Aits FT 1

FIITJEE JEE (Main), 2018
FULL TEST – I
Time Allotted: 3 Hours Maximum Marks: 360

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u l l y. Yo u a r e a l l o t t ed 5 m i n ut es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
 Yo u a r e n o t a ll o wed t o l ea v e t h e E xa m i n at i o n Ha ll b ef o r e t h e en d o f
ALL INDIA TEST SERIES
t h e t es t .
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part has only one section: Section-A.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

1. Section-A (01 to 30) contains 30 multiple choice questions which have only one correct answer.
Each question carries +4 marks for correct answer and –1 mark for wrong answer.
Name of the Candidate
Enrolment No.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
AITS-FT-I-PCM-JEE(Main)/18
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2
Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6  1019 C
Mass of electron me = 9.1  1031 kg
Permittivity of free space 0 = 8.85  1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s constant h = 6.625  1034 Js
= 6.625  10–27 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J
Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3
Physics PART – I
SECTION – A
Straight Objective Type
This section contains 30 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D),
out of which only ONE is correct.
1. A man moving on track ABC, getting rain drops vertical for

the path AB, and along same line of its motion for path BC
then actual speed of rain drop is
(A) 10 3ms1
10
(B) ms1
3
(C) 5 3ms1
(D) Can’t find
2. Two bodies A and B are at positions (2, 3) m and (5, 7) m respectively. These two are moving
with constant velocity 3 ms-1 along –ve y axis and 4ms-1 along +ve x axis respectively. Minimum
separation between them during their motion is
(A) 5 m (B) 3 m
(C) 4 m (D) 10 m
3. A force F acts tangentially on a part of a F

uniform disc of mass ‘m’ and radius ‘R’
hinged at point O. The force exerted by A B
hinge on the portion of disc initially.
4
(A)  F
   AOB  600 and OA  OB  R
4F
(B)

X
2
(C) F   O
  
F
(D)
2
Space for rough work
4
4. If acceleration gradient of a moving body along positive x-axis is -4s-2 and body starts its motion
from rest from x = 5m, having maximum acceleration (magnitude) then velocity of moving body at
x = -3m is
(A) 6 ms1 (B) 4 ms1
(C) 8 ms1 (D) Cant reach at x = -3m
5. In the figure shown ABCD is a lamina of mass 12 kg. The moment A 2m B

of inertia of the given body about an axis passing through D, and
perpendicular to the plane of the body is 1270
(A) 256 kg m 2 (B) 512 kg m 2 10 m
2
(C) 200 kg m (D) 100 kg m2 14 m
900
D
6. For the arrangement as shown in the figure,

the maximum force F, for no relative motion
between blocks is
(A) 12 N
(B) 8 N
(C) 20 N
(D) 24 N
7. One mole of a monoatomic gas undergoes a linear process P

A  B in P – v diagram. The volume of the gas when the
P0
process turns from an endothermic to an exothermic one is A
5 v
(A) v 0 (B) 0
8 2 B
8v 0 3v 0
(C) (D)
15 5 V
V0
5
8. Two coaxial solenoids having same number of turns per unit length n, and radius R and 2R
respectively have no current initially. Current in both grows uniformly such that current in the inner
one is twice that of the outer one, at any instant of time in the same direction. Current in outer one
at time t is Kt then induced electric field at a distance r from axis is (R < r < 2R).
 nK
(A) Not possible (B) 0
2r

2R2  r 2 
20nK.R2 20 nK
(C)
r
(D)
r
2R2  r 2 
9. A particle of mass m moves in a force field such that its potential energy in force field is defined
2 2
by the equation U   A  x  a   x  b  . Where A, a and b are +ve constants then body may
oscillate simple harmonically about point.
(A) a only (B) a and b both
ab
(C) only (D) b only
2
10. Find minimum value of F such that m 2 starts its motion on F

m2 m1
the ground
  2m1  m 2  g 0 0
(A) 0
2
(B) 0  2m1  m2  g
(C) 0  m1  m2  g
0  m1  m2  g
(D)
2
11. Molecule of a gas in a container hits one wall (1) normally

and rebounds back. It suffers number of collision and hits the
opposite wall (2) which is at angle of 300 with wall 1.
Assuming the collision to be elastic and the small collision
time to be the same for both the walls. The magnitude of
average force by walls and 2 are F1 and F2 provide to
molecule during collision satisfy
(A) F1  F2 (B) F1  F2
(C) F1  F2 both non zero (D) F12F220
6
12. A thermometer uses density of water as thermometric
Density
property. Actual reading in thermometer is height of water (h)
which inversely proportional to the density of water (d). In T1 T2
certain temp range density of water varies with temp as shown T1 T2
in the graph is symmetrical about maximum.
Two identical bodies (of same mass and specific heat) at
different temp T1 and T2 show the same reading of height h1 =
h2 in the thermometer. The bodies are brought in contact and
allowed to reach the equilibrium. The thermometric reading
T2
height of water for final equilibrium state hf satisfies
T1 Temp
h  h2
(A) hf  1  h1  h2
2
(B) hf  h1  h2
(C) hf ,h1  h2
(D) hf may be greater or less than h1  h2
13. A power supply of fixed emf E is connected to a variable resistor (resistance = R) and an
ammeter of resistance RA. The internal resistance of supply is r. The potential difference between
the terminals of the power supply in closed circuit is denoted by V and current in circuit denoted
by I. A graph is obtained between V and I by drawing varying amount of current from the supply.
The correct V – I graph for the given situation is
V V V V
E E
E/r I I I E/r I
I II III IV
(A) Graph I (B) Graph II
(C) Graph III (D) Graph IV
7
14. If the switch is closed for long time and then open at  s
t = 0, the P.D across indicator at t = 0 is
(A) OV
(B) 50 V

10mH
(C) 20 V 50 V
(D) 100 V
15. A disc having uniform surface charge density in upper part + and –in lower
half placed on rough horizontal surface as shown in figure. A uniform electric + + ++
++ ++ ++
field is set up as shown if mass of disc is M and its radius is R as well sufficient + + ++ ++
+
friction is present to prevent slipping. The acceleration of disc is
2 2
8 R E0 9 R E0
(A) (B)
9 M 8 M
2 2
4 R E 0 3 R E 0
(C) (D)
3 M 4 M
16. If L = 25 mH, C = 1 mF and R = 10 then R.M.S current across

source is
(A) 5 2 A (B) 2.5 2A
(C) 12.5 2A (D) 25 2 A
50 sin(200t)V
8
17. From a sphere of electrical conductivity K two planes cut a piece such
that first plane passes through the centre of sphere and second parallel
to first one at distance R/2 from centre then resistance between A
and B
1 3
(A) (B)
KR KR R/2
n3
(C) (D) None
2KR
B
A
18. A thin rectangular plate with sides of length ‘a’ and ‘b’ has mass y
 xy 
per unit area varying as    0   where 0 is a constant.
 ab 
The co-ordinate of centre of mass of the plate is
a b a b b
(A)  ,  (B)  . 
3 3  2 2
 4a 4b   2a 2b  a x
(C)  ,  (D)  , 
 3 3   3 3 
19. A wire carrying 10 A current is bent to pass through various y

side of

a cube of side 10 cm as shown in figure. A magnetic
field B  2iˆ  3ˆj  kˆ is present in region then torque on the
loop.
(A) 20  10 1Nm
(B) 20  10 2 Nm x
(C) 150  102 Nm
(D) 150  102 Nm
9
20. Above Curie temp

(A) Paramagnetic materials become ferromagnetic
(B) Ferromagnetic materials becomes diamagnetic
(C) Ferromagnetic materials becomes paramagnetic
(D) Paramagnetic materials becomes diamagnetic
0
21. If a single slit fraunhoffer diffraction set up is used with light of wavelength 4000 A . Distance D
between central maximum and first minimum found to be 0.3 cm in set up if the wavelength
0
changed to 6000 A the corresponding value of D will be
(A) 0.20 cm (B) 0.24 cm
(C) 0.30 cm (D) 0.45 cm
22. A thin slice is cut – out of a cylindrical glass along the plane
parallel to its axis. The slice is placed on a flat glass plate as
shown. The observed interference fringes from this combination
shall be
(A) Straight
(B) Circular
(C) equally spaced
(D) having fringe spacing which increases as go out ward
23. Above figure shows variation of current with anode potential I

for a photo sensitive surface for there different radiation. Let c
Ia , Ib and IC be intensities and f a f b and fc the frequencies for b
curve a, b and c respectively a
(A) fa  fb , Ia  Ib
(B) fa  fc , Ia  Ic
Anode Potential
(C) fa  fb , Ia  Ib
(D) fb  fc , Ib  Ic
24. Lead is a good absorber of x rays. Specific gravity of Pb = 11.5. To cut down the initial radiation I0
I
to 0 a shield of 1.5 cm was used. The mass absorption co-efficient is
2
(A) 0.06 cm2 / g (B) 0.462 cm 1
(C) 0.21 cm1 (D) 0.040 cm2 / g
10
25. Mx and My denote the atomic masses of the parent and daughter nuclei respectively in a radio
active decay. The Q value of a  decay is Q1 and for  decay is Q2. If me denote the masses
of electron then which of following statement is correct.
(A) Q1   Mx  My  C2 Q2  Mx  My  2me  C2
(B) Q1   Mx  My  C2 Q2  Mn  My  C2
(C) Q1   Mx  My  2mc  C2 Q2  Mx  My  2mc  C2
(D) Q1   Mx  My  2mc  C2 Q2   Mx  My  2mc  C2
26. Power emitted per unit area of a black body is R watt/m 2. At what wavelength will the power
radiated by black body be maximum if stefan’s constant is  and Wien’s constant is b then.
1 1
 b  4  b 4
(A)     (B)    
R  R
1 1
 bR  4   4
(C)    (D)   b  
   R 
27. The figure shows the initial position of a point source L

of light s, a detector D and Lens L. Now at t = 0 all 10 cms-1
three starts moving toward right with different velocity 20 cm/s
as shown in figure. The times at which detector
receives the maximum light.
(A) 0.56 s and 4.45 s s
(B) 3.8 s D 30 cms-1
(C) 8.94 s and 19.62s
1m
(D) 0.56 s
focal length = 10 cm
11
28. The figure shows a portion of a circuit. Resistor are known 9

and indicated on diagram and voltmeter are identical. If v1
voltmeters v 1 and v 2 reads 7.5v and 5v respectively then
reading of v3. 14
(A) 0v v2
(B) 10v
(C) 2.5v 24
(D) 3.0v v3
29. A liquid of density  has to spray with help of aspirator pump at A B

height H from liquid level as shown in figure. If gauge pressure Bulb
inside bulb is P and density of air is  then velocity of air in tube
AB is H
1 1
H
  2   2
 P  gH   P  gH 
(A)   (B)  
     
 2   2 
1
 2 1
 P  gH   P  gH  2
(C)   (D)  
     
 2 
30. A non uniform cylinder of mass m, length  and radius r having its

C.O.M at a distance from centre and lying on axis of cylinder. A C C.M B
4
The cylinder is kept in a liquid of uniform density . The moment
of inertia of the rod about C.O.M is I. The angular acceleration of
point A relative to point B just after the rod is released from /4
position shown in figure is.
g 2r 2 3g2r 2
(A) (B)
2 4
g 2r 2 g 2r 2
(C) (D)
 4
12
Chemistry PART – II
SECTION – A
31. For the following elementary first order reaction:

k 2B
1
A
k2 C
If k2 = 2k1 , then % of B in overall product is:
(A) 25% (B) 50%
(C) 75% (D) 100%
32. One of the allotropic form of boron is   rhombohedral boron. Number of faces and corners in its
basic building B12 icosahedral unit are:
(A) 20 and 12 respectively (B) 12 and 20 respectively
(C) 12 and 12 respectively (D) 20 and 20 respectively
33. Which of the following is bio-degradable polymer?

(A) Nylon – 6, 6 (B) Nylon – 6, 10
(C) Nylon - 6 (D) Nylon – 2-Nylon -6
34. White phosphorus is a tetra atomic solid P4 (s) at room temperature. Find average (P – P) bond
enthalpy (in kJ/mol).
Given : Hsub limation of P4  s   59 kJ / mol
Hatomization of P4  s   1265 kJ / mol
(A) 201 (B) 1206
(C) 301.5 (D) 210.83
13
35. In extraction of copper from its sulphide ore, the metal is obtained by reduction of Cu2O with:
(A) CO (B) FeS
(C) SO2 (D) Cu2S
36. NH2
HNO3, H2SO4 +
A B+C
288 K
Order of basic nature is A > B > C.

