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    How To Improve Rubber Compounds PDF (Dragged)

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    Rivaldi Jovian
    This document discusses ways to improve the heat resistance and degradation resistance of cured rubber compounds. It suggests that TOTM and TINTM plasticizers provide better heat resistance for HNBR compounds than other plasticizers like DOP and DBEEA. For NBR compounds, using higher ACN content rubber, emulsion NBR from a magnesium sulfate coagulating system, ether thioether plasticizers, or fillers like precipitated silica can improve heat resistance. For NR compounds, curing at a lower temperature for longer to form more monosulfide crosslinks or using DPG instead of a dithiocarbamate or thiuram as a secondary accelerator can enhance heat aging characteristics.

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    How To Improve Rubber Compounds PDF (Dragged)

    Uploaded by

    Rivaldi Jovian
    226 views1 page
    This document discusses ways to improve the heat resistance and degradation resistance of cured rubber compounds. It suggests that TOTM and TINTM plasticizers provide better heat resistance for HNBR compounds than other plasticizers like DOP and DBEEA. For NBR compounds, using higher ACN content rubber, emulsion NBR from a magnesium sulfate coagulating system, ether thioether plasticizers, or fillers like precipitated silica can improve heat resistance. For NR compounds, curing at a lower temperature for longer to form more monosulfide crosslinks or using DPG instead of a dithiocarbamate or thiuram as a secondary accelerator can enhance heat aging characteristics.

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    256817685 How to Improve Rubber Compounds PDF (Dragged)

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    This document discusses ways to improve the heat resistance and degradation resistance of cured rubber compounds. It suggests that TOTM and TINTM plasticizers provide better heat resistance for HNBR compounds than other plasticizers like DOP and DBEEA. For NBR compounds, using higher ACN content rubber, emulsion NBR from a magnesium sulfate coagulating system, ether thioether plasticizers, or fillers like precipitated silica can improve heat resistance. For NR compounds, curing at a lower temperature for longer to form more monosulfide crosslinks or using DPG instead of a dithiocarbamate or thiuram as a secondary accelerator can enhance heat aging characteristics.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    226 views1 page

    How To Improve Rubber Compounds PDF (Dragged)

    Uploaded by

    Rivaldi Jovian
    This document discusses ways to improve the heat resistance and degradation resistance of cured rubber compounds. It suggests that TOTM and TINTM plasticizers provide better heat resistance for HNBR compounds than other plasticizers like DOP and DBEEA. For NBR compounds, using higher ACN content rubber, emulsion NBR from a magnesium sulfate coagulating system, ether thioether plasticizers, or fillers like precipitated silica can improve heat resistance. For NR compounds, curing at a lower temperature for longer to form more monosulfide crosslinks or using DPG instead of a dithiocarbamate or thiuram as a secondary accelerator can enhance heat aging characteristics.

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    128 3Improving Degradation Resistance of Cured Rubber Compounds

    TOTM and TINTM plasticizers reportedly impart better heat resistance for
    HNBR compounds than plasticizers such as DOP and DBEEA because these
    trimellitate plasticizers have lower volatility and higher molecular weights.
    DBEEA reportedly is the most recommended for HNBR-based, sulfur-cured
    compounds because it imparts a good balance between low-temperature
    properties and heat resistance. GEN: S. Hayashi, H. Sakakida, M. Oyama,
    T. Nakagawa, Low-Temperature Properties of Hydrogenated Nitrile Rubber
    (HNBR), Rubber Chemistry and Technology, SeptemberOctober, 1991, Vol. 64,
    p. 534.

    NBR
    High-temperature applications for NBR-based compounds often use peroxides
    and thiurams as curatives. RT: Chapter 6, Elastomer Selection, R. School,
    p. 131.
    Using NBR grades with higher ACN content may improve compound heat aging
    resistance. RT: Chapter 8, Specialty Elastomers, M. Gozdiff, p. 194.
    Use an emulsion NBR that is produced from a coagulating system based on
    magnesium sulfate for better heat resistance. RT: Chapter 8, Specialty Elasto-
    mers, M. Gozdiff, p. 196.
    To impart better heat resistance to a nitrile formulation, consider ether thioether
    plasticizers, in which the sulfur functions as a secondary antioxidant. GEN:
    J. Dunn, Compounding Elastomers for Tomorrows Automotive Market, Part II,
    Elastomerics, February, 1989, p. 29.
    To impart better heat resistance to a nitrile formulation, consider using precip-
    itated silica, magnesium oxide, and zinc oxide in place of carbon black. GEN:
    J. Dunn, Compounding Elastomers for Tomorrows Automotive Market, Part II,
    Elastomerics, February, 1989, p. 29.

    Natural Rubber
    For NR compounds, cure at a lower temperature for a longer period of time to
    increase the preponderance of monosulfide crosslinks for better aging prop-
    erties. GEN: M. Studebaker, J. Beatty, Vulcanization, Elastomerics, February,
    1977, p. 41.
    For NR formulations, selecting diphenylguanidine (DPG) as the secondary
    accelerator (kicker) instead of a dithiocarbamate or a thiuram kicker for a
    primary accelerator may improve the compounds heat aging characteristics.
    GEN: B. Ashworth, K. Crawford, Effect of Secondary Accelerator Selection
    on the Aging Characteristics of Natural Rubber Vulcanizates, Rubber World,
    December, 1982, p. 20.

    RT: Rubber Technology, Compounding and Testing for Performance. 2nd ed. Edited by J. S. Dick, Hanser Publications, 2009GEN: General
    References from the LiteratureRP: Review Panel (Advisors for this book)IMPORTANT: The information contained herein is experimental
    in nature and is meant for individuals with advanced scientific training and rubber compounding experience. All safety precautions should be
    taken when replicating or applying this information. The author makes no representation or warranty, either expressed or implied.

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