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    122 Triethylene Glycol

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    eng20072007
    Triethylene glycol is a colorless, hygroscopic liquid. It is an irritant to eyes and slightly hazardous if inhaled or ingested. Triethylene glycol has a low oral toxicity, but repeated or prolonged exposure can damage target organs like the kidneys and nervous system. Proper precautions should be taken such as using splash goggles and gloves and ensuring adequate ventilation. The material is combustible at high temperatures and its decomposition may produce toxic gases.

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    122 Triethylene Glycol

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    eng20072007
    270 views6 pages
    Triethylene glycol is a colorless, hygroscopic liquid. It is an irritant to eyes and slightly hazardous if inhaled or ingested. Triethylene glycol has a low oral toxicity, but repeated or prolonged exposure can damage target organs like the kidneys and nervous system. Proper precautions should be taken such as using splash goggles and gloves and ensuring adequate ventilation. The material is combustible at high temperatures and its decomposition may produce toxic gases.

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    Triethylene glycol is a colorless, hygroscopic liquid. It is an irritant to eyes and slightly hazardous if inhaled or ingested. Triethylene glycol has a low oral toxicity, but repeated or prolonged exposure can damage target organs like the kidneys and nervous system. Proper precautions should be taken such as using splash goggles and gloves and ensuring adequate ventilation. The material is combustible at high temperatures and its decomposition may produce toxic gases.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    270 views6 pages

    122 Triethylene Glycol

    Uploaded by

    eng20072007
    Triethylene glycol is a colorless, hygroscopic liquid. It is an irritant to eyes and slightly hazardous if inhaled or ingested. Triethylene glycol has a low oral toxicity, but repeated or prolonged exposure can damage target organs like the kidneys and nervous system. Proper precautions should be taken such as using splash goggles and gloves and ensuring adequate ventilation. The material is combustible at high temperatures and its decomposition may produce toxic gases.

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    Material Safety Data Sheet

    Triethylene glycol MSDS

    Section 1: Chemical Product and Company Identification


    Product Name: Triethylene glycol Contact Information:

    Catalog Codes: SLT2644 Sciencelab.com, Inc.


    14025 Smith Rd.
    CAS#: 112-27-6 Houston, Texas 77396
    US Sales: 1-800-901-7247
    RTECS: YE4550000
    International Sales: 1-281-441-4400
    TSCA: TSCA 8(b) inventory: Triethylene glycol Order Online: ScienceLab.com
    CI#: Not available. CHEMTREC (24HR Emergency Telephone), call:
    1-800-424-9300
    Synonym: 2,2'-[1,2-Ethanediylbis(oxy)]bisethanol
    International CHEMTREC, call: 1-703-527-3887
    Chemical Formula: C6H14O4
    For non-emergency assistance, call: 1-281-441-4400

    Section 2: Composition and Information on Ingredients


    Composition:
    Name CAS # % by Weight
    Triethylene glycol 112-27-6 100

    Toxicological Data on Ingredients: Triethylene glycol: ORAL (LD50): Acute: 17000 mg/kg [Rat].

    Section 3: Hazards Identification


    Potential Acute Health Effects:
    Very hazardous in case of eye contact (irritant), of ingestion. Slightly hazardous in case of inhalation.
    Inflammation of the eye is characterized by redness, watering, and itching.

    Potential Chronic Health Effects:


    Very hazardous in case of eye contact (irritant).
    Slightly hazardous in case of inhalation.
    CARCINOGENIC EFFECTS: Not available.
    MUTAGENIC EFFECTS: Not available.
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    The substance is toxic to kidneys, the nervous system.
    Repeated or prolonged exposure to the substance can produce target organs damage.

    Section 4: First Aid Measures

    p. 1
    Eye Contact:
    Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
    keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

    Skin Contact: No known effect on skin contact, rinse with water for a few minutes.

    Serious Skin Contact: Not available.

    Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

    Serious Inhalation: Not available.

    Ingestion:
    Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
    breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

    Serious Ingestion: Not available.

    Section 5: Fire and Explosion Data


    Flammability of the Product: May be combustible at high temperature.

    Auto-Ignition Temperature: 371C (699.8F)

    Flash Points: CLOSED CUP: 177C (350.6F). OPEN CUP: 165.5C (329.9F).

    Flammable Limits: LOWER: 0.9% UPPER: 9.2%

    Products of Combustion: These products are carbon oxides (CO, CO2).

    Fire Hazards in Presence of Various Substances: Not available.

