GPA Research PDF

2014
COOPERATIVE RESEARCH
About GPA and Midstream Industry Research
Although GPA research dates back to the associations beginnings in the 1920s, the current formal research program
was developed in the early 1960s to meet the technological needs of a rapidly expanding industry. Structured early on as a
cooperative effort, it is primarily GPAs members who fund the research program, but other interested parties also contribute.
As a result of its successes and benefits to the global midstream industry, the GPA cooperative research program has received
worldwide recognition and is often used as an example for other cooperative programs.
For GPA members, the cooperative approach has proved to be especially practical, economical, and efficient because
it eliminates the needless duplication of individual company research. Furthermore, history has shown that GPA research
projects have stimulated additional research by other organizations and companies, so that total benefits accruing to the
industry go substantially beyond the results obtained from just the associations efforts.
GPA has had an outstanding history of anticipating and determining the most pressing needs of this industry. For more
than 50 years, a vast amount of data has been collected from GPA-led research efforts, leading to greatly improved predictive
models for all to use. Today, the GPA research program continues to serve as a highly effective and efficient means of:
Identifying and assigning priorities to the industrys data needs.
Auditing, compiling and evaluating available data and computational methods.
Designing and supervising experimental measurements of thermodynamic properties on a systematic basis.
Providing the computational tools for accurate and economical design of light hydrocarbon processing facilities.
The practical achievements of the GPA research program are evident in the list of published results - GPA Research Reports
- included in this brochure. Examination of this list will reveal a wide range of research investigation into virtually every area of
gas treating and processing. This data forms the basis of most process simulators used in the gas processing industry.
The midstream industry is experiencing technological advancements at a record pace. The GPA cooperative research
program is one way for all GPA members to be on the leading edge. Thank you for your continued support of GPA and our
research efforts.
Advancing the midstream industry - gpa
All GPA members contribute to the research program through their annual dues, and a number of GPSA
companies also support the program on a voluntary basis. We greatly appreciate your contributions to the program that truly
benefits the entire industry.
Thank You 2013 GPA Research Program Supporters!

Access Midstream Envantage Inc. Prism Midstream, LLC
Agave Energy Co. Exxon Mobil Upstream Research Co. Procesadora de Gas Parinas SAC
Aka Energy Group, LLC Formosa Hydrocarbons Co. PSI Midstream
AmeriGas Propane L.P. Frames Gas Processing B.V. PVR Midstream, LLC
Anadarko Petroleum Gas Processors Inc. QEP Field Services Co.
Aramco Services Co. Gas Solutions II Ltd. Red Cedar Gathering Co.
Argus Media Gas Technology Institute Regency Gas Services, LLC
Arrow Midstream Holdings, LLC Halcon Field Services, LLC Reliance Holding USA Inc.
Aspen Technology Inc. Hanlon Gas Processing Ltd. Research Institute of Natural Gas Technology
Atlas Pipeline Partners L.P. Hess Corp. Saddle Butte Pipeline, LLC
Atmos Energy Hiland Partners L.P. SAIC Energy, Environment and Infrastructure
Aux Sable Liquid Products Inc. Hunt Oil Co. SandRidge Midstream Inc.
Bahrain National Gas Co. Hunt, Guillot & Associates Santos Ltd.
Bechtel Hydrocarbon Technology Solutions Inc./IPSI, LLC IFP Energies Nouvelles Sasol North America Inc.
Black & Veatch IHS Global Inc. S-CON Inc.
Boardwalk Pipeline Partners Invensys Operations Management SemGas L.P.
BP Japan Indonesia LNG Co. Ltd. Seminole Energy
Bryan Research & Engineering Inc. KBR Shell Global Solutions (US) Inc.
Burns & McDonnell Kinder Morgan Southcross Energy GP, LLC
Caiman Energy Legion Energy Services, LLC Southern Union Gas Services
Cardinal Midstream, LLC Linde Engineering Southwestern Midstream
Carrera Gas Co., LLC Linn Operating Inc. Spectrum LNG, LLC
Castleton Commodities Partners L.P. Lyondell Basell Industries Statoil ASA
CenterPoint Energy Field Services M3 Midstream, LLC Sterling Energy Co.
Ceritas Energy, LLC Marathon Petroleum Corp. Superior Pipeline Co.
Chesapeake Energy Corp. MarkWest Energy Partners L.P. Targa Resources Inc.
Chevron North American Production Marlin Midstream TEAK Texana Pipeline, LLC
Chiyoda Corp. Martin Midstream Partners L.P. TexStar Midstream Services L.P.
Cimarex Energy Co. Meritage Midstream Services II, LLC TGGT Midstream
Citgo Petroleum Corp. Muse, Stancil & Co. Thunder Creek Gas Services, LLC
ConocoPhillips Mustang Gas Products, LLC Tomcej Engineering Inc.
Crestwood Midstream Partners L.P. NGL Energy Partners Total SA
Crosstex Energy Services L.P. Nippon Kaiji Kentei Kyokai Toyo Engineering Corp.
DCP Midstream L.P. NiSource Midstream Services, LLC Tristream Energy, LLC
Devon Energy Corp. Nuevo Midstream, LLC United Gas Derivatives Co.
Dexter Field Services ONEOK Partners US Infrastructure
DONG E&P Norge AS Optimized Gas Treating Inc. Virtual Materials Group Inc.
Dow Hydrocarbons and Resources, LLC Ortloff Engineers Ltd. Westlake Chemical Corp.
Eagle Rock Energy Partners L.P. Oxy USA Inc. Whiting Oil and Gas Corp.
EDG Inc. PB Energy Storage Services Inc. Wildcat Midstream
Elkhorn Gas Processing, LLC PDC Energy Williams
Enbridge Energy Partners Pearson Watson Millican & Co. WTG Gas Processing L.P.
EnCana Oil & Gas (USA) Inc. Pecan Pipeline Xcel Energy
Enerfin Resources Co. Phillips 66 XTO Energy Inc.
Energy Transfer Co. Phoenix Park Gas Processors Ltd.
Enogex Inc. Pilot Energy Solutions, LLC
Enterprise Products Operating L.P. Pioneer Natural Resources USA Inc.
2014 COOPERATIVE INDUSTRY RESEARCH 1

gpa - GAS PROCESSORS ASSOCIATION
HOW COOPERATIVE RESEARCH PROJECTS ARE DETERMINED

The selection of projects presented and administered by GPA is directly attributable to the members of the two Technical Section F
sub-groups who oversee the process and the projects. These committee members are highly knowledgeable of the problems faced by
this industry on a day-to-day basis, and they know the availability of, or lack of, data necessary for the resolution of the key issues. It is such
in-depth knowledge - both theoretical and practical - of data and processes that make them proficient in the guidance and evaluation of
this research effort.
In addition to the individual knowledge that each member brings, the collective synergy from the groups result in excellent supervision
and assessment of the new and continuing research, ensuring that GPA member companies receive the maximum benefit in return for their
funding contributions.
All GPA research effort is guided by a number of common sense principles:
Research must concentrate on areas of critical importance to the gas processing industry.
Research must be directed toward problems where solutions are considered possible.
The economic value to the industry must be evaluated in advance.
Projects must avoid areas of a proprietary nature or where patents would create problems.
To the individuals who serve on these Technical Section F sub-groups, and to their companies who allow them to do so, thank you. Your
time and efforts are greatly appreciated.
FUNDING LEVERAGE
Of great importance, but often overlooked, is the added value gained through associated relationships beneficial to the GPA cooperative
research program. The funds appropriated by GPA members get further multiplied as a result of co-funding from other organizations,
through partial subsidization by the research contractors and by the extension of GPA research efforts by other parties with similar vested
interests.
Included among those who provide such assistance are:
The Propane Education Research Council (PERC)
The Gas Processors Suppliers Association (GPSA)
The American Petroleum Institute (API)
2 2014 COOPERATIVE INDUSTRY RESEARCH

Technical Section F
Chairman: Dr. Karl Gerdes, Consultant, Davis, California
Sub-group #1
Chairman: Dan McCartney, Black & Veatch, Overland Park, Kansas
Kelda Bratley, BP, Houston, Texas
Michael W. Hlavinka, Bryan Research & Engineering, Bryan, Texas
Dr. Stanley Huang, Chevron, Houston, Texas
Morten Anderson, Dong Energy, Horsholm, Denmark
Al Goethe, Enterprise Products Operating, Houston, Texas
Dr. Scott Northrop, ExxonMobil, Houston, Texas
Mike Hegarty, H2W United, Denver, Colorado
karl gerdes
SECTION F CHAIRMAN Dr. Jame Yao, IPSI, Houston, Texas
Dr. Cal Spencer, KBR, Houston, Texas
Lars Henrik Gjertsen, Statoil ASA, Trondheim, Norway
Sub-group #2
Chairman: Chris Root, DCP Midstream, Denver, Colorado
Dr. Mark Johnson, BP America, Houston, Texas
Kindra Snow-McGregor, John M. Campbell/Petroskills, Parker, Colorado
Dr. Craig Schubert, Dow Chemical Co., Lake Jackson, Texas
Dr. Tim Cullinane, ExxonMobil, Annandale, New Jersey
Dr. Gerhard Lauermann, Linde Engineering Division, Pullach, Germany
Dr. Raymond French, Shell Global Solutions (U.S.) Inc., Houston, Texas
Hvard Lidal, Statoil ASA, Oslo, Norway
dan mccartney Brett Eldred, Targa Resources, Houston, Texas
SUB-GROUP #1 CHAIRMAN
Jeff Matthews, URS, Denver, Colorado
GPSA Liaison: D. John Morgan, John M. Campbell, Parker, Colorado
Table of Contents
Research Budget . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
New Projects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Continuing Research . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Chris Root
SUB-GROUP #2 CHAIRMAN Previously Funded Projects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Authorization and Funding Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
GPA Research Fiscal Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
GPA Research Reports . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Technical Publications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

2014 Research Budget

The 2014 research budget of $285,000 (the GPA member portion of the overall $635,000 research budget) follows in full detail, along
with a description of each research project. The GPA Board of Directors unanimously approved the budget at its October 2013 meeting.
For 2014, GPA has directed $50,000 from GPSA members commitments and research reserve funds to the overall budget to help reduce
the funding obligation of member companies. GPA has also directed $300,000 of funding from the Propane Education Research Council
(PERC) to supplement the overall budget. This PERC support is greatly appreciated and will be a great help in continuing GPAs efforts to
provide valuable process data to the light hydrocarbons industry.

BUDGET OVERVIEW
GPSA
GPA Member Member Contributions
Contributions PERC Support Total
Continuing Projects
131 - Distribution of Methanol in Amine Treating Systems $51,500.00 $63,500.00 $115,000.00
132 - Mercury Solubility in Various Gas Processing Solvents $56,250.00 $68,750.00 $125,000.00

New Projects
141 - Solubility of Hydrocarbons in Amine Treating Solutions $51,500.00 $63,500.00 $115,000.00
142 - Extended Mercaptan VLE in Loaded Amines $51,500.00 $63,500.00 $115,000.00
143 - Extension of Acid Gas Transport Properties near Critical Phase Envelope $51,750.00 $63,250.00 $115,000.00
144 - GPA Section B Round Robin Project (Precision Data) $22,500.00 $27,500.00 $ 50,000.00
Total 2014 Budget $285,000.00 $350,000.00 $635,000.00
New Projects
Project 141 Solubility of Hydrocarbons in Amine Treating Solutions
Objective: To extend the solubility measurements of hydrocarbons (aromatics and paraffins) in amine solutions to include the effects of
acid gas loadings. These data will be used to estimate emissions from amine units and to estimate hydrocarbon carryover into downstream
sulfur processing facilities.
Background/Description: This project continues GPAs research program on the impact of hydrocarbon solubility in amine solutions
on emissions from amine units, and operations of downstream units.
The program was first initiated by Project 971, which quantified the solubility of aromatics (benzene, toluene, ethylbenzene, and
xylenes), in unloaded amine solutions. The EPA has promulgated a number of emission standards that are applicable to the aromatics, and
in particular, benzene. In addition, aromatics absorbed in an amine unit tend to deactivate the catalyst in the downstream Claus unit. This
catalyst deactivation reduces sulfur recovery efficiency and increases sulfur emissions. This research area was further extended by Project
011 to the measurement of the solubility of a series of paraffins: n-hexane, 2,2,4-trimethylpentane and cyclohexane.
This current research project aims to extend these measurements to quantify the influence of acid gas loadings on the solubility of these
heavy hydrocarbons: benzene, toluene, ethylbenzene, xylenes, n-hexane, 2,2,4-trimethylpentane and cyclohexane. These measurements,
along with the existing data in unloaded amine solutions, will provide the GPA with a comprehensive understanding of heavy hydrocarbon
solubility in amine solutions.
This project is an extension of a number of previous GPA projects looking at the solubility of hydrocarbons in loaded and unloaded
amine solutions including RR-180, 185, 195, and 206, as well as Project 071. The previous projects have concentrated on two amine systems,
MDEA and DGA, both loaded and unloaded with several model hydrocarbons, primarily toluene and cyclohexane. The current project will

expand to other amines (including DEA and MEA), as well as measure the influence of CO2 and H2S (so called loaded amines.)
Value to Industry: Accurate hydrocarbon solubility data will be used to develop new equation of state correlations that can be applied
to the simulation of amine units. These data will be used to optimize the design and operation of amine units in which these hydrocarbons
are present in the feed gas. These data will provide a basis for accurately predicting the distribution of the heavier hydrocarbons between
the treated gas, the amine flash gas, and the acid gas streams. These data will provide a basis for accurately predicting emissions of these
hydrocarbons from the amine unit to aid in the design and operation of these units.
Estimated Duration: 2 years
2014 Budget: $115,000
Future Costs: $115,000
Project Coordinator: Mike Hegarty, H2W United
Project 142 Extended Mercaptan VLE in Loaded Amines

