SAFETY DATA SHEET

Infosafe No.: LQ5XU

Triple7 EOR (Enhanced Oil Issued Date: 23/01/2017
Recovery) Issued by: Envirofluid

1. IDENTIFICATION
GHS Product Identifier
Triple7 EOR (Enhanced Oil Recovery)
Product Code
AAEOR-5 5 litres, AAEOR-20 20 litres, AAEOR-200 200 litres, AAEOR-BB 1000 litres
Company Name
Envirofluid
Address
39 Coghlans Road Warrnambool
Victoria 3280 Australia
Telephone/Fax Number
Tel: 1800 777 580 (8am - 5pm AEST)
Fax: 1300 777 580
Emergency phone number
1800 638 556 (24h) / +61 3 5564 6455
E-mail Address
info@envirofluid.com
Recommended use of the chemical and restrictions on use
Bio based biodegradable liquid for crude oil extraction and enhanced oil recovery operations. No restrictions on use.
Additional Information
Free of ozone depleting chemicals. Triple7 EOR does not contain petroleum products, glycol ethers, terpenes, strong
acids, caustics, phosphates, lauryl sulphates, or volatile organic compounds (VOC's.) Safe for rubbers and seals.

2. HAZARD IDENTIFICATION
GHS classification of the substance/mixture
Not classified as Hazardous according to the Globally Harmonised System of Classification and Labelling of Chemicals
(GHS) including Work, Health and Safety regulations, Australia.
Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road
and Rail. (7th edition)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients
Name CAS Proportion

Ingredients determined not to be hazardous 100 %

4. FIRST-AID MEASURES
Inhalation
If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms develop and/or
persist seek medical attention.
Ingestion
Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical attention.
Skin
Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention.
Eye contact
If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue
flushing for several minutes until all contaminants are washed out completely. If symptoms develop and/or persist seek
medical attention.
First Aid Facilities
Eyewash and normal washroom facilities.
Advice to Doctor
Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use appropriate fire extinguisher for surrounding environment.
Unsuitable Extinguishing Media
Water jet.
Hazards from Combustion Products
Under fire conditions this product may emit toxic and/or irritating fumes including oxides of nitrogen, carbon monoxide
and carbon dioxide.
Specific Hazards Arising From The Chemical
The product itself does not burn. No unusual fire or explosion hazards noted.
Decomposition Temperature
Not available
Precautions in connection with Fire
Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) and full protective clothing to prevent exposure to
vapours, fumes or products of combustion. Water spray may be used to cool down heat-exposed material. If safe to do
so, remove containers from path of fire. Do not allow run-off from fire fighting to enter drains or water courses.
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures
Wear appropriate personal protective equipment and clothing. Stop the leak if safe to do so. Evacuate unprotected
personnel. If possible contain the spill. Surfaces may become slippery after spillage. Flush residue with ample water. If
spilt on electrical equipment will cause short-circuits. Place inert absorbent, non-combustible material onto spillage.
Collect the material and place into suitable labelled containers for recycling or disposal. Dispose of waste according to
the applicable local and national regulations.

7. HANDLING AND STORAGE

Precautions for Safe Handling
Avoid inhalation of vapours and mists, and skin or eye contact. Use only in a well ventilated area. Keep containers
sealed when not in use. Prevent the build up of mists or vapours in the work atmosphere. Maintain high standards of
personal hygiene by washing hands prior to eating, drinking, smoking or using toilet facilities.
Conditions for safe storage, including any incompatibilities
Store in a cool, dry, well-ventilated area, out of direct sunlight. Protect from freezing. Freezing will affect the physical
condition but will not damage the material. Store in suitable, labelled containers. Keep containers tightly closed. Store
away from incompatible materials. Ensure that storage conditions comply with applicable local and national regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure limit values
No exposure standards have been established for the mixture. However, over-exposure to some chemicals may result
in enhancement of pre-existing adverse medical conditions and/or allergic reactions and should be kept to the least
possible levels.
Biological Limit Values
No biological limits allocated.
Appropriate Engineering Controls
Use with good general ventilation. If mists or vapours are produced, local exhaust ventilation should be used.
Respiratory Protection
Respiratory protection not normally required. If engineering controls are not effective in controlling airborne exposure
then an approved respirator with a replaceable filter should be used. Reference should be made to Australian/New
Zealand Standards AS/NZS 1715, Selection, Use and Maintenance of Respiratory Protective Devices; and AS/NZS
1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances.
Eye Protection
Safety glasses with side shields or chemical goggles should be worn. Final choice of appropriate eye/face protection will
vary according to individual circumstances. Eye protection devices should conform with Australian/ New Zealand
Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.
Hand Protection
Wear impervious chemical resistant gloves. Final choice of appropriate gloves will vary according to individual
circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/
NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.
Body Protection
Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist. When large quantities are handled the use
of plastic aprons and rubber boots is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form
Liquid
Appearance
Clear free flowing liquid
Colour
Yellow to light amber
Odour
Mild surfactant
Decomposition Temperature
Not available
Melting Point
0°C (ASTM 097)
Boiling Point
100°C (ASTM 01120)
Solubility in Water
100% soluble
Specific Gravity
-1.01 (15.5°C) (ASTM 0891)
pH
9.9-10.9
Vapour Pressure
< 5 mm Hg (37.8°C) (ASTM D323)
Vapour Density (Air=1)
Not available
Evaporation Rate
>5 (relative to xylene)
Odour Threshold
Not available
Viscosity
5 cPs (24°C) (ASTM 02196)
Volatile Component
Volatiles: 93% by wt. (including water) (105°C) (ASTM 0800)
VOC: None measurable by USEPA 601, 602, 608
Partition Coefficient: n-octanol/water
Not available
Density
-1.01 kg/l (15°C)
Flash Point
>100°C (ASTM D93 Closed Cup)
Flammability
Not flammable
Auto-Ignition Temperature
Not applicable
Flammable Limits - Lower
Not applicable
Flammable Limits - Upper
Not applicable
Other Information
Surface Tension: 31.5 dynes/cm (ASTM 01331)

