GibbsPhaseRule PDF
GibbsPhaseRule PDF
GibbsPhaseRule PDF
A(xA) = A(g) *
TbB
vapor A & B
f'=2
B(xB) = B(g)
Get p1 for each component T f'=1
Get c( p1) such equations:
liquid A & B
Independent variables = c p + 2 p c( p1) f'=2
*
TbA
0 1
f=cp+2 xA, yA
Colby College
f' = c p + 1 cst. P
f "= c p cst. T&P
0 1
xA
For NaCl in water:
Eutectic -21.1 oC at 23% wt/wt giving NaCl2H2O
since: A(s) = A(l), and B(s) = B(l) (doesnt matter which phase)
Colby College