Order of % of A, B and C in overall product is:
(A) A > B > C (B) C > A > B
(C) B > A > C (D) A > C > B
37. A cell contains two hydrogen electrodes. The negative electrode is in contact with a solution of pH
= 5.5. The emf of the cell is 0.118 V at 250 C. Calculate the pH of solution at positive electrode.
(assume pressure of H2 in both electrodes = 1 bar)
(A) 3.5 (B) 7.5
(C) 4.5 (D) 6.5
38. The image formed, when a photographic film is exposed and developed, is due to formation of
3
(A)  Ag  S2 O3 2  (B) AgBr
(C) Ag (D) Ag2O
39. Wood spirit is obtained by catalytic reaction of water gas with hydrogen at 200 – 3000C. The
catalyst used is:
(A) Ni (B) ZnO – Cr2O3
(C) Cu (D) Pd – BaSO4
40. The compressibility factor (Z) of real gas is usually less than 1 at low temperature and low
pressure because
(A) a is negligible while b is not (B) b is negligible while a is not
(C) both a and b are negligible (D) neither a nor b are negligible
14
41. Zn  conc. HNO3  Zn NO3 2  X  H2 O

 Zn NO3  2  Y  H2 O
Zn  dil.HNO3 
Compounds X and Y are respectively:
(A) N2O, NO (B) NO 2 , N2 O
(C) N2 O, NO2 (D) NO2 , NO
42. Which of the following compound will give blood red colour while doing the Lassaigne’s test:
O S
|| ||
(A) H2N  C  NH2 (B) H2N  C NH2
(C) C6H5  SO3H (D) CHCl3
43. On mixing which of the following solutions, observed boiling point of mixture is higher than
theoretical boiling point?
(A) n – butylchloride + n - butylbromide (B) water + ethanol
(C) chloroform + diethyl ether (D) acetone + benzene
44. The electro negativity of H, X and O are 2.1, 0.8 and 3.5 respectively on Pauling scale. The
nature of compound HOX is:
(A) acidic (B) basic
(C) neutral (D) amphoteric
45. Acetylene on passing through excess of HOCl solution forms

(A) ethylene chlorohydrin (B) glyoxal
(C) ethylene glycol (D) dichloroacetaldehyde
46. 50 ml, 0.1 M NaHCO3 aqueous solution is mixed with 50 ml, 0.8 M Na2CO3 aqueous solution at
250C. The pH of resulting solution exists between colour transition range of an indicator which is:
K a1  4  10 7 , K a2  2  1011 for H2 CO3 
(A) Phenol red (6.8 to 8.4) (B) Propyl red (4.6 to 6.4)
(C) Phenolphthalein (8.3 to 10.1) (D) Malachite green (11.4 to 13)
15
47. In which of the following complexes of Co, the magnitude of CFSE   0  is maximum?
2 3
(A) Co  NH3 6  (B)  CoCl6 
3 3
(C) Co  C2 O4 3  (D) Co  CN6 
48. In simplified version of nucleic acid chain, nucleotides are joined together by
(A)   glycosidic linkage (B) phosphodiester linkage
(C)   glycosidic linkage (D) peptide linkage
49. The tetrahedral voids formed by ccp arrangement of Cl- ions in rock salt structure are:
(A) occupied by Na+ only (B) occupied by Cl- only
+ -
(C) occupied by either Na or Cl (D) neither occupied by Na+ nor Cl-
50. Which of the following species are incorrectly matched with their shape?
(A) ClF3 = trigonal planar (B) SF4 = folded square
(C) [XeF5]- = pentagonal planar (D) I2Cl6 = rectangular planar
51. Correct order of pKa values of

OH HO OH HO
NO 2
I, II, III , IV is:

NO 2
NO 2
(A) I < II < III < IV (B) I > II > III > IV
(C) II < I < III < IV (D) II > I > III > IV
52. Isoelectric point of gelatin solution is 4.7. Then correct option is:
(A) If pH < 4.7, it is (-)vely charged, move towards cathode
(B) If pH < 4.7, it is (+)vely charged, move towards anode
(C) If pH > 4.7, it is (+)vely charged, move towards cathode
(D) If pH > 4.7, it is (-)vely charged, move towards anode
16
H2 O
53. Mg  s   C  s  
high T
X   Mg  OH 2  Y
X and Y are respectively:
(A) Mg2 C and CH4 (B) Mg4 C3 and CH4
(C) Mg2 C3 and C3H4 (D) MgC2 and C2H2
54. In the reaction

LDA
CF3  CHCl2  
 CF2  CCl2
Intermediate formed is:
(A) carbocation (B) carbanion
(C) free radical (D) No intermediate formed
55. For an ideal diatomic gas, during any process T = KV, find out the molar heat capacity of the gas
during process (neglecting vibrational degree of freedom)
3R 5R
(A) (B)
2 2
7R
(C) (D) 2R
2
56. Cu2  aq   K 4 Fe  CN6   aq  

 X
 ppt.
Colour of precipitate (X) is:
(A) green (B) blue
(C) white (D) reddish - brown
57. In which of the following set of orbitals, nodal plane is absent?

(A) 4s,4 dz2 (B) 4s, 4dx2  y2
(C) 4p z ,4s (D) 4dyz , 4dzx
17
58. Which of the following is enantiomer of OH
H CH3
?
H OH
CH3
CH3 H
H OH HO CH3
(A) (B)
H OH H OH
CH3 CH3
CH3 H
H OH H3C OH
(C) (D)
H3C OH HO H
H CH3
59. Correct statement about classical smog (I) and photochemical smog (II) is:
(A) I = reducing smog, II = oxidizing smog (B) I = oxidizing smog, II = reducing smog
(C) Both I and II are oxidizing smog (D) Both I and II are reducing smog
60. Which of the following reaction will not proceed via carbanion intermediate?
(A) Perkin reaction (B) Cannizaro reaction
(C) Claisen condensation (D) Aldol condensation
18
Mathematics PART – III
SECTION – A
 
61. The maximum value of K for which sin x  2 x  kx  x  1  x  0,  equals
 2
4    2 4    1
(A) (B)
    1     2
4    1 4    2 
(C) (D)
2  1
62. Differential co-efficient of log10 x w.r.t logx 10 is

2 2
  log x  log10 x 
(A) 2
(B) 2
log10  log10 
2 2
logx 10    log10 
(C) 2
(D) 2
log10   logx 
sec 2 x
 f  t  dt
2
63. The value of lim is equal to
x
 2
2
4 x 
16
8 2
(A) f 2 (B) f 2
 
8  1
(C) f   (D) 4f  2 
 2
19
64. Let an 1  2  an , n = 1, 2, 3 …. & a1 = 3 then lim an is

n 
(A)  (B) 2
(C) 5 (D) 3
65. The maximum value of area of rectangle OABC, where O is origin, A lies on positive y-axis & B
ln x
lies on the curve y  2 is
x
1
(A) e-1 (B) e 2
1
(C) 1 (D) e 2

4
 1  1
66. x > −1, let f  x    loge 1  x tan z  dz , then value of f    f   equals
0  2 3
 9  9
(A) loge   (B) loge  
4 8 8 8
 9  3
(C) loge   (D) loge  
9 8
  8 2
1 cos 2 t 1 cos 2 t
67. For t  R & f be a continuous function. Let I1   x.f  x  2  x   dx & I2   f  x  2  x   dx ,
sin2 t sin2 t
I1
then
I2
(A) 1 (B) 3
1 2
(C) (D)
3 5
20
x
   yx 
68. The general solution of the differential equation x  y 2 .e xy  e y  dy  y 2 xy
 e  y e  dx is
   
   
x y
(A) e xy  e y  c (B) e xy  e x  c
x y
(C) e xy  e y  c (D) e xy  e x  c
69. Let z1, z2 & z3 are vertices of acute angled ABC in anticlockwise order and origin be the
circumcenter of the triangle. If bisector of A meets the circumcircle at point P(z), then
 z 
arg   is
 z3  z2 
 
(A) (B)
2 2

(C) (D) none of these
6
70. If from each of the three boxes containing 3 white & 1 black, 2 white & 2 black, 1 white & 3 black
balls, one ball is drawn at random, then the probability that 2 white & 1 black ball will be drawn is
13 1
(A) (B)
32 4
1 3
(C) (D)
32 16
71. The set of exhaustive values of ‘’ for which the equation x  1  x 2  x  2 has at least one
positive root, is
(A)  , 1  1,   (B) R
(C)  , 1 (D) 1, 
21
72. Consider the points A   0,1 & B   2,0  , P be a point on the line 4x + 3y + 9 = 0. Co-ordinates
of the point ‘P’ such that |PA – PB| is maximum is
 12 17   84 13 
(A)  ,  (B)  , 
 5 5   5 5 
 6 17   24 17 
(C)  ,  (D)  , 
 5 5   5 5 
73. If the tangent at the point P(2, 4) to the parabola y2 = 8x meets the parabola y2 = 8x + 5 at Q & R,
then the mid point of QR is
(A) (2, 4) (B) (4, 2)
(C) (7, 9) (D) none of these
x2 y 2
74. For an ellipse   1 , 1 & 2 are the eccentric angle of points P & Q respectively, if
25 16
1  2   then
(A) point P & Q are in opposite quadrant
(B) line PQ is parallel to major axis
(C) line PQ always passes through centre of ellipse
(D) none of these
75. The locus of point of intersection of perpendicular tangents of the hyperbola 4y2 = x2 – 1 is
(A) 4x2 + 4y2 – 3 = 0 (B) 2x2 + 2y2 – 5 = 0
(C) 3x2 + 3y2 – 4 = 0 (D) none of these
 r  r 
76. If  1  1   1  1   2 , where r1, r2, r3 are the ex radii, then the triangle is
 r 2  r 3 
(A) equilateral (B) isosceles

(C) right-angled (D) none of these
77. Volume of tetrahedron formed by the planes x + y = 0, y + z = 0, z + x = 0, x + y + z = 1 is

1 1
(A) (B)
6 3
2
3
22
          
78. The position vectors of three points are 2a  b  3c, a  2b  c & a  5b where a, b & c are
non-coplanar vectors. The points are collinear when
9 9
(A)   2,   (B)   ,   2
4 4
9
(C)   ,   2 (D) none of these
4
 
1  1  ln x 
e2010
79. The value of the definite integral  1 dx , equals
e x  x 
 ln x .ln  
  ln x  
(A) 2009  ln   2010   ln2010  (B) 2010  ln   2009   ln2009 
(C) 2009  ln   2010   ln2009  (D) 2010  ln   2010   ln2010 
80. Let the equation of the plane containing the line x – y – z – 4 = 0, x + y + 2z – 4 = 0 & is parallel to
the line of intersection of the planes 2x + 3y + z = 1 & x + 3y + 2z = 2 be x + Ay + Bz + C = 0 then
value of |A + B + C| is
(A) 9 (B) 10
(C) 4 (D) 11
81. Equation of the image of the line x  y  sin1  a 6  1  cos 1  a 4  1  tan1  a2  1, a  R about
x-axis is given by

(A) x – y = 0 (B) x  y 
2

(C) x – y =  (D) x  y 
4
82. If the sum of roots of the equation cos 4 x  6  7cos 2 x in the interval [0, 314] is k, k  R, then
k=
(A) 4930 (B) 4940
(C) 4950 (D) None of these
23
83. Let g  x   f  x  sin x , where f(x) is a twice differentiable function on (–, ), such that f      1 .
The value of g     equals
(A) 1 (B) 2
(C) –2 (D) 0
84. The line 3x + 6y = k intersect the curve 2x2 + 3y2 + 2xy = 1 at points A & B. The circle on AB as
diameter passes through the origin. The possible value of k is
(A) 3 (B) 4
(C) – 4 (D) 5
 x  m, x  1
85. Let a function f defined from R  R as f  x    . If the function is surjective on R
2mx  1, x  1
then m must lie in
(A)  1,0  (B) [–2, –1]
(C) {2} (D) (0, 2]
86. A man wants to divide 101 coins, a rupee each, among his 3 sons with the condition that no one
receives more money than the combined total of other two. The number of ways of doing this is:
100C2
(A) 100 C2  2.52 C2 (B)
3
103C2
(C) 1275 (D)
6
 
87. If Zn  cos  i sin , n  N. then the value of lim(z1 .z 2 .z 3 ......z k )is.
n(n 1)(n 2) n(n 1)(n 2) k 
1 i 1 3
(A)  (B) i
2 2 2 2
1 3 1 i
(C) i (D) 
2 2 2 2
24
88. F: R R be a differentiable function V xR. if tangent drawn to the curve at any point  x  (a, b)
always lie below the curve then
(A) f '  x   0,f"(x)  0 x  (a,b) (B) f'  x   0,f"  x   0x   a,b 
(C) f'  x   0,f"(x)  0 x  (a,b) (D) None of these
n dy y
89. If x 2 y 3   x  y  ,  then n =
dx x
(A) 2 (B) 3
(C) 5 (D) 6
90. Number of integral value of a such that x 2  ax  a  1  0 has integral root is

(A) 1 (B) 2
(C) 3 (D) more than 3
FIITJEE JEE (Advanced), 2018
FULL TEST – I
Paper 1

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
4. Each part is further divided into two sections: Section-A & Section-C

on OMR sheet.

1. Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer.
Section-A (09 – 12) contains 4 multiple choice questions which have more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
Section-A (13 to 18) contains 3 paragraphs with each having 2 questions. Each question carries
+3 marks for correct answer and –1 mark for wrong answer.
2. Section-C (01 – 05) contains 5 Numerical based questions with answers as numerical value and
each question carries +4 marks for correct answer. There is no negative marking.
Enrolment No.
2
AITS-FT-I-(Paper-1)-PCM-JEE(Advanced)/18
Useful Data
PHYSICS

CHEMISTRY
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
= 6.625  10–27 ergs
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3
Physics PART – I
SECTION – A
1. Point A on the rod AB has an acceleration of 5 m/s2 and Y

a velocity of 6 m/s at an instant as shown in the figure.
The acceleration of the end B at the same moment is: A
80
(A)  î m / s2 aA = 5 m/s2
3
  5m
80 vA = 6 m/s
(B) î m / s2 4m
3
40
(C)  î m / s2
3 O B X
75
(D)  î m / s2
6
2. Current I0 is flowing through a bent wire a  b  c  d in z – x plane as shown in figure, then

 
 B.d over the loop PQRS lying in the X-Y plane as shown in figure, due to the bent wire abcd
Y z
I0
R Q
 a c
2 
2
O X

O X
2 
2
S P
  d b
2 2 
0I0 0I0
(A) (B)
8 7
0I0 0I0
(C) (D)
5 3
4
3. The circuit is completed at t = 0, then heat loss in R  4

