Unit - I
Unit - I
Unit - I
• Material –
• The matter from which things can be made.
• Matter –
• Physical substance that occupies space and posses rest mass.
Engineering Metallurgy by Mr. Ajay A. Joshi
(Assistant Professor, Department of Mechanical Engineering, 15
SBJITMR, Nagpur)
Important terminologies
• States of matter –
• Crystalline –
• periodic arrangement of atoms: definite repetitive pattern
• Non-crystalline or Amorphous –
• random arrangement of atoms.
• The periodicity of atoms in crystalline solids can be described by a
network of points in space called lattice.
Engineering Metallurgy by Mr. Ajay A. Joshi
(Assistant Professor, Department of Mechanical Engineering, 39
SBJITMR, Nagpur)
Space Lattice, Bravais Lattice and
Crystal System
• In the FCC lattice each atom is in contact with 12 neighbor atoms. FCC coordination
number Z = 12
• For example, the face centered atom in the front face is in contact with four corner
atoms and four other face-centered atoms behind it (two sides, top and bottom) and is
also touching four face-centered atoms of the unit cell in front of it.
• In Hexagonal lattice Z = 12. The center atom of the top face is in touch with
six corner atoms, three atoms of the mid layer and other three atoms of
the mid layer of the unit cell above it.
Engineering Metallurgy by Mr. Ajay A. Joshi
(Assistant Professor, Department of Mechanical Engineering, 57
SBJITMR, Nagpur)
Atomic Packing Factor and Lattice
defects
• a = Lattice parameter
• R = Radius of atom
Engineering Metallurgy by Mr. Ajay A. Joshi
(Assistant Professor, Department of Mechanical Engineering, 60
SBJITMR, Nagpur)
APF (FCC)
• In the FCC unit cell effective number of atoms = 8 corner atoms x (1/8) (each
atom is shared by 8 unit cells) + 6 face centered atoms x1/2 (each shared by two
unit cells) = 4
• Total volume of atoms = × ×
• The relation between R and the FCC cell side a is
• (DB)2=(DC) 2+(CB) 2
• (4R) 2=a2+a2
• a 2= 4R
× ×
• APF (FCC) =
=
= 0.74
Engineering Metallurgy by Mr. Ajay A. Joshi
(Assistant Professor, Department of Mechanical Engineering, 61
SBJITMR, Nagpur)
APF (FCC)
× ×
• APF (BCC) =
=
= 0.68