Astm D1310 PDF
Astm D1310 PDF
Astm D1310 PDF
1. Scope *
1.1 This test method covers the determination by Tag
Open-Cup Apparatus of the flash point and fire point of liquids
having flash points between 0 and 325F (18 and 165C) and
fire points up to 325F.
1.2 This test method, when applied to paints and resin
solutions that tend to skin over or that are very viscous, gives
less reproducible results than when applied to solvents.
NOTE 1In order to conserve time and sample, the fire point of a
material may be determined by the Tag Open-Cup Method by continuing
the heating of the specimen to its fire point. Fire points may also be
determined by Test Method D 92, which should be used for fire points
beyond the scope of this test method.
3. Terminology
3.1 Definitions:
3.1.1 flash pointthe lowest temperature, corrected to a
pressure of 760 mm Hg (101.3 kPa, 1013 mbar), at which
application of an ignition source causes the vapor of the
specimen to ignite by the procedure described.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 fire pointthe lowest temperature at which a specimen sustains burning for a minimum of 5 s by the procedure
described.
4. Summary of Method
4.1 The specimen is placed in the cup of a Tag Open-Cup
Apparatus and heated at a slow, but constant rate. A small test
flame is passed at a uniform rate across the cup at specified
intervals until a flash occurs. To determine the fire point, the
test is continued until the application of the test flame causes
the specimen to ignite and burn for at least 5 s.
2. Referenced Documents
2.1 ASTM Standards:
D 92 Test Method for Flash and Fire Points by Cleveland
Open Cup2
D 850 Test Method for Distillation of Industrial Aromatic
Hydrocarbons and Related Materials3
1
This test method is under the jurisdiction of ASTM Committee D01 on Paint
and Related Coatings, Materials, and Applications and is the direct responsibility of
Subcommittee D01.22 on Health and Safety.
Current edition approved Dec. 10, 2001. Published February 2002. Originally
published as D 1310 52 T. Last previous edition D 1310 86(1997){1.
2
Annual Book of ASTM Standards, Vol 05.01.
3
Annual Book of ASTM Standards, Vol 06.04.
4
5
D 1310
government regulations.
6. Apparatus
6.1 Flash TesterTag Open-Cup Apparatus (Fig. 1), as
Metric Equivalents
in.
mm
2
3316
678
71.4
81
174.5
13 16
D 1310
TABLE 1 Thermometers
Flash Point/
Fire Point:
0 to 60F
18 to 15C
60 to 200F
15 to 93C
200 to 325F
93 to 165C
ASTM
Thermometer
Number
Thermometer Range
Thermometer
Subdivisions
33F-75
33C-75
9F-75
9C-75
35F-79
35C-79
36.5 to + 107.5F
38 to + 42C
20 to 230F
5 to 110C
194 to 338F
90 to 170C
0.5F
0.2C
1F
0.5C
0.5F
0.2C
mm) above the top edge of the glass cup when it is in place. It
is imperative that this adjustment be made as accurately as
possible. Raising or lowering the taper can be achieved by
bending it slightly or preferably by adding and removing thin
metal shims as required from between the taper and the vertical
supporting member of the swivel holder.
8.4 With the glass cup in place in the bath, adjust the
thermometer holder so that the thermometer is supported firmly
in a vertical position halfway between the center and edge of
the cup and on a line passing through the center of the cup and
the pivot of the taper. Place the thermometer so that the bottom
of the bulb is 14 in. (6.4 mm) from the inner bottom of the cup.
8.5 Set the draft shield around the tester so that the sides
form right angles with each other and the tester is well toward
the back of the shield.
9. Procedure
9.1 Flash Points from 0 to 60F (18 to 16C) (Warning
Meticulous attention to all details relating to the taper, size of
taper flame, rate of temperature increase, and rate of passing
the taper over the sample is necessary for good results.)
9.1.1 Equip two 500-mL flasks with rubber stoppers through
which are inserted ASTM 33F (33C) thermometers. Cool a
quantity of 1 + 1 water-glycol solution in one stoppered
500-mL flask to approximately 20F (30C) by immersing
the flask in a solid carbon dioxide-acetone bath or other
coolant. Use extreme care not to contaminate the water-glycol
solution with either acetone or carbon dioxide.
9.1.2 Pour the cooled water-glycol solution into the tester
bath to a predetermined level 18in. (3.2 mm) below the top
when the cup is in place. An overflow is desirable for
controlling the liquid level in the bath.
9.1.3 At the same time the water-glycol coolant is being
chilled, cool a portion of the sample to approximately 10F
(25C) in the second stoppered 500-mL flask. If solid carbon
dioxide and acetone or other volatile solvents are used as a
coolant, extreme care must be exercised to avoid contamination of the sample. Cool the glass cup and place it in the bath.