Objective: To build on earlier GPA-sponsored measurements of vapor-liquid equilibrium (VLE) of sulfur species in loaded amines.
These data will aid in understanding the distribution of sulfur species in amine plants, and thus help to estimate how much mercaptan (and
other sulfur species) can be removed by a given amine.
Background: Aqueous amines are often used to remove contaminants such as H2S and CO2 from natural gas. In many cases, other
species (COS, CS2, and mercaptans) also contaminate the raw gas. Since there is usually a total sulfur specification on the treated gas, it is
necessary to understand how these sulfur-containing molecules distribute themselves throughout the treating process.
Recent GPA-sponsored work in this area involved the collection of data for n-propyl and n-butyl mercaptan, plus dimethyl sulfide (DMS)
in unloaded and loaded solutions of MDEA and DEA. The proposed project plans to collect VLE data on sulfur species like methyl- and
ethyl-mercaptan in solutions of other amines such as DGA and piperazine/MDEA, for both loaded and unloaded solutions. This selection of
amines (along with earlier work on MDEA and DEA) covers a wide range of natural gas treating applications.
Value to Industry: This work will provide the gas industry with more data to improve models that can be used to design better amine
treating systems, as well as to improve the operation of existing plants. Stricter environmental regulations further increase the need for such
data.
2014 Budget: $115,000
Project Coordinator: Stanley Huang, Chevron Energy Technology Co.
Project 143 Extension of Acid Gas Transport Properties near Critical Phase Envelope
Objective: To determine heat capacity, density, thermal conductivity and viscosity for specification of the compression and cooling
equipment required for acid gas injection near the critical pressure and temperature. The data shall be provided for a predefined mixture (or
mixtures) of hydrogen sulfide, carbon dioxide, methane and water.
Background: Acid gas injection involves compressing the blend of acid gas, water and hydrocarbon commonly produced during
sour gas sweetening. This acid gas blend is compressed to a pressure suitable for injection into the designated formation. Measuring the
transport properties near the critical point of the phase envelope will improve the specification of equipment and operating conditions.
A previous project, (GPA Project 042), examined the transport properties and hydrate formation for acid gas over a range of pressure,
temperature and gas compositions. This study shall focus on the transport property data only at near critical point pressure and temperature.
Value to Industry: Measuring the transport properties will allow reduction of design margins and thus lower cost of design. Improved
knowledge of the transport properties will also improve selection of operating conditions for multi stage compression and cooling for acid
gas injection.
2014 Budget: $115,000
Project Coordinator: Tim Cullinane, ExxonMobil

Project 144 GPA Section B Round Robin Project

Objective: To establish precision statements for four existing GPA Analytical Standards that currently lack the reference data set
required for the development. The Standards are:
1. GPA 2103-03, Tentative Method for the Analysis of Natural Gas Condensate Mixtures Containing Nitrogen and Carbon Dioxide by Gas
Chromatography
2. GPA 2186-02, Method for the Extended Analysis of Hydrocarbon Liquid Mixtures Containing Nitrogen and Carbon Dioxide by
Temperature Programmed Gas Chromatography
3. GPA 2199-99, The Determination of Specific Sulfur Compounds by Capillary Gas Chromatography and Sulfur Chemiluminescence
Detection
4. GPA 2286-95, Tentative Method of Extended Analysis for Natural Gas and Similar Gaseous Mixtures by Temperature Programmed Gas
Chromatography
Background: Round-Robin testing has been utilized by GPA Section B for the production of data used for the development of precision
statements for certain analytical standards. Currently, precision statements exist for five of the fifteen standards. Six of the ten standards may
not require precision statements. The four listed above need precision statements.
Value to Industry: The Precision Statements in analytical methods allow the users of analytical data to understand the accuracy of
the data. Understanding the accuracy of these data can help define expectations related to overall product measurement and uncertainty
associated with the analytical data. Reasonability assessments of the data require defined precision parameters. Since the analytical data
provided by these methods affects both quantity and quality of products analyzed, the financial ramifications are directly related to the
analytical accuracy.
2014 Budget: $50,000
Future Cost: $50,000
Project Coordinator: Joe Landes, SPL Inc.
Continuing Research
Project 131 Distribution of Methanol in Amine Treating Systems
Objective: To measure the distribution of methanol in aqueous amine treating systems. These data will be used to estimate methanol
emissions from amine units, estimate methanol carryover into downstream sulfur processing, and estimate the quantity of methanol in the
treated gas and amine flash gas streams.
Background/Description: Methanol injection is commonly used as a preventative for hydrates and ice formation in both natural gas
production and gathering systems. As a result residual methanol in the natural gas will be introduced into an amine treating system if the
removal of CO2 and/or H2S is required.
It is well known that aqueous amine solvents have a high affinity for methanol. These solvents tend to absorb a significant fraction of
the methanol present in the feed gas. The ultimate disposition of the methanol between the treated gas, amine flash gas, and stripped acid
gas stream will depend on the design and operating parameters of the amine system.
Significant methanol present in a CO2 vent stream will impact VOC emissions, as well as the design and operation of the downstream
thermal oxidizer. Similarly, significant methanol in the acid gas feed to the Claus Sulfur Recovery Unit can cause premature catalyst
degradation, leading to lower sulfur recoveries and higher sulfur emissions. Finally, high levels of methanol in the treated gas can result in
excessive levels of oxygenated hydrocarbon (methanol) in the NGL liquid product stream from the downstream NGL Recovery Unit.
This project is an extension of a number of previous GPA projects looking at distribution of water-methanol-hydrocarbons including
RR-117, 177, 184, and 198. The initial project will concentrate on two amine systems, unloaded MDEA and DGA. Subsequent projects will
expand to other amines as well as measure the influence of CO2 and H2S (so called loaded amines.)

Value to Industry: In basic terms, this data will help designers and operators of amine systems avoid operations issues, emissions
violations, and off-spec products. Specifically, accurate methanol solubility data will be used to develop new equation of state correlations
that can be applied to the simulation of amine units. The data will be used to optimize the design and operation of amine units in which
methanol may be present in the feedgas. The data will provide a basis for accurately predicting the distribution of methanol between the
treated gas, the amine flash gas, and the acid gas streams.
2014 Budget: $115,000
Future Cost: None
Investigator: LTP
Project Coordinator: Dr. Gerhard Lauermann, Linde Engineering Division
Project 132 Mercury Partitioning Solubility in Various Gas Processing Solvents

Objective: To determine solubility data for elemental mercury in typical solvents used for gas conditioning at conditions that closely
resemble key separation equipment in gas plants. Specifically, the work includes:
Literature search of existing mercury solubility data with relevant glycol, methanol and amine systems
Measurement of liquid concentrations of mercury in selected glycol (MEG, TEG), amine (MEA, MDEA) and MeOH solutions
The scope of this project also includes a number of solubility measurements in common amine solvents, both with and without acid
gas loading.
Background: Mercury occurs in gas plant streams in elemental (metallic), organic and inorganic forms. Although the reasons may
vary, in most cases the presence of these mercury compounds cannot be tolerated and they must be removed. Some specific examples of
potential hazards if left untreated:
Mercury will attack brazed aluminum type heat exchangers in cryogenic facilities. A number of exchanger failures have been
attributed to mercury corrosion.
Mercury presents a health hazard when vented to atmosphere e.g., in glycol or amine regenerator vents.
In its inorganic form, dissolved in aqueous streams it may be a health hazard when discharged through a waste water stream.
Mercury in production sludge presents a disposal problem.
Mercury may also harm catalysts in downstream facilities that process gas plant products.
Previous projects examined options available to the gas processor for the removal of mercury in its various form (Project 051.1) and
determined the solubility of elemental mercury in various light hydrocarbon systems (Project 051.2). GPA Project 113 laid the foundation for
the subject of this RFP by measuring the solubility of elemental mercury in a number of pure solvents that are commonly found in the gas
processing industry, namely methanol, mono-ethylene glycol (MEG) and tri-ethylene glycol (TEG).
Value to Industry: Gas processing plant operators must be able to accurately predict the distribution of mercury in the various plant
streams. Based on this knowledge, appropriate removal facilities can be designed and installed to ensure safe and trouble free operation.
Similarly, this project will assist the plant designer in ensuring that environmental limitations on plant effluent streams relative to mercury
are properly addressed.
2014 Budget: $125,000
Future Cost: None
Investigator: Wiltec Research Co.
Project Coordinator: Al Goethe, Enterprise Products Operating

PREVIOUSLY FUNDED PROJECTS

In 2014 a total of 30 research projects are underway or proposed. Continuing and new projects for 2014 are described in the Project
Descriptions section. Other projects, whose funding was approved in previous years, are in various stages of completion. These projects
are briefly summarized below.
PROJECT 921 (Ongoing) Enthalpy and Phase Equilibrium Database

This is an ongoing project to maintain an up-to-date, PC-compatible, database of validated experimental and phase equilibrium data
that are needed for the proper design and operation of gas gathering and processing equipment. These data are particularly important in
designing heat exchangers and towers at low temperature, high pressure, or high acid gas conditions. This project is one of the projects
funded from the annual budget provided by GPSA Data Book funds and overseen by the Technical Committee. The 2009 GPA Data Bank,
5th and latest edition delivers over 35 years of GPA research data for immediate, productive use in process simulation tools. Included is a
completely remastered thermophysical property database with all 219 Research Reports and Technical Publications and powerful data
fitting, correlation, and phase equilibrium software. The GPA Data Bank is over twice the size of previous versions and includes a signficant
amount of new VLE data for low-boiling hydrocarbons.
Investigator: Epcon
Project Coordinator: Cal Spencer, KBR
PROJECT 035 (Final Report Under Review) Equilibrium Data between Heavy Hydrocarbons and
Light Hydrocarbons at Cryogenic Temperatures
This project is to perform a literature search and measure new data to check and improve the accuracy of the GPA correlation to predict
the freeze point of aromatics and heavy hydrocarbons in multi-component streams.
Project Coordinator: Cal Spencer, KBR
PROJECT 042 (Final Report Under Review) Acid Gas Injection Design Data
This project is to develop data specific to design and operation of acid gas injection facilities. Measuring physical property data and
hydrate formation conditions will allow lower cost designs and improved operations. These data measured by this project will allow lower
cost designs and improved operations of acid gas injection facilities.
Project Coordinator: Craig Schubert, Dow Chemical Co.
PROJECT 051.2 (Ongoing) Elemental Mercury Equilibrium Data in Selected Saturated Hydrocarbons
The first phase of the project (published as RR-191) was a survey of commercially available mercury removal technologies provide key
engineering and economical parameters. The survey included technologies for elemental, organic and inorganic mercury in gas, liquid and
aqueous streams. Phase II will experimentally determine distribution of mercury in gas plant streams. Experimental data for the distribution
of elemental mercury will provide design and plant engineers with a basis for establishing optimum removal concepts for mercury. Together
with the survey of available removal technology this will provide the industry with solid strategies to control mercury for the benefit of
increased equipment life as well as compliance with product and effluent specifications.

PROJECT 052 (Work Completed, Published as RR-219) Methanol Distribution (as a contaminant) in
Fractionation Products and Freeze Out boundaries
The purpose of this project is to enhance cryogenic plant designs and operation by determining the impact, solubility, and freezing
concentration of methanol pressure range of 200-1000 psia and a temperature range of -200 to +200 degrees F. This research will be of
benefit to LNG plants, high recovery cryogenic plants, and NRU plants. The results will provide guidance on inlet specifications and on
methanol distribution in product streams.
Investigator: ARMINES
Project Coordinator: Dr. Gerhard Lauermann, Linde Engineering Division
PROJECT 071 (Final Report Under Review) Solubility of Heavy Hydrocarbons in Loaded Amine Solutions
This is an ongoing project to extend the solubility measurements of heavy hydrocarbons (aromatics and paraffins) in amine solutions to
include the effect of acid gas loadings. These data will be used to estimate emissions from amine units and to estimate hydrocarbon carryover
into downstream sulfur processing. Accurate hydrocarbon solubility data will be used to develop new equation of state correlations that can
be applied to the simulation of amine units. These data will be used to adjust conditions in the amine unit to reduce the absorption of the
troublesome hydrocarbons. These data will provide a basis for accurately predicting the emissions of these hydrocarbons from the amine
unit as required by the Clean Air Act.
Investigator: LTP GmbH Oldenburg
Project Coordinator: Mike Hegarty, H2W United
PROJECT 072 (In Progress) Distribution of Sulfur Species in 3-Phase Separators

This is an ongoing project that, when complete, will provide an accurate prediction as to how sulfur species partition in an inlet
separator of any typical gas processing plant involving three phases: aqueous liquid, hydrocarbon liquid, hydrocarbon vapor. At present,
downstream sulfur species removal processes for hydrocarbon gas, hydrocarbon liquid and water are not always optimized with the right
degree of treatment, resulting in unnecessarily expensive processing costs, as well as emission and waste disposal problems. This project
will measure data to allow accurate prediction of the distribution of sulfur species in the various streams coming out of 3-phase separators.
The effect of the presence or absence of impurities such as methanol in the water phase will also be determined.
Project Coordinator: Kindra Snow-McGregor, John M. Campbell
PROJECT 074 (In Progress) Effect of Gas Gravity, H2S, and Salinity on the Water Content in Natural Gas
This is an ongoing project with the goal of extending the work completed under Project 032 to mixtures with heavier hydrocarbons
(e.g. gravity > 1.0), mixtures with CO2, H2S, and to verify the salinity correction.
The revision of the McKetta chart and the new thermodynamic model are based on the data measured under Project 032, data
measured under other GPA projects (e.g. RR-174, RR-187), data provided by member companies (e.g. TP-28) and literature data. This work
has identified the need for follow-up work beyond the original scope to fill-in gaps and address inconsistencies in the exisiting data. For
example, some recent data are inconsistent with the historical correction for gas relative density.
Investigator: Alberta Sulfur Research Ltd.
Project Coordinator: Raymond French, Shell Global Solutions

