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Final04 PDF

1. A first-order reaction is taking place in a recycle reactor with an initial concentration of 4 mol/L, reactor volume of 200 L, and volumetric flow rate of 20 L/s. With a recycle ratio of 5, a conversion of 60% is achieved. To replace this with a CSTR-PFR combination achieving the same conversion, the required volume of the PFR is the question. 2. Rate data is given for a reaction at various concentrations to determine the reaction order and rate constant. 3. For an irreversible liquid-phase reaction A + B → C in a CSTR, various parameters including feed rates, temperatures, heat capacities, rate constant, heat transfer

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Naeem Ashraf
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190 views6 pages

Final04 PDF

1. A first-order reaction is taking place in a recycle reactor with an initial concentration of 4 mol/L, reactor volume of 200 L, and volumetric flow rate of 20 L/s. With a recycle ratio of 5, a conversion of 60% is achieved. To replace this with a CSTR-PFR combination achieving the same conversion, the required volume of the PFR is the question. 2. Rate data is given for a reaction at various concentrations to determine the reaction order and rate constant. 3. For an irreversible liquid-phase reaction A + B → C in a CSTR, various parameters including feed rates, temperatures, heat capacities, rate constant, heat transfer

Uploaded by

Naeem Ashraf
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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1. A first-order reaction A → B is taking place in a recycle reactor.

The initial concentration is


4 mol/liter, the reactor volume is 200 liters and the volumetric flow rate is 20 liters/s. For a
recycle ratio of 5, a conversion of 60% is obtained. This configuration is to be replaced with
a CSTR-PFR combination. A 50-liter CSTR is followed by a PFR of unknown volume.
What volume of PFR is required is achieve the same conversion as in the recycle reactor?
17 points
2. Rate versus concentration data for a reaction is given below. Find the order of the reaction
and the reaction rate.

Con. (mol/liter) 1.5 1.3 1.1 0.9 0.7 0.5 0.3


Rate (mol/lit-sec) 28 20 12.8 7.7 4.1 1.8 0.5

16 points
3. An elementary irreversible liquid-phase reaction A + B → C is carried out in a CSTR. A and
B are fed at molar rates of 1.25 mol/s and 1 mol/s respectively, at a temperature of 300 K.
The reactor is jacketed and the jacket temperature can be assumed to be 310 K. An agitator
contributes a work of 20.9 kW to the reactor. The volumetric flow rate is 5 lit/s. Additionally:
H A0 (298 K ) = −20 kcal/mol H B0 (298 K ) = −25 kcal/mol H C0 (298 K ) = −60 kcal/mol
cal cal
C pA = C pB = 40 , C pC = 55
mol ⋅ K mol ⋅ K
lit cal
k = 0.01 at 300 K, U ⋅ A = 75 , E = 8 kcal/mol
mol ⋅ s s⋅K
Determine the volume of the reactor for 60% conversion of A.
17 points
4. Mechanism of a catalytic reaction A → B is shown below.

⎯⎯→ A ⋅ S
A + S ←⎯⎯
kA

k− A

⎯⎯→ B ⋅ S
kS
A ⋅ S ←⎯⎯
k− S

⎯⎯→
kD
B ⋅ S ←⎯⎯ B+S
k− D

Write down the rates of adsorption, surface reaction and desorption and derive an effective rate
when, surface reaction is rate controlling.

16 points
5. A first-order reaction A → 3B is taking place in a PBR. The particles are 10 mm in diameter
and the intrinsic rate constant ( k ′ )is 0.8 lit/kg-cat-s. A conversion of 75% is desired. Feed
at 4 mol/s, containing 40% A and 60% inerts enters the reactor at 1270C and 5 atmospheres.
The engineer designing the reactor neglects to consider that there might be internal diffusion
to consider.
a. What weight of the catalyst does the engineer pack the reactor with?
b. If the diffusion coefficient is 0.08 cm2/s ad bulk density of the catalyst is 2.8 kg/liter,
what conversion would actually result with the catalyst packed?
c. What weight of the catalyst did he need to use to meet the design specifications of
75% conversion?
Assume that the reactor operates at constant pressure.

17 points
6. The residence time distribution function for a reactor is given below. The reaction is ½
mol1/2
order, CA0= 1 mol/lit and the rate constant is 2 1/2 . Determine the conversion in the
lit − min
reactor using the segregated-flow model.

0.5
E(t)

0 t (min) 2
17 points

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