R  4 resistance, till the capacitor gets fully
charged:
(A) 64 J
 q0 0
(B) 384 J 18 v 3v 
C C 0
(C) 320 J
(D) 576 J
6 3
C  16 F
q 0  64C
4. A simple harmonic plane progressive wave is travelling along the +ve x – axis having amplitude A
and    rad / s. At t = 1 sec, particle at x = 2 m and x = 3 m are moving in downward and
A
upward direction respectively at the position y   . The time when maximum power transfer will
2
11
takes place at x  m?
4
5 5
(A) sec (B) sec
4 3
7 7
(C) sec (D) sec
4 5
5. There is sufficient friction between long plank of mass 2 m and 

sin
cylinder of mass m and radius R to prevent slipping. Whole m
g
system is placed on the smooth inclined surface. Now, force 3
=
F  3mgsin  is applied on the ideal string wrapped over the d er F
lin
cylinder as shown in figure. Choose correct option: cy
(A) If the plank moves down a distance of S m, work done by
m
R
the applied force F on the string is 5 mg sin S

m
(B) if the plank moves down a distance of S m, work done by

2

(C) If the plank moves down a distance of S m, work done by
the applied force F on the string is 12 mg sin S 
(D) If the plank moves down a distance of S m, work done by
5
6. A vertical thermally insulated cylinder of volume V contain n moles of an ideal monoatomic gas
under a weightless piston. A load of weight W is placed on the piston as a result of which the
piston is displaced. If the initial temp of the gas is 300 K, area of piston is A and atmospheric
pressure P0. (take W = P0A). Determine the value of final temperature of the gas.
(A) 375 K (B) 425 K
(C) 475 K (D) 515 K
7. A open organ pipe containing air resonates in fundamental mode due to a tuning fork. The
measured value of length   in cm  of the pipe and radius r  in cm  of the pipe are
  94.0  0.1, r  5.0  0.05. The velocity of the sound in air is accurately known. The maximum
percentage error in the measurement of the frequency of that tuning fork by thus experiment, will
be:
(A) 0.16 (B) 0.64
(C) 1.2 (D) 1.6
8. A metallic spherical shell has mass m, radius R and Bulk modulus of elasticity B. The change in
radius of the shell due to gravitational pressure
Gm 2 Gm2
(A) (B)
3BR 3 8BR3
Gm2 Gm2
(C) 3
(D)
24BR 36BR3
Multiple Correct Choice Type
This section contains 04 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out of which only ONE OR MORE THAN ONE is/are correct
9. In the given circuit, the AC source has 200f

100
  50 rad / s considering the inductor and
capacitor to be ideal, the correct choice(s) is/are 50
(A) The voltage across 100 resistor  20
I 1H
(B) The voltage across 50 resistor  20
5
(C) The current through the circuit is I  A
2 40 V
(D) The current through the circuit is I  1.2A
6
1 
10. In YDSE, D = 1 m, d = 4 mm and   mm In the figure
2 x
s1
shown, a parallel beam of light is incident on the plane of
the slits of YDSE. Light incident on the slit s1, passes
through a medium of variable refractive index    2x  1 d = 4 mm
O
(where x is the distance from the plane of slits in mm) up
to a distance   1 mm before falling on s1. Rest of the
s2
space filled with air. Then choose the correct option(s): Screen
(A) Position of central bright fringe is at a distance
1
y= m above the central line
3 D=1m
1
(B) Position of central bright fringe is at a distance  mm
2
1
y = m above the central line
2
(C) Number of maxima obtaining on the screening is 7
(D) Number of maxima obtaining on the screening is 8
11. A rough L – shaped rod is located in a horizontal plane 1

and a sleeve of mass m is inserted in the rod. The rod is
rotated with a constant angular velocity  in the horizontal X
plane. The lengths  1 and  2 are shown in figure. The
normal reaction and frictional force acting on the sleeve  2
when it starts slipping are
  : coefficient of friction between rod and sleeve  .
(A) N  m   1
2
sleeve
 2 g2
(B) 4  2
 2   2  21
(C) N  m g2  4 21
(D) f  N
7
12. Consider a uniformly charged sheet ABCD, which is a part of an O

equilateral triangular sheet of a side a as shown in the figure.
Choose the correct options regarding the electric field E at point
O due to this sheet.
600 600
(A) Magnitude of E, increases with the increase in a (Keeping D C
a
charge density same) 2
(B) Magnitude of E, decreases with increase in a (keeping total
charge same) 600 600
(C) If charge density is  and a = 1 m, magnitude of E is equal A B
7 a
to In 2
440
(D) If charge density is  and a = 2 m, magnitude of E is equal
7
to In 2
220
Comprehension Type
This section contains 3 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which only ONE is
correct
Paragraph for Questions 13 & 14
Consider a perfectly conducting uniform disc of mass m and radius

‘a’ hinged in a vertical plane from its centre and free to rotate with
respect to hinge. A resistance R is connected between centre of the
m
disc and periphery by using two sliding contacts C1 & C2. A long non
– conducting massless string is wrapped around the disk, whose C1 C2
ma2
another end is attached with a block of mass m. There exists a 2
uniform horizontal magnetic field B, whose arrangement is shown in
figure.
Given system is released from rest at t = 0. Assume friction between
string and disc is sufficient so that there is no slipping between them R
let at any instant t, velocity of block is v, angular velocity of the disc is B
g
 and current in resistance is i. m
13. Find the terminal speed of the block of mass m is (Terminal speed = constant speed attained by
the block after very long time)
mgR 2mgR
(A) 2 2 (B) 2 2
Ba Ba
3mgR 4mgR
(C) 2 2 (D) 2 2
Ba Ba
8
14. Just after t = 0, the acceleration of block is:

g
(A) g (B)
2
2g g
(C) (D)
3 5
Let us assume that the current voltage graph for photoelectric tube consists of two straight lines as
shown.
On such a photoelectric tube, light of wavelength 310 nm is incident. The work function of the emitter
plate is 2eV. The tube effectively acts as a solar cell to supply current to an external resistor R. Saturation
current is 2A.
emitter collector
i
Is
-vs v R
15. How does the current depend for R

i i
(A) (B)
R R
i i
(C) (D)
R R
9
16. At the what value of R will be the power dissipated in R maximum

(A) 1 (B) 2
1 1
(C)  (D) 
2 4
Curved surface of a vessel has shape of truncated cone 370

having semi – vertex angle 370. Vessel is full of water
(density   1000 kg / m3 ) upto a height of 13 cm and is placed
on a smooth horizontal plane. Upper surface is opened to
atmosphere. A hole of 1.5 cm is made on curved wall of a 13 cm
height of 8 cm from bottom as shown in figure. Area of water
surface in the vessel is large as compared to the area of the 8 cm
hole.
A B
17. The initial horizontal force required to keep the vessel in static equilibrium
(A) 0.12N (B) 0.15 N
(C) 0.25 N (D) 0.35 N
18. The initial horizontal range of water from point B is

(A) 16 cm (B) 12 cm
(C) 10 cm (D) 8 cm
SECTION – C
(One Integer Value Correct Type)
This section contains 5 questions. Each question, when worked out will result in one integer from 0 to 9
(both inclusive).
19. A very long non- conducting cylindrical shell of length q

  10m is free to rotate about its fixed axis. A light F
P
inextensible thread is wrapped over non – conducting
cylindrical surface and one end P is pulled with constant
F
acceleration of . F is the force applied at P and m is the
2m
mass of cylinder. Then charge on the cylinder will be
5  10 K coulomb.  Given m  25 kg,   10m. Find the
value of K?
10
20. A point object is kept at a distance of 2 m from y

quarter cylinder
origin on x – axis. A quarter cylinder of radius
R = 30 cm and refractive index   1.5    1.5 
having its axis r to plane of paper is placed
between the object and the parabolic reflector
at a distance of 130 cm from origin as shown O
in figure. The position of the image after P x
130 cm 30cm 40 cm
reflection from the parabolic reflector y 2  2x
is 25  cm. Find the value of  ?
y 2  2x
21. Two identical particles A & B of mass m = 2 kg is connected at v0

the end of the spring  K  50 N / m  and placed on a smooth F A B
2F
horizontal surface. Now, force F = 10 N and 2 F are applied on m k m
the particles in opposite direction as shown in figure. Initially
spring is in natural length.
Simultaneously particle A receives an impulse towards B which
imparts speed v 0 to it, find v0 in m/s for which length of elongation
is two times the length of compression in the spring during
subsequent motion?
22. A cylinder of mass M and radius R moves with constant speed v R

through a region of space that contains dust particles of mass m
which is at rest. There are n number of particles per unit volume.
The cylinder moves in a direction perpendicular to its axis. v
Assume m <<M, and assume the particles do not interact with
each other. All the collision takes place is perfectly elastic and
the surface of the cylinder is smooth. The drag force per unit M
length of the cylinder require to maintain the speed v constant for
K
the cylinder is nmRv 2 . Find the value of K?
3
23. In a hydrogen like atom an electron is orbiting in an orbit having quantum number n. Its frequency
of revolution is found to be 13.2  1015 Hz. Energy required to free the electron from the atom from
the above orbit is 54.4 eV. In time 7 nano – second the electrons jumps back to orbit having
n
quantum number .  be the average torque acted on the electron during the above process,
2

then find  1027 in N – m.
5
 h 34 
 Given  2.1 10 J  s  Frequency of revolution of electron in the ground state of H – atom
  
15
f0  6.6  10 Hz and ionization energy of H – bond E0  13.6 eV
11
SECTION – A
24. A gas X is passed through water to form a saturated solution. The aqueous solution on treatment
with AgNO3 gives white precipitate. The saturated aqueous solution also dissolves magnesium
ribbon with evolution of a colourless gas Y.
(A) X is CO2 and Y is Cl2 (B) X is Cl2 and Y is CO
(C) X is Cl2 and Y is H2 (D) X is H2 and Y is Cl2
25. The method of zone refining of metals is based on the principle of:
(A) Greater mobility of the pure metal than that of impurity
(B) Higher melting point of the impurity than that of the pure metal
(C) Greater noble character of the solid metal than that of the impurity
(D) Greater solubility of the impurity in the molten state than in the solid
26. 50 ml of 0.2 M solution of a compound with empirical formula CoCl3.4NH3 on treatment with
excess of AgNO3(aq) yields 1.435 gm of AgCl. Ammonia is not removed by treatment with
concentrated H2SO4. The formula of compound is:
(A) Co  NH3  4 Cl3  (B) Co  NH3 3 Cl Cl2
(C) Co  NH3  4 Cl2  Cl (D) Co  NH3  Cl3  NH3
27. Determine the amount of AgI which may be dissolved in 1.0 litre of 1.0 M CN- solution. Ksp for AgI

and equilibrium constant for  Ag  CN 2  formation are 1.19  1017 M2 and 7.11 1019 M2
respectively.
(A) 1.0 mole (B) 0.5 mole
(C) 4.0 mole (D) 2.5 mole
12
28. O H O OH
H OH H OH
-H2O Na - Hg
HO H Br2 HO H Pyridine pH 3 - 5
X Y Z
H OH H2O H OH (Epimerization)
H OH H OH
OH OH
What is Z
(A) D - Mannose (B) D - Xylose
(C) D - Xylitol (D) D - Talose
29. OH
HBr Me3CO- CH2I2/Zn(Cu)
X Y Z
Me3COH Et2O
Z is
(A) (B) I
I
(C) (D)
30. For a reaction nA 

 B, following plots are given:
1
d  A  A
A 
dt
A t t
The order of reaction for above plots are -
(A) 1, 0, 2 (B) 0, 1, 2
(C) 1, 1, 2 (D) 0, 2, 1
13
31. Which of the following products are formed when potassium bromide reacts with potassium
permagnate in alkaline pH?
(A) BrO3 , MnO2 (B) BrO 4 , Mn2
(C) Br2 , MnO2 (D) BrO , MnO24
for its answer, out of which only ONE OR MORE THAN ONE is/are correct.
32. O
O
+
H
-H2O repeated sequence NH3
A B C D E F
-H+, +H+
O
(A) (B)
OH
B is N
F is H
O O
(C) (D) NH2
B is E is
33. For an isothermal irreversible expansion of 1 mole of a perfect gas, identify the correct relation,
where symbols have their usual meaning
(A) U  0 (B) H  0
 P  P 
(C) q  RT  1  2  (D) w  RT n  2 
 P1   P1 
14
34. The vander waal gas constant ‘a’ is given by

1
(A) Vc (B) 3Pc Vc2
3
1 RTc 27 R2 Tc2
(C) (D)
8 Pc 64 Pc
35. Degree of hydrolysis of a salt of strong acid and weak base is:
(A) Independent of dilution (B) Increases with dilution
(C) Decreases with increase in Kb value (D) Increases with increase in Kb value
Comprehension Type
correct.
Deuterium is the isotope of hydrogen of mass number 2, with a proton and a neutron in its nucleus. The
chemistry of deuterium is nearly identical to the chemistry of hydrogen, except that C – D bond is slightly
(5.0 KJ/mole) stronger than the C – H bond. Reaction rates tend to be slower if a C – D bond as opposed
to a C – H bond is broken in a rate limiting step. This effect on the rate is called a kinetic isotope effect.
O
||
D2 O,D
36. 
CH3  C  CH3  
X
X is
O OD
(A) || (B)
CD3  C  CD3 H2C C CH3
OH O
(C) (D) ||
H2 C C CH3 CH3  C  CD3
15
37. HO OH
HNO3
+ I2
KH
I
OH OH
D D
D D
HNO3
+ I2
KD
D I
K KH
(A) H  1 (B) 4
KD KD
KD KD
(C) 4 (D) 2
KH KH
Galvanic cells generate electrical energy at the expense of a spontaneous redox reaction. In an electrode
concentration cell two like electrodes having different concentrations, either because they are gas
electrodes operating at different pressures or because they are amalgams (solutions in mercury) with
different concentrations are dipped into the same solution.
Eg. An example is a cell composed of two chlorine electrodes with different pressure of Cl2:
Pt L Cl2 PL  HCl  aq  Cl2  PR  Pt R
Where PL and PR are the Cl2 pressure at the left and right electrodes.
38. Calculate the EMF of the electrode concentration cell represented by:
Hg  Zn  c1  Zn2 aq Hg  Zn  c 2 
At 250 C. c1 = 2g of Zn per 100 g of Hg and c2 = 1 g of Zn per 50 g of Hg
(A) 0.059 V (B) 3
(C) 0 (D) data insufficient
16
39. A cell represented by the following cell diagram is generated to measure the solubility product of
AgCl.
Ag Ag  aq  Cl  aq  AgCl  s  Ag
K 0sp  AgCl at 298 K and 1 bar pressure is:
Given :
AgCl  e   Ag  Cl E0  0.22 V
Ag  e   Ag E0  0.79V
 RT.  2.303  
 Take 10  3.16 &  0.06 

 F 
10
(A) 3.16  10 (B) 3.16  10 11
(C) 3.16  10 9 (D) data insufficient
Aldehyde and Ketone molecules having   hydrogen atoms undergo aldol condensation reaction. Aldol
condensation reaction proceeds in acidic and basic conditions. In basic medium, aldol condensation
product will be formed involving enolate ion formation. Here the enolate ion acts as nucleophile. Other
carbonyl group containing compounds also perform similar type of reactions.
40. (i) PPh3

