the same test information screen described in Section 4.5.2: Entering Test
Information.
4.7 EXPORTING AND ERASING DATA

Because the memory of the iPAQ is limited, you should periodically backup the data on your analyzer, and
erase the memory. Depending on test volume, it is recommended that all data is erased on a weekly or
monthly basis.
4.7.1 Installing ActiveSync

In order to copy files between the iPAQ and a desktop PC, Microsoft Active Sync Software must be
installed on the desktop PC. Innov-X strongly recommends that you download the latest version of
ActiveSync from the internet. ActiveSync v3.7 may be downloaded from
http://www.microsoft.com/windowsmobile/resources/downloads/pocketpc/activesync37.mspx
If it is not possible to download the latest version, an ActiveSync CD (v3.5) was shipped with your
analyzer. Check behind the foam in the instrument case.
The iPAQ cradle should be hooked up to the USB port on the desktop computer before installing software.
The Procedure for installing and setting up ActiveSync is as follows:
1. Insert the ActiveSync CD in your CD Drive. It will start automatically. The CD contains
information about Getting Started with Your Pocket PC. This changes periodically, so its
difficult to describe exactly what the screens will look like. Step through the screens until you see
the option Install ActiveSync. Select this to start the installation process.
2. Follow the prompts on the screen. When given the choice, select Run this program from its
current location and click OK.
3. Complete the install process. You will be required to restart your computer in order to complete
the installation.
4. After restarting your computer, dock the iPAQ in the cradle. The iPAQ should automatically
communicate with your computer. If it doesnt, check the connections and try removing the iPAQ
and reseating it. If that doesnt work, try doing a soft reset on the iPAQ
5. When the computer communicates, you will be prompted to Set Up a Partnership. Select Yes,
with this computer
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6.
Enter a name for your iPAQ and click next.
7.
You will be prompted to Select Synchronization Settings. Select Files only. It is important
to make sure that Files is the only item checked. Otherwise, the files such as address books and
emails will be copied from the desktop computer to the iPAQ.
8.
Step through the rest of the process.
9.
A folder will automatically be created on the PCs desktop with the name of the device entered in
step 8 above. Results files saved on the iPAQ will automatically be synched and will be stored in
this folder. Opening this folder and clicking on the name of the file will open the file in Excel.
10. After ActiveSync is set up correctly, copying results to a desktop computer will consist of
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a.
b.
c.
Exporting results on the iPAQ. (described in section 4.6.2)

Synching the iPAQ to the computer
Opening the results in Excel for viewing, or printing.
4.7.2 Exporting Results

All data from your Innov-X Systems analyzer can be exported as a comma delimited text file (csv). This
format allows the data to be easily exported to spreadsheet programs. It is possible to export all data from
a single day, or to export all data saved in the iPAQ. Results and spectra are exported separately.
To export or erase data, you must be in the Results Screen. This is automatically opened when a reading is
taken, or can be accessed by choosing ViewResults from any analysis screen.
From the results screen, select FileExport Results
You can choose to export All Readings or just Readings on a

specific date. Choosing All Readings: will export all readings saved
in memory and is a good choice if you want to backup all data stored
on the instrument before deleting. If a large number of readings
stored, this option will take several minutes.
Choosing Export Readings on date requires that you pick a date
from the calendar below. It is strongly recommended that you use this
option and export data on a daily basis.
The customize export option allows users with administrative
password privileges to customize the format in which data is exported.
This is described in Section 4.7.3: Customizing Results Export.
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After choosing which readings to export, you may choose to export all
data, or just data from a specific mode. Selecting the arrow to the
right of the mode to export will open a drop-down menu. Select the
mode for which you want to export data.
All standardization data are stored as results files. These data are
automatically included in exported results files when the selected
Mode to export is All. Additionally, it is possible to export only the
standardization data by selecting Standardization as the Mode to
export.
When the proper selections have been made, select OK. A Save As
box will appear. Select the folder in which you want to save the data,
and name the file. The file Type will always be Comma Separated
Values. The recommended Location is Main memory and Folder is
None. This will export files into the My Documents folder in the
main Memory of the iPAQ.
If you select a File Name which already exists, you will be asked if
you want to replace the existing file. If you do, select Yes. Otherwise
select No and choose another file name.
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A status bar will indicate the progress of the export. It may take
several minutes to export many readings. Daily downloading and
weekly erasing of data simplifies and shortens this procedure.
When all readings are exported, a message will appear confirming the
export. Tap ok to acknowledge and clear the reading.
4.7.3 Customizing Results Export

All units come with a standard results export format which reports a variety of information relevant to a
test. Users can select which fields are exported as well as modify the order.
To modify exported results files, select File Export Readings
from the Results screen.
Tap the Customize Export box.
Enter the administrative level password when prompted.
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Two columns appear on the screen; the column on the left lists fields
which will NOT be exported, and the right-hand column lists fields
which will be exported.
Fields can be moved from one column to another via the >> and <<
buttons located in the center of the screen
Exported field order can be changed by using the Up/Down buttons.
Select a field and move it up or down as desired
Once all changes have been made, choose Specify Chemistry if
changes need to be made to the list of exported elements.
In chemistry is not edited, select Save Changes to keep the modified
settings, or Discard Changes to ignore any changes.
The Specify Chemistry screen resembles the previous screen. Move

elements to the appropriate column, depending on whether or not an
element should appear in exported files.
Select Include Errors to export the error associated with each

measurement.
Select Display All to include all measured elements. This setting is

recommended, as it will ensure that all data measured with the
instrument is exported.
When all changes have been made, tap Save Changes or Discard
changes, depending on whether the changes should be saved.
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4.7.4 Exporting spectra

Only one spectrum may be exported at a time. In the results screen,
scroll to the reading for which you wish to export the spectrum, and
Select FileExport Spectrum.
Choose the File name, and make sure that Comma Separated Values
and Main Memory are selected. This will save the spectrum to the
My Documents folder in the Main Memory of the iPAQ.
A message will appear indicating a successful export. Tap ok to

acknowledge and clear the window.
4.7.5 Erasing readings

It is possible to erase a single reading, a range of readings, all readings from a specific data, or all readings
before a specific date.
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In order to erase a single reading, the reading to be erased must

displayed on the screen before selecting delete. If necessary scroll to
the reading you wish to delete.
In order to select a range of readings, you must have a reading open
from the date you wish to delete the readings. If a reading from the
desired date is not open, you may select ViewGo to date, and select
the appropriate date.
The reading displayed in the results screen is not relevant if you want
to delete all readings from a specific date, or all readings before a
specific date .
From the results screen, select FileErase Readings.
A message box will appear prompting you to enter your password.
Enter your administrative level password and select OK.
A dialogue box will appear allowing a choice of which results to
delete. Select the appropriate choice:
Selecting Delete current reading will delete the reading that is
currently open.
Choosing Delete readings XX to XX will delete a range of
readings from the date of the reading that is currently open.
Delete all readings on date deletes all readings from a specific
day.
Delete readings before date deletes all readings taken prior to a
specific day.
If you select Delete all readings on date or Delete readings before
date, you must specify a date from the calendar. The default date is
the current date.
When youve selected the readings to delete, Click OK. You will be
asked if youre sure you want to proceed. If you want to proceed with
the data erase, select Yes. Otherwise, click No.
4-21
A message will indicate the readings were successfully deleted. Tap

ok to acknowledge and clear the message window.
4-22
Chapter 5
Soil Analysis
The Innov-X analyzer can be used to analyze in situ (directly on the ground), bagged or prepared soil
samples. A guide to Soil analysis using field portable X-ray fluorescence is found in the appendix. This
document summarizes EPA Method 6200 which is the standard protocol for field screening. It also
provides information on prepared sample testing.
5.0 CHECK STANDARDS