PROJECT 082 (In Progress) Impact of Aromatics on Acid Gas Injection

The objective of this project is to determine the impact of aromatic compounds on phase behavior for acid gas mixtures. The focus
will be to determine vapor-liquid equilibrium of the mixtures to allow determination of the dew point. The hydrate formation conditions
will be determined for the liquid phases in equilibrium with the acid gas. The research will study several different acid gas compositions to
determine the phase behavior with four overall mixtures of acid gas (0/100, 25/75, 50/50, and 75/25 hydrogen sulfide/carbon dioxide as
used in previous work) and a range of concentrations of aromatic compounds from about 1000 ppm(v) to 5000 ppm(v) in the vapor phase.
Various individual compounds or combinations of aromatic compounds (benzene, toluene, ethyl benzene, and xylenes) will be used. Water
will be included as a component in the system and a small amount of methane and other light paraffin hydrocarbons (about 1% total) will
be included in all mixtures. The goal is to determine the dew point at pressures between 200 psia and 1100 psia (14 to 75 bar); however,
with the low concentrations of condensable components it is expected to be difficult to accurately determine the dew point by direct
measurement. Instead, it will be necessary to perform vapor-liquid equilibrium (VLE) measurements on richer mixtures that will produce
vapor phase aromatic concentrations in the desired range. Hydrate measurements will be made in a typical acid gas liquid.
Investigator: Armines
Project Coordinator: Chris Root, DCP Midstream
Project 084 (Project Extension Ongoing) Propane-Water-Methanol Mutual Solubilities & Freeze Protection
This is an extension of the work which was fully funded with PERC funds exclusively in 2008. This GPA Project 084 will be limited to
collecting the basic water content data to determine the soluble limits of water in pure propane and commercial propane mixtures, and
collect water / methanol / propane mutual solubility and concentration needed to prevent freezing / hydrate formation. These data will
be fundamental to alerting propane producers and purchasers to acceptable water content, and what concentration of methanol may be
used to negate operating problems where excessive water is present. The equilibrium methanol concentration resulting in the propane
product will also be determined.
Project Coordinator: Jeff Mathews, URS
PROJECT 085 (Final Report Under Review) Freeze Valve Water Content in LPG Systems
The objective of this work is to obtain water content data in LPG mixtures, which is correlated to results from the freeze valve test
method (ASTM D-2713). Development of basic data and a suitable correlation for prediction of freezing based on moisture content of LPG
product streams will allow the industry to gradually retire the freeze valve test in favor of more automated methods. In addition, it will
improve safety and eliminate the emissions associated with the freeze valve method. This project was specifically chosen by GPA Section F
for the Propane Education Research Council (PERC) for their generosity in contributing to the GPA Research Program.
Investigator: Epcon
Coordinator: Dan McCartney, Black & Veatch
PROJECT 101 (In Progress) Corrosion in Acid Gas Injection Systems

The objective of this project is to ascertain conditions and compositions that result in corrosion in acid gas injection systems and to
establish reasonable specifications for acid gases that are to be re-injected via these systems.
Re-injection of carbon dioxide or combined acid gases is becoming increasingly important. The applications range from acid gas
disposal to the looming issue of carbon sequestration. Common to these injection systems is a high pressure pipeline transport system
and the need for gas clean-up to prevent damage to pipelines and injection wells. For instance, water removal may be needed, since the
mechanism of corrosion due to the presence of liquid water in these systems is well understood and documented.
Some think that corrosion may also occur in the absence of free water in a single (dense) phase system containing acid gases and
water. Also, depending on the source of the acid gases, other corrosive compounds such as oxygen, SO2, SO3 or NOx may be present. The
objective of this project is to ascertain conditions and compositions that result in corrosion and to establish reasonable specifications for
acid gases that are to be re-injected via these systems. At present, default specifications are being established by the few operators of
systems associated with EOR.
Investigator: Trimeric/Honeywell
Project Coordinator: Scott Northrop, ExxonMobil

PROJECT 102 (In Progress) High Pressure (1200 psia to 5000 psia) Hydrocarbon Mixtures
Thermophysical Property and Vapor / Liquid / Equilibrium Data
The project will focus on the measurement of hydrocarbon mixture properties at elevated pressures. The purpose of this project is
to fill gaps in hydrocarbon mixture data that are used for equipment design. The properties that will be measured are density, viscosity,
thermal conductivity, surface tension, heat capacity, and vapor / liquid K values for the two phase mixtures, focusing in the region of the
cricondenbar. This project will supplement the recent high pressure gas studies completed by GPA:
Project 985 High Pressure Gas Separation and Conditioning (maximum pressure studied was 2500 psia)
Project 061 Part 1 Glycols Transport Properties (maximum pressure studied was 2000 psia)
Project 043 High Pressure Demethanizer Physical Properties (pressures from 700 to 1000 psia)
Specific data gaps include heat capacity data of natural gas mixtures at near-critical, two-phase conditions. These data are important
for heat exchanger and compressor design. Similar gaps exist for viscosity and thermal conductivity, which are also important properties for
equipment design. Existing predictive models for transport and physical properties of mixtures cannot be validated for natural gas mixtures
near the critical point at temperature and pressure around -90F and 825 psig ( 0.95<TR<1.1 and PR>1.0) due to lack of data.
Investigator: University of Western Australia/Minerals & Energy Research Institute of Western Australia
Project Coordinator: Brett Eldred, Targa Resources
Project 111 (RFP Development) Comparison of GPA Data to Simulator Predictions

This project is to compare the ability of commercially available simulators which are widely used in the oil and gas industry to predict
high quality laboratory scale data. The scope includes but is not limited to data contained in GPA research reports. The scope includes single
phase mixtures, two phase systems and three phase systems.
Investigator: TBD
Project Coordinator: Mark Johnson, BP
Project 112 (In Progress) CO2 Freezing in Cryogenic Processes

This proposed research project is intended to extend solubility and enthalpy measurements of solid CO2 in gaseous and liquid
hydrocarbons at cryogenic conditions. These data will be used to improve simulations of cryogenic processes involving CO2-containing
gases, including extractive distillation processes like Ryan-Holmes.
Investigator: Armines
Project Coordinator: Scott Northrop, ExxonMobil
PROJECT 113 (In Progress) Mercury Partitioning in Gas Processing Systems

This project is to determine the elemental mercury concentrations in the vapor and liquid phases of various common gas processing
systems. This project is the continuation of Project 051 (Mercury in Gas Processing Plants). The new project will address the mercury
distribution in important systems not included in the previous work, focusing on less volatile systems such as natural gas liquids (NGL) as
well as selected glycols and amines.
Project 121 (In Progress) Solubility of Amines and TEG in Dense Phase Gases (Natural Gas and CO2)
This project is to establish solubility data of amines (DEA, MDEA) and tri-ethylene glycol (TEG) in dense phase natural gas (methane,
ethane) and CO2 mixtures at temperatures and pressures valid for contactor conditions, as well as, transportation systems downstream. Data
within a range of pressures and temperatures are needed to predict where and how much will precipitate or drop out. These data, which
is currently lacking in the industry, is needed as a basis for predictive model development and validation.
Investigator: Trimeric Corp.
Project Coordinator: Lars Gjertsen, Statoil ASA

Project 122 Solubility of Hydrocarbons in Aqueous Piperazine and Aqueous

Piperazine/MDEA Systems and Associated Transport Properties
This project is an extension of Projects 061 and 071 and will focus on the measurement of hydrocarbon (HC) solubility in aqueous
Piperazine and Piperazine-activated MDEA solutions at varying solution strengths. In addition, this project will measure physical transport
properties of these solutions. Measured data will cover typical operating temperatures and pressures, and will include a comprehensive
range of light hydrocarbons, including aromatic compounds. Physical transport properties measured will be viscosity density, thermal
conductivity and heat capacity.
Investigator: SINTEF
Project Coordinator: Hvard Lidal, Statoil ASA
Project 133 Co-Funded Project GPA/API Precision Improvement -

High Performance Densitometer Calibration and Master Metering Proving Methodology
This project is to develop a master meter density proving method for hydrocarbon liquids, including densitometer calibration coefficients
for various operating conditions. The master meter density proving method may also have applications for proving densitometers measuring
viscous hydrocarbons which do not lend themselves to Pycnometer proving. The scope will include:
Improvement of density measurement precision by determining the calibration constants within the operating range of hydrocarbon
liquids at the pressure, temperature and composition ranges expected at the density meters installed location.
Development of a master density meter proving method as an alternative to the pycnometer method which has the same
performance level as pycnometer proving, while reducing the complexity and time required for the proving.
Investigator: MV Atchison and Associates
Project Coordinators: Don Sextro, Targa Resources, GPA Technical Section H
Sally Goodson, API

AUTHORIZATION and FUNDING PROCEDURES

Adequate and equitable funding, with a rigid approval procedure and continuing oversight, are key elements in the impressive
accomplishments of the GPA research program. Details of the authorization and funding procedure may be summarized as follows:
1. Research proposals usually originate in one of the two sub-groups of Section F (Technical Data Development) or other Working
Sections of the GPA Technical Committee. The sub-groups are made up of research engineers and other technical specialists. Other
Technical Sections are staffed by appropriate experts appointed by member companies. The responsible Sub-group or Section will
outline a research schedule for a suitable project and recommend a level of funding to be incorporated in the general research
budget.
2. Project proposals are submitted to the Technical Committee for general endorsement. The Technical Committee represents all
phases of GPA technical interest and thus provides an appropriate screen to ensure projects of specific need and broad industry
application.
3. The proposal next goes to the Board of Directors, which must approve the project(s) by a majority of those present at the meeting.
Once project proposals are approved by the GPA Board of Directors, the project is considered approved by GPA membership and
will move forward with each GPA member company receiving their GPA dues invoice, including their portion of the GPA cooperative
research program funding portion which is based on that companys midstream man hours reported for that year on a tiered
structure.
4. Following GPA Board approval and assured funding of a project, the originating Sub-group or Technical Section develops a detailed
Request for Proposal which defines the problem, outlines work needed, and specifies funds necessary. Generally, proposals are
solicited from select research organizations known to have facilities and interest appropriate to the proposed project.
5. Selection of the project investigator is made by the responsible Sub-group or Technical Section, and a contract is awarded. The
Committee designates a project coordinator who works directly with the investigator and exercises oversight responsibility for the
duration of the project. The project coordinator keeps the Committee and GPA staff informed on project progress, problems, and
budgetary compliance. Section F, the Technical Committee and GPA Staff are charged with the responsibility of terminating a project
if the contractors are not performing adequately as detailed in the projects agreement.
RESEARCH FISCAL SUMMARY

GPA/GPSA Non Production-Based
GPA Production-Based Member Contributions,
Members Contribution PERC Support and Research Reserve Total
1963-1970 $ 827,000
1971-1980 1,950,000
1981-1990 4,403,700
1991-2000 3,360,000 1, 2, 3, 4, 5
2001 300,000 70,000 370,000 6
2002 340,000 70,000 410,000 6
2003 300,000 150,000 450,000 7
2004 375,000 75,000 450,000 8
2005 400,000 25,000 425,000 9
2006 410,000 50,000 460,000 10
2007 505,000 25,000 530,000 8
2008 505,000 25,000 530,000 8
2009 550,000 50,000 600,000 8
2010 325,000 175,000 500,000 8
2011 255,000 300,000 (PERC) 555,000 8
2012 265,000 300,000 (PERC) 565,000 8
2013 275,000 300,000 (PERC) 575,000 8
2014 285,000 350,000 (PERC) 635,000 8
1 Does not include API co-funding of $60,000 and GRI cofunding of $400,000.
2 Does not include API co-funding of$53,200 and GRI cofunding of $900,000.
3 Does not include GRI co-funding of $900,000 (1993), $1,100,000 (1994 and 1995).
4 Does not include PERC co-funding of $100,000, API/MMS/NPRA/CMA co-funding of $100,000, and GPA Operating Fund/GPSA co-funding of $40,000.
5 Does not include PERC co-funding of $100,000.
6 Does not include PERC co-funding of $50,000 and GPSA co-funding of $25,000.
7 Does not include GPSA co-funding of $25,000 and BP co-funding of $50,000. Does include a one time grant of $50,000 from GPSA for this years program.
8 Does not include GPSA funding of $25,000.
9 Does not include GPSA funding of $25,000 nor Norsk Hydros funding of Project 031.
10 Does not include GPSA Funding of $25,000 nor Norsk Hydros $30,000 funding of Project 062.