O
(ii) C2H5O-
Br X
OEt (iii) CH3CHO
Final product X is
O
(A) (B) CH3 CHO and CH3 COOH
Me OEt
O
O
H and C2H5OH
(C) Me (D) Br and C2H5OH
OH
O
17
41. O O
CH3 - CHO
X
HO OH Piperidine, Pyridine
Final product X is
HOOC CH COOH
HOOC C COOH
(A) HC OH (B)
HC CH3
CH3
O
C
(C) H3C CH C O (D) COOH
C
O
SECTION – C
(both inclusive).
42. Let (+) tartaric acid has a specific rotation of + 11.1. Calculate the specific rotation of a mixture of
68% (+) tartaric acid and 32% (-) tartaric acid.
43. O
O
OH-
+ X

Total number of  bonds in X is
44. Find the number of molecules having two lone pair of electrons on central atom.
I3 , XeF2 , XeF4 , H2 O, NH2 , H2 S, H2 SO4 , NF3

45. A Boron mineral have pentaborate anion whose molecular formula is B5 O6  OH 4  . The number
of B – O - B linkage present are?
46. The electron in the first excited state (n1 = 2) of H – atom absorbs a photon and is further excited
to nth shell. The de-Broglie wavelength of the electron in this excited state is 1340 pm. Find the
value of n.
18
SECTION – A
47. The sum of abscissa of the points of inflexions of curve y =

x 7 2 x 6 3 x 5 x 4 2x 3
f x       99 x  2010 is,
42 15 20 3 3
(A) -1 (B) 0
(C) 2 (D) none of these
48. In triangle ABC, if y = x+1 & y = 2x + 3 are altitude through A & angle bisector of B respectively. If
vertex C  ( 3 , 4 ) then equation of median through C is
(A) x + 7y = 25 (B) 7x + 2y = 25
(C) 7x + y = 25 (D) 2x + 7y = 25
49. Equation of curve passing through (1, 1) & satisfying the differential equation
 xy 2  y 2  x 2 y  2xy  dx   2xy  x 2  dy  0 Is
(A) xy  x  y   2e1 x (B) xy  x 2  y 2   2e x 1
(C) x 2 y 2  x  y   2 (D) x 2 y 2  x 2  y 2   2
50. In a bag there are 10 black & 10 white balls. A ball is drawn at random & 5 extra balls of same
color as of drawn ball are added in the bag along with the drawn ball. Now another ball is drawn
and replaced in the bag but 4 balls of color same as drawn ball are removed from the bag. Again
a ball is drawn and found to be white find the probability that the second drawn ball was black.
4 3
(A) (B)
7 7
2 1
(C) (D)
7 7
19
51. Let f  x   x  { x }2 where {x} is fractional part of x. The area between the curves y = f(x),
3
y  f 1(x) , x = 0 and x = is,
2
1
(A) (B) 1
2
3
(C) (D) 2
2
52. f & g are two real valued continuous functions and let
4
1 3
 g  x  dx  f  x  and f  x   x  x  sin x  2 then the value of  xg  x  dx is
2
11 2 11 2
(A)  (B) 
4  4 
11 2 11 2
(C)  (D) 
4  4 
53. The value of the limit lim 


cos 1 2x 1  x 2  is equal to
1 1
x
2 x
2
(A) 2 (B) 2 2
(C) 2 2 (D) doesn’t exist
n 2n 3r
k
54. If 1  x  x 2    ar x r , then the value of   1 ak nC3 r  k where 3r  n  is a1a2 Ca3 . Then value
r 0 k 0
of a1  a2  a3 is
(A) n+1 (B) r+1
(C) n+r+1 (D) n + r
20

55. x + y = 2 and x – y = 2 are tangents on a parabola at (1, 1) and (4, 2) respectively. Which of the
followings is/are correct.
(A) Equation of directrix is x + 3y = 2 (B) Equation of axis is 3x – y = 5

8 6  33 13 
(C) Focus of the parabola is at  ,  (D) Vertex of the parabola is at  , 
5 5  20 20 
56. Line OQ is angle bisector of angle O of right angle triangle OPR, right angled at P. Point Q is
such that ORQP is concyclic. If point O is origin and points P, Q, R are represented by the
z2 3
complex numbers z3, z2, z1 respectively. If 2  then (R is circum radius of OPR)
z1z2 2
     
(A) Angles of OPR are , , (B) Angles of ∆OPR are , ,
6 3 2 4 4 2
(C) Area of OPR is 2 2R 2 (D) Area of OPR is 2R 2
57. In ABC, X and Y are foot of perpendicular from A and C respectively on median BE. If
area  BYC 
 4 , then which of the following is/are correct.
area  AXE 
area  ABC 
(A) 3 (B) BX = 2XY
area  AXB 
(C) 2 area (AXB) = area (XYC) (D) none of these
21
58. If a, b, c are in AP and A, B, C are in GP (common ratio 1). Then which of the following is/are
correct.
A B C
(A) , , are in HP if common ratio of GP is c/a.
a b c
a b c
(B) , , are in HP if common ratio of GP is equal to common difference of AP.
A B C
A2 B 2 C 2 c
(C) , , are in HP if common ratio of GP is
a b c a
a b c
(D) 2 , 2 , 2 are in HP if common ratio of GP is equal to square root of common difference
A B C
of AP.
Comprehension Type
correct.
x6 y 4 x8 z4 

Lines L1 :
3

2
 z  2 and L2 :
4
 y 2 
2
meets the plane  : r . 2lˆ  jˆ  kˆ  7 at  
points A and B.
59. Area of the triangle formed by the lines L1 , L2 & AB is

 19 19
(A) (B)
2 2 2
11
(C) (D) 6 5
4
22
60. Equation of line joining the images of the point of intersection of L1 & L2 with respect to the plane
 and the line AB is
3x  14 3y  7 3z  7
  3 x  14 3 y  7 3z  7
(A) 4 5 1 (B)  
3 3 6
3x  14 3y  7 3z  7 3x  14 3y  7 3z  7
(C)   (D)  
0 3 4 0 3 3

n
n x i
Let xi  R, i  1,2,3.......n are numbers such that i xi  i 2  i 1
and x1  x2  ......  xn  280
i 1 2
61. No. of ways of distribution of n identical objects among 3 persons such that each get at least 1
object is
(A) 4 (B) 10
(C) 20 (D) 140
62. Probability that a randomly selected triangle formed by vertices of a 2n + 1 sided regular polygon
is isosceles is
3 5
(A) (B)
13 13
7 9
(C) (D)
13 13
Let p (n) denotes the number of different ways the positive integer n (n>1) can be expressed as the sum
of 1’s and 2’s. For example P (5) = 8, i – e
i.e. 5 =1 + 1 + 1 + 1 +1
=1 + 1 + 1 + 2 = 1+ 1+ 2+1 = 1 + 2 + 1 + 1 = 2 + 1 + 1 + 1
=1 + 2 + 2 = 2 + 1 + 2 =2 + 2 + 1
63. The value of p(p(6)) is

(A) 356 (B) 377
(C) 389 (D) 427
23
64. The number of solutions of the equation p(n) = n + 1 where n = N is

(A) 1 (B) 2
(C) 3 (D) 4
SECTION – C
(both inclusive).
65. Number of triangle ABC  B = 900 such that point B is vertex and A & C are point of zeros of a
Quadratic expression y = ax 2 + bx + c where b is an odd integer & a, c  z, is
  sin x 
66. The value of   2
dx  is (where [.] is greatest integer).
   1  tan x 
67. Two circles of unequal radii have four common tangents. A transverse common tangent meets
the direct common tangents at the points P & Q. If length of direct tangent (between the point of
contacts) is 8 then length of PQ is
 5 6  det  Am  5 Am 1 
68. If A    then the value of  m, n  N  is
 1 1 det  A n  5 An 1 
69. Integral part of the area of figure bounded by the tangents at the end of latus rectum of ellipse
x2 y 2 x2 y 2
  1 and directrices of hyperbola   1 is
9 4 9 72
FIITJEE JEE (Advanced)-2018
FULL TEST – I
Paper 2

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
4. Each part is further divided into two sections: Section-A & Section-C

on OMR sheet.

1. Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer.
Section-A (09 – 12) contains 4 multiple choice questions which have more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
Section-A (13 to 18) contains 3 paragraphs with each having 2 questions. Each question carries
+3 marks for correct answer and –1 mark for wrong answer.
2. Section-C (01 – 05) contains 5 Numerical based questions with answers as numerical value and
each question carries +4 marks for correct answer. There is no negative marking.
Enrolment No.
2
Useful Data
PHYSICS
CHEMISTRY

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
= 6.625  10–27 ergs
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3
Physics PART – I
SECTION – A
1. A ball is dropped from rest at height 4h. After it has fallen a distance d, a second ball is dropped
from rest at height h. What should d be (in terms of h) so that the balls hit the ground at the same
time?
3H H
(A) d  (B) d 
2 3
(C) d = H (D) d = 3H
2. What is the acceleration of the upper block of the system as shown in the
figure? Assume pullies and strings are ideal. Given mA  0
(A) 4g (B) 2g mA
g
(C) g (D)
2
B m
3. The pitch of a screw gauge is 0.5 mm and there are 50 divisions on its circular scale and one
main scale division = 0.5 mm. Before starting the measurement it is found that when jaws of the
screw gauge are brought in contact, the zero of the circular scale lies 4 division above the
reference line. When a metallic wire is placed between the jaws, five main scale divisions are
clearly visible and 18th division on the circular scale coincides with the reference line. The
diameter of the wire is
(A) 2.68 mm (B) 2.72 mm
(C) 2.64 mm (D) 2.62 mm
4
4. A point like particle of mass ‘m’ (very small) is projected in the vertically upward direction where
 3
already exist, a uniform horizontal electric field E . The field strength is such that qE= mg,
4
where q is the charge on the particle. After what time the radius of curvature of the charged
particle will be minimum.
V 8V0
(A) 0 (B)
g 25g
16V0 25V0
(C) (D)
25g 16g
5. Consider a thin conducting shell of radius R carrying total

charge Q .Two Point charges Q and 2Q are placed on points R
A
R B
A and B, which are at a distances of and 2R from the R C
2 2
center of the cell respectively as shown in the figure. If the

cell is earthed how much charge will flow to the earth?
(A) 3Q (B) Q
Q
(C) 2Q (D)
2
6. Figure shows an object ‘o’ placed in front of a 3 Plane mirror

 3 2
biconvex lens     behind which there is water
 2 4
O
 4
    and a plane mirror at a distance of 20m. A 45cm 3
 3
point object ‘O’ is placed at a distance of 45 cm from
the lens as shown in the figure .The position of the
20cm
image of the object coincides with the object itself,
then radius of curvature of the lens is.
(A) 20cm
(B) 45cm
(C) 60cm
(D) 30cm
5
7. A satellite of mass m is orbiting the earth in a circular orbit of radius r. It starts losing its
mechanical energy due to small air resistance at the rate of k joule/sec .The time taken by the
satellite to hit the surface of the earth is (M and R are the mass and radius of the earth)
GMm  1 1  GMm  1 1 
(A)    (B)   
K R r  2K  R r 
2GMm  1 1  GMm  1 1 
(C)    (D)   
K R r  K R r 
8. There is a container ABCD which is accelerating towards right, at 20m

B C
g
the rate of m / s 2 . Container is filled completely by a liquid of
2
relative density 3. A small ball of relative density 1 is released 10m
from rest with respect to the container at point A of the container.
At what distance from the end point B, the ball will hit to the top
A D
surface of the container.
(A) 2m (B) 5m
(C) 15m (D) 10m

9. A pendulum swings back & forth between two horizontal positions as shown in the figure, under
uniform gravity, then
II
I
(A) There are more than one points in the part I where acceleration is vertical.
(B) There is at least one point in part I where acceleration is horizontal.
(C) During the motion in both parts tension is maximum only once.
(D) Acceleration of the bob is never directed towards the point of suspension O.
6
10. In the arrangement as shown in the figure, S1 and S3 are already closed for a long time. Now at
t = 0 the S2 is closed and S1, S3 are opened. [ = 1 volt, L = 1 henry, R = 1 Ω & C = 1 Faraday]
S1 S2 S3
C L
 
R
(A) After S2 is closed the maximum current through the indictor is 2A.
(B) After S2 is closed the maximum current through the indictor is 2A
(C) Maximum charge on the capacitor is 2  2 coulomb
(D) Maximum charge on the capacitor is 2 coulomb
11. A particle of mass m = 3 kg is moving on a straight line in a conservative force field in which the
potential energy associated with the particle is given by U (y)  2 y 2  30 y  450 . At t = 0, particle
is at y = 8 m and moving towards positive y-axis with 1 m/s.
4
(A) During the course of its motion the maximum speed of the particle will be m/s.
3
(B) Particle will never cross the origin.
5
(C) Particle will come to its equilibrium position for the first time at second
4 3
(D) The amplitude of oscillation for the particle is 1m.
12. Figure shows two reservoirs containing two liquids of masses 4 m and 2 m and their specific heat
capacities are S and 2S respectively. Their initial temperatures are 4T0 and T0 respectively. The
containers are joined by a conducting rod of thermal conductivity K, length l and cross section
area A specific heat capacity of the rod is negligible.
P
4m 2m
S l,k,A 2S
4T 0 T0
(A) The temperature of mid-point ‘P’ of the rod is always constant.
(B) Heat extracted from container 1 = Heat supplied to container 2
2msl
(C) After time t0 = ln2 the temperature difference between containers becomes half of the
ka
initial temperature difference.
msl
(D) After time t0 = ln2 the temperature difference between containers becomes half of the
ka
initial temperature difference.
7
Comprehension Type
correct.
In the arrangement shown in the fig the cylinder is insulating one. Both
n vaccum n
sides same diatomic gas is trapped by two insulting massless pistons
P0 f P0
with the help of an ideal spring. The natural length of the spring is
equal to the length of the cylinder. Initial state of the gases are as V0 f
V0
shown in the figure.
13. What is the value of energy stored in the spring?