It is recommended that a check standard is measured after each standardization, and periodically
throughout the day. Innov-X provides several NIST certified standards for verification. The certified
values for these samples are provided in the appendix. At least one standard should be measured for a
minimum of 1 minute. Elemental concentrations for elements of interest plus or minus the error on the
reading should be within 20% of the standard value. The Field screening guide in the appendix describes
in more detail recommended quality assurance considerations.
The standards provided with the XRF analyzer are contained in XRF sample cups with a Mylar window
(through which the soil can be viewed) on one side, and a solid cap on the other side. Samples should be
measured in the sample cup, through the Mylar window. The best way to measure a prepared sample is
using the test stand. If this is not available, the sample may be placed on the ground, and the analyzer may
be pointed downwards in full contact with the soil cup. Do not hold the soil cup in your hand while
measuring.
5.1 SAMPLE PRESENTATION

In situ testing:
In situ testing is performed by pointing the analyzer at the ground. Any grass or large rocks should be
cleared away and the analyzer should be held such that the front of the probe head is held flush to the
ground.
Since dirt can accumulate on the analyzer window, it is recommended that the window is wiped clean after
each analysis. The window should also be checked to ensure it is not ripped or punctured. Instructions for
replacing the window are found in the appendix.
Bagged or prepared sample testing:

It is strongly recommended that all prepared samples be analyzed in the testing stand. Samples should be
placed on top of the testing stand, completely covering the window. Never hold prepared or bagged
samples while testing, as this could expose the operator to the x-ray beam.
Avoid measuring very thin samples, as this can affect results. Prepare samples cups to contain at least 0.5
inches of packed samples. When analyzing bagged samples, make sure that sufficient sample exists in the
bag to completely cover the window with a sample thickness of a minimum of 0.5 inches.
5.2 TESTING IN SOIL MODE

After the instrument has been standardized, testing can begin. Simply pull the trigger or press Start on the
iPAQ screen to begin the test. The red warning light on the top of the instrument will blink, indicating Xrays are being emitted. The screen will display the words Test in progress and the time elapsed. The
word Testing will blink on and off in the low right hand corner of the screen.
5S-1
After a minimum time has elapsed,

intermediate results will be
displayed on the screen. Until this
minimum time has elapsed, the
words WAITING FOR DATA
will appear instead. This minimum
time can be set by the user by
selecting OptionsSet Testing
Times, which is described in
Section 5.4: Soil Mode Options.
Each line of the results display
shows the name of an element, its
calculated concentration and the
error on the measurement. This
error is the 1 sigma error on the
counting statistics of the
measurement. The error will
decrease with increased testing time.
Too many elements are measured in soil mode to display them at one
time. However, is possible to use the scroll bar located to the right of
the chemistry display to view other elements. The complete display
shows detected elements first, listed in order of emission line energy,
from lowest to highest. Following the detected elements are the
elements which are below the detection limit of the instrument. These
elements are shown as less than a calculated LOD. This LOD is
defined as three times the error on the counting statistics of the
measurement.
When the measurement is complete the results screen will open,
displaying the final results of the measurement.
5.3 SOIL RESULTS SCREEN

5.3.1 Results View Menu
The standard Soil Mode results
screen displays the concentration
(in ppm) and error in
measurement for detected
elements, followed by the list of
non-detected elements with the
calculated limit of detection for
each element for that test. If the
display does not show soil
chemistry results, change the
display by selecting
ViewResults.
5S-2
The standard soil chemistry display can be modified by using the View Menu. As with all Innov-X
analytical modes, it is possible to view spectra and Test Information.
5.3.2 Spectrum Screen

This screen displays a plot of the x-ray fluorescence spectrum for an
individual test, plotting the intensity on the y-axis versus the energy of
the fluorescence x-rays on the x-axis.
Tapping on the spectra will show the energy scale and counts rate at
the selected point
It is possible to zoom in on certain

areas of the graph by selecting
one corner and drawing out the
region
Tapping the symbol in the upper
right hand corner beneath the X
will restore the graph to full scale.
5.3.3 Test Info Screen

The test information screen shows any test information that was entered prior to the start of the test.
Changes to that test information can be made by selecting EditTest Information.
5.4 SOIL MODE OPTIONS

The length of tests in Soil Mode is user settable. Users may select a minimum testing time, and as well as
choose from a variety of test end conditions.
The options related to test time are contained in two menus: OptionsSet Testing Times, and
OptionsSet Test End Condition. Set Testing Times contains minimum and maximum testing time
information, while Set Test End Condition allows the user to select test end conditions.
5S-3
5.4.1 Set Testing Times

To set the minimum and maximum test lengths, select OptionsSet
Testing Times
A screen appears prompting you to enter a Minimum and Maximum

Testing times. Instruments equipped with the optional LEAP package
will be able to set Light Element Testing times in this screen, as well.
The minimum testing time is the required time that must elapse before results can be calculated. Live
Update results will not be displayed on the screen until the minimum has elapsed, likewise a test must
complete the minimum time before any test end condition can be used. If a test is stopped before the
minimum testing time has elapsed, the test will be aborted, and no results will be calculated.
Maximum testing time is relevant only if Maximum Testing Time is selected from Set Test End
Condition. This will automatically end the test at a preset testing time. Typically, the maximum testing
time will be in excess of 30 seconds, and may be 1 or 2 minutes, depending on detection limits and desired
precision.
It should be noted, that all testing times in this section refer to Real Time, the time the measurement takes
when timed on a normal clock. The time stored with each analytical result (accessible by selecting
ViewTest Information from the Results screen), refers to the tests Live Time. This is the amount of
time that the analyzer hardware was collecting spectra. Since there is some detector dead time associated
with a measurement, the live time of a test will be slightly shorter than the preset Real time.
5.4.2 Soil Mode Test End Condition

Four options exist for the test end criteria in soil mode. Depending on your application, you may choose to
end the test manually, at a preset testing time, or when the uncertainty in the measurement is within a
5S-4
specified relative standard deviation of the reading. Additionally, you can set up an action level for a single
element. As soon as the measuring statistics are good enough to ensure that that the reading is above,
below or at the action level, the test will end automatically. This allows for very rapid tests for elements
that are well above or below an action level.
In all modes, pressing Stop, or pulling the trigger will end the test. If the minimum testing time has
elapsed, results will be calculated. Otherwise the test will be aborted without calculating results.
Changes to the test end condition are made by selecting OptionsSet
Test End Condition
The currently selected end condition will be displayed at the bottom
of the screen above the Start button on the Ready To Test screen.
Manual: This option allows you to look at the results which are
being continually updated on the screen and determine when the
results look satisfactory. The test will continue until the trigger is
pulled, or Stop is tapped on the iPAQ screen. Results will be
calculated if the testing time has exceeded the Minimum Test time
which is set up in OptionsSet Testing Times. In order to preserve
battery life, the software will stop if the testing time exceeds 300
seconds, since there is little to no advantage to continuing a test
beyond 300 seconds.
To use Manual Test End Condition, simply choose OptionsSet Test
End Condition and select Manual. Press OK to return to the analysis
screen.
Maximum Time: If Maximum Time is selected, the test will continue

until the preset time is reached. This is useful if you wish to do a set
of measurements with the same testing time.
To choose to end test based on a maximum time, select OptionsSet
Test End Condition and select Maximum Time. Enter the desired
testing time in the appropriate box. Tap OK to save your selections.
5S-5
Action Level: System ends test when result for target analyte
including chosen precision level is above or below pre-set action
level.
To choose to end a test based on an Action Level, select OptionsSet
Test End Condition and select Action Level. Select a target analyte,
specify an action level in ppm, and a confidence level. This
confidence level refers to the number of sigma required for the
precision. This should typically be set to 2. Tap OK to save your
selections.
Relative Standard Deviation (RSD): When RSD is selected as a test

end criteria, the system will end a test when the relative standard
deviation on a target analyte reaches a pre-set level. This standard
deviation is specified as a percentage of the reading. For example, if
the measured value for an analyte was 1000 ppm, and the RSD was
set to 10, the reading would stop when the error reached 100 ppm, or
10% of 1000.
To choose to end a test based on a Relative Standard Deviation, select
OptionsSet Test End Condition and select Rel. Std. Dev (%).
Select a target analyte and the desired Relative Standard Deviation.
Tap OK to save your selections.
5.5 LEAP Mode (Light Element Analysis Program):

