Data sheet DS/PGC5007B-EN Rev.

PGC5007B Total sulfur analyzer

PGC5000 Series gas chromatographs

Measurement made easy

Online ASTM method

D7041-04 (2010)

ASTM method approval Flexible analyzer system configuration options

— The first and only Total Sulfur Process Analyzer with an — PGC5000 Series multiple oven platform
online ASTM method — Extensive I/O options
— ASTM D7041-04(2010) — Standard modular SHS (vapor and liquid)
— Optional Smart SHS compatibility (vapor and liquid)
Wide range of streams and measurement levels — Added to existing PGC5000 series applications
— Vapor and liquid samples
— Percent to ppb level measurements Simplest Total Sulfur application method
— Sample Injection Oxidation Separation Detection
Data and commincation
— Designed for the process analytical network Online, process analysis design
— Industry standards available for Distributed Control — Process hardened hardware
Systems (DCS) — Valves
— Vaporizer
— Furnace
— Column
— Detector
PGC5007B Total sulfur analyzer
PGC5000 Series gas chromatographs

Latest analyzer designs

New LSV and vaporizer assembly
— Thermal isolation for sample lines from oxidation furnace
temperature
— Prevents unwanted vaporizaztion of liquids with
highly volitle components, i.e. gasoline
— Provides improved analysis accuracy

Direct injection for liquid samples

— Provides complete vaporization of heavy samples and
ensures complete oxidation in furnace
— Improves analysis on heavy samples
— Improves detection limits and performance for
sub-ppm levels
— Eliminates contamination from partially vaporized
samples

New oxidation furnace

— Lower furnace temperature requirement
— 900 °C for complete conversion and longer life-
expectancy of quartz
— Reliability
— Easier to maintain and more accessible furnace
assembly

New flame photometric detector (FPD) with latest

photomuliplier tube (PMT) technology
— Smaller compact design saves space for use in the
PGC5000B Smart OvenTM
— Overall smaller design enhances sensitivity for ppm
and ppb sulfur measurements
— Thermo electrically cooled PMT provides superior life
expectancy

2 PGC5007B Total sulfur analyzer | PGC5000 Series gas chromatographs | DS/PGC5007B-EN

ASTM D7041-04(2010) Method highlights:
Sample sweep
Precision and bias data: — Results are a matrix independent measurement at the
Repeatability and Reproducibility detector
— Guaranteeing interference free measurements
X Gasoline Gasoline Diesel Diesel — Insures complete oxidation of the injected sample
(mgS/kg) Repeatability Reproducibility Repeatability Reproducibility

3 0.53 2.08 0.28 2.63 Lower oxidation furnace temperature

6 0.53 2.28 0.33 3.15 — Leads to a long life span of the oxidation chamber and

9 0.53 2.47 0.37 3.5 heating element

15 0.53 2.87 0.42 3.99

30 0.53 3.85 0.5 4.78 Usage:

50 0.53 5.17 0.57 5.45 The PGC5007 performs a Total Sulfur analysis for a range of

80 0.53 7.14 0.65 6.16 streams, liquid and vapor, from natural gas to gasoline and
diesel. The reaction below demonstrates the conversion of the
Application sample to Total Sulfur for measurement.

Description: R-S + R-H + Air(O2) SO2 + CO2 + H2O

A fixed volume of sample from the process stream is injected
via a sample inject valve. Air transports the sample into the 900°C
furnace, where it oxidizes the sample to carbon dioxide,
water, and sulfur dioxide. These components are separated
using packed columns and pass into the FPD, where the
trace levels of Total Sulfur are measured.

DS/PGC5007B-EN | PGC5000 Series gas chromatographs | PGC5007B Total sulfur analyzers 3

PGC5007B Total sulfur analyzer
PGC5000 Series gas chromatographs

Standard vapor sample system

Sulfinert coating, single stream,
single calibration, single validation.

Standard liquid sample system

Sulfinert coating, single stream,
single calibration, single validation.