10. STABILITY AND REACTIVITY

Reactivity
Reacts with incompatible materials.
Chemical Stability
Stable under normal conditions of handling and storage.
Conditions to Avoid
Extremes of temperature and direct sunlight.
Incompatible materials
Not available
Hazardous Decomposition Products
Thermal decomposition may result in the release of toxic and/or irritating fumes, smoke and gases including: carbon
monoxide and carbon dioxide.
Possibility of hazardous reactions
Not available
Hazardous Polymerization
Will not occur

11. TOXICOLOGICAL INFORMATION

Toxicology Information
The available toxicity data is given below.
Acute Toxicity - Oral
LD50 (rat): >5000 mg/kg bw
Acute Toxicity - Dermal
LD50 (rabbit): >2000 mg/kg bw
Ingestion
Ingestion of this product may irritate the gastric tract causing nausea and vomiting.
Inhalation
Inhalation of product vapours may cause irritation of the nose, throat and respiratory system.
Skin
Causes mild skin irritation. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin
dryness and cracking and may lead to dermatitis.
Primary Skin Irritation in Rabbits: Cat. III, Moderate Irritation at 72-hrs.
Eye
Causes mild eye irritation. On eye contact this product can cause tearing, stinging, blurred vision, and redness.
Sample caused minimal occular irritation (In Vitro Occular Irritection test)
Respiratory sensitisation
Not expected to be a respiratory sensitiser.
Skin Sensitisation
Not expected to be a skin sensitiser.
Germ cell mutagenicity
Not considered to be a mutagenic hazard.
Carcinogenicity
Not considered to be a carcinogenic hazard.
Reproductive Toxicity
Not considered to be toxic to reproduction.
STOT-single exposure
Not expected to cause toxicity to a specific target organ.
STOT-repeated exposure
Not expected to cause toxicity to a specific target organ.
Aspiration Hazard
Not expected to be an aspiration hazard.

12. ECOLOGICAL INFORMATION

Ecotoxicity
The available ecological data is given below. Not expected to be harmful to aquatic organisms.
Persistence and degradability
The product is biodegradable.
Mobility
The product is miscible with water. May be spread in water systems.
Bioaccumulative Potential
Does not bioaccumulate.
Other Adverse Effects
Not available
Environmental Protection
Prevent large amounts from entering waterways, drains and sewers.
Acute Toxicity - Fish
LC50(Pimephales promelas): 316mg/l/96h (100% survival at 100 mg/l)
Acute Toxicity - Algae
EC50 (Skeletonema costatum): 18.74 mg/kg/72h
Other Information
10-day Acute Toxicity LC50 (Crustacea, Corophium volutator): >16203 mg/kg
13. DISPOSAL CONSIDERATIONS
Disposal considerations
Dispose of waste according to applicable local and national regulations.

14. TRANSPORT INFORMATION

Transport Information
Road and Rail Transport (ADG Code):
Not classified as Dangerous Goods according to the Australian Code for the Transport of Dangerous Goods by Road
and Rail (ADG Code) (7th edition).

Marine Transport (IMO/IMDG):

Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code)
for transport by sea.

Air Transport (ICAO/IATA):

Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous
Goods Regulations for transport by air.
U.N. Number
None Allocated
UN proper shipping name
None Allocated
Transport hazard class(es)
None Allocated
Special Precautions for User
Not available
IMDG Marine pollutant
No
Transport in Bulk
Not available

15. REGULATORY INFORMATION

Regulatory information
Not classified as Hazardous according to the Globally Harmonised System of Classification and labelling of Chemicals
(GHS) including Work, Health and Safety regulations, Australia.
Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling of Medicines and Poisons
(SUSMP).
Poisons Schedule
Not Scheduled
 16. OTHER INFORMATION
Date of preparation or last revision of SDS
SDS reviewed: January 2017
Supersedes: September 2016
References
Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice.
Standard for the Uniform Scheduling of Medicines and Poisons.
Australian Code for the Transport of Dangerous Goods by Road & Rail.
Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted
hazardous chemicals.
Workplace exposure standards for airborne contaminants, Safe work Australia.
American Conference of Industrial Hygienists (ACGIH).
Globally Harmonised System of classification and labelling of chemicals.

END OF SDS
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