This is a factory installed optional module. Instruments can be upgraded to LEAP capabilities. Please
contact the Innov-X Systems Sales department for information and pricing.
The LEAP module provides the lowest possible detection limits for elements lighter than iron. The
standard LEAP package includes the elements Ti, Ba and Cr. Elements as low as Phosphorus can be
detected with the Advanced LEAP package which includes a thin window detector.
The standard x-ray beam conditions used by Innov-X environmental analyzers are designed to provide
good excitation for a wide range of detected elements. However it is not possible to select one beam
condition which provides the absolute best excitation conditions for all elements of interest. Elements such
as Chromium produce lower energy x-rays then other elements analyzed. These lower energy x-rays are
not as effectively excited by the standard conditions. LEAP works by changing the X-ray tube beam
conditions to settings which are optimized for the detection of elements lighter than iron. Instruments are
factory calibrated with the LEAP beam conditions for all applicable elements.
5S-6
5.5.1 LEAP Settings

To activate LEAP, select
OptionsLEAP Settings from
the Soil analysis screen. This
brings up the menu shown below
on the right.
Standard Test Only: The analyzer will provide analysis for the standard suite of elements.
Light Element Analysis Only: The analyzer will provide analysis for elements in the LEAP suite
(Typically Ti, Ba and Cr)
Sequential Testing: When sequential testing is selected, all tests will start with an analysis of elements in
the standard suite. If that test ends due to reaching the selected end condition of Maximum Test Time,
Action Level, or RSD, then the analyzer will immediately begin a second test analyzing the LEAP suite of
elements. At the conclusion of this test, the Results screen will open with two new entries. The first
summarizes the standard test results, while the second summarizes the LEAP results. For safety reasons,
the second test will not begin if the test ends due to user intervention (pulling the trigger or hitting Stop). In
this case, the Results screen will open with only one reading.
If Light Element Analysis Only is
activated, the words Light
Element Analysis Mode will
appear above the currently
selected End Condition.
Instrument operation in this mode
is identical to Standard (NonLEAP) analysis. Tests can be
started or stopped either by
pulling the trigger, or by tapping
the Start/Stop button on the iPAQ
screen. The results screen for a
test will show results for all
elements analyzed with the LEAP
mode.
Test in progress screen, LEAP
Only, Live Updates on
Results Screen Showing LEAP

results
5S-7
If Sequential testing is selected,

the words Sequential Current
Test: Standard will appear above
the currently selected End
Condition. When a test is started,
the instrument will appear to
operate in the same manner as a
Standard test. However, if the test
ends according to the specified
end condition (excluding
Manual), the results screen will
not open. Instead, the timer will
reset to 0, and the description of
the current test will change from
Standard to LEAP. The live
update screen will begin to show
analysis for all LEAP elements.
Test in progress screen,

Sequential.
First Test Standard Analysis.
Test in progress screen,

Sequential.
Second Test LEAP Analysis
5.5.2 Testing Times

To set the minimum and maximum test lengths for LEAP analysis,
select OptionsSet Testing Times.
The testing time screen includes an extra section labeled Light
Element Test that is not found on non-LEAP systems. These are the
minimum and maximum test lengths for any LEAP tests.
As with standard tests, the minimum testing time is the required time that must elapse before results can be
calculated. Live Update results will not be displayed on the screen until the minimum has elapsed, likewise
a test must complete the minimum time before any test end condition can be used. If a test is stopped
before the minimum testing time has elapsed, the test will be aborted, and no results will be calculated.
5S-8
Appendix 1: Troubleshooting GuideSoil Analysis

Problem
Possible Solutions
Software wont start:
The flash card or the iPAQ may not be correctly seated

in the black external sleeve. Remove the flash card and
press it firmly into its holder. Press the iPAQ down into
the black sleeve.
Software will not start when the Innov-X Systems Icon

is tapped.
Software wont start:

Software doesnt start when the Innov-X System icon is
tapped; instead, the following error message occurs:
Cannot find startup (or one of its components). Make
sure the path and filename are correct and all the
required libraries are available
IPAQ locks up:
iPAQ screen locks up and doesnt respond when
screen is tapped or buttons are pressed
The flash card or the iPAQ may not be correctly seated

in the black external sleeve. Remove the flash card and
press it firmly into its holder. Press the iPAQ down into
the black sleeve.
Remove the iPAQ from the analyzer and perform a soft

reset by pressing the tip of the stylus into the small
indentation found on the bottom of the iPAQ. If the
iPAQ is lying flat on a table with the screen facing
upwards, the reset button is found to the extreme right of
the side containing the power plug and connector.
See Page 4 of the Compaq Getting Started manual for
an illustration showing the location of the reset button.
Soil Appendix 1
Try again. Choose File -> Standardize to attempt a new

standardization. Also be sure the standardization cap is
on correctly, and that the solid half is in front of the
window. It is OK to try this 2-3 times in the event of a
failure.
Analyzer will not standardize
If a repeat attempt fails: Change the battery. In some

cases the battery may be too low to provide enough
power for tube startup. Follow this procedure:
Reset the iPAQ;
Turn off the analyzer and remove the battery.
Verify that the battery is completely charged. If it is
not, replace it with a fresh battery. Even if the battery
has been recently recharged, remove it, and replace it in
the analyzer.
Restart the analyzer and software. Wait several minutes
after the software has initialized before attempting
standardization.
Results screen doesnt show new readings after a test
is completed
Check the date on the iPAQ. The Innov-X Systems

software indexes stored results by date. If the date is
incorrect, results may not be displayed in the correct
order.
Serial Communication Error Message:
This error reflects the temporary loss in communications

when the iPAQ was removed. To avoid this problem,
always use the File / Exit command to exit the software
properly. Try simply removing and reseating the iPAQ
to solve this problem. If that fails, see steps 1 4
below.
Serial Communication error occurs because iPAQ has

been removed from instrument or cradle, with the
software open and the instrument standardized.
Serial communication error on startup, or while

testing.
Soil Appendix 2
1. If the analysis screen is still open, attempt

another test.
2. Verify that the iPAQ is correctly seated in the
analyzer by removing and replacing it.
3. Remove the iPAQ and perform a soft reset.
Replace iPAQ and restart software.
4. Turn the analyzer off and restart it.
Results take a very long time to display on the first

test of the day.
There may be too many readings stored in memory.

Erase readings from the results screen by selecting File
Delete Readings.
Trigger will not start test.
Verify that the trigger lock is off.

