Lesson 19
Lesson 19
Lesson 19
Aim :
To study metallic bonds and the electrical conductivity of metals in terms of conduction
bands.
Learning Outcomes :
Underlying Principles
1. Making the invisible, visible.
2. Enabling students to know what to look for.
Differentiation
Questions in the student notes are designed to enable all students to complete the activity.
The pop-up answers are provided for the students to view when they have considered their
responses. Worksheet questions include questions that require recall, understanding and
application of the new concepts learned.
1.1 The atoms in sodium are held together by metallic bonds. Metallic
bonds are the forces of attraction between the positive metal ions
and the negative delocalised electrons that surround the metal ions.
+
Na ions
sea of electrons
3. Band theory
3.1 a. i. The valence band is a group of very closely spaced molecular orbitals
that contain the valence electrons.
ii. The electrons in the 4s band in calcium jump up into the 4p band
which is empty. The electrons can then hop from one empty orbital of
an atom to another empty orbital of a neighbouring atom.
4. Band models
4.1 Conductors are substances that are capable of conducting electric current while
insulators are substances that are poor conductors of electricity.
The valence and conduction bands in conductors overlap. The conduction band is
always partly filled with electrons which can move throughout the solid.
There is a large gap between the valence and conduction bands in an insulator. No
electrons exist in the conduction band as a large amount of energy is needed to
excite an electron from the valence band into the conduction band. As a result,
electrons cannot move freely throughout the solid.
Conduction band
Conduction band
Energy
Energy
Energy gap
Valence band
Valence band
Conductor Insulator