Research Reports
Research Reports can be ordered online at www.GPAglobal.org. Click on Publications and then Order Publications. From that page,
select Research Reports for the appropriate reference number. All GPA companies will receive research reports the year of publication.
GPSA companies who are research project sponsors will also receive research reports the year of publication. All others wishing to receive
copies of GPA research reports will pay a fee of $500 per report.
RR-1 Bibliography of Data Sources for Low-Temperature Vapor-Liquid Equi- RR-12 Enthalpy and Phase Boundary Measurements on Carbon Dioxide and
libria in Non-Absorber Oil Systems - R. D. Gunn and S. V. Mainkar, Univer- Mixtures of Carbon Dioxide with Methane, Ethane and Hydrogen Sul-
sity of Texas, Austin, Texas. Project 692-A. February, 1971. fide - Grant M. Wilson and James M. Peterson, Brigham Young University,
Provo, Utah. Project 731. June, 1975.
RR-2 K-Values in Highly Aromatic and Highly Naphthenic Real Oil Absorber
Systems - Grant Wilson and Sherman T. Barton, P-V-T Inc., Houston, Tex- RR-13 Prediction of Absorber Oil K-Values and Enthalpies - John H. Erbar, Okla-
as. Project 691. March, 1971. homa State University, Stillwater, Oklahoma. Project 714. March, 1977.
RR-3 Enthalpy and Entropy of Non-Polar Liquids at Low Temperatures - K. C. RR-14 Solubility of Heavier Hydrocarbons in Liquid Methane - Fred Kurata,
Chao and R. A. Greenkorn, Purdue University, Lafayette, Indiana. April, Center For Research Inc., Lawrence, Kansas. Project 738-A. March, 1975.
1971.
RR-15 The Equilibrium Phase Properties of Selected Binary Systems at Low
RR-4 Evaluation of Eight Enthalpy Correlations - Kenneth E. Starling, David Temperature: Nitrogen-Hydrogen Sulfide, Ethane-Hydrogen Sulfide
W. Johnson and Philip C. Colver, University of Oklahoma, Norman, Okla- and n-Butane-Carbon Dioxide - D. B. Robinson and H. Kalra, University
homa. Project 68l. May, 1971. of Alberta, Edmonton, Alberta, Canada. Project 738. March, 1975.
RR-5 Experimental Measurements of Vapor-Liquid Equilibrium Data for the RR-16 Solubility Limits of Heavy Hydrocarbons in NGL and LNG Mixtures - Will
Ethane-Carbon Dioxide and Nitrogen-n-Pentane Binary Systems - Ku- DeVaney, Bert Eakin and James M. Berryman, P-V-T Inc., Houston, Texas.
rata-Swift Consulting Engineers, Lawrence, Kansas. Project 692-B. De- Project 735-A. November, 1975.
cember, 1971.
RR-17 Smoothed Experimental Enthalpy Data for Three Methane-Ethane Bina-
RR-6 Enthalpies of Methane-C7 Systems - Bert Eakin, Grant M. Wilson and Will ries and a Methane-Ethane-Propane Ternary - John E. Powers, Andre W.
E. DeVaney, P-V-T, Inc., Houston, Texas. Project 661. August, 1972. Furtado, Ravi Kant and Adriana Kwan, University of Michigan, Ann Arbor,
Michigan. Project 723. May, 1975.
RR-7 The Equilibrium Phase Properties of the Binary Systems: Nitrogen-Hy-
drogen Sulfide, Isobutane-Hydrogen Sulfide, Isobutane-Carbon Dioxide RR-18 The Equilibrium Phase Properties of Selected Binary Systems: n-Hep-
and Isobutane-Ethane - D. B. Robinson and G. J. Besserer, University of tane-Hydrogen Sulfide, n-Heptane-Carbon Dioxide and i-Butane-Ni-
Alberta, Edmonton, Alberta, Canada. June, 1972. trogen - D. B. Robinson and H. Kalra, University of Alberta, Edmonton,
Alberta, Canada. Project 745. August, 1976.
RR-8 1971-1972 Enthalpy Correlation Evaluation Study - Kenneth E. Starling,
University of Oklahoma, Norman, Oklahoma. Project 713. October, RR-19 Vapor Phase Data for the Binary Systems of Methane with n-Butane, n-
1972. Pentane, n-Hexane and n-Heptane - Roger J. J. Chen, Patsy S. Chappe-
lear and Riki Kobayashi, Rice University, Houston, Texas. Project 692-B.
RR-9 Enthalpies of Hydrogen Sulfide-Methane-Ethane Systems - Bert Eakin September, 1976.
and Will E. DeVaney, P-V-T Inc., Houston, Texas. Project 722. February,
1975. RR-20 K-Values for the Methane-n-Butane, Methane-n-Pentane and Methane-
n-Hexane Systems - Doug Elliot, Y. N. Lin, T. C. Chu, Patsy S. Chappelear
RR-10 Solubility of Solid Carbon Dioxide in Pure Light Hydrocarbons and Mix- and Riki Kobayashi, Rice University, Houston, Texas. Project 692-B. Sep-
tures of Light Hydro-carbons - Fred Kurata, Center for Research Inc., tember, 1976.
Lawrence, Kansas. February, 1974.
RR-21 Dew-Point Values for the Methane-Carbon Dioxide System - S. C.
RR-11 GPA Experimental Enthalpy Values Referred to Two Base Levels - John Hwang, Ho-Mu Lin, Patsy S. Chappelear and Riki Kobayashi, Rice Univer-
M. Lenoir and Gene A. Cochran, University of Southern California, Los sity, Houston, Texas. Project 739. September, 1976.
Angeles, California. Project 733. September, 1974.
RR-22 Solubility of Hydrocarbons in Cryogenic LNG and NGL Mixtures - James
P. Kohn and Kraemer D. Luks, University of Notre Dame, Notre Dame,
Indiana. Project 735. December, 1976.

RR-23 Measurement of Ethane and Propane Recovery and Total Fraction Con- RR-35 Computer Simulations of Vapor-Liquid Compositions of Propane-Bu-
densed for Simulated Natural Gas Mixtures - Grant M. Wilson, John R. tane Mixtures in Cold Weather Field Tests - Thomas H. May and Dorab
Cunningham, B. Steve Lofgren and Veldon E. Messick, Thermochemical N. Baria, University of North Dakota, Grand Forks, North Dakota. Project
Institute, Brigham Young University, Provo, Utah. Project 737. May, 1977. 789-B. March, 1979.
RR-24 Enthalpy and Phase Boundary Measurements on Mixtures of Nitrogen RR-36 Literature Survey for Synthetic Gas Components-Thermodynamic
with Methane, Carbon Dioxide and Hydrogen Sulfide - Grant M. Wilson, Properties - P. Pendergraft, M. Marston, M. Gonzales, V. Rice and J. Erbar,
John R. Cunningham and Paul F. Nielsen, Brigham Young University, Oklahoma State University, Stillwater, Oklahoma. Project 746. October,
Provo, Utah. Project 741. May, 1977. 1979.
RR-37 Enthalpy Measurements on Synthetic Gas Systems: Hydrogen-Meth-
RR-25 The Vapor-Liquid Equilibrium of the CH4-CO2 System at Low Tempera- ane, Hydrogen-Carbon Monoxide - James M. Berryman, Will E. DeVaney,
tures - S. C. Mraw, S. C. Hwang and Riki Kobayashi, Rice University, Hous- Bert E. Eakin and Nancy L. Bailey, P-V-T, Inc., Houston, Texas. Project 742.
ton, Texas. Project 739. April, 1977. August, 1979.
RR-26 Statistical Thermodynamics of Solutions in Natural Gas and Petroleum RR-38 A Preliminary Version of the PHC Equation of State Computerized for
Refining - M. D. Donohue and J. M. Prausnitz, University of California, Engineering Calculations - E. C. Hohmann, California State Polytechnic
Berkeley, California. Project 721. July, 1977. University, Pomona, California. Project 771. May, 1979.
RR-27 Solubility of Hydrocarbons in Cryogenic LNG and NGL Mixtures - James RR-39 The Equilibrium Phase Properties of Selected m-Xylene and Mesitylene
P. Kohn and Kraemer D. Luks, University of Notre Dame, Notre Dame, Binary Systems: CH2-m-Xylene, CO2-m-Xylene, CH4-Mesitylene - D. B.
Indiana. Project 735-A. December, 1977. Robinson, H-J Ng and S-S Huang, University of Alberta, Edmonton, Al-
berta, Canada. Project 755-B. May, 1979.
RR-28 The Characterization of the Heptanes and Heavier Fractions for the GPA
Peng-Robinson Programs - D. B. Robinson and D. Y. Peng, University of RR-40 Measurement of Ethane and Propane Recovery and Total Fraction
Alberta, Edmonton, Alberta, Canada. Project 756. March, 1978. Condensed in the Bubble Point Region of Two Simulated Natural Gas
Mixtures - John R. Cunningham, John L. Oscarson and Mark L. Jenson,
RR-29 The Equilibrium Phase Compositions of Selected Aromatic and Naph- Brigham Young University, Provo, Utah. Project 737. February, 1980.
thenic Binary Systems: Toluene-Carbon Dioxide, Toluene-Hydrogen
Sulfide, Methylcyclohexane-Carbon Dioxide and Methylcyclohexane- RR-40-A Phase Equilibria of a High Nitrogen Content Synthetic Natural Gas -
Hydrogen Sulfide - D. B. Robinson and H-J Ng, University of Alberta, James P. Kohn and Robert C. Merrill, University of Notre Dame, Notre
Edmonton, Alberta, Canada. Project 755, 755A and 757B. March, 1978. Dame, Indiana. Project 795. February, 1982.
RR-30 High Temperature V-L-E Measurements for Substitute Gas Components RR-41 Vapor-Liquid Equilibrium Data on Water-Substitute Gas Components:
- Will DeVaney, James M. Berryman, Pen-Li Kao and Bert Eakin, P-V-T, Inc., N2-H2O, H2-H2O, CO-H2O and H2-CO-H2O and H2S-H2O - Paul C. Gillespie
Houston, Texas. Project 757. February, 1978. and Grant Wilson, Wilco Research Co., Provo, Utah. Project 758-B. April,
1980.
RR-31 The Equilibrium Phase Properties of a Synthetic Sour Gas Mixture and
a Simulated Natural Gas Mixture - D. B. Robinson, H. Kalra and Hans RR-42 Predicting Synthetic Gas and Natural Gas Thermodynamic Properties
Rempis, University of Alberta, Edmonton, Alberta, Canada. Project 737- Using a Modified Soave Redlich Kwong Equation of State - J. H. Erbar, A.
A & 737-B. May, 1978. K. Jagota, S. Muthswamy and M. Moshfeghian, Oklahoma State Univer-
sity, Stillwater, Oklahoma. Project 752. August, 1980.
RR-32 Vapor-Liquid Compositions of Propane-Butane Mixtures in Cold Weath-
er Field Tests - Thomas H. May and Dorab N. Baria, University of North RR-43 The Equilibrium Phase Properties of Selected m-Xylene and Mesitylene
Dakota, Grand Forks, North Dakota. Project 789-A. May, 1978. Binary Systems: m-Xylene-Mesitylene-H2S, Mesitylene-CO2 - D. B. Rob-
inson and S-S Huang, University of Alberta, Edmonton, Alberta, Canada.
RR-33 Solubility of Hydrocarbons in Cryogenic LNG and NGL Mixtures - James Project 755-B. June, 1980.
P. Kohn and Kraemer D. Luks, University of Notre Dame, Notre Dame,
Indiana. Project 735. November, 1978. RR-44 Vapor-Liquid and Liquid-Liquid Equilibria in the Methane-Toluene Sys-
tem and Relation of Liquid-Liquid Equilibrium Behavior at Low Tem-
RR-34 Sour Water Equilibria: Ammonia Volatility Down to ppm; Effect of Elec- peratures to Vapor-Liquid Equilibria Behavior at High Temperatures
trolytes on Ammonia Volatility; pH vs. Composition - Grant Wilson, Rich- and Elevated Pressures - Yeuh-Neu Lin, Shuen-Cheng Swang and Riki
ard S. Owens and Marshall W. Roe, Wilco Research, Provo, Utah. Project Kobayashi, Rice University, Houston, Scott W. Hopke, Exxon Production
758-A. November, 1978. Company, Houston, Texas. Project 757. December, 1980.

RR-45 The Water Content and Correlation of the Water Content of Methane in RR-54 The Equilibrium Phase Behavior of Several Solute Gases in the Solvent
Equilibrium with Hydrates, (I); and the Water Content of a High Carbon Phenanthrene - Robert L. Robinson, Jr., Philip J. Carlberg, John J. Heid-
Dioxide Simulated Prudhoe Bay Gas in Equilibrium with Hydrates, (II) man and Yick-Kwan Chen, Oklahoma State University, Stillwater, Okla-
- Keichi Aoyagi, Kyoo Y. Song and Riki Kobayashi, Rice University, Hous- homa. Project 757-A. November, 1981.
ton, Texas, E. Dendy Sloan and P. B. Dharmawardhana, Dept. of Chemical
Engineering, Colorado School of Mines, Golden, Colorado. Project 775. RR-55 Phase Equilibrium Studies for Methane/Synthesis Gas Separation: The
December, 1980. Hydrogen-Carbon Monoxide-Methane System - Joint research report
for GPA and Gas Research Institute. Jane Huey Hong and Riki Kobayashi,
RR-46 Vapor Liquid Equilibrium Study of the H2-CH4 System at Low Tempera- Rice University, Houston, Texas. Project 757. November, 1981.
tures and Elevated Pressures - Joint research report for GPA and Gas
Research Institute. Jane Huey Hong and Riki Kobayashi, Rice University, RR-56 Measurement of Total Fraction Condensed and Phase Boundary for a
Houston, Texas. Project 757. December, 1980. Simulated Natural Gas - Joint research report for GPA and Gas Research
Institute. John L. Oscarson and Bert Saxey, Brigham Young University,
RR-47 Behavior of CH4-CO2-H2S Mixtures at Sub-Ambient Temperatures - Provo, Utah. Project 737. May, 1982.
Joint research report for GPA and Canadian Gas Processors Association.
D. B. Robinson, H-J. Ng and A. D. Leu, University of Alberta, Edmonton, RR-57 The Phase Behavior of Two Mixtures of Methane, Carbon Dioxide, Hy-
Alberta, Canada. Project 738-A. January, 1981. drogen Sulfide and Water - D. B. Robinson, S-S Huang, A. D. Leu and H-J
Ng, University of Alberta, Edmonton, Alberta, Canada. Project 758-A.
RR-48 Vapor-Liquid and Liquid-Liquid Equilibria: Water-Methane; Water- February, 1982.
Carbon Dioxide; Water-Hydrogen Sulfide; Water-nPentane; Water-
Methane-nPentane - Paul Gillespie and Grant Wilson, Wiltec Research RR-58 The Equilibrium Phase Properties of Selected Naphthenic Binary Sys-
Company, Provo, Utah. Project 758-B. April, 1982. tems: Ethylcyclohexane-Carbon Dioxide, Ethylcyclohexane-Nitrogen
and Ethylcyclohexane-Methane - D. B. Robinson, C-J Chen and H-J Ng,
RR-49 Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures - James P. University of Alberta, Edmonton, Alberta, Canada. Project 755-B. March,
Kohn, University of Notre Dame, Notre Dame, Indiana and Kraemer Luks, 1981.
University of Tulsa, Tulsa, Oklahoma. Project 795. March, 1981.
RR-59 Vapor-Liquid Equilibrium Measurements on the Systems N2-Toluene,
RR-49-A Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures (Raw Data) N2-m-Xylene, and N2-Mesitylene - S. Laugier, D. Legret, J. Desteve, D.
- James P. Kohn, University of Notre Dame, Notre Dame, Indiana and Richon and H. Renon, ARMINES, Paris, France. Project 755-C. June, 1982.
Kraemer D. Luks, University of Tulsa, Tulsa, Oklahoma. Project 795.
March, 1982. RR-60 Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures: Phase II -
James P. Kohn and Robert C. Merrill, University of Notre Dame, Notre
RR-50 Measurement and Interpretation of the Water Content of a Methane- Dame, Indiana and Kraemer D. Luks, University of Tulsa, Tulsa, Oklahoma.
Propane (5.31 mol %) Mixture in the Gaseous State in Equilibrium with Project 795. March, 1982.
Hydrate - Hyoo Y. Song and Riki Kobayashi, Rice University, Houston,
Texas. Project 775. January, 1982. RR-6l An Evaluation of the GPSA Engineering Data Book Volume Correction
Factor Table for Light Ends - David B. Manley, University of Missouri,
RR-51 The Equilibrium Phase Properties of Selected Naphthenic Binary Sys- Rolla, Missouri. Project 819. March, 1982.
tems: Methylcyclohexane- Nitrogen, Ethylcyclohexane-Hydrogen Sul-
fide and n-Propylcyclohexane-Hydrogen Sulfide - D. B. Robinson, S-S RR-62 Water-Hydrocarbon Liquid-Liquid-Vapor Equilibrium Measurements to
Huang and A. D. Leu, University of Alberta, Edmonton, Alberta, Canada. 530 degrees F - Joint research report for GPA and American Petroleum
Project 755-B. March, 1981. Institute. C. Jeffrey Brady, John R. Cunningham and Grant Wilson, Wiltec
Research Co., Provo, Utah. September, 1962.
RR-52 Vapor-Liquid Equilibria for Sour Water Systems with Inert Gases Pres-
ent - Jonathan L. Owens, John R. Cunningham and Grant Wilson, Wiltec RR-63 Experimental Enthalpies for Pure Toluene and Pure Methylcyclohexane -
Research Co., Provo, Utah. Project 805. April, 1982. Luis E. Cediel, Philip T. Eubank, James C. Holste and Kenneth R. Hall, Texas
A&M University, College Station, Texas. Project 792-82. December, 1963.
RR-53 Experimental Densities and Enthalpies for Water-Natural Gas Systems -
John J. Scheloske, Kenneth R. Hall, Philip T. Eubank and James C. Holste, RR-64 Development of GPA Data Bank of Selected Enthalpy and Equilibria Val-
Texas A&M University, College Station, Texas. Project 772. September, ues - Thomas E. Daubert, Pennsylvania State University, University Park,
1981. Pennsylvania. Project 806/822. March, 1983.
RR-53-A Thermophysical Properties Tables for Wet, Sweet and Sour Natural Gas- RR-64A GPA Data Bank of Selected Enthalpy and Equilibria Values - Thomas E.
es: Data Supplement to RR-53 - John J. Scheloske, Kenneth R. Hall, Philip Daubert, Pennsylvania State University, University Park, Pennsylvania.
T. Eubank and James C. Holste, Texas A&M University, College Station, Project 806/822. April, 1986.
Texas. Project 772. November, 1981.