4 PGC5007B Total sulfur analyzer | PGC5000 Series gas chromatographs | DS/PGC5007B-EN

Application
Chromatograms and detector linearity:

Concentration Peak area

(ppm) (counts)
0.00 11.76
1.95 36.41
3.90 60.50
Peak Area (counts)

7.81 110.23
15.63 210.42
31.25 423.07
62.50 864.21
Total 125.00 1671.13

Concentration (ppmwt)

DS/PGC5007B-EN | PGC5000 Series gas chromatographs | PGC5007B Total sulfur analyzers 5

PGC5007B Total sulfur analyzer
PGC5000 Series gas chromatographs

PGC5007B Oven
Physical
Environmental (enclosure): Protected from weather: IP 54, (NEMA 3 equivalent)
Ambient temperature range: 0 to +50° C (32 to 122° F)
Humidity: 95% relative humidity, non-condensing
Dimensions: 596.5 mm W x 419.1 mm D x 609.6 mm H
(23.5 in. W x 16.5 in. D x 24 in. H)
Weight: 54.4 kg (120 lb) (minimum, configuration dependent)
Wall: 32 mm (1.3 in.) from wall with brackets
Floor: Optional dolly with casters
EMI/RFI considerations: Conforms to Class A industrial environment
Electrical entries: Left side
Pneumatic entries: Right side
Sample entries: Vapor: right side, 1 each model M2CP
Liquid: right side, 1 each model 791 LSV
Vents: Right side

Safety area classification

CSA / NRTL: Class I, Division 1; Gas groups B, C, D with type Y-Purge
Class I, Division 2; Gas groups B, C, D
Temperature code T3 – T2
ATEX / IEC: Zone 1: CE 0344; II2G, Ex py de IIB+H2 T3 – T2
Zone 2: CE; II3G Ex nA nL de IIB+H2 T3 – T2
CN / KO / RU: Ex px de IIB+H2 T3 – T2
With X-purge power interlock
(Purge wait time) 18 minutes (Class I, Division 1 / Zone 1 area)

Power (Hot, neutral, ground)

Voltage: 100-240 Vac
Frequency: 50/60 Hz
Power consumption: 1,200 Watts startup, 900 Watts steady-state operation
Typical, varies with installed options

Instrument air
Supply connection: 3/8 inch tube, minimum
Supply pressure: 414 kPa (60 psig)
Quality: Instrument grade: Clean, oil free and -34° C, (-30° F) dewpoint
Flow rates: Steady state: 127-147 L/min (4.5-5.2 ft3/min) at 20° C
Y-purge types

6 PGC5007B Total sulfur analyzer | PGC5000 Series gas chromatographs | DS/PGC5007B-EN

Analytical detectors

Standard detector: Photomutiplier tube with flame photometric burner block

Isothermal analytical oven

Oven liner: Stainless Steel
Internal dimensions: 327.7 mm W x 391.16 mm H x 287 mm D
(12.9 in. W x 15.4 in. H x 11.3 in. D)
Number of valves: Vapor application: 1 internal vapor sample valve
Liquid application: 1 external liquid sample valve
Columns: Packed
Heat: Forced air
Temperature control method: Closed loop PID
Oven temperature: Ambient +30°C to 180°C
Set to ~ 112° C for total sulfur applications
Setpoint resolution: 1°C
Temperature stability: Steady ambient: ±0.1°C
Ambient range: ±1.0°C

Oxidation furnace
Furnace material: Stainless Steel shell over a ceramic core, all enclosed in a flameproof housing
Internal dimensions: 305 mm W x 153 mm H x 102 mm D
(12 in. W x 6 in. H x 4 in. D)
Ceramic core heat: Electric
Temperature control method: Closed loop PID
Furnace temperature: 900°C

Gas control
Electronic control method: Closed loop PID; temperature stabilized
Number of zones: 1 for air, 1 for burner fuel and 1 for sweep gas
Filtration: 2µm at inlet, provided
Inlet pressure: Minimum: Setpoint + 69 kPa (10 psig)
Maximum: 1034 kPa (150 psig)
Range: 0-100 psig, bubble tight, non-venting
Gauges: Electronic readout: 0.01 psig resolution
Setpoint resolution: 0.01 psig
Accuracy: 0-50 psig: 1.7%
50-100 psig: 2.7%
Repeatability: ±0.1 psig
Allowable gasses: Zero grade air - carrier,
Zero grade air - burner air
GC grade H2 - burner fuel

DS/PGC5007B-EN | PGC5000 Series gas chromatographs | PGC5007B Total sulfur analyzers 7

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