Reset the instrument. If this fails, call Innov-X Systems
Technical Support at 781-938-5005.
The window is designed as a barrier to dust and dirt. If it
is damaged, it should be replaced.
Broken Kapton Window
To change the window:

Turn off the analyzer
Remove the screws holding the front plate in place.
Remove the old kapton and adhesive, replace with new
kapton and replace front plate.
Important Note: It is very important to avoid getting
dirt and sharp objects within the probe, due to the close
proximity of the detector. Do not use the analyzer
without a kapton window for any length of time. Also,
be very careful when removing/replacing screws in face
plate so as to not accidentally damage the detector. If the
detector is damaged, the instrument will require factory
service.
Results screen shows message Error in calculation:
No Results
The soil mode calculation is only valid for soil-like

samples which contain primarily light elements such as
carbon, oxygen and silicon. If a dense, highly metallic
sample is analyzed, the calculation fails.
Make sure the sample being analyzed is a soil sample, if
it is and this message occurs repeatedly; call Innov-X
technical support.
Soil Appendix 3
Appendix 2:
Metals in Soil Analysis Using Field Portable X-ray

Fluorescence
A guideline to using portable XRF according to EPA Method 6200, basic overview
of the technique of x-ray fluorescence (XRF), appropriate data quality assurance
protocols and sample preparation steps for operators analyzing prepared soil
samples.
Prepared by:
January, 2003
Innov-X Systems
300 Wildwood Ave, Suite 210
Woburn, MA 01801
781-938-5005
781-938-0128 (fax)
info@innov-xsys.com
www.innov-xsys.com
Soil Appendix 4
Section 1: Regulatory Status for Field Portable XRF

EPA Reference Method 6200 has been incorporated into SW486 under RCRA, and is now
available for field portable XRF analysis of soils and sediments. Please call or email Innov-X
Systems for a copy of Method 6200.
Method 6200: Field Portable XRF Spectrometry for the Determination of Elemental
Concentrations in Soil and Sediment.
Features of this method:
1. It is a field screening method, for analysis of in-situ or bagged samples.
2. The method provides basic quality assurance methods, including calibration verification,
determination of instrument precision, accuracy and limit of detection.
3. The method recognizes the some XRF instruments do not require site-specific calibrations by
the operator, that is, the factory calibration provides appropriate data quality.
4. The method recommends that a minimum of 5-10% of samples tested by XRF be confirmed
by an outside laboratory using a total-digestion EPA analytical reference method.
The purpose of EPA Method 6200 is NOT to replace laboratory analysis. There are two primary
sources of error in assessing a site for metal concentration: Analytical error and Sampling
error. Analytical error is the error in the analysis of any one sample by whatever technique is
used, for example XRF, ICP, or AA. Sampling error arises when too few samples are collected
and tested. In this case an incomplete picture of the extent of metals contamination may be
obtained. Although any one sample may be analyzed with very high analytical accuracy,
measuring too few samples may result in contamination plumes being mis-judged in size, or
depth into the soil. In extreme cases contamination may missed entirely.
EPA Method 6200 was developed to reduce Sampling Errors by increasing the number of
samples measured. In general, a large number of screening-level measurements provide a better
characterization of contamination than a small number of measurements produced by sample
removal and analytical analysis. Portable XRF is an ideal tool to make a large quantity of
measurements in a short period of time. A large number of in-situ samples provides detailed data
on contamination profiles, depth (provided surface soil is moved aside), and approximate
contamination levels. Portable XRF also can provide results with a high degree of analytical
accuracy on any given sample. Please see Section 2 Overview of Field Usage for this
discussion.
Soil Appendix 5
Section 2: Overview of Field Usage:

Field portable XRF is generally used in three ways to test for metals in soil:
In-situ soil testing: The XRF is placed directly onto the ground for soil testing.
Operators remove any plant growth and foreign objects so that the analyzer probe is
flush to the soil.
Bagged soil sample testing. A soil sample is collected in a thin plastic bag (i.e. a
Baggie) and testing directly through the Baggie. Except for a few elements
namely Cr, V and Ba testing through the thin plastic used for a plastic bag has little
effect on the test result. Results for Cr, V and Ba will be lower by 20-30%.
Prepared soil sample testing. Prepared sample testing assures the operator of the
maximum possible accuracy. Prepared sample tests require a sample to be collected,
dried if necessary, sieved and ground into a powder. The prepared sample is then
placed into a baggie or XRF cup for analysis. A complete Soil Preparation Guide
is provided in Appendix 1.
All analytical methods require a uniform, homogenous sample for the best results. XRF is no
different! The methods described in EPA Method 6200, namely In-situ and bagged sample
testing, are considered field-screening methods. Although a field-screening method, in-situ
testing is a valuable technique because it generates a great deal of data very quickly. Prepared
soil samples generally offer the best accuracy, albeit with several minutes of sample preparation
required per sample.
Figure 1. Use of a field portable XRF for in-situ soil testing.
Subsection 2-A: Data Quality Objectives.

The objectives of the testing generally determine the mixture of in-situ versus prepared sample
testing. It is important to understand your data quality objectives (DQO) in order to determine the
appropriate mix of field screening and prepared sample testing.
Soil Appendix 6
In-situ testing usually provides only screening-level data quality. This is because analytical
testing always requires a uniform, homogeneous sample matrix. A laboratory achieves this by
digesting the sample into a hot acid before analysis. Testing directly on the ground does not
ensure uniformity is met. Preparing a sample provides a uniform sample and likely better
analytical data quality, although several minutes of testing time is required.
Most portable XRF operators use a mixture of in-situ and prepared sample testing. Several
examples are described below. The exact mixture of in-situ and prepared sample testing depends
upon the goals of the soil testing. The examples below serve as guidelines. Please contact InnovX (1-866-4 Innov-X or 866-446-6689) to discuss your specific testing requirements.
Example 1: Initial site investigation to provide detailed contamination data with efficient
use of laboratory analysis costs.
Problem: Site needs to be assessed for metals contamination. Little information is available about
what metals are present, likely contamination levels or geographic profile of contamination.
The goal of testing is to determine what metals are present at what levels, both in area and in
depth into soil. Additionally, testing will locate possible contamination plumes and/or possible
sources of contamination.
Recommended Testing Plan: This example uses predominately in-situ testing. The analyst will
perform in-situ testing, and gather samples into plastic bags for XRF analysis. A testing grid
should be established in two or three dimensions, every several feet. XRF tests can be taken at
each location or bagged samples can be collected from each location for later analysis. The insitu data for each element analyzed may be plotted in a 2-dimensional grid (X, Y coordinates
versus elemental concentration) to profile a site. These concentration profiles are ideal for
showing contamination patterns, boundaries and plumes. Combining this data with historical use
data from the site often allows the operator to deduce sources of contamination. Obtaining this
level of geographic data with purely laboratory analysis would produce excessive analytical costs.
Prepared sample analysis should also be done to confirm the regions where in-situ data indicates
low or non-detected levels of metal contaminant. There is little need to prepare areas where insitu testing indicates high concentration levels. Innov-X recommends the same procedure as EPA
Method 6200. For locations where in-situ tested indicate low or non-detected concentrations,
calculate the total number of in-situ tests, collect 5% of this number of tests from the various
locations, and prepare these samples according to Appendix 1. Use these prepared samples to
confirm the findings of the in-situ testing. Send a subset of these prepared samples to a
laboratory for confirmatory results.
Cost Justification. To adequately characterize a site may require 100-200 samples/acre to be sure
the contaminated areas are firmly established. This work may be done with in-situ testing to
generate laboratory savings of $5,000 - $10,000/acre depending upon the number of elements
being analyzed. The cost reduction in off-site analysis often justifies the price of the XRF.
Example 2: Monitor remediation efforts and assure site meets clearance levels before
contractors leave the site.
Goal: Minimize remediation costs by only treating contaminated soil, and obtain immediate
verification that various site locations meet clearance objectives.
Soil Appendix 7
Recommended Testing Plan: This type of project uses a lot of both in-situ and prepared sample
testing. Use in-situ testing to thoroughly delineate contamination regions in both area and depth.
To determine depth profiles, test surface soil, remove at least 1-2 inches, and retest. Repeat this
step as necessary to profile contamination depth to guide remediation activities. (XRF is a
surface technique and only analysis the first few mm of soil sample). As part of clearance, collect
several samples from cleared area. Prepare samples according to Appendix 1 and test with
portable XRF.
If XRF indicates that concentration levels are in excess of clearance requirements, then continue
remediation efforts.
If XRF indicates that concentration levels are below clearance requirements, then discontinue
remediation efforts, and send a subset of the samples to an analytical laboratory to confirm
results. Most operators safely assume that the cleanup requirements have been met for the
elements in question, but await final analysis from the laboratory.
If XRF lists concentration levels as non-detected, but the detection level reported exceeds
clearance requirements, send samples to a laboratory for final results.
Cost Justification: In-situ results are used to guide remediation efforts, in order to obtain
maximum efficiency. Efficiency is produced because contamination boundaries are firmly
established, thus avoiding remediation efforts with clean soil. Prepared sample testing is used
to assure that clearance requirements are met on-site in near real-time (pending laboratory
confirmation). Costs savings are generated by avoiding clearance failures. The contractors can
leave the site earlier and will not be called back to the site for additional cleanup.
Important Note: Never clear a site based solely on in-situ testing. Always use well-prepared
samples to make a clearance decision.
Example 3: Minimize volume of hazardous waste for treatment or disposal.