RR-64B GPA Data Bank of Selected Enthalpy and Equilibria Values - Thomas E. RR-75 Vapor-Liquid Equilibria Measurements on the Systems N2-n-Propylcy-
Daubert, Pennsylvania State University, University Park, Pennsylvania. clohexane, CO2-n-Propylcyclohexane, CH4-n-Propylcyclohexane, CH4-
Project 806/822-89. June, 1990. n-Propylbenzene and CO2-n-Propylbenzene - S. Laugier, P. Alali, A. Valtz,
A. Chareton, F. Fontalba, D. Richon and H. Renon, ARMINES, Paris, France.
RR-64C GPA Data Bank of Selected Enthalpy and Equilibria Values - Thomas E. Project 755-C-82. February, 1984.
Daubert, Pennsylvania State University, University Park, Pennsylvania.
Project 806/822. January, 1993. RR-76 Phase Equilibrium Studies for Processing of Gas from CO2 EOR Projects-
Phase II - Project supported jointly by the Gas Processors Association
RR-65 Vapor-Liquid Equilibria for Sour Water Systems at High Temperatures - and special industry contributions. Jane Huey Hong and Riki Kobayashi,
Jonathan L. Owens, John R. Cunningham and Grant M. Wilson, Wiltec Rice University, Houston, Texas. Project 826-83. February, 1984.
Research Co., Provo, Utah. Project 805-82. August, 1983.
RR-77 Evaluation of GPA*SIM Computer Program with GPA Data Bank of Se-
RR-66 Equilibrium Phase Composition and Hydrating Conditions in Systems lected V-L-E Data - Thomas E. Daubert, Pennsylvania State University,
Containing Methanol, Light Hydrocarbons, Carbon Dioxide and Hydro- University Park, Pennsylvania. Project 806-83. May, 1984.
gen Sulfide - Joint research report for GPA and Canadian Gas Processors
Association. H-J. Ng and D. B. Robinson, D. B. Robinson & Assoc., Ltd., RR-78 Sulfur Compounds and Water V-L-E and Mutual Solubility MESH-H2O;
and University of Alberta, Edmonton, Alberta, Canada. Project 825-82. ETSH-H2O; CS2-H2O; and COS-H2O - Paul C. Gillespie and Grant M. Wil-
April, 1983. son, Wiltec Research Co., Provo, Utah. Project 758-80. May, 1984.
RR-67 Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures: Phase III-Ni- RR-79 Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures (Phase IV - Ni-
trogen Rich Systems - James P. Kohn and Robert C. Merrill, Jr., University trogen-Rich Systems) - James P. Kohn and Feliciano M. Llave, University
of Notre Dame, Notre Dame, Indiana and Kraemer D. Luks, University of of Notre Dame, Notre Dame, Indiana and Kraemer D. Luks, University of
Tulsa, Tulsa, Oklahoma. Project 795-82. May, 1983. Tulsa, Tulsa, Oklahoma. Project 795-83. June, 1984.
RR-68 Excess Enthalpy Experimental Data-Binary Systems: Water + n-Pen- RR-80 The Water Content of CO2-Rich Fluids in Equilibrium with Liquid Water
tane, Water + n-Hexane, Water + n-Heptane, Water + n-Octane - C. J. or Hydrate - Kyoo Y. Song and Riki Kobayashi, Rice University, Houston,
Wormald, C. N. Colling, N. M. Lancaster and A. J. Sellers, University of Texas. Project 775-83. May, 1984.
Bristol, Bristol, England. Project 773-A-79. May, 1983.
RR-81 Evaluation of Peng-Robinson Computer Program with GPA Data Bank of
RR-69 Evaluation of GPA*SIM Computer Program with GPA Data Bank of Se- Selected Enthalpy Values - Thomas E. Daubert, Pennsylvania State Uni-
lected Enthalpy Values - Thomas E. Daubert, Pennsylvania State Univer- versity, University Park, Pennsylvania. Project 822-83. August, 1984.
sity, University Park, Pennsylvania. Project 822-82. July, 1983.
RR-82 Vapor-Liquid Equilibria Measurements on the Systems Ethane-Toluene,
RR-70 Phase Equilibrium Studies for Processing of Gas From CO2 EOR Projects Ethane-n-Propylbenzene, Ethane-Metaxylene, Ethane-Mesitylene, Eth-
- Project supported jointly by the Gas Processors Association and spe- ane-Methylcyclohexane - S. Laugier, A. Valtz, A. Chareton, D. Richon and
cial industry contributions. Jane Huey Hong and Riki Kobayashi, Rice H. Renon, ARMINES, Paris, France. Project 755-C-83. September, 1984.
University, Houston, Texas. Project 826-82. August, 1983.
RR-83 Excess Enthalpy Experimental Data Binary Systems: Water-Carbon Mon-
RR-71 Water Content of NGL in Presence of Hydrates - Kevin A. Sparks and E. oxide, Water-Carbon Dioxide - C. J. Wormald, N. M. Lancaster, A. J. Sellars,
Dendy Sloan, Colorado School of Mines, Golden, Colorado. Project 775- University of Bristol, Bristol, England. Project 773-A-81. June, 1985.
B-82. September, 1983.
RR-84 Evaluation of Equi-Phase (Peng-Robinson) Computer Program with GPA
RR-72 Measurement of Ethane and Propane Recovery and Total Fraction Con- Data Bank of Selected V-L-E Data - Thomas E. Daubert, Pennsylvania
densed for a Simulated Natural Gas in the Retrograde Region - John L. State University, University Park, Pennsylvania. Project 806-84. March,
Oscarson, Brigham Young University, Provo, Utah. Project 815-81. De- 1985.
cember, 1983.
RR-85 Enthalpies of Solutions of CO2 in Aqueous Diglycolamine Solutions -
RR-73 Heats of Mixing of Steam with N2, CO2, H2, CH4, and CO at High Tem- Scott P. Christensen, James J. Christensen and Reed M. Izatt, Brigham
peratures and Pressures Using a New High Temperature Calorimeter Young University, Provo, Utah. Project 821-84. May, 1985.
- Grant M. Wilson and C. Jeff Brady, Wiltec Research Co., Provo, Utah.
Project 773-79 & 80. December, 1983. RR-86 Properties of CO2-Rich Mixtures - Joint research report for GPA and Gas
Research Institute. K. R. Hall, J. C. Holste, P. T. Eubank and K. N. Marsh, Tex-
RR-74 The Influence of Methanol on Hydrate Formation at Low Temperatures as A&M University, College Station, Texas. Project 842-84. June, 1985.
- H-J. Ng and D. B. Robinson, D. B. Robinson & Assoc. Ltd., Edmonton,
Alberta, Canada. Project 825-83. March, 1974.

RR-87 Hydrate Formation and Equilibrium Phase Compositions in the Pres- RR-97 Excess Enthalpy Experimental Data Binary Systems: Water + Ethylene,
ence of Methanol: Selected Systems Containing Hydrogen Sulfide, Car- Water + Ethane, Water + Propane, Water + n-Butane - Ternary System:
bon Dioxide, Ethane or Methane - H-J. Ng, C-J. Chen and D. B. Robinson, Water + Methane + Carbon Dioxide - C. J. Wormald and N. M. Lancaster,
D. B. Robinson & Assoc. Ltd., Edmonton, Alberta, Canada. Project 825- University of Bristol, Bristol, England. Project 773-B-82. February, 1986.
84. March, 1985.
RR-98 Glycol Vaporization Losses in Super-Critical CO2 - Y. Adachi, Patrick
RR-88 Vapor-Liquid Equilibria Measurements on the Systems Ethane-n-Prop- Malone, Toshikuni Yonemoto and Riki Kobayashi, Rice University, Hous-
ylcyclohexane, Propane-Cyclohexane, Propane-n-Propylcyclohexane, ton, Texas. Project 856-85. June, 1986.
Propane-n-Propylbenzene and Propane-Mesitylene - S. Laugier, A. Valtz,
A. Chareton, D. Richon and H. Renon, ARMINES, Paris, France. Project RR-99 The Water Content of CO2 - Rich Fluids in Equilibrium with Liquid
755-C-84. July, 1985. Water and/or Hydrates - Kyoo Y. Song and Riki Kobayashi, Rice Univer-
sity, Houston, Texas. Project 775-85. June, 1986.
RR-89 Vapor-Liquid Equilibrium and Condensing Curves for a Typical Gas
Condensate - H-J Ng and D. B. Robinson, D. B. Robinson & Assoc. Ltd., RR-100 Water Content of NGL in Presence of Hydrates - Mark S. Bourrie and E.
Edmonton, Alberta, Canada. Project 815-82 & 83. March, 1985. Dendy Sloan, Colorado School of Mines, Golden, Colorado. Project 775-
A-83 & 84. June, 1986.
RR-90 Vapor-Liquid Equilibrium Measurements on the Ammonia-Water Sys-
tem from 313K to 589K - Joint research report for GPA and AIChE-DIPPR. RR-101 Vapor-Liquid Equilibria Measurements on the Systems Methane-Meth-
C. Gillespie, W. Vincent Wilding and Grant M. Wilson, Wiltec Research Co., ylcyclohexane, Nitrogen-n-Propylbenzene, Hydrogen Sulfide-n-Propyl-
Provo, Utah. Project 758-B-81. October, 1985. benzene, Propane-Toluene, Propane-m-Xylene and Propane-Methylcy-
clohexane - A. Chareton, A. Valtz, C. Lafeuil, S. Laugier, D. Richon and H.
RR-91 Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures - Phase V - Renon, ARMINES, Paris, France. Project 755-C-85. June, 1986.
James P. Kohn and F. M. Llave, University of Notre Dame, Notre Dame,
Indiana and Kraemer D. Luks, University of Tulsa, Tulsa, Oklahoma. Proj- RR-102 Enthalpies of Solution of CO2 in Aqueous Methyldiethanolamine Solu-
ect 795-85. November, 1985. tions - Keith E. Merkley, James J. Christensen and Reed M. Izatt, Brigham
Young University, Provo, Utah. Project 821. September, 1986.
RR-92 The Effect of Ethylene Glycol or Methanol on Hydrate Formation in Sys-
tems Containing Ethane, Propane, Carbon Dioxide, Hydrogen Sulfide or RR-103 Enthalpies and Phase Boundary Measurements: Equal Molar Mixtures
a Typical Gas Condensate - H-J Ng, C. J. Chen and D. B. Robinson, D. of n-Pentane with Carbon Dioxide and Hydrogen Sulfide - John R. Cun-
B. Robinson & Assoc. Ltd., Edmonton, Alberta, Canada. Project 825-85. ningham, Brigham Young University, Provo, Utah. Project 763. Decem-
September, 1985. ber, 1986.
RR-93 Gas Solubilities and Vapor-Liquid Equilibrium Measurements of H2, CO2 RR-104 Equilibrium Solubility of Carbon Dioxide or Hydrogen Sulfide in Aque-
and NH3 in Water-Phenol Mixtures from 110 degrees F to 550 degrees ous Solutions of Monoethanolamine, Diglycolamine, Dieth-anolamine
F - Paul C. Gillespie, Jonathan L. Owens and Grant M. Wilson, Wiltec Re- and Methyldiethanolamine - R. N. Maddox, A. H. Bhairi, James R. Diers
search Co., Provo, Utah. Project 758-B-81 & 82. January, 1986. and P. A. Thomas, Oklahoma State University, Stillwater, Oklahoma. Proj-
ect 841. March, 1987.
RR-94 Phase Equilibrium Studies for Processing of Gas from CO2 EOR Projects
(Phase III): A. The Effect of Toluene as an Extractive Agent; B. The Effect RR-105 Vapor-Liquid Equilibrium and Condensing Curves for a Gas Condensate
of Methane on V-L-E Behavior in CO2-Rich Gas n-Pentane Quasi-binary Containing Nitrogen - H-J Ng, H. Schroeder and D. B. Robinson, D. B.
Mixtures - Project supported jointly by GPA special industry contribu- Robinson & Assoc., Ltd., Edmonton, Alberta, Canada. Project 815-85 &
tions. Jane Huey Hong and Riki Kobayashi, Rice University, Houston, 86. April, 1987.
Texas. Project 826-84 & 85. February, 1986.
RR-106 The Influence of High Concentrations of Methanol on Hydrate Forma-
RR-95 Application of a High Pressure, Multiproperty Apparatus for the Mea- tion and the Distribution of Glycol in Liquid-Liquid Mixtures - H-J Ng,
surement of Thermo-dynamic and Transport Properties to Measure the C. J. Chen and D. B. Robinson, D. B. Robinson & Assoc. Ltd., Edmonton,
Phase and Volumetric Properties of a Supercritical Extractive System: Alberta, Canada. Project 825-86. April, 1987.
The Carbon Dioxide-n-Hexadecane System - Joint research report for
Gas Processors Association and Gas Research Institute. T. Charoensom- RR-107 Thermodynamic Properties of Pure Hydrogen Sulfide and Mixtures
but-amon and Riki Kobayashi, Rice University, Houston, Texas. Project Containing Hydrogen Sulfide with Methane, Carbon Dioxide, Methyl-
826-85. May, 1986. cyclohexane and Toluene - Donald M. Bailey, Chung Hsiu Liu, James C.
Holste, Kenneth R. Hall, Philip T. Eubank and Kenneth M. Marsh, Texas
RR-96 Vapor-Liquid Equilibrium and Condensing Curves in the Vicinity of the A&M University, College Station, Texas. Project 792. March, 1987.
Critical Point for a Typical Gas Condensate - H-J. Ng, C. J. Chen and D.
B. Robinson, D. B. Robinson & Assoc. Ltd., Edmonton, Alberta, Canada.
Project 815-A-84. April, 1986.