Position the appropriate thermometer (Table 1) as described in
8.4 and fill the cup with cooled sample to a depth approximately 18 in. (3.2 mm) below the edge as determined by the
leveling device.
NOTE 3Remove all bubbles from the surface of the liquid before
starting a determination.
6
Satisfactory n-heptane and p-xylene can be obtained from Special Products
Division, Chemical Department, Phillips Petroleum Company, Drawer O, Borger,
TX 79607.
7
Satisfactory isopropanol may be obtained from Exxon Chemical, Americus P.
O. Box 3272, Houston, TX 77001, Shell Chemical Co., One Shell Plaza, Houston,
TX 77002, or Union Carbide Co., P. O. Box 8361, South Charleston, WV 25303.
8
Satisfactory diethylene glycol may be obtained from Union Carbide Co., S.
Charleston, WV.
D 1310
9.3.5 Apply full heat to the liquid bath; when the temperature of the specimen reaches approximately 190F (90C),
adjust the heat input so that the temperature of the specimen
increases at a rate of 2 60.5F (1 6 0.25C)/min.
D 1310
acceptability of results between 0 and 200F (18 and 93C) at
the 95 % confidence level).
13.1.1 RepeatabilityTwo results, each the mean of three
determinations, obtained by the same operator should be
considered suspect if they differ by more than 4F (2C).
13.1.2 ReproducibilityTwo results, each the mean of three
determinations, obtained by operators in different laboratories
should be considered suspect if they differ by more than 7F
(4C).
13.2 The following criteria should be used for judging flash
points between 200 and 325F (93 and 165C) at the 95 %
confidence level.
13.2.1 RepeatabilityTwo results, each the mean of three
determinations, obtained by the same operator should be
considered suspect if they differ by more than 9F (5C).
13.2.2 ReproducibilityTwo results, each the mean of three
determinations, obtained by operators in different laboratories
should be considered suspect if they differ by more than 12F
(7C).
13.3 On the basis of an interlaboratory test of the method,
using viscous, heavily-pigmented materials that tended to form
a surface film, the within-laboratory standard deviation was
found to be 3F (2C) and the between-laboratories standard
deviation was found to be 7F (4C). Based on these standard
deviations, the following criteria should be used for judging the
acceptability of results at the 95 % confidence level:
13.3.1 RepeatabilityTwo results, each the mean of three
determinations, obtained by the same operator on different
days should be considered suspect if they differ by more than
9F (5C).
13.3.2 ReproducibilityTwo results, each the mean of three
determinations, obtained by operators in different laboratories
should be considered suspect if they differ by more than 24F
(13C).
13.4 The precision of fire points will be determined. See
Test Method D 92 for precision using the Cleveland Open Cup.
13.5 BiasNo estimate of bias of flash point and fire point
tests can be determined, as no absolute values are available.
The tests are equipment and method dependent.
(1)
(2)
(3)
where:
C = observed flash point in C
F = observed flash point in F
p = ambient barometric pressure in kPa
P = ambient barometric pressure in mm Hg.
NOTE 9The barometric pressure used in this calculation is the
ambient pressure for the laboratory at the time of the test. Many aneroid
barometers, such as those used at weather stations and airports are
precorrected to give sea level readings and would not give the correct
reading for this test.
14. Keywords
14.1 fire point; flash point; liquids; paints; resin solutions;
Tag tester
9
Supporting data are available from ASTM International Headquarters. Request
RR: D01 1002.
D 1310
ANNEXES
(Mandatory Information)
A1. APPARATUS
Metric Equivalents
in.
mm
in.
mm
932
516
38
58
2132
0.8
5.5
7.0
7.5
9.5
15.9
16.6
1
138
112
178
2
2132
2316
212
30.1
34.9
38.1
47.6
50.8
51.6
55.5
63.5
1 32
7 32
3 16
D 1310
Metric Equivalents
in.
mm
18
0.125 6
0.003
532
1
2
212
5
0.8
3.2
3.18 6 0.08
1 32
4.0
25.4
50.8
63.5
127
FIG. A1.2 Leveling Device for Adjusting Liquid Level in Test Cup, Height of Taper above Cup, and Size of Test Flame
D 1310
SUMMARY OF CHANGES
Committee D01 has identified the location of selected changes to this standard since the last issue,
D 1310 - 86 (1997){1, that may impact the use of this standard.
(1) Deleted Note 3 and changed caution statement to a warning
that is included in 9.1.
(2) Deleted Section 10 and replaced it with a new Section 10
that simplifies instrument verification procedure.
(3) Added Section 11 on correcting for barometric pressure
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