(A) P0V0 (B) 2P0V0
PV
(C) 4P0V0 (D) 0 0
2
14. Now the gases are heated slowly, such that their temperature becomes three times to their initial
temperature. The total heat given to the system is
(A) 12P0 V0 (B) 8P0 V0
(C) 5P0V0 (D) 6P0 V0
Initially the nucleus of radium-226 is at rest. It decays due to which and α particle and the nucleus of
radon are created. The released energy during the decay is 4.87 Mev, which appears as the kinetic
energy of the two resulted particles.  m  4.002amu, mRn  222.017amu,
15. Kinetic energies of  particle & radon nucleus are respectively

(A) 0.09 Mev, 4.08 Mev (B) 4.78 Mev , 0.09 Mev
(C) 4.08 Mev , 0.09 Mev (D) 3.68 Mev , 0.08 Mev
16. What is the linear momentum of the α – particle?

(A) 2.01 10 19 kgms1 (B) 1.01 1019 kgms1
(C) 4.01 1019 kgms1 (D) 8.01 10 19 kgms1
8
There is a hollow cylinder of radius R and it is rotating with constant angular 

speed . There is a point mass which rotates along with the cylinder and
gets carried upward. Friction is enough such that the point mass does not
slip with respect to the cylinder as long as the normal force is becomes zero. h
If the path of the particle after it lost contact with the cylinder is as shown in o
the figure then,
17. In Order to happen this where most the particle lose contact with the cylinder?
R R
(A) h  (B) h 
2 3
R R
(C) h  (D) h 
2 
18. What is the value of  (in terms of g and R)

g g
(A) (B)
3R 2 R
g g
(C) (D)
2R 2R
SECTION – C
(both inclusive).
19. A square of elastic sheet of dimension (a × a) has a mass 125 gm. A force of 2.5 N is applied to
each of the four edges. What is the velocity of waves on the sheet? a = 0.75 m.
20. In a Young’s double slit experiment, the angular separation of the interference fringes on a distant
4
screen is 0.04A0. The angular separation if the entire apparatus is immersed in a liquid of R.I.
3
is 0.0n A0, then what is the value of n?
9
p 2  3
21. In the circuit shown, the reading of the ammeter is amp. 1
q
What is the value of p + q? A
3 2 2
4 volt
22. In the figure shown there is non- conducting disc of mass M = 2kg + ++
and radius R = 4 m. On its upper & lower part of circumference ++ +
+
+
+Q and –Q charge are uniformly attached such that liner charge + +  
+ +
Q - Eg
density is . The disc can freely rotate about an horizontal axis - O
-
R -
- -
passing through O. There is a uniform electric field  in the - - -
-- - -
vertical direction such that QE= mg. If the disc is rotated by a
small angle it performs S.H.M. its time period is given by
p
T  then, P + n is. (Take 2  g )
n
23. There is a non-conducting disc of mass 4kg and ĵ

radius 1m placed on a rough non conducting
surface. A conducting ring of same mass is tightly
fixed 
around the disc. There exists a magnetic O
field B  4iˆ  4t 2 jˆ. The resistance of the ring is iˆ
8Ω. Find the time after which the system will start k̂
toppling.
10
SECTION – A
24. Which of the following is/are incorrect statement (s):

(I) CHCl 3 is less acidic than CHF3
(II) Dipole moment of chlorobenzene is more than chlorocyclohexane
(III) Dipole moment of fluoromethane is more than chloromethane
(IV) NH 2NH 2 .HCl show positive test for nitrogen in lassaigne’s test
(V) Dipole moment of difluoromethane is more than dichloromethane.
(A) I Only (B) II Only
(C) I, II, III and IV (D) I, II, III, IV and V
25. O
O Br H3O+ NaOH, CaO

KOH
A B C
(Base) (excess)
Br
R
Which of the following is correct statement?
(A) Monobromination of C gives two product. (B) Degree of unsaturation of C is five.
(C) Degree of unsaturation of B is 8 (D) None of these.
11
26. O
C
H I. OD-/D2O
2 A + B
II. D3O+
Which of the following statement is correct?

(A) O
C CH2OH
O D
A is and B is
(B) O
C CHDOD
O H
A is and B is
(C) Order of reaction of I is 4 at very high concentration of OD-
(D) Order of reaction of I is 3 at very high concentration of OD-
27. Which of the following statement is incorrect?

(A) Cr CO 6  Fe CO 5  Ni CO 4 (Order of increasing CO bond strength.)
 
(B) V CO 6   Cr CO  6   Mn CO 6  (order of increasing M – C bond strength where M is
central metal atom/ion)
 
(C) V CO 6   Cr (CO)6   Mn CO  6  (Effective atomic no)

(D) V CO 6   Cr CO  6   Mn CO  6 ] (Order of increasing CO bond strength)
12
28. 1. HNO2
P
2. 
OH NH2
The P is
(A) (B) O
NH2
(C) (D) O
O
29. An element undergoes a reaction as shown

x  2e   x 2
Energy released = 30.87 ev/atom. If the energy released, is used to dissociate 4 g of H2
molecules equally into H+ and H* where H* is excited state of H atoms where the electron travels
in orbit whose circumference equal to four times its de – Broglie’s wavelength. Determine the
minimum number of moles of x that would be required
Given: IE of H = 13.6 ev/atom, bond energy of H2 = 4.526ev/molecule
(A) 1 (B) 2
(C) 3 (D) 4
30. How much Ag Br could be dissolved in 1 litre of 0.40 M NH3? Assume that only complex formed
is [Ag(NH3)2]+. Given Ksp(AgBr) = 5.0 × 10-13 ; Kf of [Ag(NH3)2]+= 1.0 × 108
(A) 2.82 × 10-3 M (B) 2.22 × 10-4
(C) 2.22 × 10-3 (D) 2.82 × 10-4
31. If E10 is standard electrode potential for Fe/Fe+2 and E20 is for Fe 2 / F e 3 and E30 for Fe/Fe+3.
which of the following relation is correct?
(A) E30  E10  E20 (B) E 30   E10  E 20  / 2
(C) E30  E20  2E10 (D) E 30   E20  2E10  / 3
13

32. A salt MX has NaCl type lattice in which r is the minimum distance between Mz+ and Xz-. Each
M z  ion is surrounded by
(A) 6 X z  ions, each at a distance r (B) 12 M z  ions, each at a distance 2 r.
(C) 8 X z  ions, each at a distance 3 r. (D) 12 M z  ions, each at a distance 4 r.
33. " a MnO4  b H2O2  c H   d Mn 2  e O2  f H 2O " is a balanced chemical equation (reaction).

The values of a, b, c, d, e and f are
(A) 2, 1, 6, 2, 3 and 4 respectively (B) 2, 3, 6, 2, 4 and 6 respectively
(C) 2, 7, 6, 2, 6 and 10 respectively (D) None of these
34. Og   e   Og2 H1

O g   e   Og  H 2
O2g   O2g   e  H 3
O(g)  Og   e  H 4
 
H 2 g   H 2 g 
e H 5
H g   Hg   e  H 6
O g   2e   O 2 H7
Which of the following option(s) is/are correct?
(A) H1  H2 (B) H 4  H3
(C) H5  H6 (D) H7 is +ve
14
35. (i) O
CH3
Trace of
P1
NaOH
CH3
(ii) O
CH3
Trace of
P2
NaOH
CH3
(iii) O
H3C CH3
Trace of
P3 + Q 3
NaOH
(iv) O
CH3
Trace of
P4
NaOH
All products are in keto form .The correct statement(s) is/are.

(A) P1 and P2 are diastereomeric pair.
(B) P1 and P2 are identical compound.
(C) In reaction (iv) reactant and product are enantiomeric pair.
(D) P3 and Q3 are optically active stereo isomers and both are enantiomeric pair.
15
Comprehension Type
correct
Aryl halides undergo nucleophilic substitution reaction only in extreme condition. Except to certain
industrial processes where very severe conditions are feasible, one does not ordinarily prepare phenols
(ArOH), ethers (ArOR), amines (ArNH2) or nitriles (ArCN) by nucleophilic attack on aryl halides . The
presence of electron withdrawing groups like –NO2, -CF3 at ortho or para position to the halogen atom
makes the aryl halides more susceptible to nucleophilic attack. The reaction of unactivated or deactivated
aryl halide with strong bases or at high temperature proceed via the benzyne intermediate.
36. Me
O
Cl
NaNH2
Product. The predominant product is
NH3
(A) Me (B) Me
O O
NH2
NH2
(C) NH2 (D) Me
O
Cl
NH2
16
37. Cl
KNH2
+ (A)
LiqNH3
Identity A in the above reaction
(A) (B)
17
Ideal gas equation is represented as PV = nRT. Gases present in universe were found ideal in the Boyle’s
temperature range only and deviated more from ideal gas behavior at high pressure and low temperature.
PV
The deviation are explained in term of compressibility factor z. For ideal behavior Z   1 . The main
nRT
cause to show deviation were due to wrong assumptions made about forces of attractions (which
becomes significant at high pressure) and volume V occupied by molecules in PV = nRT is supposed to
be volume of gas or the volume of container in which gas is placed by assuming that gaseous molecules
do not have appreciable volume. Actually volume of the gas is that volume in which each molecule of gas
can move freely. If volume occupied by gaseous molecule is not negligible, then the term V would be
replaced by the ideal volume which is available for free motion of each molecule of gas in 1 mole gas.
Vactual = volume of container – volume occupied by molecules
=v–b
Where, b represent the excluded volume occupied by molecules present in one mole of gas.
Similarly for n mole gas
Vactual = v - nb
38. As the pressure approaching zero ie. at very low pressure. The curves plotted between
compressibility factor Z and P for n mole of gases have the following characteristics.
(I) The intercept on y axis leads to a value of unity
(II) The intercept on y axis leads to a value of ‘n’.
(III) The curves possess same slope for different gases at same temperature.
(IV) The curves possess different slopes for different gases at same temperature.
(V) The curves possess same slope for a gas at different temperature.
(A) I, IV, V (B) II, III
(C) I, II, III, IV (D) II, III, V
 V 
 
T P
39. The ratio of coefficient of thermal expansion    and the isothermal compressibility
V
 V 
 
 P T
 for an ideal gas is:
V
P P
(A)  (B)
T T
T T
(C) (D) 
P P
18
A Colorless solid A liberates a brown gas B on acidification, a colorless alkaline gas (C) on treatment with
NaOH and a colorless non-reactive gas D on heating. If heating of the solid is continued, it completely
disappears.
40. The compound A is

(A) NH 4 NO2 (B) PH 4 NO3
(C) NH 4 NO3 (D) none of these
41. Which one of the following is correct?

(A) Bond order of D is 2.5
(B) D is a paramagnetic gas
(C) Smell of gas c is like rotten fish
(D) Ionization energy of gas D is more than N atom
SECTION – C
(both inclusive).
42. Find out no of compounds that gives positive iodoform test (either in cold or hot condition)
(A) H3C C CH2 CH3 (B) I 3C C CH2 CH3
O O
(C) CH3 C CH2CH3 (D) CH 2I CH CH2CH3
OH OH
(E) CH3CH2OH (F) O
C
CH3
(G) Br (H) O O
H3C C CH3 H3C C CH2 C CH3
Br
(I) H3C C O Et
19
43. Find out no of compound which has non zero Dipole moment
(A) OH (B) OH
OH
OH
(C) SH (D) F F
C C C
H H
SH
(E) F H (F) F F
C C C C C C C
H F H H
(G) F H (H) O
C C C C P
O O
H F O
P O P
O O
P
O
(I) PCl 2F 3 (J) I2Cl6
20
44. Find out no of correct statements.

(A) N2  N (Ist ionization Energy)
(B) O2  O (Ist ionization Energy)
(C) H 2  H (Ist ionization Energy)
(D) N2  N 2 (Stability)
(E) O2  O (Ist Electron affinity)
(F) H 2  H (Ist Electron affinity)
(G) Na2CO3  Li 2CO3 (Thermal stability)
(H) No of co-ordinate bond in P4O10 is 4
(I) No of  bond in P4O8 is 2
45. Find out no of compounds which show mutarotation
(A) Cellobiose
(4 – O – (β – D – glucopyranosyl) – D – glucopyranose)
(B) Maltose
(4 – O – ( – D – glucopyranosyl) – D – glucopyranose)
(C) Lactose
(4 – O – ( – D - galactopyranosyl) – D – glucopyranose)
(D) Gentiobiose
(6 – O – ( – D - glucopyranosyl) – D - glucopyranose)
(E) Sucrose
(α – D – glucopyranosyl –  – D - fructofuranoside)
(F) Methyl α – D – galactopyranoside.
(G) α –D – allopyranose
(H)  – D – glucopyranose
(I) α – D - fructofuranose
46. Cl2
Products
h
Find out no of correct statements about above reaction.
(A) No of monochlorinated products are three
(B) No of optically active monochlorinated products are two
(C) No of optically inactive monochlorinated product is one
(D) No of dichlorinated products are ten
(E) No of optically active dichlorinated product are six
(F) No of optically inactive dichlorinated products are 4
(G) No of meso dichlorinated products are two
(H) No of dichlorinated products are six
(I) No of optically active dichlorinated products are seven
(J) No of meso dichlorinated products is one
21
SECTION – A
1  3  32 1  3  32  33
47. If Sn  3   .......................... upto n – terms
3! 4!
Then the value of  lim Sn  is, (where [.] represent G.I.F)
 n 
(A) 6 (B) 7
(C) 8 (D) 9
48. Let f(x) be a polynomial of degree 4,

with f  2   1, f '  2   0, f ''  2   2, f '''  2   12, f ''''  2   24 , then the value of f '' 1 is
(A) 24 (B) 26
(C) 28 (D) 30
49. A person whose hobby is tossing a fair coin is to score one point for every tail and two points for
every head. The person goes on tossing the coin, till his score reaches 100 or exceeds 100. Then
the probability that his score attains exactly 100 is,
2 1 2 1
(A)  (B) 
3 3.2100 3 3.2100
2 1 2 1
(C)  100 (D)  100
3 2 3 2
1
50. Let f  x   x5  3  , x  0 & f  0   0 (where [.] represent G.I.F), Then lim f  x 
x  x 0
(A) Does not exist (B) 1