    Explosion Hazards in Presence of Various Substances:


    Risks of explosion of the product in presence of mechanical impact: Not available.
    Risks of explosion of the product in presence of static discharge: Not available.

    Fire Fighting Media and Instructions:


    SMALL FIRE: Use DRY chemical powder.
    LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

    Special Remarks on Fire Hazards: Not available.

    Special Remarks on Explosion Hazards: Not available.

    Section 6: Accidental Release Measures


    Small Spill:
    Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
    container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and
    regional authority requirements.

    Large Spill:
    Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by
    spreading water on the contaminated surface and allow to evacuate through the sanitary system.

    Section 7: Handling and Storage


    Precautions:

    p. 2
    Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the
    residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/
    vapour/spray. Avoid contact with eyes If ingested, seek medical advice immediately and show the container or
    the label.

    Storage:
    Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly
    closed. Keep in a cool, well-ventilated place. Combustible materials should be stored away from extreme heat
    and away from strong oxidizing agents.

    Section 8: Exposure Controls/Personal Protection


    Engineering Controls:
    Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
    respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
    work-station location.

    Personal Protection: Splash goggles. Lab coat.

    Personal Protection in Case of a Large Spill:


    Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a
    specialist BEFORE handling this product.

    Exposure Limits: Not available.

    Section 9: Physical and Chemical Properties


    Physical state and appearance: Liquid. (Hygroscopic liquid.)

    Odor: Not available.

    Taste: Not available.

    Molecular Weight: 150.18 g/mole

    Color: Colorless.

    pH (1% soln/water): Not available.

    Boiling Point: 285C (545F)

    Melting Point: -5C (23F)

    Critical Temperature: Not available.

    Specific Gravity: 1.1274 (Water = 1)

    Vapor Pressure: Not available.

    Vapor Density: 5.17 (Air = 1)

    Volatility: Not available.

    Odor Threshold: Not available.

    Water/Oil Dist. Coeff.: Not available.

    Ionicity (in Water): Not available.

    Dispersion Properties: See solubility in water.

    p. 3
    Solubility: Easily soluble in cold water.

    Section 10: Stability and Reactivity Data


    Stability: The product is stable.

    Instability Temperature: Not available.

    Conditions of Instability: Not available.

    Incompatibility with various substances: Not available.

    Corrosivity: Non-corrosive in presence of glass.

    Special Remarks on Reactivity: Not available.

    Special Remarks on Corrosivity: Not available.

    Polymerization: No.

    Section 11: Toxicological Information


    Routes of Entry: Eye contact. Ingestion.

    Toxicity to Animals: Acute oral toxicity (LD50): 17000 mg/kg [Rat].

    Chronic Effects on Humans: The substance is toxic to kidneys, the nervous system.

    Other Toxic Effects on Humans:


    Very hazardous in case of ingestion.
    Slightly hazardous in case of inhalation.

    Special Remarks on Toxicity to Animals: Not available.

    Special Remarks on Chronic Effects on Humans: Not available.

    Special Remarks on other Toxic Effects on Humans: Not available.

    Section 12: Ecological Information


    Ecotoxicity: Not available.

    BOD5 and COD: Not available.

    Products of Biodegradation:
    Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    arise.

    Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

    Special Remarks on the Products of Biodegradation: Not available.

    Section 13: Disposal Considerations


    Waste Disposal:

    p. 4
    Section 14: Transport Information
    DOT Classification: Not a DOT controlled material (United States).

    Identification: Not applicable.

    Special Provisions for Transport: Not applicable.

    Section 15: Other Regulatory Information


    Federal and State Regulations:
    Pennsylvania RTK: Triethylene glycol
    TSCA 8(b) inventory: Triethylene glycol

    Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

    Other Classifications:

    WHMIS (Canada): Not controlled under WHMIS (Canada).

    DSCL (EEC): R41- Risk of serious damage to eyes.

    HMIS (U.S.A.):

    Health Hazard: 1

    Fire Hazard: 1

    Reactivity: 0

    Personal Protection: j

    National Fire Protection Association (U.S.A.):

    Health: 1

    Flammability: 1

    Reactivity: 0

    Specific hazard:

    Protective Equipment:
    Not applicable.
    Lab coat.
    Not applicable.
    Splash goggles.

    Section 16: Other Information


    References: Not available.

    Other Special Considerations: Not available.

    Created: 10/10/2005 08:31 PM

    Last Updated: 10/10/2005 08:31 PM

    The information above is believed to be accurate and represents the best information currently available to us. However, we

    p. 5
    make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we
    assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
    information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any
    third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even
    if ScienceLab.com has been advised of the possibility of such damages.

    p. 6

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