Goal: For some cleanup projects, the cost of soil disposal in a hazardous waste landfill is much
greater than disposal in a standard landfill. Testing soil samples with XRF may minimize the
amount of clean soil that is inadvertently shipped to a hazardous-waste landfill.
Recommended Testing Plan: This example is almost entirely prepared sample testing.
Representative samples are removed from the soil being hauled to landfill. Obtaining an accurate
analysis of the samples is crucial for making a hazardous versus non-hazardous determination.
For this reason, prepared sample testing is strongly recommended.
Important Note: These types of samples are subject to TCLP procedures for the landfill
determination. In general, 20 times the XRF result should be less than the allowable limit for the
metal in question. Please contact Innov-X Systems for more details on testing samples versus
TCLP regulatory requirements.
Soil Appendix 8
Section 3: Quality Assurance.

Quality assurance is detailed for both the proper use of the analyzer (which is also provided in
Method 6200) and for verifying the data quality of in-situ testing. All operators should perform
the QC procedure, regardless of their data quality objectives. Method 6200 has strict
requirements about quality assurance. Additionally, Innov-X recommends that operators verify
the data quality of in-situ test results, if they are using in-situ data to guide their reporting or
remediation decisions. Procedures are listed below:
3.1: Proper verification of instrument operation
These procedures are taken from EPA Method 6200 and updated to be specific to the Innov-X
analyzer. Quality assurance here consists of testing known standards to verify calibration, as well
as testing blank standards to determine limits of detection and to check for sample crosscontamination or instrument contamination. EPA Method 6200 provides a detailed procedure,
which is provided here in abbreviated form.
Components of instrument QC:
1.
2.
3.
4.
5.
6.
An energy calibration check sample at least twice daily

An instrument blank for every 20 environmental samples
A method blank for every 20 prepared samples
A calibration verification check sample for every 20 samples
A precision sample at least one per day.
A confirmatory sample for every 10 environmental samples
Energy Calibration Check: The Innov-X analyzer performs this automatically; this is the
purpose of the standardization check when the analyzer is started. The software does not allow
the analyzer to be used if the standardization is not completed.
Instrument Blank: The operator should use the SiO2 (silicon dioxide) blank provided with the
analyzer. The purpose of this test is to verify there is no contamination on the analyzer window or
other component that is seen by the x-rays. Method 6200 recommends an instrument blank at
least once per day, preferably every 20 samples. For either in-situ or prepared-sample testing, the
operator should just test the SiO2 blank to be sure there are no reported contaminant metals.
Method Blank: The purpose of the method blank is to verify that cross-contamination is not
introduced into samples during the sample preparation process. Method 6200 recommends
following the sample preparation procedures with clean SiO2 once very 20 prepared samples.
This QC step is not required if the operator is not preparing samples.
Calibration Verification: Innov-X provides NIST standard reference samples for calibration
check by operator. The operator should perform a 2-minute test on a NIST standard. The
difference between the XRF result for an element and the value of the standard should be 20% or
less. Calibration Verification should be performed upon instrument startup and periodically
during testing. Note: Innov-X recommends a calibration check every 4 hours. EPA Method 6200
recommends a calibration check every 20 samples NIST reference standards are generally
applicable for Pb, As, Cr, Cu, Zn. Innov-X provides additional reference standards for other
RCRA or Priority Pollutant metals including Cd, Se, Ag, Hg, Ag, Ba, Sn, Sb, and Ni.
Soil Appendix 9
Precision Verification: Quoting from EPA A minimum of one precision sample should be run
per day by conducting from 7 to 10 replicate measurements of the sample. The precision is
assessed by calculating a relative standard deviation (RSD) of the replicate measurements for the
analyte. The RSD values should be less than 20 percent for most analytes, except chromium, for
which the value should be less than 30 percent.
Confirmatory Sample: It is recommended that one confirmatory sample is run for every 10
samples collected. According to EPA Method 6200: Confirmatory samples are collected from
the same sample material that is analyzed on site, but are sent to an off-site laboratory for formal
analysis. The purpose of a confirmatory sample is to judge the accuracy of the data obtained by
analysis on site and to allow corrections, if necessary.
Important Notes about confirmatory samples:
Innov-X always recommends that customers compare prepared-sample results to laboratory
results. To do this, collect and prepare a sample following the protocols of Appendix 1. Take a
subsample and submit to the laboratory for analysis. The single largest error in XRF analysis is
lack of sample preparation. For the best comparison, always use prepared samples.
3.2: Determining data quality of in-situ testing:

For operators relying extensively on in-situ testing, it is important to determine the data quality of
this testing at a given site. This protocol is not intended for every sample, but rather for a small
percentage of samples considered representative of the site. If the operator can demonstrate that
quantitative data is achieved with little or no sample preparation, then the site characterization
will be completed much more quickly but correctly.
For example, an operator may be able to demonstrate that the XRF result changes considerably
when samples are passed through a 2 mm sieve, but that XRF results do NOT change appreciably
upon finer sieving. In this case the operator can conclude that good XRF data is achievable with
only 2 mm sieving. Sieving only to this level requires far less time than a more robust sample
preparation. A protocol to determine the appropriate level of sample preparation is the following:
1. Delineate a region of soil approximately 4" x 4".
2. Perform several in-situ tests in this area, or collect the top (approximately) quarter inch of
soil from this region, bag the soil, test through the bag. In either case, average the results.
3. If you did not bag the in-situ test sample, collect the top (approximately) quarter inch of
soil from this region and sieve through the 2 mm sieve provided. Otherwise sieve the
bagged sample used for the in-situ test. Thoroughly mix the sieved sample, and place
some of the sieved material into an XRF cup, and perform a test of this sample.
4. If the results of this prepared sample differ less than 20% with the average in-situ result,
this indicates the soil in this region is reasonably homogeneous. The data quality in this
case is probably at the semi-quantitative level, rather than just screening data.
5. If the results differ by more than 20%, this indicates the soil is not very homogeneous,
and there are serious particle size effects affecting your in-situ measurements.
6. In this case, sieve the sample through the 250 ~m sieve. Mix this sample and place a subsample into an XRF cup for testing. If this result differs from the previous by less than
20% then this indicates that at a minimum the 2mm sieving is necessary to achieve higher
data quality.
Soil Appendix 10
7. If this result differs by more than 20% from the sample sieved through 2 mm, then
particle size effects are still affecting the XRF result. In this case samples should be
sieved through 125 m to assure data quality at the quantitative level.
Section 4: Calibration for Innov-X Portable XRF