(C) 1 (D) None of these
22
51. In an examination of the maximum marks for each of the three papers are 50 each and maximum
marks for the fourth paper is 100. Then the number of ways in which a candidate secure 60%
marks in aggregate is
(A) 110551 (B) 40375
x
1 y   dx
2
  dx 
52. If the solution of the differential equation e y y  x    xy 2  y 3   0 is
 dy   dy 
x
Ae xy  Be y  C  0, Then A + B is
(A) 1 (B) 0
53. If the line x  y  1  0 and y  2x  5  0 are tangents to a parabola whose focus at (1, 2), then
 29 14 
the equation of normal to the parabola through  ,   is,
 17 17 
(A) 2x  4y  1  0 (B) y  3x  2  0
(C) 4x  y  5  0 (D) None of these
54. If a  b  c  5, a2  b2  c 2  12 and a3  b3  c 3  25 Then the value of a 4  b4  c 4 is

251 253
(A) (B)
6 6
255 257
(C) (D)
6 6

55. If C1 and C2 are two concentric circles of radii 4 and 5 respectively with centre at origin. A
tangents is drawn to circle C2 at a given point ‘P’. This tangent is the diameter of a variable circle
C3, which touches C1 externally. Also this tangent meet C3 in Q & R. If the diameter QR subtends
a constant non – zero angle at a fixed point T on line joining O & P. Then the locus of the point ‘T’
for various positions of P on C2 is
(A) x 2  y 2  2 (B) x 2  y 2  4
(C) x 2  y 2  64 (D) x 2  y 2  36
23
x
56. If g(x) is a continuous function such that  g  t  dt  , as x
0
 , Then the value of K for which
x
2
line y = Kx intersect the curve  g  t  dt  2  y
0
(A) -1 (B) 2
(C) 3 (D) 1
57. ABCD is a regular tetrahedron. P & Q are the mid – points of the edges AC
and AB
respectively,
G is the centroid of the face BCD and  is the angle between the vectors PG and DQ , then
 
(A) The angle between AB and CD is 900
 5 
(B) The angle  is   cos1  
3 3 
 5 
(C) The angle  is   cos1  
6 3 
 
(D) The angle between AB and CD is 1200
r  4n 1
 r 2  13n2  7rn 
58. If P   
n3

r  3n  
 r 2  13n2  7rn 
r  4n
& Q  
r  3n 1  n3
 Then

5 5
(A) P  (B) Q 
6 6
5 5
(C) Q  (D) P 
6 6
24
Comprehension Type
correct
If n be a natural number define polynomial fn  x  of nth degree as follows

fn  cos    cosn 
i.e f2  x   2x 2  1 f3  x   4x 3  3x,
Then
10 10
59. x  x2  1   x  x2  1  is equal to
(A) f10  x  (B) f11  x   f9  x 

(C) f11  x  (D) 2f10  x 
60. f6  x  is equal to
(A) 36x 6  48x 4  18x 2  5 (B) 32x 6  48x 4  18x 2  1
(C) 36x 6  45x 4  18x 2  8 (D) 36x 6  48x 4  18x 2  7
If the integrand is a rational function of x and fractional powers of a linear fractional function of the form
Ax  B
, then rationalization of the integral is affected by the substitution
Cx  D
Ax  B
 tm
Cx  D
1
 2x  3  2 1 7
1 5
1 1 1

61. If  1
dx  3   2x  3  6   2x  3  6   2x  3  2   2x  3  6  g  x    C
 2x  3  3 1 7 5 3 
Then g(x) is,
1 1
(A) tan1  2x  3  6 (B)  2x  3  6
1 1
(C) 3 tan1  2x  3  6 (D) 4  2x  3  6
25
dx 1 x
62. If   K3  C,
3 2
 x  1  x  1
4 1 x
Then K is equal to,

2 3
(A) (B) 
3 2
1 1
(C) (D)
3 2
x  3 y 1 z  2
Consider a plane P  2x  y  z  5  0, a line   and a point A  3, 4,1 . L2 is a line
2 3 1
passing through A intersecting L1 an parallel to the plane P.
63. Plane containing L1 and L2 is,

(A) Parallel to yz - plane (B) Parallel to x-axis
(C) Parallel to y-axis (D) Passing through origin
64. Line L1 intersect plane P at Q and xy – plane at R, then the volume of tetrahedron OAQR is,
(where ‘o’ is origin)
14
(A) 0 (B)
3
3 7
(C) (D)
7 3
SECTION – C
(both inclusive).
x2 y 2
65. If the set of ‘K’ for which two distinct chords of the ellipse  1 passing through (2, -1) are
8 2
bisected by the line x + y = K is [a, b], then (a + b) is……………..
26
 27ab 2 
66. If ax3  cx  b  0  x  R  0, where a, b, c  R+. Then the minimum value of  3  is….
 c 
67. If x, y, z are positive real number, such that x + y + z = 1, If the minimum value of
 1  1  1 2
 1    1    1   is K , then K is………………….
 x  y  z
68. Let A be a square matrix of order 3 satisfies A 3  6A 2  12A  8I  0 & B  A  2I

 
If A  8 & adj I  2A 1  K, then K  ……………..where [.] represents G.I.F
9a 5b 9a sin  5b cos 
69. If   56 and  0
cos  sin  cos2  sin2 
2 23
  2
If the value of  9a  3   5b  3    8K  Then K is…………………
 
1
AITS-FT-I-PCM (Sol.)-JEE(Main)/18
FIITJEE JEE(Main), 2018
ANSWERS, HINTS & SOLUTIONS
FULL TEST – I
(Main)
Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. B 31. B 61. B
2. A 32. A 62. A
3. A 33. D 63. A
4. C 34. A 64. B
5. B 35. D 65. A
6. D 36. C 66. B
7. A 37. A 67. A
8. B 38. C 68. A
9. B 39. B 69. B
10. A 40. B 70. A
11. A 41. B 71. C
12. A 42. B 72. D
13. A 43. C 73. A
14. D 44. B 74. B
15. A 45. D 75. A
16. B 46. D 76. C
17. C 47. D 77. C
18. D 48. B 78. C
19. A 49. D 79. A
20. C 50. A 80. D
21. D 51. A 81. D
22. A 52. D 82. C
23. A 53. C 83. C
24. B 54. B 84. A
25. A 55. C 85. D
26. D 56. D 86. C
27. A 57. A 87. D
28. D 58. C 88. D
29. A 59. A 89. C
30. D 60. B 90. B
2
Physics PART – I
SECTION – A

1. VR  Vx i  Vy i
A
B Vx
300
C
Vy
For path AB Vx = 5 ms-1
For path BC velocity of rain r to BC should be zero hence
5
Vx sin30o  Vy cos 30o Vy  ms 1
3
2 2 10 1
VR  Vx  Vy  ms
3
 
2. since VAB and RBA are antiparallel to each other initial separation is minimum at initial state
FR 2F
3.       2
.2 
mR mR
R
a = R'
R'

F'

sin  
2R 6 2R
Position of C.O.M = .    R
3  
 
6
4F
Acceleration of C.O.M =
m
4R
Hence F  F   .m
m
4
F   F
  
4. a = –Kx  K = 4 s-2
Then  vdv  K  xdx
v  8 ms 1
3
5. portion DEA and DFC are identical hence moment of inertia of ABCD is same as ABFDEA
E 6m A 2m B
8m 1270
10 m 8m
900 8m
F
D
6m
C
2
M   BE 
I  2.
3
 512 kgm 2
6. To start motion F > 8 M
F 8
Acceleration =
8
F/2
3
fr
F F 8 F
 fr  3     3  fr
2  8  8
Fmax
 3  fLm  6N  Fmax  24Nx
8
7. the point where adiabatic curve touch the line AB the nature of process will change from endo
thermic to exothermic.
P0
A
C
B
V0
V0
P0 P
  
V0 V
  mv  P0  P0
m   m
V V0
P0 5
mv 1     P0 V   V0
m 1    8
4
8.   0 nkt r 2  0 n2kt .R 2
2kt
kt
d
E.2r 
dt

 0 nk  2R 2  r 2 
9. the point x = a and b are stable equilibrium point.
1 2
10. Fx  0 m1gx  kx  0
2
0 m2 g
x
k
2mv 2mv cos 30o

11. F1  F2 
t t
Hence F1 > F2
12. since mass and specific heat of two different bodies are same
h  h2
hf  1  h1  h2
2

13. 
R  RA  r
R RA
A B
 r
r   R  RA 
V     r 
 R  RA  r  R  RA  v 
14. at steady state 5A current through inductor hence P.D across indicator at t = 0
20  5 = 100 V
 s

10mH
50 V
 R 2   4R 
15. Dipole moment    2. 
 2   3 
5
E0
+ + ++
++ ++ ++
+ + + ++ ++
4R 3 
3
f r = Ma
4R 3  MR 2
E  fr R  
3 2
a

R
For pure rolling
8 ER 2
a
9 M
16. current across inductor and capacitor are out of phase and same magnitude hence only
resistance will be operated.
2.5 2 A
1 dx
17.  K .  R 2
 x2 
1 dx 1
RT   ln  3 
K   R2  x2
 2K R 
dx
R
R/2 x
1 dx
dR 

K  R2  x2 
 x
18. dm   0  y  dy  dx 
 ab 
y
dy
b
y
x
x a

R   x, y 
  0 xy
 R.dm   ab

 dxdy  xiˆ  yjˆ 
 0 xy
 dm  ab dx.dy
6
 0 xy  xy
 x dx.dyiˆ  0 dx.dy  y  jˆ
ab  ab
 0 xy  0 xy
 ab dx, yd  ab dx.dy
y  COM x
dy  dx 
a b
2 2
 x dx y dy
0
a
iˆ  0
b
ˆj
 xdx
0
 ydx
0
2a ˆ 2b ˆ
i  j
3 3

19. 
M  10 100  10 4 iˆ  50  10 4 jˆ  50  104 kˆ 

 10iˆ  5 ˆj  5kˆ  103 Am 2

B  2iˆ  3 jˆ  kˆ
  
  M  B  10  20  10 2 Nm  20  10 1 Nm
20. C
21. Distance between central bright and first minimum,

D
y
d
y 1 1

y2 2
22. A
23. stopping potential for a and b are same. Hence f a = f b but current Ib is more than Ir at zero
potential.
I0
24. 
I2  I0 1  e x  I
2
, x  1.5 cm 1
  0.462 cm 2 / g
25. A
R
26. R  T 4  T 4 

T  b
27. A
28. since voltmeter are identical
7
7
9 I1
v1
5
14 I2
v2
24
I3
v3
R
1 3 3
 let 2  x 1  x
2 2 2
3
9 x  14 x  5  7.5  0
2
x  5.0 A   2
 7.5 A  1
27 x  28 x
 2.5
2
Hence resistance of voltmeter is 1 
253  7.5  7.5  9  75
3  3A
Hence V3 = 3.0 V
1
29. PB  V 2  PA  P
2
B
A
P 1
PB   P  V 2
A 2
P
  gH
A
2  P  gH 
V 

8
30. FBuoyancy  r 2 g

F buoyance
A B
mg
r 2  2 g
Torque =
4
2 2 gr 2

4
9
SECTION – A
1 d B  d B 
31.  k1  A    2k1  A 
2 dt dt
d C
 k2  A 
dt

B  2k1  1
 C k 2
1
 % B    100  50%
1 1
32. B12  12 corners

Icosahedral = 20 faces.
33. Nylon – 2 – Nylon – 6
-copolymer of glycine and amino caproic acid
-biodegrable.
34. Average (P – P) bond enthalpy
1265  59
  201 kJ / mol
6
35. Self reduction:
Cu2O  Cu2S   Cu  SO 2
36. NH2 NH2 NH2

NH2
HNO3, H2SO4 NO2

+ +
288 K
(B) NO2
(A) (C)
(47%) (2%)
NO2
(51%)
Order of basic nature: A > B > C
37. Anode     H2  g  
 2H
5.5

aq.  2e
1 atm 10 M
Cathode     2H  aq.  2e 

 H2  g 
xM
1 atm 
5.5 2
0.118 V  0 
0.059
log10
10   x  10 3.5 M
2
2  x
 pH  3.5
38. Reaction involved in developer:
K 2FeII  C2 O 4 2  AgBr  KFeIII  C2O 4  2  Ag  KBr
Ni
39. CO  3H2   CH4  H2 O
10
ZnO  Cr2 O3
CO  2H2   CH3 OH
Cu
CO  H2  HCHO  g
40. Z < 1 means attraction forces are dominating  a is considerable, b can be negligible at low
temperature and low pressure.
41. X  NO2 , Y  N2 O
42. Organic compound having C, N and S give blood colour in Lassaigne’s test with neutral FeCl3,
due to formation of Fe(SCN)3.
43. Chloroform and diethylether on mixing show –ve deviation from Raoult’s law, in which V.P.
decreases and b.p. increases.
44. E.N difference  O  X  O  H

 H  O  X  H  O   X 
 basic nature.
45. HO
HOCl
HC CH H C CH
Cl
HOCl
Cl O Cl OH
-H2O
H C C H H C CH
Cl Cl OH
46. Buffer solution
CO32   40 
pH  pK a2  log 
 11  log2   log  
HCO3   5 
 11  2log2  11.6
47.  0  Strength of ligand

max imum for CN 

48. Representation:
Base  Base  Base
|  |  |
 sugar  phosphate   sugar  phosphate   sugar 
 
 
 n
49. Na+ occupies octahedral voids formed by close packing of Cl- in ccp in which all tetrahedral voids
are vacant.
50. ClF3  T – shaped
1
51. Acidic strength: 
pK a
11
OH OH OH HO
NO 2
> > > (acidic strength)
NO 2
NO 2
52. Below pI, cationic species, goes to cathode.
Above pI, anionic species, goes to anode.
53.  high T H2O
Mg + C MgC2 Mg2C3 Mg(OH)2 + C3H4
54. F H F
LDA -
F C C Cl F C C Cl F 2C CCl 2
(strong hindered base)
F Cl F Cl
55. T  KV  PV 0  constant
R R R R 5R
C     R
 1 n 1 7 0 1 2
1
5
7R

2
4
56. Cu2  Fe  CN6   Cu Fe  CN 
2 6
Chocolate brown /reddish brown ppt.
57. For s-orbital,   0  no nodal plane

