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    Acid Number Measurements of Crude Oil and Petroleum Products Using ASTM D8045

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    Corina Stanculescu
    Thermometric titration provides a more accurate, reproducible, and faster method for determining the Acid Number of crude oils and petroleum products according to a new ASTM standard method (D8045). The new method takes only 60 seconds to generate results, uses less solvent, and does not require sensor maintenance or conditioning like the previous potentiometric titration method (D664). The Metrohm 859 Titrotherm analyzer is well-suited for Acid Number measurements using the new thermometric titration method.

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    Acid Number Measurements of Crude Oil and Petroleum Products Using ASTM D8045

    Uploaded by

    Corina Stanculescu
    93 views4 pages
    Thermometric titration provides a more accurate, reproducible, and faster method for determining the Acid Number of crude oils and petroleum products according to a new ASTM standard method (D8045). The new method takes only 60 seconds to generate results, uses less solvent, and does not require sensor maintenance or conditioning like the previous potentiometric titration method (D664). The Metrohm 859 Titrotherm analyzer is well-suited for Acid Number measurements using the new thermometric titration method.

    Original Description:

    Chimie -laborator

    Original Title

    Metrohm _ASTM 8045 Aciditate IPA Isopropanol

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    Thermometric titration provides a more accurate, reproducible, and faster method for determining the Acid Number of crude oils and petroleum products according to a new ASTM standard method (D8045). The new method takes only 60 seconds to generate results, uses less solvent, and does not require sensor maintenance or conditioning like the previous potentiometric titration method (D664). The Metrohm 859 Titrotherm analyzer is well-suited for Acid Number measurements using the new thermometric titration method.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    93 views4 pages

    Acid Number Measurements of Crude Oil and Petroleum Products Using ASTM D8045

    Uploaded by

    Corina Stanculescu
    Thermometric titration provides a more accurate, reproducible, and faster method for determining the Acid Number of crude oils and petroleum products according to a new ASTM standard method (D8045). The new method takes only 60 seconds to generate results, uses less solvent, and does not require sensor maintenance or conditioning like the previous potentiometric titration method (D664). The Metrohm 859 Titrotherm analyzer is well-suited for Acid Number measurements using the new thermometric titration method.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    Acid Number measurements of crude oil

    and petroleum products using ASTM D8045

    Reproducible and accurate results in 60 seconds!


    New method uses thermometric titration

    02 Acid Number (AN) is an important crude oil quality para


    meter used to determine a refining value for crude oil.
    ween laboratories and often disputes regarding
    the quality and the price per barrel of the crude.
    Petroleum refining and transportation infrastructure is
    also impacted by the accuracy of AN measurements as Metrohm has partnered with industry leaders to
    these acidic compounds lead to corrosion. Until now AN develop an alternative to D664 for the measure
    has been measured by ASTM method D664. However, ment of crude oil and petroleum products. The
    when analyzing crude oils and heavy refinery fractions, resulting ASTM method D8045 describes the use
    method D664 presents the analyst with a number of thermometric titration for this analysis.
    of challenges leading to poor reproducibility bet

    Thermometric titration is ...

    more accurate and reproducible with an improved solvent


    mixture that better dissolves difficult samples containing high
    paraffinic content
    uses less solvent saving you substantial costs for waste disposal
    much faster because results are available in 60 seconds
    without prior sensor conditioning and calibration required

    See for yourself

    ASTM D664 ASTM D8045


    (Potentiometric) (Thermometric)
    Titrant 0.1 mol/L KOH in IPA 0.1 mol/L KOH in IPA
    Solvent Toluene/IPA/water Xylene/IPA
    Solvent volume 125 mL 3035 mL
    Titration time ~220 s ~60 s
    Conditioning of electrode 35 min none
    Solvent wash, rehydration,
    Sensor maintenance IPA dip, refill with electrolyte, Solvent wash is sufficient
    store in LiCl in ethanol
    Sample size (expected AN
    20 2 g ~10 g
    of 0.05 <1.0 mg KOH/g)
    03

    The 859 Titrotherm is available as a walk-up analyzer or an automated configuration.

    859 Titrotherm the best solution for ASTM D8045

    The Metrohm 859 Titrotherm and ASTM D8045 is the What is thermometric titration?
    best solution for the measurement of AN in crude oil and Thermometric titration uses a highly sensitive, fast res
    petroleum products. The 859 Titrotherm is easy to use as ponding sensor to detect an enthalpy change at a single
    it requires no sensor maintenance aside from a sol endpoint. Because all of your sample is dissolved, a con
    vent rinse; this means no hydration, no calibration sistent, reproducible measurement with RSD values less
    and no filling solutions. The entire system is operated than 2% is obtained. Whether you are using a walk-up
    by tiamo, the worlds number one titration software analyzer or an automated systems the results are consis
    where pre-defined methods make it easy to view and tent between operators or locations.
    report results.

    Our automated systems allow you to simply weigh your


    samples and make the measurement. These systems also
    reduce exposure to solvents and will safely operate in a
    fume hood.

    For a complete video demonstration visit


    Get one, well-
    www.metrohm.com/ASTM-D8045

    Thermometric titration determines the endpoint (EP) via the


    reaction enthalpy, i.e. the temperature change in the measuring
    solution

    Metrohm offers dedicated analyzer configurations for ASTM D8045. Please contact your local sales office for
    more information and ordering information.
    Subject to change
    Layout by Ecknauer+Schoch ASW, printed in Switzerland at Metrohm AG, CH-9100 Herisau, Switzerland
    8.000.5199EN 2016-11

    www.metrohm.com

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