The Innov-X analyzer may run three different calibration methods, described below. In nearly all
cases, customers use the Compton Normalization method. This method (recognized in EPA
6200) offers speed, ease of use, and generally good accuracy for concentration ranges from the
ppm level up to 2-3% concentrations. As most field-testing is seeking to remediate or locate
environmental contaminants, the upper limit of the calibration (2-3%) is generally not a
limitation. If customers do require a calibration up to 100% concentration (i.e. a pure element)
then Innov-X recommends they also include the Fundamental Parameters (FP) software module
with the analyzer. The FP module may be added at time of purchase or as an upgrade at any later
date.
Note: In general customers do not need to calibrate the Innov-X analyzer for soil testing. The
analyzer is delivered with a factory calibration, generally based upon the Compton Normalization
(CN) method. The CN method has been proven over the past several years to provide a robust
calibration generally independent of site-specific soil matrix chemistry. The operator may
calibrate the Innov-X system if desired, but calibration is not required to use the analyzer
effectively. All customers should follow the QC procedure described in Section 3, which
includes a check of the calibration.
The final model is the empirical calibration. In this case, customers run standards to generate
calibration curves for various elements in specific soil matrices. Provided the sample is wellprepared, the empirical method generally yields the most accurate result. In our experience, the
accuracy gains going from Compton Normalization to Empirical Mode are small and not worth
the extra effort in setting up calibration curves. (The greatest source of error for in-field XRF
analysis of soil is lack of adequate sample preparation, thus there is little gained in developing a
sophisticated empirical calibration if the operator does to grind and homogenize the all measured
samples). The empirical calibration module is an optional software package, available for an
upgrade fee at the time of purchase, or as an upgrade at any later date.
Calibration Requirements:
The concentration of an element in a soil sample is well-described by the formula:
wi =
ki
Ii
M (Z , i)
ki = calibration constant for element i

i = concentration of element i the quantity being measured.
Ii = measured x-ray intensity from element i
M(Z,I) = Soil matrix value
Soil Appendix 11
The factory calibration determines the value of the calibration constants ki for each element, and a
typical value M(Z,I). The calibration method either CN, fundamental parameters, or empirical
performs the necessary corrections to the value M(Z,I) that are important for the site-specific soil
chemistry. The XRF analyzer uses the measured intensity of each elements fluorescence from
the sample, and the calibration data, to produce elemental concentrations.
Compton Normalization:
The Compton Normalization method calibration consists of the analysis of a single, wellcharacterized standard, such as an SRM or SSCS. The standard data are normalized to the
Compton peak. The Compton peak is produced from incoherent backscattering of X-ray radiation
from the excitation source and is present in the spectrum of every sample. The matrix affects the
way in which source radiation is scattered off the samples. This scatter is directly related to the
intensity of the Compton peak. For that reason, normalizing to the Compton peak can reduce
problems with matrix effects that vary among samples. Compton normalization is similar to the
use of internal standards in analysis for organic analytes.
Fundamental Parameters Calibration:
The fundamental parameters (FP) calibration is a "standardless" calibration. Rather than
establishing a unit's calibration curve by measuring its response to standards that contain analytes
of known concentrations, FP calibration relies on the known physics of the spectrometer's
response to pure elements to set the calibration. Built-in mathematical algorithms are used to
adjust the calibration for analysis of soil samples and to compensate for the effects of the soil
matrix. The FP calibration is performed by the manufacturer, but the analyst can adjust the
calibration curves (slope and y-intercept) on the bases of results of analyses of check samples,
such as SRMs which are analyzed in the field.
Empirical Calibration:
The empirical calibration method requires that a number of site-specific calibration standards
(SSCS) are used to establish calibration parameters. The instrument response to known analytes
is measured and used to create calibration curves. Empirical calibration is effective because the
samples used closely match the sample matrix. SSCSs are well-prepared samples collected from
the site of interest in which the concentrations of analytes have been determined by inductively
coupled plasma (ICP), atomic absorption (AA), or other methods approved by the US
Environmental Protection Agency (EPA). The standards should contain all the analytes of interest
and interfering analytes. Manufacturers recommend that 10 to 20 calibration samples be used to
generate a calibration curve. The empirical method is the least desirable calibration method as it
requires that new standards and curves are generated for each site that is analyzed.
Section 5: Effects of Moisture on XRF Results:

Sample moisture has two effects on XRF results:
It alters the soil chemistry, since water is another chemical compound that comprises the
soil matrix.
Moisture impedes the ability to properly prepare samples.
Soil Appendix 12
Laboratory results are provided on a dry weight basis.
Effect on Soil Chemistry:

While the presence of significant moisture does impact the soil chemistry, modern XRF analyzers
all perform automatic corrections for variations in soil chemistry from site to site. Indeed, such
variations are expected, and that is the reason analyzers use Compton Normalization or
fundamental parameters, in order to correct for moisture content changes as well as other
differences in soil geochemistry.
EPA Method 6200 states Moisture content above 20 percent may cause problems, since moisture
alters the soil matrix for which the FPXRF has been calibrated. However, the Compton
Normalization or fundamental parameters methods are implemented in order to automatically
correct results for changes to the soil matrix. Thus, we believe that soil moisture is not a
significant effect on accuracy due to effects of soil matrix, except for the dilution effect that can
cause discrepancies with laboratory results which is described below.
Sample preparation issues:

The inability to adequately prepare a wet sample is, we believe, the single biggest contributor to
errors when testing wet samples. It is very difficult to grind or sieve a wet sample. The highest
quality XRF results are generally obtained from prepared samples. If the operator is unwilling to
dry the sample to prepare it, comparisons to the laboratory may yield poorer correlation since the
samples are not homogeneous.
Laboratory Tests on Dry-Weigh Basis:
Laboratories always dry samples prior to analysis. They report percent weight content based
upon a dry sample basis. Portable XRF may often be used to analyze wet samples in the field,
and results are thus reported that include the moisture content. Thus, with all other factors the
same, the laboratory will report results higher than portable XRF. The results will be higher by
the amount of moisture content in the sample. For example laboratory results will be 10% higher
compared to XRF results, if the sample contained 10% by weight water when it was tested with
XRF. Recall, this applies to samples where other possible sources of error are the same or
negligible.
Section 6: Comparing XRF Results to Laboratory Results:

Innov-X strongly recommends that operators compare prepared sample results to laboratory
results. This is because prepared-sample results yield the best possible accuracy with portable
XRF. Moreover, the most common source of error is due to non-uniform samples. The XRF
technique, nor can any analytical technique, properly account for non-uniform sample types.
To perform a comparison between XRF results and laboratory:
1. Collect a sample and prepare it according to the sample preparation guide in Appendix 1.
Soil Appendix 13
2. Take a sub-sample (5-10 grams) of the fully-prepared sample, place it into an XRF cup
and perform at least a one-minute test on that sample.
3. Send the same sample to the laboratory for wet chemistry analysis.
4. Require the laboratory to use a total-digestion method. If the laboratory does not use a
total digestion method, they may not extract all of the elemental metal from the sample.
In this case, the lab result will be lower than the XRF result. Incomplete sample
digestion is one of the most commons sources of laboratory error, thus it is very
important to request a total digestion method.
Example of Error: The operator collects a bag of sample, performs XRF analysis on one part of the bag,
and sends the bag, or part of the bag of sample to a laboratory for analysis. The laboratory reports a very
different value than the operator obtained with the XRF.
Problem: Since the sample is very non-homogeneous, the operator did not obtain a result that was
representative of the entire bag of sample. The lab analyzed a different part of the sample and obtained a
very different result due to the non-uniformity of the sample. The solution to this problem is, at a
minimum, to test several locations in the bag of sample and report the average value. Also note the
differences between the tests, as this is indicative of the non-uniformity of the sample. Operator should
send entire bag of sample to the lab, and instruct lab to prepare the sample before removing sub-sample for
lab analysis.
Best Practice: The operator should homogenize and prepare the entire bag of sample, and then
collect a sub sample for XRF testing. After testing, the same sample should be sent to the lab.
Section 7: Common Interferences:

