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Material Safety Data Sheet

Cobalt Chloride Solution MSDS
Section 1: Chemical Product and Company Identification

Product Name: Cobalt Chloride Solution Contact Information:

Catalog Codes: SLC3259 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: Mixture. Houston, Texas 77396
RTECS: Not applicable. US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Water; Hydrochloric acid;
Cobalt chloride hexahydrate Order Online: ScienceLab.com

CI#: Not available. CHEMTREC (24HR Emergency Telephone), call:

1-800-424-9300
Synonym: Cobalt Chloride Solution
International CHEMTREC, call: 1-703-527-3887
Chemical Name: Not applicable.
For non-emergency assistance, call: 1-281-441-4400
Chemical Formula: Not applicable.

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Water 7732-18-5 95.2
Hydrogen chloride 7647-01-0 3.63
Cobalt chloride hexahydrate 7791-13-1 1.2

Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat]. Cobalt chloride
hexahydrate: ORAL (LD50): Acute: 766 mg/kg [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact
(corrosive, sensitizer, permeator), of eye contact (corrosive), of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid
or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin
contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of the eye is characterized
by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Cobalt chloride hexahydrate]. Mutagenic for bacteria and/or yeast. [Cobalt chloride

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hexahydrate]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Reproductive system/
toxin/male [POSSIBLE] [Cobalt chloride hexahydrate]. The substance may be toxic to blood, lungs, upper respiratory tract,
skin, eyes, , teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or
prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged
exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated
exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical
attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may
be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or
corrosive. Seek medical attention.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Non combustible
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

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Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:
Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray
to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.
In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show
the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organic
materials, metals, alkalis, moisture.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 24°C (75.2°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection:
Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Hydrogen chloride STEL: 7.5 (mg/m3) from ACGIH (TLV) [United States] STEL: 5 (ppm) from ACGIH (TLV) [United States]
CEIL: 5 (ppm) from NIOSH CEIL: 7.5 (mg/m3) from NIOSH CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3)
from OSHA (PEL) [United States]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Not available.
Taste: Not available.
Molecular Weight: Not applicable.
Color: Not available.
pH (1% soln/water): Neutral.
Boiling Point: The lowest known value is 100°C (212°F) (Water).
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: Weighted average: 1.01 (Water = 1)

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Vapor Pressure: The highest known value is 2.3 kPa (@ 20°C) (Water).
Vapor Density: The highest known value is 0.62 (Air = 1) (Water).
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water, diethyl ether, acetone.
Solubility:
Easily soluble in cold water, hot water. Soluble in diethyl ether, acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.
Conditions of Instability: Incompatible Materials
Incompatibility with various substances: Reactive with oxidizing agents, organic materials, metals, alkalis.
Corrosivity:
Highly corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive in presence
of glass.
Special Remarks on Reactivity:
It reacts with oxidizers releasing chlorine gas. Incompatible with alkalis, amines, metals [copper and alloys (brass), zinc
(galvanized materials), hydroxides, organic materials, alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides,
sulphides, phospohides, cyanides, carbonates, It can react with formaldehyde. Reacts with most metals to produce flammable
Hydrogen gas.
Special Remarks on Corrosivity:
Highly corrosive. There is no data on corrosivity in presence of zinc, steel, copper or brass. However, hydrochloric acid is
incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum, silver, and certain
alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.
Toxicity to Animals: Acute oral toxicity (LD50): 766 mg/kg [Rat]. (Cobalt chloride hexahydrate).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrogen chloride]. MUTAGENIC EFFECTS:
Mutagenic for mammalian somatic cells. [Cobalt chloride hexahydrate]. Mutagenic for bacteria and/or yeast. [Cobalt chloride
hexahydrate]. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/male [POSSIBLE] [Cobalt chloride
hexahydrate]. May cause damage to the following organs: upper respiratory tract, skin, eyes, teeth.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive, sensitizer,
permeator), of eye contact (corrosive), of inhalation (lung sensitizer, lung corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects. May affect genetic material.

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Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. May be absorbed through skin in harmful
amounts. Eyes: Causes severe eye irritation and burns. May cause irritation of the conjuctiva or blindness Inhalation: Causes
irritation and possible burns of the respiratory tract and mucous membranes. May affect the liver and sense organs Ingestion:
May be harmful if swallowed. Causes irritation with vomiting, nausea, diarrhea, pain. May cause burning of the gastrointestinal
tract. Can cause nausea and vomitting. May affect behavior, the cardiovascular system, and urinary system

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Hydrochloric Acid Solution UNNA: 1789 PG: III
Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric
acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK
hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts
RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:
Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid TSCA 8(b)
inventory: Water; Hydrochloric acid; Cobalt chloride hexahydrate TSCA 4(a) proposed test rules: Hydrochloric acid SARA
302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release
reporting: Hydrochloric acid 9.8% CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg);
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic
effects (VERY TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC):
R20- Harmful by inhalation. R25- Toxic if swallowed. R34- Causes burns. R42/43- May cause sensitization by inhalation and
skin contact. S1/2- Keep locked up and out of the reach of children. S23- Do not breathe gas/fumes/vapour/spray [***] S24-
Avoid contact with skin. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident

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or if you feel unwell, seek medical advice immediately (show the label where possible). S46- If swallowed, seek medical advice
immediately and show this container or label.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection:
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/10/2005 12:59 AM
Last Updated: 05/21/2013 12:00 PM

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