RR-108 Enthalpies of Solution of CO2 in Aqueous Diethanolamine Solutions - RR-121 Experimental Enthalpies of Pentanes-plus Fractions - P. T. Eubank, K. R.
Rebecca Helton, James J. Christensen and Reed M. Izatt, Brigham Young Hall, J. C. Holste and M. G. Johnson, Texas A&M University, College Sta-
University, Provo, Utah. Project 821-86. May, 1987. tion, Texas. Project 811. January, 1989.
RR-109 Acoustic Determination of the Thermodynamic Reference State Heat RR-122 Thermodynamic Properties of Near-Equimolar Mixtures for CO2-CH4
Capacity of n-Heptane Vapor - Sam O. Colgate, A. Sivaraman and Kyle and CO2-N2 - D. M. Bailey, G. J. Esper, J. C. Holste, K. R. Hall, P. T. Eubank,
Reed, University of Florida, Gainesville, Florida. Project 831-83 through K. N. Marsh, W. J. Rogers, Texas A&M University, College Station, Texas.
86. May, 1987. Project 842. July, 1988.
RR-110 Thermophysical Properties for Special High CO2 Content Mixtures - RR-123 Reference State Heat Capacities of Three C8 Compounds - Sam Colgate,
James F. Ely, J. W. Magee and W. M. Haynes, National Bureau of Stan- A. Sivaraman and K. Reed, University of Florida, Gainesville, Florida. Proj-
dards, Boulder, Colorado. Project 839-Part I. May, 1987. ect 831. March, 1989.
RR-111 Additional Evaluation of GPA*SIM Computer Program with GPA Data RR-124 Equilibrium Solubility of CO2 or H2S in Aqueous Solutions of DEA at Low
Bank of Selected VLE Data - Thomas E. Daubert, Pennsylvania State Uni- Partial Pressures - R. N. Maddox and E. M. Elizondo, Oklahoma State Uni-
versity, University Park, Pennsylvania. Project 856. December, 1987. versity, Stillwater, Oklahoma. Project 841. July, 1989.
RR-112 Additional Evaluation of Equi-Phase (Peng Robinson) Computer Pro- RR-125 Equilibrium Solubility of CO2 or H2S in Protonated Solutions of DEA - R.
gram with GPA Data Bank of Selected VLE Data - Thomas E. Daubert, N. Maddox, M. Abu-Arabi and E. M. Elizondo, Oklahoma State University,
Pennsylvania State University, University Park, Pennsylvania. Project Stillwater, Oklahoma. Project 841. June, 1989.
806-86. December, 1987.
RR-126 Phase Behavior and Properties of an Aromatic Condensate Containing
RR-113 Vapor Liquid Equilibrium in Propane-Odorant Systems - Heng-Joo Ng 20 Mole Percent Nitrogen - H.-J. Ng, H. Schroeder, D.B. Robinson, DB
and Donald B. Robinson, DB Robinson & Associates Ltd., Edmonton, Al- Robinson Research Ltd., Edmonton, Alberta, Canada. Project 815. De-
berta, Canada. Project 876. January, 1989. cember, 1989.
RR-114 Enthalpies of Solution of H2S in Aqueous Diethanolamine Solutions - RR-127 Enthalpies of Solution of H2S in Aqueous Methyldiethanolamine Solu-
Rebecca Van Dam, James J. Christensen, Reed M. Izatt, and John L. Os- tions - J.L. Oscarson, R.M. Izatt, Brigham Young University, Provo, Utah.
carson, Brigham Young University, Provo, Utah. Project 821. May, 1988. Project 821. August, 1990.
RR-115 Liquid-Liquid-Vapor Equilibria in Cryogenic LNG Mixtures - Phase VI - W. RR-128 Enthalpies of Water + Methanol Mixtures between 180 and 320 K - S.W.
L. Chen, James P. Kohn, University of Notre Dame, Notre Dame, Indiana Cochran, J. C. Holste, K. N. Marsh, B.E. Gammon and K.R. Hall, Texas A&M
and Kraemer D. Luks, University of Tulsa, Tulsa, Oklahoma. Project 795. University, College Station, Texas. Project 881. May, 1991.
December, 1987.
RR-129 Human Response Research Evaluation of Alternate Odorants for LP-GAS
RR-116 Vapor Liquid Equilibrium and Condensing Curves for a Highly Aromatic - D.L. Ripley, J.W. Goetziner, M.L. Whisman, NIPER, Bartlesville, Oklahoma.
Gas Condensate - H.-J. Ng, H. Schroeder, C. J. Chen, and D. B. Robinson, Project 898. October, 1990.
DB Robinson & Associates, Edmonton, Alberta, Canada. Project 815.
August, 1988. RR-130 A Thermodynamically Consistent Model for the Prediction of Solubili-
ties and Enthalpies of Solution of Acid Gases in Aqueous Alkanolamine
RR-117 The Solubility of Methanol or Glycol in Water-Hydrocarbon Systems - C. Solutions - John L. Oscarson, Xuemin Chen and Reed M. Izatt, Brigham
J. Chen, H.-J. Ng, and D. B. Robinson, DB Robinson & Associates, Edmon- Young University, Provo, Utah. Project 821. August, 1995.
ton, Alberta, Canada. Project 825. March, 1988.
RR-131 The Solubility of Selected Aromatic Hydrocarbons in Triethylene Glycol
RR-118 GPSWAT: GPA Sour Water Equilibria Correlation and Computer Program - H.-J. Ng, C.-J. Chen, D.B. Robinson, DB Robinson Research Ltd., Edmon-
- Grant Wilson and Wayne W. Y. Eng, Wiltec Research Co., Provo, Utah. ton, Alberta, Canada. Project 895. December, 1991.
Project 758. February, 1990.
RR-132 Water Content of Ethane, Propane, and Their Mixtures in Equilibrium
RR-119 Triethylene Glycol Vaporization Losses In Supercritical CO2 - T. Yonemo- with Liquid Water or Hydrates - K.Y. Song, R. Kobayashi, Rice University,
to, T. Charoensombut-Amon, and Riki Kobayashi, Rice University, Hous- Houston, Texas. Project 875. February, 1991.
ton, Texas. Project 856. March, 1989.
RR-133 Volume Correction Factors for Natural Gas Liquids_Phase I - J. F. Ely, Na-
RR-120 Water Content Values of a CO2 - 5.31 Mol Percent Methane Mixture - tional Institute of Standards and Technology, Boulder, Colorado. Project
Kyoo Y. Song and Riki Kobayashi, Rice University, Houston, Texas. Project 899. December, 1991.
775. January, 1989.

RR-134 Evaluation of Four Methods for Predicting Hydrate Equilibria - Thomas RR-146 Fluoride Contamination in LP-Gas - J. W. Mausteller, MSA Research Corp.,
E. Daubert, Pennsylvania State University, University Park, Pennsylvania. Pittsburgh, Pennsylvania. Project 919. August, 1995.
Project 806. December, 1991.
RR-147 Density Measurements on Natural Gas Liquids - C. D. Holcomb, J. W.
RR-135 Vapor Liquid Equilibria for Volatile-Sulfur-Containing Systems - A. Valtz, J. Magee, W. M. Haynes, National Institute of Standards and Technology,
Schwartzentruber, D. Richon, H. Renon, ARMINES, Paris, France. Project Boulder, Colorado. Project 916. September, 1995.
876. February, 1994.
RR-148 Volume Correction Factors for Natural Gas Liquids - Phase II - James F.
RR-136 A Predictive Model for the Thermophysical Properties of Carbon Dioxide Ely, Colorado School of Mines, Golden, Colorado. Project 916. October,
Rich Mixtures - J. W. Magee, J. A. Howley, National Institute of Standards 1995.
and Technology, Boulder, Colorado and J. F. Ely, Colorado School of
Mines, Golden, Colorado. Project 839. March, 1994. RR-149 Vapour-Liquid and Vapour-Liquid-Liquid Equilibria for H2S, CO2, Select-
ed Light Hydrocarbons and a Gas Condensate in Aqueous Methanol or
RR-137 The Solubility of Selected Aromatic Hydrocarbons in Monoethylene Ethylene Glycol Solutions - H.-J. Ng, C.-J. Chen, DB Robinson Research
Glycol - H.-J. Ng, C.-J. Chen, D. B. Robinson, DB Robinson Research Ltd., Ltd., Alberta, Canada. Project 905. March, 1995.
Edmonton, Alberta, Canada. Project 895. March, 1994.
RR-150 Mutual Solubility in Water-Hydrocarbon Systems - H.-J. Ng, C.-J. Chen,
RR-138 Thermodynamic Properties of CO2 + CH4 Mixtures - C-A. Hwang, H. DB Robinson Research Ltd., Alberta, Canada. Project 895. July, 1995.
Duarte-Garza, P. T. Eubank, J. C. Holste, K. R. Hall, Texas A&M University; B.
E. Gammon, and K. N. Marsh, Thermodynamics Research Center, College RR-151 Reaction Kinetics of CO2 with MEA, DEA, and MDEA-Based Blends -
Station, Texas. Project 842. June, 1995. Ralph H. Weiland, Optimized Gas Treating Inc., Houston, Texas. Project
911. August, 1996.
RR-139 Thermodynamic Properties of CO2 + C2H6 Mixtures - C-A. Hwang, H.
Duarte-Garza, P. T. Eubank, J. C. Holste, K. R. Hall, Texas A&M University; B. RR-152 Physical Properties of MEA, DEA, MDEA, and MDEA-Based Blends Load-
E. Gammon, and K. N. Marsh, Thermodynamics Research Center, College ed with CO2 - Ralph H. Weiland, Optimized Gas Treating Inc., Houston,
Station, Texas. Project 842. June, 1995. Texas. Project 911. August, 1996.
RR-140 Thermodynamic Properties of CO2 + N2 Mixtures - C-A. Hwang, H. Du- RR-153 Enhancement Factors for Acid Gas Removal with Single and Mixed
arte-Garza, P. T. Eubank, J. C. Holste, K. R. Hall, Texas A&M University; B. E. Amines - Ralph H. Weiland, Optimized Gas Treating Inc., Houston, Texas.
Gammon, and K. N. Marsh, Thermodynamics Research Center, College Project 911. August, 1996.
Station, Texas. Project 842. June, 1995.
RR-154 Experimental Enthalpies of Light/Heavy Hydrocarbon Systems:
RR-141 Thermodynamic Properties of CO2 + H2S Mixtures - S. J. Kellerman, C. Methane/n-Heptane, Methane/Methylcyclohexane, Methane/Toluene
E. Stouffer, P. T. Eubank, J. C. Holste, K. R. Hall, Texas A&M University; B. E. - Loren C. Wilson and Grant M. Wilson, Wiltech Research Company Inc.,
Gammon, and K. N. Marsh, Thermodynamics Research Center, College Provo, Utah. Project 901. October, 1997.
Station, Texas. Project 842. June, 1995.
RR-155 Solubility of H2S and CO2 in Alkanolamines - S.H. Huang and H.-J. NG,
RR-142 Experimental Enthalpies of Nitrogen-Rich Systems - L. C. Wilson, W. V. DB Robinsons Research Ltd., Edmonton, Alberta, Canada. Project 911.
Wilding, G. M. Wilson, Wiltec Research Company Inc., Provo, Utah. Proj- September, 1998.
ect 891. March, 1994.
RR-156 Hydrate Phase Equilibria in Inhibited and Brine Systems - P. Raj Bishnoi,
RR-143 A Study of Passivation Agents for Odorized Propane Containers - W. Pankaj D. Dholabhai, and Kal N. Mahadev, University of Calgary, Calgary,
Goetzinger, D. L. Ripley, Bartlesville, Oklahoma. Project 939. March, Alberta, Canada. Project 905-93 (Sub-Project 2). August, 1996.
1994.
RR-157 Acid Gas Treating with Aqueous Alkanolamines - Part I: A Mass Transfer
RR-144 Enthalpies of Mixing of Systems Containing Methane, Methanol and C7 Model for Predicting Rates of Absorption of Stripping of H2S and CO2
Hydrocarbons - J. Oscarson, J. Coxam, Sue Gillespie, Brigham Young Uni- in MDEA, DEA, and Blends of DEA and MDEA - Edward B. Rinker, Sami
versity, Provo, Utah. Project 881. May, 1996. S. Ashour, and Orville C. Sandall, University of California, Santa Barbara,
California. Project 911 - Part I. December, 1997.
RR-145 Enthalpies of C7 + Methane + Methanol Mixtures Between 180 and
320K - S.J. Kellerman, S.W. Cochran, J.C. Holste, and K.R. Hall, Texas A&M RR-158 Acid Gas Treating with Aqueous Alkanolamines - Part II: Physical Prop-
University, College Station, Texas; and B.E. Gammon and K.N. Marsh, erty Data Important in Modeling H2S and CO2 Absorption into Aqueous
Thermodynamics Research Center, College Station, Texas. Project 881. DEA, MDEA, and Blends of DEA and MDEA - Edward B. Rinker, Sami S.
December, 2002. Ashour, and Orville C. Sandall, University of California, Santa Barbara,
California. Project 911 - Part II. December, 1997.