An interference occurs when the spectral peak from one element overlaps either partially or
completely with the spectral peak of another. If the XRF is calibrated for both elements (CASE
1) i.e. the one causing the interference and the one being interfered with, it is generally capable of
correctly handling the interference. In this case, the element being interfered with may be
measured with a poorer detection limit or poorer precision, but the analytical results should still
be acceptable for field-portable XRF. If the XRF is not calibrated for the element causing the
interference (CASE 2), then the XRF may report the presence of elements not in the sample, or
greatly elevated concentrations of elements in or not in the sample.
Example CASE 1: Lead and arsenic. Most XRFs are calibrated for lead and arsenic. Lead
interferes with arsenic (not vice-versa though). The net effect is a worsened detection limit for
arsenic, and poorer precision. The XRF handles the correction automatically, but the precision is
affected. The loss of precision is also reported by the XRF. (Please refer to Innov-X
Applications Sheet: In-field Analysis of Lead and Arsenic in Soil Using Portable XRF for more
detail).
Example CASE 2: Bromine in the sample, but XRF is not calibrated for bromine. Bromine, as a
fire retardant, is being seen more and more in soil and other sample types. For this reason, InnovX analyzers include Br in the calibration data. If Br is not calibrated, but is present in the sample,
the analyzer will report highly elevated levels of Pb, Hg and As. The levels will depend upon the
concentration of Br in the sample.
Soil Appendix 14
Interferences between elements can be broadly categorized into a) Z, Z-1, Z+1 interferences, and
b) K/L interferences. Interference type a occurs when high levels of an element of atomic
number Z are present. This can cause elevated levels of elements with atomic number Z-1 or
Z+1. Generally, portable XRFs have good correction methods, so this interference only causes
problems with very high levels of the element in question. Example: High concentrations of Fe
(Z=26) in excess of 10% may cause elevated levels of Mn or Co (Z=25 or Z=27 respectively).
The type b interference occurs when the L-shell line of one element overlaps with the K-shell spectral
line of another element. The most common example is the lead/arsenic interference where the L-alpha line
of lead is in nearly the exact same location as the K-alpha line of arsenic.
Soil Appendix 15
Collect 50-100g Sample
Dry (if necessary)
Sieve using 2mm Mesh
Place 5-10g Sample into XRF test cup
Grind remaining sample material using a

Mortar/Pestle or Grinder
Test with Innov-X Analyzer
Sieve thru 250m mesh
Record Test 1 Results for comparison
Optional : Sieve Thru

125m mesh
Place in 5-10g Sample in

XRF test cups
Test with Innov-X Analyzer (Test 2

and Optional Test 3)
Record Test 2 and Optional Test 3 Results for comparison
Compare Test 1with Test 2 Results and Optional Test 3 Results
Take Sub Sample for

Lab Analysis.
If results change by
<20% from Test 1 to
Test 2 then only sieve
thru 2mm mesh.
Send out to Independent

Lab for results. Use
Total Digestion Method.
If results change by >20%

from Test 1 to Test 2,
sieve thru at least 250m
mesh
Confirm results are

consistent with Test 2
and Optional Test 3
Soil Appendix 16
Appendix 3: Guide to Product Registration

Generally, the Innov-X portable XRF system must be registered in the state of usage. Registration
requirements are somewhat state dependent, but there are many similarities. You may contact Innov-X at
866-4-Innov-X (781-938-5005) to receive specific registration information. Innov-X also maintains sample
registrations for every state that we can forward to you.
Common Registration Features:

Most states require the following for registering an x-ray emitting device that does NOT use radioactive
sources:
1.
Registration within 30 days of receipt of the analyzer.
2.
Annual fee ranging from $25 to $100, depending upon the state.
3.
Basic registration form with main information described below.
Common information required on Registration Form, and responses:

Company name, address, phone/fax numbers.
Name of responsible person:
Generally the person designated as the Radiation Safety
Officer (RSO).
Name of the manufacturer:
Innov-X Systems, Inc., Woburn, MA
Model of Analyzer:
Alpha XXXX
Tube Operating Parameters:
40 kV, 20 uA current.
Type of Analysis:
Choose Analytical or Industrial
(as opposed to radiography, medical, dental, veterinarian, etc.)
Utilization Mode:
Portable or Mobile assuming you will carry system to different
locations.
Fixed or stationary ONLY if you will always use the analyzer
in the docking station
Soil Appendix 17
General Appendix 1
Technical Specifications
Description:
Innov-X Systems analyzers are hand-held, battery operated energy dispersive x-ray
fluorescence analyzers. They are utilized for the detection and quantification of
elements ranging from phosphorus (atomic number 15) though uranium (atomic number
92). Measurable concentrations of elements range from ppm to 100%.
Weight:
Excitation Source:
Detector:
Power:
Battery Life:
Display:
Data Storage:
Computer:
Optional Accessories:
2.625 lbs (Base wt.) 3.375 lbs (1.6 kg) with batteries
X-ray tube, Ag or W anode, 10-40 kV, 5-50 uA, 5 filter positions
Si PiN diode, thermoelectrically cooled, resolution < 280 eV.
Li-ion batteries, or AC power with Testing Stand
4-8 hours, depending on duty cycle.
Color, high-resolution touch screen with variable backlighting on
analyzer. Software available for PC/laptop operation also.
10,000 tests with spectra minimum, expandable to 100,000+ with 1 Gb
flash card.
HP iPAQ with Intel processor, 64 Mb minimum memory, Windows CE
operating system (unless operated from PC).
Bluetooth wireless printing and data transfer, integrated bar-code reader,
wireless LAN, other standard PDA accessories.
Operating Conditions
Temp 0 40 C
Humidity 10 90 % RH, no condensation
Altitude rating 2000 meters
Innov-X Analyzer Limited Warranty