For dz2  orbital,   2  2 conical node, no nodal plane.
58. OH CH3 H CH3 H
H CH3 H OH HO CH3 H OH H3C OH
H OH H OH H OH H3C OH HO H
H3C CH3 CH3 H CH3
(2R, 3R) (2S, 3R) (2S, 3R) (2S, 3S) (2R, 3S)
diastereomer diastereomer enantiomer diastereomer
59. Classical smog is a reducing mixture, while photochemical smog has high concentration of
oxidizing agents.
60. Cannizaro reaction involves attack of OH– on carbonyl carbon and H– shift on another carbonyl
carbon, no carbanion intermediate.
12
SECTION – A
61. Let f  x   sinx  2 x  kx 2  kx

f   x   cos x  2  2kx  k
f   x    sin x  2k
The inequality is trivially true for k < 0
For k  0, we have f(x) < 0
The curve y = f(x) is concave downwards
 4    1
f 0 k 
2
      2
1 1
62. y  log10 x & z  logx 10  
log10 x y
2
1 dy 1 1   logx 
y   2  2
 2
z dz z logx 10  log10 
sec 2 x
 f  t  dt  
f sec 2 x  2 sec 2 x.tan x 8
63. lim 2
2
 lim  f 2
x
  x
 2x 
4 x2  4
16
64. lim an  lim an 1  L

n  n 
 lim an 1  lim 2  an
n  n 
 L  2  L  L  2 & L  1  N.D
65. Area = A = xy
ln x dA 1  ln x
A  
x dx x2
dA
0x e
dx
+ -
e
1 1
Hence x = e is point of maxima; Amax = e. 
e2 e
  1 
 1  1
4  1  2 tan z 
66. let I  f    f     loge   dz
2 3 0  1  1 tan z 
 3 

4
 3 2  tan z 
  loge   dz
0  2 3  tan z 
13

Replacing z  z
4

4
 3 3  tan z 
We get I   loge   dz
0  4 2  tan z 

4
9  9
 2I   loge   dz  I  loge  
0 8 8 8
b b
67.  f  x  dx   f  a  b  x  dx
a a
1 cos 2 t 1 cos 2 t 1 cos2 t
I1   x.f  x  2  x   dx    2  x  f  x  2  x   dx  2  f  x  2  x    I1
sin2 t sin2 t sin2 t
1 cos2 t
I1
 2I1  2  f  x  2  x   dx  2I 1  2I2 
I2
1
sin2 t
x
 2 xy y
  yx 2 xy

68. x  y .e  e  dy  y  e  y .e  dx
   
   
x
 y 2  xdy  ydx  e xy  e y  ydx  xdy 

x
ydx  xdy x
 e xy d  xy   e x / y 2
 e y .d  
y y 
x
 e xy  e y  c
69. since OP  BC
A(z1)
O
B(Z2) C(Z3)
P(Z)
 z  
 arg  
 z3  z2  2
70. you can have W, W, B or W, B, W or B, W, W
3 2 3 3 2 1 1 2 1 9 3 1 13
Required probability = . .  . .  . .    
4 4 4 4 4 4 4 4 4 32 32 32 32
71. x 2  x  2  x  1 ( Let x  1  0 )
 x 2  3  0 (No solution)
Now,
x 2  x  2  1  x  x  1  0 
 x 2  2x  1  0
Let f (x)  x 2  2x  1
14
 D  0    ( , 1]  1,  

b
If both roots –ve, then f  0   0 & 00
2a
So for α  1 both roots of this equation are –ve & α  1 at least one root is +ve and for –ve value
afx αx- 1  0 for positive values of x.
72. AB  PA  PB
So PA – PB is maximum when P is collinear with AB.
1
Equation of AB  y  1   x  0 
2
 x  2y  2   i 
& solve with 4x + 3y + 9 = 0  (ii)
(I) & (ii)
 24 17 
P  , 
 5 5 
73. A
74. As eccentric angle    0,2 

 1  2    2    1
P   5cos ,4 sin   Q   5cos 2 ,4 sin 2  or Q  5 cos ,4 sin  
 PQ  y  4 sin 1
75. equation of director circle.
 s  b  s  c  2 2 2
76. 1   1    2 a  b c
 s  a  s  a 
77. solving the planes taking 3 at a time vertices of tetrahedron are

0   0,0,0  , A  1,1, 1 , B  1, 1,1 ,C   1,1,1
1
Volume of tetrahedron = × (area of base) (height)
3
78. if the points be A, B, & C respectively then
           
 
AB  OB  OA  a  2b  c  2a  b  3c  a  b     3  c
          
 
AC  OC  OA  a  5b  2a  b  3c     2  a  4b  3c
 
Points are collinear if AB  t AC
9
   ,   2
4
79. put ln x  t .
80. Plane containing the line of intersection of the given planes is

 x  y  z  4     x  y  2z  4   0
s.e.    1 x     1 y   2  1 z  4    1  0
Vector normal to it
V     1 iˆ     1 Jˆ   2  1 Kˆ
15
Vector along the line of intersection of the planes

2 x  3 y  z  1  0 & x  3 y  2z  2  0 is


Given by n  3 iˆ  Jˆ  Kˆ 

& n is parallel to the pane  (i)
 1
 n.v  0   
2
& hence the required plane is
x  3 y  4z  4  0
 A  B  C  11
81. sin-1 is defined for [-1, 1]  a  0


 x + y = sin1 1  cos1 1  tan1 1 
4
Clearly image about x – axis will be x – y = /4.
82. cos 4 x  6  7cos 2 x  0

  cos 2 x  1 2cos 2 x  5   0
5
 cos 2 x  & cos 2x  1
2
2x = 2nπ  x = nπ
Sum in [0,314].
 [1  2  .......  100]  100  5050  100  4950
83. we have g(x) = f(x) Sinx  (i)
Diff. w.r to x.
g’(x) = f(x) Cosx + f’(x) Sinx  (ii)
Again diff.
g”(x) = f(x) (-Sinx)+ f’(x) Cosx + f’(x) Cosx +f”(x) Sinx
 g "( )  2 f'().Cos( )  2  1 1  2
Hence g "()  2
3 x  6y
84. we have  1  (i)
k
& 2 x 2  2xy  3 y 2  1  0  (ii)
Now Homogenising (2) with the help of (1),
We get
2
 3 x  6y 
2 x 2  2xy  3 y 2    0
 k 
2
 
 K 2 2x 2  3 x  3 y 2   3 x  6 y   0
Now coff. of x2 + coff. of y2 = 0
 K 2  9  K  3
85. D
86. Let the amount received by sons be Rs. X, Rs. Y & Rs. Z respectively, then
x  y  z  101  x
i .e 2x  101  x  50, y  50 & z  50 & x  y  z  101
 Coff. of x101 in the expansion of (1 + x + x 2 + …..+ x50)3
1103 C101  3.52 C50 103 C2  3.52 C2
16
 n k 1   n k 1 
87. z1, z2, z3 .......zk  cos     i sin  
 n 1 n(n 1)(n 2)   n 1 n(n 1)(n 2) 
  1 1
 cos  i sin  i
4 4 2 2
88. Since the tangent at any point  x (a, b) lies below the curve
 the curve is concave upward in the interval (a, b)
 f”(x) > 0  x  (a, b)
n
89. x2y 3   x  y 
dy  dy 
2 xy 3  3 x 2 y 2  n(x  y)n 1  1  
dx  dx 
n
n  x  y   dy y 
 5 xy 3    
x  dx x 
n n
 5x  y   nx  y 
n5
90.     a  (i)
.  a 1  (ii)
Adding (I) & (ii)
      1     1  1  2
α & β are integral
  1  1,   1  2
  1  1,   1  2
  0,   1
Or
  2 &   3

a  1 or 5
1
AITS-FT-I-(Paper-1)-PCM (Sol.)-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018

FULL TEST – I
PAPER-1
Q. Q. Q.
PHYSICS CHEMISTRY MATHEMATICS

No. No. No.
1. A 24. C 47. B
2. D 25. D 48. C
3. B 26. C 49. A
4. B 27. B 50. A
5. D 28. A 51. B
6. A 29. D 52. A
7. A 30. A 53. C
8. C 31. A 54. C
9. ABC 32. AB 55. AC
10. AD 33. ABC 56. AD
11. BCD 34. BD 57. AC

12. BC 35. BC 58. ABD
13. D 36. A 59. B
14. C 37. B 60. D
15. C 38. C 61. C

16. A 39. A 62. A
17. A 40. A 63. B
18. C 41. D 64. D
19. 4 42. 4 65. 0

20. 2 43. 5 66. 2
21. 6 44. 5 67. 8

22. 8 45. 6 68. 1
23. 3 46. 4 69. 7
2
Physics PART – I
SECTION – A
    
1. 
aB  a A    rB,A  2 rB,A 
 5j  4i  3j  12i  16j 
aB along y  axis should be zero.
 11  3  0
4
    rad / s 2
3
80
aB   4  12  i   i m / s2
3

2. y tan 
2
 y
dy  sec 2 d 
2 R Q

4   B 
8  Bdy cos  
0
 B
a b  c  d
.d  0I0 x
 
2  
4
8 I 2  I0
0 4 0x0 . . sec 2  cos    B.d  0I0
2 2 a b c  d
x2 
4 S P
2 
0I0   B.d  0I0
3 a b c  d
  2 I
 B.d  0I0  0I0  0 0
a b  c  d 3 3
3. Let R  2  R1
t R  4
3CE   
qt   1  e 2R1C 
2   q

t q1
dq 3E 
2R1C
I  e 2  64  q1   q  q1 
dt 4R1
+ +
2
Heat loss in R1   I R1dt
8v
C - -C
 576 J
2
so, heat lossin R  4 is  576   384 J
3
4. Maximum power transfer will takes place when v P is maximum.
5. aC  R  for no slipping 
3
VC  R  VC is the speed of cylinder w.r.t plank 
)
nk
la
aC  3aP  0
tp
.r.
F
(w
VC  3VP  0 V
P
C
a
P
a
S C  3SP  0

f
f
6. Let T1 and T2 be the initial and final temperature, then
P0 V  nRT1 ...... i 
 W
 P0  A   V  Ah   nRT2 ....  ii
 
Where h is the displacement of piston.
Also, work done on gas  U
3
Wh  nCV T  nR  T2  T1  ........  iii
2
From euqation  i  ,  ii  and  iii 
2 WV
Wh   Wh  P0 Ab
3 A
WV
or, Ah 
5
P0 A  W
3
 
 W  Wv 
T2   P0   V  
 A  5
 P0 A  W 
 3 
5 5
T2  T1   300  5  75K.
4 4
v v
7. f 
2    2  0.6r  2    1.2r 
f v     1.2r 
  
f v    1.2r 
v
Here 0
v
f
 100  
   1.2r   100
f    1.2r 
 0.16
Gm 2
8. P 
8 R 4
4
P
B
V / V
3dR Gm2
B. 
R 8R 4
Gm 2
dR 
24BR3
20
9. I1  2
z1
2 100 100
I1
 A at 450 leading
5 2
20 2
I2   A at 450 lagging I2 XL  50
z2 5 50
1
I1R.M.S  A
5 40 V
2
I2R.M.S  A
5
10. For central height fringe

dsin   2mm
4mm sin   2mm
  300 S1 y
y 
tan300 
2
1
y m.
3 S2
For bright fringe  dsin   2   n
where n is 0,1,2,3.........
11. N12  N22  N2

 1
N2  mg
2
m   sin   f 
f  m 2  2
N1  m2 1 2
x
f
N1 N2
m2 x
5
 1  dx  1  O
12. dE  2    
 40  x  2 
 dx
dE  x
4 0 x D C
7
E In 2
440
A B
  dx
13. & 14.

Writing energy equation
dv d 2
mgv  mv I i R .....  i  
dt dt
C1 C2
v  a
dv d
a
dt dt B
i
Ba2 Bva
i  .....  ii
2R 2R R
From equation  i  and  ii 
g
3m dv B 2a 2
 mg  v v
2 dt 6mR
 B2 a2 
  t 
4mgR  6mR 
v  2 2 1 e   
Ba  
 
B 2a 2
dv 2g  6mR t
 e
dt 3
15. & 16.

Vemit  Vcollector
V  iR I
hc  2A e
Vstop    2v
e e
i  2V
i
I  2  iR
i 1  R   2
2V V V I R
2
i
1 R
4R
P  i2R  2
1  R 
dP
0
dR
2
4 1  R   4R  2 1  R   0
4  4R  8R
R  1
6
17. & 18.

V  2gh  1 m / s 1 m/s
8 3 1
  t   10Xt 2 370
100 5 2
1
t  sec
5
4 1
 x    100  16 cm
5 5
horizontal range from point B  16  6  10cm
Force required to keep the vessel in equlibrium  AV 2 cos 370
 0.12 N
SECTION – C
0 q2R2
19. FR    mR2 
4
  q2 
F  R m  0 
 4 
F F
 R 
2m  q2
m 0
4
m  4
q  5  10 4
0
20. After refraction through the quarter cylinder the emergent ray falls on the parabolic reflector
parallel to x – axis.
1
tan         y1 (x1, y1)
dy
A
dx  x1 ,y1 

2 tan  y1
tan2  2
 
1  tan  x 2  x1
2 
1
 x 2  m  50 cm. C
2
(x2, 0)
Ac is a normal at A
2
1 m 2 1  3F  3F 3F
21. . v0  K    .
2 2 2 K  2 K
4  9F2
v 20 
Km
v0  6 m / s
7
22. In the frame of the heavy cylinder the particle comes in with speed V and then bounces off.