RR-159 Acid Gas Treating with Aqueous Alkanolamines - Part III: Experimental RR-170 Prediction of Sulfur Compound Distribution in Fractionators. Measure-
Absorption Rate Measurements and Reaction Kinetics for H2S and CO2 ment of Phase Equilibrium Data, and Extension and Test of Applicabil-
in Aqueous DEA, MDEA, and Blends of DEA and MDEA - Edward B. Rink- ity of the PSRK Group Contribution Method to LNG Related Systems:
er, Sami S. Ashour, and Orville C. Sandall, University of California, Santa I - Experimental Part: Results for the Binary Systems Hydrogen Sulfide-
Barbara, California. Project 911 - Part III. December, 1997. Carbonyl Sulfide, Hydrogen Sulfide-Dimethyl Sulfide, Hydrogen Sulfide-
Ethyl Methyl Sulfide, Methane-Methanethiol, and Methane-Ethanethio;
RR-160 Mutual Solubility in Gas Condensate - EG Solution Systems - H.J. Ng and II - Reevaluation of Distribution Coefficients of Sulfur Compounds Di-
C.J. Chen, DB Robinson Research Ltd., Edmonton, Alberta, Canada. Proj- luted in (C1 to C4)-Hydrocarbons and their Mixtures with Hydrogen
ect 895-2. Sulfide (experimental results from GPA Project 876) - P. Guilbot, P. Theve-
January, 2000. neau, A. Valtz, A. Baba-Ahmed, D. Richon, ARMINES, Paris, France; and
K. Fischer, University of Oldengurg, Germany. Project 986. September,
RR-161 Kinetics of Gas Hydrates with and without Inhibitors - Kyoo Y. Song, Guil- 2000.
laume Feneyrou, Raymond Martin, and Riki Kobayashi, Rice University,
Houston, Texas. Project 905-95. May, 1997. RR -171 Solids Deposition in Natural Gas Systems - Amyn Teja, Vicky Smith, Tong-
fan Sun, and Janette Mendez-Santiago, Georgia Institute of Technology.
RR-162 Vapor-Liquid Equilibria for Volatile-Sulfur-Containing Systems III. Project 905-93. February, 2000.
Butane-Sulfur Compounds Containing Systems IV. Hydrocarbon-Hy-
drocarbon-Sulfur Compounds Containing Systems V. Hydrocarbon(s)- RR-172 See GTI Report No. 404.
Hydrogen Sulfide-Sulfur Compounds Containing Systems - A. Valtz, P.
Guilbot, D. Richon, ARMINES, Paris, France. Project 876. September, RR173 GPA Thermodynamic Data Base - Jan Wagner, Khaled Gasem, and
1998. Eric Maase, Oklahoma State University, Stillwater, Oklahoma. Projects
921/925. May, 2000.
RR-163 Diffusion Coefficients in Aqueous Amines - Richard Rowley, Brigham
Young University, Provo, Utah. Project 911. March, 1999. RR-174 Water Content of Natural Gas Systems Containing Acid Gas - Heng-Joo
Ng, C.-J. Chen, and Helmut Schroeder, DB Robinson Research Ltd., Ed-
RR-164 Phase Equilibria and Kinetics of Sulfur Species-Hydrocarbon-Aqueous monton, Alberta, Canada. Project 945. January, 2001.
Amine Systems - Henj-Joo Ng, DB Robinson Research Ltd., Edmonton,
Alberta, Canada, and F.-Y. Jou and A.E. Mather, University of Alberta, Ed- RR-175 COS Removal from Propane - Bret Rhinesmith, P.J. Archer, S.J. Watson,
monton, Alberta, Canada. Project 941. December, 1998. Pearl Development Co., Bailey, Colorado. Project 991-1. June, 2001.
RR-165 The Collection of VLE Data for Acid Gas - Alkanolamine Systems Using RR-176 Removal of Propylene from Fuel Grade Propane / LPG - Paul F. Bryan,
Fourier Transform Infrared Spectroscopy - Jerry A. Bullin, Richard R. Davi- Mount Vernon, Indiana. Project 008. August, 2001.
son, and William J. Rogers, Texas A&M University, College Station, Texas.
Project 911. March, 1997. RR-177 Vapor-Liquid Equilibrium Studies on Water-Methanol-TEG-Hydrocarbon
Systems - Heng-Joo Ng and Helmut Schroeder, DBR Research Inc., Ed-
RR-166 Enthalpies of Mixing of CO2/CH4 or H2S/CH4 Mixtures with Aqueous So- monton, Alberta, Canada. Project 966. March, 2002.
lutions of Methyldiethanolamine and Diethanolamine - John L. Oscar-
son, Helga K. Grimsrud, Sue E. Gillespie and D. Brett Pennington, Brigham RR-179 Vapor-Liquid Measurements on Propane, n-Butane, Isobutane, Ethane,
Young University, Provo, Utah. Project 911. April, 2007. n-Pentane, and n-Hexane - David M. VonNiederhausern and Neil F. Giles,
Wiltec Research Co., Inc., Provo, Utah. Project 012. September, 2001.
RR167 CO2 and H2S Thermodynamics and Kinetics in Aqueous Alkanolamines
- Gary Rochelle, Msafiri Mshewa, Mark Posey, Manuel Pacheco, and Shoi- RR-180 Amine BTEX Solubility - A. Valtz, P. Gilbot, and D. Richon, ARMINES, Paris,
ch Kaganoi, The University of Texas at Austin, Austin, Texas. Project 911. France. Project 971. December, 2002.
March, 2000.
RR-181 Hydrate Phase Composition for Multicomponent Gases - Ken Marsh,
RR-168 Hydrate Phase Composition for Multicomponent Gases - Heng-Joo University of Canterbury, Christchurch, New Zealand. Project 976-2.
NG, and Craig Borman, DB Robinson Research Ltd., Edmonton, Alberta, November, 2003.
Canada. Project 976-1. June, 1999.
RR-182 Kinetics of Sulfur Species-Hydrocarbon-Aqueous Amine Systems -
RR -169 GPSA Engineering Data Book Revitalization and Maintenance - Water- Orville C. Sandall, University of California, Santa Barbara, California.
Hydrocarbon Mutual Solubility Data - Jan Wagner, Oklahoma State Uni- Project 962. December, 2002.
versity, Stillwater, Oklahoma. Project 975. June, 1999.

RR-183 The Impact of Sulfur Species on Glycol Dehydration - A Study of the RR-196 Testing of Instruments for Measuring Hydrocarbon Dew Points In Natu-
Solubility of Certain Gases and Gas Mixtures in Glycol Solutions at El- ral Gas Streams, Phase 1 - D.L. George, Ph.D., R.C. Burkey, Southwest Re-
evated Pressures and Temperatures, P.M. Davis, P.D. Clark, E. Fitzpatrick, search Institute, San Antonio, Texas. Project 063. January, 2008.
K.L. Lesage, W.Y. Svrcek, and M. Satyro, Alberta Sulfur Research Laborato-
ries, Calgary, Alberta, Canada. Project 992-1. January, 2003. RR-197 Moisture Analyzers Survey - Howard S. Meyer, Osman Akpolat, Gas Tech-
nology Institute, Des Plains, Illinois. Project 022. April, 2008.
RR-184 Vapor Liquid Equilibrium Studies on Water Methanol - MDEA - Hy-
drocarbon Systems - Heng-Joo Ng, Oilphase DBR, Edmonton, Alberta, RR-198 Water and Inhibitor Distribution in Gas Product Systems - Antonin
Canada. Project 034. June, 2003. Chapoy, Amir H Mohammadi, Alain Valtz, Christopher Coquelet, Domi-
nique Richon, Armines, Paris, France. Project 987. February, 2008.
RR-185 Solubility of Hydrocarbon in Amine Solutions - Dominique Richon,
ARMINES, France. Project 011. March, 2004. RR-199 Testing of Methods for Measuring Hydrocarbon Dew Points, Part 2 -
D.L. George, Ph.D., R.A. Hart. Southwest Research Institute, San Antonio,
RR-186 Determination of VLE Data on CO2 and H2S in MDEA and its Blends With Texas. Project 063. September, 2008.
Other Amines - Ir. H. ter Maat, S. Praveen, Msc, Ir. P. Ijben, D Arslan, Ing.
H.F. Wouters, Ir. P.J.G. Huttenhuis, Dr. ir. J.A. Hogendoorn, and Prof. Dr. ir. RR-200 Water Content of High Pressure, High Temperature Methane, Ethane
GF. Versteeg. Procede Twente B.V., Enschede, The Netherlands. Project and Methane +CO2, Ethane + CO2 - Matt Yarison, Kyoo Y. Song, Kenneth
001. May, 2004. R. Cox, Dick Chronister, Walter G. Chapman. Rice University, Houston,
Texas. Project 032. March, 2008.
RR-187 Low Temperature VLE Data for Water, CO2, and Light Hydrocarbon Sys-
tems - Kyoo Song, Matt Yarrison, Riki Kobayashi, and Walter Chapman. RR-201 Oxygen Removal in Natural Gas Systems - Rosalind Jones, Ken McIn-
Rice University, Houston, Texas. Project 997. January, 2005. tush, and Charlie Wallace, Trimeric Corporation, Buda, Texas. Project
073. February 2010.
RR-188 GPA Round Robin Chromatograph Test Project - Ronald Beaty and Karen
West, Premier Measurement Services. Houston, Texas. April, 2005. RR-202 Vapour-Liquid Equilibrium, Interfacial Tension and Transport Properties
of Aqueous Solutions of Ethylene Glycol or Triethylene Glycol in the
RR-189 The Impact of Sulfur Species on Glycol Dehydration - A Study of the Sol- Presence of Methane, Carbon Dioxide and Hydrogen Sulfide Heng-
ubility of Certain Gases and Gas Mixtures in Glycol Solutions at Elevated Joo Ng, Na Jia, Yuengsheng Cheng, Kurt A. G. Schmidt and Herlmut
Pressures and Temperatures - R.A. Marriott, E Fitzpatrick, P.M. Davis, P.D. Schroeder. DBR Technology Center, Edmonton, Alberta, Canada. Project
Clark, W.Y. Svrcek, M.A. SAtyro, Calgary, Alberta, Canada. Project 992-2. 061. September 2009.
December, 2005.
RR-203 High Pressure Demethanizer Physical Properties - Sven Horstmann, An-
RR-190 An Examination of Interfering Factors in the ASTM D-1838 Copper dreas Grybat, Christan Ihmels, and Kai Fischer. LTP GmBH University of
Strip Test - P.d. Clark and K.L. Lesage, Alberta Sulphur Research Ltd., c/o Oldenburg, Oldenburg, Germany. Project 043. September 2010.
Department of Chemistry, The University of Calgary, Calgary, Alberta,
Canada. Project 982-2. March, 2006. RR-204 Impact of Sulfur Species on Glycol Dehydration (GPA 992-3): Solubility
Study of Certain Sulfur Species in Glycol Aqueous Solutions Waheed
RR-191 State of Mercury Removal Technology - Kent Pennybaker, Thomas Afzal, Amir H. Mohammadi and Dominique Richon, Armines, Paris,
Ruddy, River City Engineering Inc, Lawrence, Kansas. Project 051-1. July, France. Project 992-3. January 2008.
2006.
RR-205 Hydrates in High Inhibitor Concentration Systems - A. Chapoy and B.
RR-192 Carbonyl Sulfide Removal from Propane - Michael D. Armidis, The Uni- Tahidi, Hydrafact Limited, Edinburgh, UK. Project 062-1. October 2010.
versity of South Carolina, Columbia, South Carolina. Project 991. March,
2006. RR-206 Solubility of Hydrocarbons in Amine Solutions - GPSA Data Book Proj-
ect. Darryl Mamrosh, Kevin Fisher and Carrie Beitler, Trimeric, Buda,
RR-193 High Pressure Gas Separation and Conditioning - Heng-Joo Ng, Shawn Texas. Project 975-5. October, 2011.
Taylor, Helmut Schroeder, and Don Sieben, Oilphase-DBR Schlumberg-
er, Edmonton, Alberta, Canada. Project 985. January, 2008. RR-207 Vapor-Liquid Equilibrium Studies of Organic Sulfur Species in MDEA,
DEA Aqueous Solutions - Christophe Coquelet, Javeed A. Awan, Eric
RR-194 Gas Hydrate Plug Dissociation Kinetics and Predictive Model Develop- Boonaert, Alain Valtz, Pascal Thveneau and Dominique Richon. Project
ment - Kenneth N. Marsh and Thomas J. Hughes, University of Canter- 037. April 2011.
bury, Christchurch, New Zealand. E. Dendy Sloan, Colorado School of
Mines, Golden, Colorado. Project 036. January, 2008. RR-208 Methanol Solubility in Natural Gas - Darryl Mamrosh, Kevin Fisher and
Teresa Kerr, Trimeric, Buda, Texas. Project 975-7. October, 2011.
RR-195 Mutual Solubility of Hydrocarbons and Amines - S. Mokraoui, A. Valtz, C.
Couquelet, D. Richon, Armines, Paris, France. Project 021. January, 2008.