General Terms
EXCEPT AS EXPRESSLY SET FORTH IN THIS LIMITED WARRANTY, INNOVX SYSTEMS, INC. (INNOV-X) MAKES NO OTHER WARRANTIES OR
CONDITIONS, EXPRESSED OR IMPLIED, INCLUDING ANY IMPLIED
WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR
PURPOSE. INNOV-X EXPRESSLY DISCLAIMS ALL WARRANTIES AND
CONDITIONS NOT STATED IN THIS LIMITED WARRANTY. ANY IMPLIED
WARRANTIES THAT MAY BE IMPOSED BY LAW ARE LIMITED IN DURATION
TO THE LIMITED WARRANTY PERIOD.
This Limited Warranty applies to Innov-X analyzers sold or leased from Innov-X
its affiliates, authorized resellers, or country distributors (collectively referred to in
this Limited Warranty as (Innov-X)).
Innov-X warrants that the analyzer and all its internal components that you have
purchased are free from defects in materials or workmanship under normal use
during the Limited Warranty Period. The Limited Warranty Period starts on the
date of shipment by Innov-X. You may be required to provide proof of purchase
or lease as a condition of receiving warranty service. You are entitled to warranty
service according to the terms and conditions of this document if a repair to your
Innov-X analyzer is required within the Limited Warranty Period.
During the Limited Warranty Period, Innov-X will repair or replace the defective
component parts. All component parts removed under this Limited Warranty
become the property of Innov-X. In the unlikely event that your Innov-X analyzer
has a recurring failure, Innov-X, at its discretion, may elect to provide you with a
replacement unit of Innov-Xs choosing that is at least equivalent to your Innov-X
analyzer. This is your exclusive remedy for defective products. The repaired or
replacement analyzer is warranted for the remainder of the limited Warranty
Period.
YOU SHOULD MAKE PERIODIC BACKUP COPIES OF THE DATA STORED ON
YOUR ANALYZER AS A PRECAUTION AGAINST POSSIBLE FAILURES,
ALTERATION, OR LOSS OF THE DATA. BEFORE RETURNING ANY UNIT FOR
SERVICE, BE SURE TO BACK UP DATA AND REMOVE ANY CONFIDENTIAL,
PROPRIETARY, OR PERSONAL INFORMATION. INNOV-X IS NOT
RESPONSIBLE FOR DAMAGE TO OR LOSS OF ANY PROGRAMS, OR DATA.
INNOV-X IS NOT RESPONSIBLE FOR THE RESTORATION OR
REINSTALLATION OF ANY PROGRAMS OR DATA OTHER THAN SOFTWARE
INSTALLED BY INNOV-X WHEN THE ANALYZER IS MANUFACTURED.
Innov-X does not warrant that the operation of this analyzer will be uninterrupted
or error-free. Innov-X is not responsible for damage that occurs as a result of
your failure to follow the instructions that came with the Innov-X analyzer.
This Limited Warranty does not apply to expendable parts. This Limited Warranty
does not extend to any analyzer from which the serial number has been removed
or that has been damaged or rendered defective (A) as a result of accident,
misuse, abuse, or other external causes; (b) by operation outside the usage
parameters stated in user documentation that shipped with the product; (c) by
modification or service by anyone other than (i) Innov-X, or(ii) a Innov-X
authorized service provider, (d) installation of software not approved by Innov-X.
These terms and conditions constitute the complete and exclusive warranty
agreement between you and Innov-X regarding the Innov-X analyzer you have
purchased or leased. These terms and conditions supersede any prior
agreements or representations --- including representations made in Innov-X
sales literature or advice given to you by Innov-X or any agent or employee of
Innov-X --- that may have been made in connection with your purchase or lease
of the Innov-X analyzer. No change to the conditions of this Limited Warranty is
valid unless it is made in writing and signed by an authorized representative of
Innov-X.
Limitation of Liability
IF YOUR INNOV-X ANALYZER FAILS TO WORK AS WARRANTED ABOVE,
YOUR SOLE AND EXCLUSIVE REMEDY SHALL BE REPAIR OR
REPLACEMENT. INNOV-XS MAXIMUM LIABILITY UNDER THIS LIMITED
WARRANTY IS EXPRESSLY LIMITED TO THE LESSER OF THE PRICE YOU
HAVE PAID FOR THE ANALYZER OR THE COST OF REPAIR OR
REPLACEMENT OF ANY COMPONENTS THAT MALFUNCTION IN
CONDITION OF NORMAL USE.
INNOV-X IS NOT LIABLE FOR ANY DAMAGE CAUSED BY THE PRODUCT
OR THE FAILURE OF THE PRODUCT TO PERFORM INCLUDING ANY LOST
PROFITS OR SAVINGS OR SPECIAL, INCIDENTAL, OR CONSEQUENTIAL
DAMAGES. INNOV-X IS NOT LIABLE FOR ANY CLAIM MADE BY A THIRD
PARTY OR MADE BY YOU FOR A THIRD PARTY.
THIS LIMITATION OF LIABILITY APPLIES WHETHER DAMAGE ARE
SOUGHT, OR A CLAIM MADE, UNDER THIS LIMITED WARRATNY OR AS A
TORT CLAIM (INCLUDING NEGLIGENCE AND STRICT PRODUCT LIABILITY),
A CONTRACT CLAIM, OR ANY OTHER CLAIM. THIS LIMITATION OF
LIABILITY CANNOT BE WAIVED OR AMENDED BY ANY PERSON. THIS
LIMITATION OF LIABILITY WILL BE EFFECTIVE EVEN IF YOU HAVE
ADVISED INNOV-X OR AN AUTHORIZED REPRESENTATIVE OF INNOV-X
OF THE POSSIBILITY OF ANY SUCH DAMAGES.
Software
This Limited Warranty does not warrant software products. The Innov-X software
installed on your analyzer is covered by the Innov-X Software License.
Warranty Period
The warranty period for a Model XT-245 or Model XT-260 Innov-X analyzer is
two years or four thousand hours of use, whichever occurs first. The warranty for
all other analyzers is one year or two thousands hours of use whichever occurs
first. This warranty does not extend to expendable parts. Extended warranties
are available from Innov-X.
Warranty Returns
A Return Material Authorization (RMA) Number must be obtained from the
INNOV-X Service Department before any items can be shipped to the factory.
Returned goods will not be accepted without an RMA Number. Customer will
bear all shipping charges for warranty repairs. All goods returned to the factory
for warranty repair should be properly packed to avoid damage and clearly
marked with the RMA Number.
Warranty Repairs
Warranty repairs will be done either at the customer's site or at the INNOV-X
plant, at our option. All service rendered by INNOV-X will be performed in a
professional manner by qualified personnel.
Contacting Innov-X
Be sure to have the following information available before you call Innov-X:
Analyzer serial number, model name, and model number

Applicable error messages
Description of problem
Detailed questions
Methods of Contact
Phone:
781-635-5005
Fax
781-938-0128
Email
service@Innov-Xsys.com
Mail & Shipping Address: Innov-X Systems, Inc. 10 Gill Street,
Suite Q. Woburn MA 01801

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Instruction Manual Innov-X Systems Alpha Series™ X-Ray Fluorescence Spectrometers

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INSTRUCTION MANUAL

Innov-X Systems, Inc.

Copyright Innov-X Systems, Inc. 2003

Chapter 2: USAGE AND ASSEMBLY OF ACCESSORIES

Chapter 3: RADIATION SAFETY

4.6.2 Entering Test Information

1.1 COMPONENTS INCLUDED WITH THE ANALYZER

Analyzer, with iPAQ attached.

Two, Li-ion batteries (one shown).

Standardization cap and weld mask (optional)

Battery charger and an AC adaptor. Battery shown

iPAQ cradle and AC adaptor. The cradle is used to

Testing stand. This is the benchtop docking

1.2 QUICK START INSTRUCTIONS

Place a battery in the analyzer.

Innov-X User Manual Version 2.1

1.3 INTRODUCTION TO XRF: X-RAY FLUORESCENCE

Secondary X-ray Photon Fluorescence

Innov-X User Manual Version 2.1

This is described by the formula

Innov-X User Manual Version 2.1

Innov-X User Manual Version 2.1

Handheld EDXRF Spectrometers for Field Analyses

Innov-X User Manual Version 2.1

Docking station available for use as standard benchtop unit

Innov-X User Manual Version 2.1

Chapter 2. Usage and Assembly of

2.1 ANALYZER BATTERY

Figure 2.1. Li-ion

Battery power indicators:

2.2 CHANGING A BATTERY

Innov-X User Manual Version 2.1

Figure 2.2b Insert new battery

2.3 BATTERY CHARGER

Figure 2.3. Battery charger.

Innov-X User Manual Version 2.1

2.4 HP IPAQ POCKET PC BATTERY

2.5 REMOVING THE IPAQ FROM THE ANALYZER

Innov-X User Manual Version 2.1

Figure 2.4. Removing the iPAQ from the analyzer.

2.6 STANDARDIZATION CAP and/or WELD TESTING MASK

Innov-X User Manual Version 2.1

Figure 2.5 Standardization cap and welding mask. (Optional accessory)

2.7 TESTING STAND (optional accessory)

Components of the testing stand:

Three (3) short legs

Figure 2.6. Assembled Testing Stand

Assembly of Testing Stand

Figure 2.7. Mounting Lower Stand onto Short

Innov-X User Manual Version 2.1

2. Mount the three Long Legs onto the Lower Stand by

Figure 2.8. Mounting Long Legs onto Lower

3. Mount the Upper Stand onto the Long Legs. The

Figure 2.9. Mounting Upper Stand onto

Figure 2.10. Connecting iPAQ to Auxiliary

Innov-X User Manual Version 2.1

Chapter 3 Safety Information

Important Notice for all Canadian Users:

3.1 GENERAL SAFETY PRECAUTIONS AND INFORMATION: