Heattreatment English 99
Heattreatment English 99
Heattreatment English 99
HEAT TREATMENT
OF TOOL STEEL
Contents
What is tool steel? ................................................. 3
Hardening and tempering .................................... 3
Dimensional and shape stability .......................... 8
Surface treatment .................................................. 10
Testing of mechanical properties ........................12
Some words of advice to tool designers .............13
2
Heat treatment
The purpose of this brochure is to provide some becomes alloyed with carbon and carbide-forming
idea of how tool steel is heat-treated and how it elements.
behaves. When the steel is heated to the hardening tem-
Special attention is paid to hardness, tough- perature (austenitizing temperature), the carbides
ness and dimensional stability. are partially dissolved, and the matrix is also
altered. It is transformed from ferrite to austenite.
This means that the iron atoms change their posi-
What is tool steel? tion in the atomic lattice and make room for atoms
of carbon and alloying elements. The carbon and
Uddeholm has concentrated its tool steel range on alloying elements from the carbides are dissolved
high-alloyed types of steel, intended primarily for in the matrix.
purposes such as plastics moulding, blanking and If the steel is quenched sufficiently rapid in the
forming, die-casting, extrusion, forging and wood- hardening process, the carbon atoms do not have
working. time to reposition themselves to allow the re-form-
Conventional high-speed steels and powder ing of ferrite from austenite, i.e. as in annealing.
metallurgy (PM) steels are also included in the Instead, they are fixed in positions where they really
range. do not have enough room, and the result is high
Tool steel is normally delivered in the soft an- microstresses that can be defined as increased
nealed condition. This is to make the material easy hardness. This hard structure is called martensite.
to machine with cutting tools and to give it a micro- Thus, martensite can be seen as a forced solution
structure suitable for hardening. of carbon in ferrite.
The microstructure consists of a soft matrix in
which carbides are embedded. In carbon steel, = Iron atoms
these carbides consist of iron carbide, while in the = Possible positions for carbon atoms
alloyed steel they are chromium (Cr), tungsten
(W), molybdenum (Mo) or vanadium (V) car-
bides, depending on the composition of the steel.
Carbides are compounds of carbon and these
alloying elements and are characterized by very
high hardness. A higher carbide content means
higher resistance to wear.
In alloy steels, it is important that the carbides
are evenly distributed. 2,86 A
Other alloying elements are also used in tool
steel, such as cobalt (Co) and nickel (Ni), but Unit cell in a ferrite crystal. Body-centred cubic (BCC).
these do not form carbides. Cobalt is normally
used to improve red hardness in high-speed steels,
nickel to improve through-hardening properties.
3,57 A
Hardening
and tempering
When a tool is hardened, many factors influence 3,57 A
the result.
Unit cell in an austenite crystal. Face-centred cubic (FCC).
SOME THEORETICAL ASPECTS
In soft annealed tool steel, most of the alloying ele-
ments are bound up with carbon in carbides. In
addition to these there are the alloying elements
cobalt and nickel, which do not form carbides but
2,98 A
are instead dissolved in the matrix.
When the steel is heated for hardening, the
basic idea is to dissolve the carbides to such a de-
gree that the matrix acquires an alloying content
that gives the hardening effectwithout becoming
2,85 A
coarse-grained and brittle. Note that the carbides
are partially dissolved. This means that the matrix Unit cell in a martensite crystal.
3
Heat treatment
When a steel is hardened, the matrix is not Tool steel should always be double-tempered.
completely converted into martensite. Some auste- The second tempering takes care of the secondary
nite is always left and is called retained austenite. martensite formed after the first tempering. Three
The amount increases with increasing alloying tempers are recommended for high-speed steel
content, higher hardening temperature and longer with a high carbon content.
soaking times.
After quenching, the steel has a microstruc-
ture consisting of martensite, retained austenite
and carbides.
This structure contains inherent stresses that
can easily cause cracking. But this can be pre-
vented by reheating the steel to a certain tempera-
ture, reducing the stresses and transforming the re-
tained austenite to an extent that depends upon
the reheating temperature.
This reheating after hardening is called tem-
pering. Hardening of a tool steel should always be
followed immediately by tempering. Tempered once. Tempered twice. 1000x
It should be noted that tempering at low tem- RIGOR, hardened and tempered.
peratures only affects the martensite, while tem-
pering at high temperature also affects the retained
austenite.
After one tempering at high temperature, the HOW HARDENING AND TEMPERING
microstructure consists of tempered martensite, IS DONE IN PRACTICE
newlyformed martensite, some retained austenite
and carbides. Precipitated secondary (newly- Distortion due to hardening must be taken into
formed) carbides and newly-formed martensite can consideration when a tool is rough-machined.
increase hardness during high-temperature tem- Rough machining causes local heating and mech-
pering. Typical of this is the so-called secondary anical working of the steel, which gives rise to
hardening of e.g. high-speed steel and high-alloyed inherent stresses. This is not serious on a symmet-
tool steels. rical part of simple design, but can be significant in
asymmetrical machining, for example of one half
Hardness of a die-casting die. Here, stress-relieving is always
recommended.
C
B Stress relieving
This treatment is done after rough machining and
D
entails heating to 550650C (10201200F). The
material should be heated until it has achieved
uniform temperature all the way through and then
A
cooled slowly, for example in a furnace.
The idea behind stress relieving is that the
yield strength of the material at the elevated tem-
perature is so low that the material cannot resist
Tempering temperature.
the inherent stresses. The yield strength is ex-
ceeded and these stresses are released, resulting
A = martensite tempering in a greater or lesser degree of distortion.
B = carbide precipitation
C = transformation of retained austenite to martensite
D = tempering diagram for high speed steel and high-alloy The correct work sequence is: rough machining,
tool steel stress relieving and finish machining
A+B+C = D
The excuse that stress relieving takes too
much time is hardly valid. Rectifying a part during
finish machining of an annealed material is with
few exceptions cheaper than making dimensional
adjustments on a hardened tool.
4
Heat treatment
Quenching
The choice between a fast and slow quenching rate
is usually a compromise: to get the best micro-
structure and tool performance, the quenching
rate should be rapid; to minimize distortion, a slow
quenching rate is recommended.
Slow quenching results in less temperature
difference between the surface and core of a part,
and sections of different thickness will have a more
uniform cooling rate.
This is of great importance when quenching
Batch-type furnace with a controlled atmosphere. through the martensite range, below the Ms tem-
perature. Martensite formation leads to an increase
in volume and stresses in the material. This is also
the reason why quenching should be interrupted
before room temperature has been reached,
normally at 5070C (120160F).
However, if the quenching rate is too slow,
especially with heavier cross-sections, undersirable
transformations in the microstructure can take
place, risking a poor tool performance.
Water is used as a quenching medium for
unalloyed steels. 810% sodium chloride (salt) or
soda should be added to the water in order to
Salt bath furnace. achieve optimum cooling efficiency.
5
Heat treatment
6
Heat treatment
7
Heat treatment
300
250
200
100
8
Heat treatment
Machining allowance
Volume
Grade of steel on length and diameter
as % of dimension
ARNE 0,25 %
RIGOR 0,20 %
SVERKER 21 and SVERKER 3 0,20 %
CARMO 0,20 %
VANADIS 4 SuperClean 0,15 %
VANADIS 6 SuperClean 0,15 %
Transformation
VANADIS 10 SuperClean 0,15 %
to austenite
VANADIS 23 SuperClean 0,15 %
CALMAX 0,20 %
GRANE 0,15 %
Transformation
to martensite Ms AC1 AC3 STAVAX ESR 0,15 %
ELMAX SuperClean 0,15 %
Temperature
ORVAR 2 Microdized 0,20 %
Volume changes due to structural transformation. ORVAR SUPREME 0,20 %
VIDAR SUPREME 0,20 %
QRO 90 SUPREME 0,30 %
HOTVAR 0,40 %
DIEVAR 0,30 %
9
Heat treatment
Examples of applications
Nitriding is used in some cases on prehardened
plastic moulds in order to prevent indentation
and defects on the parting faces. It should be
noted, however, that a nitrided surface cannot
be machined with cutting tools and can only be
ground with difficulty. A nitrided surface will
cause problems in weld repairing as well.
Nitriding can also have a stress-relieving effect.
Heavily machined parts may, therefore, undergo Ion nitriding plant.
some distortion during nitriding due to the re-
lease of residual stresses from machining and in
such a case, a stress relieving between rough CASE HARDENING
and finish machining is recommended.
In this method, the steel is heated in a medium
The life of forging dies can be increased by
that gives off carbon (gas, salt or dry carburizing
nitriding. It must be noted, though, that the
compound). The carbon diffuses into the surface of
treatment can give rise to higher susceptibility
the material and after hardening this gives a sur-
to cracking in sharp corners. Furthermore, the
face layer with enhanced hardness and wear resis-
edge of the flash land must be given a rounded
tance. This method is used for structural steel, but
profile.
is not generally recommended for alloy tool steels.
Extrusion dies of ORVAR 2 M can be nitrided to
advantageespecially in the case of aluminium
alloys. Exceptions can be profiles with sharp
corners and thin sections of the dies.
10
Heat treatment
Coated tools.
11
Heat treatment
Vickers (HV)
Testing In Vickers hardness testing a pyramid-shaped
Rockwell (HRC)
In Rockwell hardness testing, a conical diamond is Principle of Vickers hardness testing.
first pressed with a force F0, and then with a force
F0+F1 against a specimen of the material whose
hardness is to be determined. After unloading to Brinell (HB)
F0, the increase (e) of the depth of the impression In Brinell hardness testing, a ball is pressed
caused by F1 is determined. The depth of penetra- against the material whose hardness is to be deter-
tion (e) is converted into a hardness number mined. After unloading, two measurements of the
(HRC) which is read directly from a scale on the diameter of the impression are taken at 90 to each
tester dial or read-out. other (d1 and d2) and the HB value is read off a
F0 F0+F1=F F0 table, from the average of d1 and d2.
h0 h e HRC D
F
Surface of specimen
100 h0
Hardness scale
e d
0,2 mm h
h
HRC
0
12
Heat treatment
TENSILE STRENGTH
Tensile strength is determined on a test piece
Some words
which is gripped in a tensile testing machine and of advice to
subjected to a successively increasing tensile load
until fracture occurs. The properties that are nor- tool designers
mally recorded are yield strength Rp0,2 and ulti-
CHOICE OF STEEL
mate tensile strength Rm, while elongation A5 and
reduction of area Z are measured on the test piece. Choose air-hardening steels for complex tools.
In general, it can be said that hardness is depend-
ent upon yield strength and ultimate tensile DESIGN
strength, while elongation and reduction of area Avoid:
are an indication of toughness. High values for
sharp corners
yield and ultimate tensile strength generally mean
low values for elongation and reduction of area. notch effects
Tensile tests are used mostly on structural large differences in section thicknesses.
steels, seldom on tool steels. It is difficult to per-
form tensile tests at hardnesses above 55 HRC. These are often causes of quench cracks,
Tensile tests may be of interest for tougher types especially if the material is cooled down too far or
of tool steel, especially when they are used as high- allowed to stand untempered.
strength structural materials. These include e.g.
IMPAX SUPREME and ORVAR 2 M.
Unsuitable Preferred alterna-
design tive
IMPACT TESTING
A certain quantity of energy is required to produce
a fracture in a material. This quantity of energy can
be used as a measure of the toughness of the ma-
terial, a higher absorption of energy indicating
Fillet
better toughness. The commonest and simplest
method of determining toughness is impact test-
ing. A rigid pendulum is allowed to fall from a
known height and to strike a test specimen at the
lowest point of its swing. The angle through which
the pendulum travels after breaking the specimen
is measured, and the amount of energy that was
absorbed in breaking the specimen can be calcu-
lated.
Several variants of impact testing are in use.
The various methods differ in the shape of the
specimens. These are usually provided with a V- or
U-shaped notch, the test methods being then
known as Charpy V and Charpy U respectively.
For the most part, tool steel has a rather low
toughness by reason of its high strength. Materials
of low toughness are notch-sensitive, for which HEAT TREATMENT
reason smooth, unnotched specimens are often
used in the impact testing of tool steels. The re- Choose suitable hardnesses for the application
sults of the test are commonly stated in joules, or concerned. Be particularly careful to avoid tem-
alternatively in kgm (strictly speaking kgfm), perature ranges that can reduce toughness after
although J/cm2 or kgm/cm2 is sometimes used tempering.
instead, specially in Charpy U testing. Keep the risk of distortion in mind and follow
There are several other variants of impact recommendations concerning machining allowan-
testing which are used outside Sweden, e.g. DVM, ces.
Mesanger andespecially in English-speaking It is good idea to specify stress relieving on the
countriesIzod. drawings.
13