RR-209 CO2/H2S Solubility in Glycol - Darryl Mamrosh, Kevin Fisher and Carrie RR-214 Solubility of Non-Aromatic Hydrocarbons in TEG Solutions - Sven Horst-
Beitler, Trimeric, Buda, Texas. Project 975-8. October, 2011. mann, Christian Ihmels, and Andreas Grybat, LTP GmbH. Project 083.
December, 2011.
RR-210 Acid Gas Water Content GPSA Data Book Project - Walter Chapman
and Kyoo Y. Song, Rice University, Houston, Texas. Project 975-6. Octo- RR-216 Hydrates in High Inhibitor Concentration Systems - H. Adidharma, M.
ber, 2011. Radosz. University of Wyoming, Laramie, Wyoming. Project 062-2. June,
2012.
RR-211 Hydrates in High Inhibitor Concentration Systems - Bahman Tohidi,
R. Burgrass and Antonin Chapoy, Hydrafact, Edinburgh, UK. Project 062- RR-217 GPA Technical Data Development Committee Support for GPSA Data
1 Part 2. October, 2011. Book 13th Edition - Brian Walter and Barry Friedman, URS Corporation,
Denver, Colorado. Project 975-9. June, 2012.
RR-212 Glycol Systems With Impurities - Christian Ihmels, Sarah Thiede, Sven
Horstmann, and Andreas Grybat, LTP GmbH Oldenburg, Oldenburg, RR-218 Loaded Amine Transport Properties - Christian Ihmels, Sarah Thiede,
Germany. Project 031. October, 2011. Sven Horstmann, and Andreas Grybat, Oldenburg, Germany. Project
061-2. March, 2013.
RR-213 Practical Hydrocarbon Dew Point Specification for Natural Gas Trans- RR-219 Methanol Distribution (As A Contaminant) in Fractionation Products
mission Lines - Jerry A. Bullin and Karl Fitz, Bryan Research and Engi- and Freeze Out Boundaries - Xavier Courtial, Eric Booneart, Alain Valtz,
neering, Bryan, Texas. Todd Dustman, Questar Pipeline Company, Salt Pascal Theveneau, Paolo Stringari, Christophe Coquelet, Armines, Paris,
Lake City, Utah. Project 081. March, 2011. France. Project 052. March, 2013.
TECHNICAL PUBLICATIONS
Technical Publications can be ordered online at www.GPAglobal.org. Click on Publications and then Order Publications. From that
page, select Technical Publications and scroll through the titles to find the desired report. GPA members realize savings over non-members
for the publications.
TP 1 Liquid Densities of Ethane, Propane and Ethane Propane Mixtures - J. R. TP 8 The Solubility of Carbon Dioxide in Propylene Carbonate at Elevated
Tomlinson, Gulf Research & Development Co., Pittsburgh, Pennsylvania. Pressures and Higher Than Ambient Temperatures - P.D. Mantor, O.Abib,
February, 1971. Jr., K.Y. Song and R. Kobayashi, Rice University, Houston, Texas. July,
1982.
TP 2 Liquid Densities of High Ethane Raw Make Streams - T. K. Provence, Jr.,
Mobil Pipe Line Co., L. D. Wiener and D. K. Walton, Mobil Research & TP 9 The Water Content and the Solubility of CO2 in Equilibrium with DEG
Development Corp., Dallas, Texas. February, 1972. Water and TEG Water Solutions at Feasible Absorption Conditions - S.
Takahashi and R. Kobayashi, Rice University, Houston, Texas. December,
TP 3 A Model for the Precise Calculation of Liquefied Natural Gas Densities - 1982.
M. A. Albright, Phillips Petroleum Co., Bartlesville, Oklahoma. June, 1973.
TP 10 Hydrate Decomposition Conditions in the System Hydrogen Sulfide,
TP 4 Low Temperature Data from Rice University for Vapor Liquid and P V T Methane and Propane - J. P. Schroeter and R. Kobayashi, Rice University
Behavior - R. Kobayashi, P.S. Chappelear and T. W. Leland, Rice University, and H. A. Hildebrand, Exxon Production Research Co., Houston, Texas.
Houston, Texas. April, 1974. December, 1982.
TP 5 Relation of Liquid Liquid Equilibrium Behavior at Low Temperatures to TP 11 Vapor Liquid Equilibria Study of Light Gases in Hydrogen Coal Liquid
Vapor Liquid Equilibria Behavior at High Temperatures and Elevated Model Compound Systems - T. Kragas and R. Kobayashi, Rice University,
Pressures - S. C. Hwang, Y. Lin and R. Kobayashi, Rice University and S.W. Houston, Texas. August, 1983.
Hopke, Exxon Production Research Co., Houston, Texas.
August, 1978. TP 12 Liquid Densities of Ethane Propane Mixtures - W. R. Parrish, Phillips Pe-
troleum Co., Bartlesville, Oklahoma. February, 1985.
TP 6 Experimentally Based Thermodynamic Properties of Propane - V. L.
Bhirud and J. E. Powers, University of Michigan, Ann Arbor, Michigan. TP 13 Experimental Orifice Meter Studies - R. G. Teyssandier, Z. D. Husian and
January, 1982. M. F. Zendan, Daniel Industries Inc., Houston, Texas. February, 1985.
TP 7 Excess Enthalpy Experimental Data, Binary Systems: Water Hydrogen, TP 14 Energy Functions for Gaseous CO2 H2O Mixtures - M.R. Patel, J.C. Holste,
Water Methane, Water Nitrogen, Water Argon - C. J. Wormald, C. N. K.R. Hall and P.T. Eubank, Texas A&M University, College Station, Texas.
Colling, University of Bristol, Bristol, England. June, 1982. May, 1987.

TP 15 A Simplified Vapor Pressure Correlation for Commercial NGLS - D. L. Em- TP 24 Solubility and Vapor-Liquid Equilibrium Data for Systems Containing
bry, D. G. Glascock and R. W. Hankinson, Phillips Petroleum Company, Diamondoids, Gas Mixtures, Feed Stock Oil, and Triethylene Glycol -
Bartlesville, Oklahoma. June, 1988. Heng-Joo Ng, DB Robinson Research Ltd., Edmonton, Alberta, Canada.
December, 1997.
TP 17 Table of Physical Properties of Hydrocarbons for Extended Analysis of
Natural Gases - B. E. Gammon, Thermodynamic Research Center, Texas TP 25 Temperature Correction for the Volume of Light Hydrocarbons, Tables
A&M University, College Station, Texas. December, 1988. 24E and 23E - A joint publication of API, ASTM, and GPA. September,
1998.
TP 18 GPA Experimental Enthalpy Values Referred to Two Base Levels from Ex-
cess Enthalpy Data - P.S. Chappelear, Houston, Texas. October, 1989. TP 26 Mutual Solubility in Water / Methanol Hydrocarbon Solutions - DB Rob-
inson Research Ltd., Edmonton, Alberta, Canada and Norsk Hydro, Oslo,
TP 19 Vapor Solid Equilibrium Ratios for Structure I and Structure II Natural Gas Norway. May, 2000.
Hydrates - S.L. Mann, Mobil Oil Corp., L.M. McClure, Columbus Energy
Corp., E.D. Sloan and F.H. Poettmann, Colorado School of Mines. De- TP 27 Temperature Correction for the Volume of NGL and LPG, Tables 23E,
cember, 1988. 24E, 53E, 54E, 59E and 60E - A joint publication of API, ASTM and GPA.
September, 2007.
TP 20 Effects of Amonia on LP-Gas Odorant - J.W. Goetzinger and D.L. Ripley,
National Institute for Petroleum Energy Research, Bartlesville, Oklaho- TP 28 Water Content of CO2 Rich Phase of Gaseous Mixtures Containing 10-20
ma. May, 1996. Mol Percent CH4 in CO2 in Equilibrium with Water and/or Hydrate - Kyoo
Song, Riki Kobayashi, Walter Chapman, Rice University, Houston, Texas.
TP 21 Trace Contaminants in Natural Gas Liquids - GPA Technical Section C, March, 2003.
Product Specifications, Tulsa, Oklahoma. July, 1996.
TP 29 Hydrocarbon / Water and Hydrocarbon / Aqueous Amines Mutual Solu-
TP 22 Convergence Pressure and Vapor-Equilibrium Ratios - GPSA Editorial tions - Huntsman supplied data. August, 2003.
Review Board, Tulsa, Oklahoma. June, 1999.
TP 30 Foaming In Glycol and Amine Systems - Howard S. Meyer, Gas Technol-
ogy Institute. Project 006. July, 2007.

gpa l KATZ AWARD
The DONALD L. KATZ AWARD is named in honor of the highly esteemed
Professor Emeritus of the University of Michigan.
It was initiated in 1985 to recognize outstanding accomplishments in gas processing research and technology,
and/or for excellence in engineering education. Dr. Katz was closely associated with GPA and the natural gas and
gas industry during his long and distinguished career. He and his students developed much of the classic data
and many of the correlations that are essential to understanding the science and engineering of light hydrocarbon
production and processing. He was the 1950 recipient of the GPA Hanlon Award, the first of some 21 major
scientific honors and awards received during his career.
The Katz Award, symbolized by a wall plaque bearing an engraved likeness of the late Dr. Katz, is not an annual
event, but is conferred as deemed appropriate by GPA research leaders and the Awards Committee. It is presented
at the Opening General Session of GPAs Annual Convention.
DONALD L. KATZ AWARD RECIPIENTS
1985 Professor Riki Kobayashi, Rice University
1986 Don Robinson, D. B. Robinson & Associates
1987 None
1988 James P. Kohn, University of Notre Dame
1989 Grant Wilson, Wiltec Research Co.
1990 Dr. Frank Dotterweich, Texas A&M University
1991 None
1992 John Prausnitz, University of California, Berkeley
1993 Fred Poettmann, Colorado School of Mines
1994 Dr. K. C. Chao, Purdue University
1995 None
1996 Dr. John Erbar (posthumous)
1997 Dr. Kenneth Hall, Texas A&M University
1998 Dr. Fred D. Otto, University of Alberta
Dr. Alan Mather, University of Alberta
1999 Dr. Orville Sandall, University of California
2000 Dr. E.Dendy Sloan, Jr., Colorado School of Mines
2001 Dr. Dominique Richon, ARMINES
2002 Dr. Raj Bishnoi, University of Calgary
2003 Dr. Ken Starling, Starling & Associates
2004 Dr. Jerry Bullin, Texas A&M University and Bryan Research & Engineering
2005 Dr. Heng-Joo Ng, Oilphase - DBR, Edmonton
2006 Dr. Ding-Yu Peng, University of Saskatchewan
2007 Dr. Ken Marsh, University of Canterbury
2008 Dr. Peter Clark, University of Calgary
2009 Dr. James F. Ely, Colorado School of Mines
2010 Dr. Walter G. Chapman, Rice University
2011 Dr. Gary T. Rochelle, University of Texas
2012 Dr. John J. McKetta Jr., University of Texas
2013 Dr. Arthur Kidnay, Colorado School of Mines
w w w . G PA g l o b a l . o r g | 6 5 2 6 E a s t 6 0 t h S t r e e t | T u l s a , O k l a h o m a 7 4 1 4 5

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2014

Thank You 2013 GPA Research Program Supporters!

2014 COOPERATIVE INDUSTRY RESEARCH 1

HOW COOPERATIVE RESEARCH PROJECTS ARE DETERMINED

2 2014 COOPERATIVE INDUSTRY RESEARCH

GPSA Liaison: D. John Morgan, John M. Campbell, Parker, Colorado

Authorization and Funding Procedures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

GPA Research Fiscal Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

GPA Research Reports . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

2014 COOPERATIVE INDUSTRY RESEARCH 3

2014 Research Budget

4 2014 COOPERATIVE INDUSTRY RESEARCH

Project 142 Extended Mercaptan VLE in Loaded Amines

2014 COOPERATIVE INDUSTRY RESEARCH 5

Project 144 GPA Section B Round Robin Project

6 2014 COOPERATIVE INDUSTRY RESEARCH

Project 132 Mercury Partitioning Solubility in Various Gas Processing Solvents

2014 COOPERATIVE INDUSTRY RESEARCH 7

PREVIOUSLY FUNDED PROJECTS

PROJECT 921 (Ongoing) Enthalpy and Phase Equilibrium Database

8 2014 COOPERATIVE INDUSTRY RESEARCH

PROJECT 072 (In Progress) Distribution of Sulfur Species in 3-Phase Separators

2014 COOPERATIVE INDUSTRY RESEARCH 9

PROJECT 082 (In Progress) Impact of Aromatics on Acid Gas Injection

PROJECT 101 (In Progress) Corrosion in Acid Gas Injection Systems

10 2014 COOPERATIVE INDUSTRY RESEARCH

Project 111 (RFP Development) Comparison of GPA Data to Simulator Predictions

Project 112 (In Progress) CO2 Freezing in Cryogenic Processes

PROJECT 113 (In Progress) Mercury Partitioning in Gas Processing Systems

2014 COOPERATIVE INDUSTRY RESEARCH 11

Project 122 Solubility of Hydrocarbons in Aqueous Piperazine and Aqueous

Project 133 Co-Funded Project GPA/API Precision Improvement -

12 2014 COOPERATIVE INDUSTRY RESEARCH

AUTHORIZATION and FUNDING PROCEDURES

RESEARCH FISCAL SUMMARY

2014 COOPERATIVE INDUSTRY RESEARCH 13

14 2014 COOPERATIVE INDUSTRY RESEARCH

2014 COOPERATIVE INDUSTRY RESEARCH 15

16 2014 COOPERATIVE INDUSTRY RESEARCH

2014 COOPERATIVE INDUSTRY RESEARCH 17

18 2014 COOPERATIVE INDUSTRY RESEARCH

2014 COOPERATIVE INDUSTRY RESEARCH 19

20 2014 COOPERATIVE INDUSTRY RESEARCH

2014 COOPERATIVE INDUSTRY RESEARCH 21

22 2014 COOPERATIVE INDUSTRY RESEARCH

2014 COOPERATIVE INDUSTRY RESEARCH 23

24 2014 COOPERATIVE INDUSTRY RESEARCH

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