2 v
f  2mv cos2   Rd cos   vn 

 
2
v
f 8 
 mv 2nR.
 3
z2 z2
23. f  f0  2 ......  i
n3 n3
z2 z2
E  E0 2  2  4 ii 
n n
Solving (i) and (ii) n = 2 z = 4
nh
L  mvr 
2
h
L  t  n
2
n h
 .
t 2
  1027  15
8
SECTION – A
24. (C)
Fact based
25. (D)
Zone refining is based on difference in solubility of impurity in its molten as well as solid state.
26. (C)
1.435 gm
No. of moles of AgCl =  0.01 moles
M AgCl
No. of moles of CoCl3.4NH3 = 0.01 moles
1 ionizable Cl per mole of CoCl3.4NH3
27. (B)


AgI  s  
 Ag  aq   I  aq
 
K sp   Ag  aq  I  aq  




Ag  aq  2CN  aq 
  Ag  CN2   aq

 Ag  CN 2 
Kf   
 Ag  CN 
Now, let a moles of AgI dissolved in CN- solution



AgI  s   2CNaq 
  Ag CN 2   Iaq
 aq
1 mole 0 0
12 x  mole x mole xmole
As CN   M.V  1 1  1 mole

x.x
 Kc  2
1  2x 
also K c  K f .K sp
x2
 2
 1.19  10 17 M2  7.11 1019 M2
1  2x 
 x  0.5
28. (A)
O
CHO COOH COOH CHO
H OH H OH HO H HO H O Na - Hg HO H
-H2O
HO H Br2 Pyridine pH 3 - 5 HO H
HO H HO H HO H
H OH H2O H OH H H OH
H OH
H OH H OH H OH H OH H OH
OH OH OH OH OH
D - mannose
9
29. (D)
OH
HBr Me3CO- CH2I2/Zn(Cu)

Br
Me3COH Et2O
30. (A)
d  A
  k . A  ; for first order reaction
dt
 A   A0  kt; for zero order reaction
1 1
  kt for sec ond order reaction
 At  A0
31. (A)
2KMnO4  KBr  H2 O  KBrO3  2KOH  2MnO2
32. (A, B)
O O
OH O
O
-H2O
H
(A)
OH (C)
+
(B) H
OH
O O O O
NH3 -H2O
H
(E) NH2 (D) OH
N
H
33. (A, B, C)
U  nCV T  T  0; U  0 
H  nCP T  T  0; H  0 
1st law U  q  w  0
10
 q  w
V2
w    Pext dv
V1
Pext  P2 ; w  P2 V2  V1 

 RT RT 
w  P2   
 P2 P1 
 P 
 RT 1  2 
 P1 
 P 
 q  RT 1  2 
 P1 
34. (B, D)
1 a
PC 
27 b 2
VC  3Vb
8 a
TC 
27 Rb
35. (B, C)
Kw
As for salt of strong acid and weak base degree of hydrolysis, h 
Kb .C
36. (A)
D
+ +
O O D
D-O-D
H3C C CH3 H3C C CH3 + D2O
O D O D
H3C C CH H3C CH CH2
+
H D+ H
return to keto form
+
O D O O
-D+ repeat
H3C C CH2 D H3C C CH2 D D 3C C CD3
37. (B)
As deprotonation step in case of iodination is rate determining.
11
38. (C)
o RT
Ecell  Ecell  lnQ
nF
RT  C2 
Ecell 0 ln  
nF  C1 
 1 
RT  50 
 ln  
nF  2 
 100 
 0V
39. (A)
oxidation half  cell reaction
Ag  s   Ag  aq   e 
Re duction half  cell reaction
AgCl  s   e   Ag  s   Cl  aq 
Net cell Reaction : 
AgCl  s  
 Ag  aq  Cl  aq
At equilibrium : 
RT
0
Ecell  0  E cell  n K sp
nF
and E0cell  E0Cl / AgCl/ Ag  E0 Ag / Ag
 0.57V
K sp  1010  10
 3.16  10 10
40. (A) O
O Base
PPh3 +
Ph3P
Br OEt
OEt
-
O O
CH3CHO +
Ph3P
Me OEt OEt
12
41. (D) H
OH O O
O
- - +
O O + H-B
O H H OH
B Me
C O
H
H
O O
- +
O O + H-B
-
Me O
H
O O H
+ O O
- H-B
O O
O OH
Me OH
Me OH
-H2O
-CO2
COOH
Me
SECTION – C
42. 4
d 68  32
Enantiomeric excess =  100   100  36%
d 68  32
 Optical rotation of this mixture = 36%   11.10  = 4
43. 5
Aldol condensation
44. 5
I3 , XeF4 , H2 O, NH2 , H2 S
45. 6
H O O H
B O O B
-
O B O
B O O B
O H
H O
46. 4
 1340
n  4
2r1 2  3.14  53
13
SECTION – A
x 6 12 5 5 x 3 4 4 x 3
47. f ' x   x  x   2x 2  99
6 15 20 3
f "  x   x5  4 x 4  3x 3  4x 2  4x

x x 4  4 x 3  3x 2  4x  4 
2
x  x  1 x  2   x  1
Pt of inflexion at X = -1, 0 &1
So -1+0+1 = 0
 4 17  A
48. Equation of BC is x + y = 7 so B =  , 
3 3  y = 2x + 3
Let slope of AB is m so,
m2 2 1

1  2m 1 2
1 C ( 3, 4 )
m B
7 y=x+1
So equation of AB is 3x + 21y – 123 = 0
 17 21   67 131 
So A ≡  ,  mid-point of AB =  , 
 4 4   24 24 
Equation of medium through C is 7x + y = 25
49.    
 xy 2 dx  y 2 dx  2 xydy   x 2 ydx  2 xydx  x 2dy  0
 
e xy dx  e  y dx  xd  y    e x ydx  e  2 xydx  x dy   0
x 2 x 2 2 x 2 x 2
d  e xy   d  e x y   0
x 2 x 2
e x xy 2  e x x 2 y  C
Passing through (1, 1) so C = 2e so, curve is xy  x  y   2e1 x xy ( x  y )  2e1 x
50.
10 B
10 W
1 1
2 2
15 B 10 B
10 W 15 W
10 15
15
25 10 25
25
25
11 B 15 B 6 B 10 B
10 W 6 W 15 W 11 W
Required probability,
14
1 15 10 1 10 15
    
2 25 21 2 25 21
1 15 10 1 10 6 1 10 15 1 15 11
          
2 25 21 2 25 21 2 25 21 2 25 21
2 20 4
  
2 11 11  20  4 7
1  1
5 10
3 y=x
51. Required area is times the area of loop y
2
1
y = f(x) y  f 1  x
3
2

 2  x  x 2  x  dx 
0
o 1 3 2 x
2
4
52. Let I   g  x  dx
2
Using by parts
4 4
I  x.f 1  x     f 1  x  dx
2 2
4
→ 1
1 1 1
I  4f  4   2f  2    f  x  dx
2
Now,
f 1  f  x    x
f 1  f  0    0  f 1  2   0
alsof 1  f 1   1  f 1  4   1
b f b
1
 f  x  dx     f  x  dx  bf  b   af (a)
a f a
1 4
 f  x  dx   f 1  x  dx  1.f 1  0.f 0 
0 2
1 4
 x 
3
 x  sin x  2 dx   f 1  x  dx  4
0 2
1
1
4  x 4 x 2 cos x 
also 2 f  x  dx  4      2x 
 4 2  0
53. Let x = cos

1 
x ,  
2 4

 2
cos 1 cos 2 2
As lim  lim
 1  1
4 cos   4 cos  
 
2 2
2
lim 2 2
  sin 

4
n
Coeff. X3r in 1  x  x 2  . 1  x  
n
54.
 
15

 coeff .of x 3 r in  a0  a1x  .....a2 x 2 n n
c0 
 nc 1  ..... 

n
 Cr
55.  Tangents are  r . so, they intersect on A(1,1)

directrix.
Point of intersection = (2,0) mid-point of (1,1) & (2,0)
5 3  5 3
(4,2) is  ,   , 
 2 2
 2 2
3 S
0
Slope of axis = 2 3 B
(4,2)
5
2
2
1
Equation of directrix, y    x  2 
3
x  3y  2
AB is focal chord,
462 8
BS = ( r distance from B on directrix) = 
10 10
1 3  2 2
AS = ( r distance from A on directrix) = 
10 10
8 6
So, focus divides AB in 1: 4 ratios. So S =  , 
5 5
56. By Rotation theory P (z3)

z2
 cos e i  Q (z2)
z1 
O  R (z1)
z3 cos 2 i 
 .e
z2 cos 
z2 2 cos2  3
so  
z3 z1 cos 2 2


6
57. AXE  CYE A

so, ar  AXE   ar  CYE   1 Y
E
ar  BYC   ar  BEC   1
41  ar  BEC   1
X
ar  BEC   31  ar  ABE   ar  AXB   ar  AXE  C
 so, ar  AXB   21 B
ar  ABC   2ar  BEC   61

A B C
58. , , HP
a b c
16
2b a c
  
B A C
 2bB  aC  cA
 aB  cB  aC  cA
 a B  C   c  A  B 
c
so, r 
a
A B C2
2 2
c
, , areinHP  r 2 
a b c a
59 – 60. A  (3, 2, 1), B  (4, 1, 2) point of intersection  (0, 0, 0)

1 19
Area of triangle = (3iˆ  2 jˆ  kˆ )  (4iˆ  jˆ  2kˆ ) 
2 2
 14 7 7 
Also image of (0, 0, 0) w.r.t plane  is  , , 
 3 3 3 
 14 16 2 
Image of (0, 0, 0) w.r.t AB is  , , 
 3 3 3
3 x  14 3 y  7 3z  7
Equation of line joining these two points =  
0 3 3
n 1
61 – 62. x
i 1
i  2i xi  i 2  0 
n 1 2

i 1
xi  i 2   2i x i  i 2  i 2  0
n 1 2

i 1
xi  i 2  i  0
so, xi  2i 2
Now, x12 +……+ xn2 = 280
2 12  22  ........n 2   280
n7
y1  y 2  y 3  7
y 11  y 21  y 31  4
4  3 1
C3  6C3  20
15  14  13 15
Total triangles formed = C3 
6
N of isosceles triangles formed = 15 × 7
15  7
probalality = 6
15  14  13
3
13
63 – 64. p (n) = p(n - 1) + p(n - 2)
17
SECTION – C
65. Consider y = ax 2  bx  c
Slope of BA. Slope of BC = -1
D D
4a . 4a  1
b b
x1  x  C
2a 2 2a A
D2 b2 b (x 10) (x 20)
 2
 2   x1  x2   x1x2  0 B
16a 4a 2a 
 b D 
, 
 2a 4a 
D2 b2 b b  c
 2
 2    0
16a 4a a  2a  a
 D  0or 4

sin x
66. I  dx
 1  tan2 x

2
sin x
I 2 dx
 1  cot 2 x

2

2
 4 cos x sin xdx
0
8

3
I   2
67. PA = PR = 8 – a A
So PQ = 8 – a + b 8-a
Also QD = QR = 8 – b P
So QP = 8 – b + a
aB
8–a+b=8–b+a Sa
ab
PQ  8
C bR
b Q 8-b D
68.  
det A 1  A  5I   det(A 1 ).de  A  51
 4
69. Tangent at  5,  is 5 x  3 y  9 x=1 is directrix of Hyperbola.
 3
 9 5
So, A =  1,  & B = (0, 3)
 3 

18
Area of figure OGAB is

B
9 5  1  9 5 
1     1  3   C A  
 3  2  3   5, 3 
    
9 5 5
 
3 6
H O G (3, 0 )
18  5

6
Area of required figure is
18  5  36  2 5 D F x=1
4  E
 6  3
Integral part of area is 7.
1
FIITJEE JEE(Advanced)-2018

FULL TEST – I
PAPER-2
Q. Q. Q.
PHYSICS CHEMISTRY MATHEMATICS

No. No. No.
1. C 24. C 47. C
2. A 25. B 48. B
3. C 26. C 49. B
4. C 27. D 50. D
5. A 28. C 51. A
6. D 29. B 52. C
7. B 30. A 53. D
8. B 31. D 54. D
9. ABC 32. ABC 55. BC
10. BD 33. D 56. ABCD
11. ABCD 34. ABCD 57. AC

12. ABC 35. ACD 58. AB
13. A 36. A 59. D
14. A 37. A 60. B
15. B 38. A 61. A

16. B 39. B 62. B
17. C 40. A 63. A
18. D 41. D 64. D
19. 4 42. 9 65. 1

20. 3 43. 9 66. 4
21. 4 44. 6 67. 8

22. 3 45. 7 68. 1
23. 2 46. 7 69. 7
2
Physics PART – I
SECTION – A
gt12 2h 2h
1. For the 1st ball, 4h =  t1  2 & For second ball t 2 
2 g g
2h 2d 2h
also  2 2 h  d  h d h
g g g
mA  4T  mA2
2. From F.B.D. we get
mA  2T  T  mA1
a1 T 4T
A B
mA
2T mg a2
On solving these two we get

aA = 4g
3. Zero error = +4  0.01 = +0.04 mm
Measured diameter = M.S.R. + L.C.  C.S.R.
= (50.5) mm + (0.01mm)  18 = 2.68 mm
 Actual diameter = 2.68 - (0.04) = 2.64 mm
16V0
4. When radius of curvature is minimum v is  to a & it is at t =
25g
5. Since shell is earthed its potential is zero

KQ1 K  2Q  Q1
 0 -Q
R 2R
Q
2Q
 Q1  Q A B
R
Hence 3Q will flow to the earth. 2
3 1 1
6.   (1)

2v 1 45 2R
3 1
  (2)

2v1 6R
from (1)and (2)
R  30 cm
dv
7. F.v  k  .m .v  k
dt
t m vt m  6M 6M 
0 dt  k v i vdv  2k  R  r 
6Mm  1 1 
t   
2k  R r 
3
8. F.B.D. of the ball in the frame of the container is as shown in the figure
2 mg
mg
 Distance from B = 5m
Qi2 1 2 1 2
10.  Li i  Limax
2c 2 2
Imax  2 amp
2
Qi2 1 2 Qmax
Also,  Li i 
2c 2 2c
du
11.  F  0 (For equilibrium)
dy
Particle is performing simple harmonic motion
12. dQ   4m  s  dT1    2m  2s  dT2

 KAt
On solving we get Tf  Ti e 2 msl
Temperature of point P remains constant
13. If x be the initial length of the gas chambers & A be the area of cross section of the cylinder then,
V
x  0 Also P0 A = 2kx
A
P0
 2kx  P0V0  2kx 2
x
1 2 1
 k  2x   K 4 x 2  2kx 2  P0V0
2 2
v
14. Similarly, Pf A  2k f
A
V0
P0 A  2k
A
Pf Vf P
  P  0v
P0 V0 V0
Now  Q = dU + W
5
2  PV  P0V0   w
= 2 1 1
 12P0V0
15 – 16.P= mv &
P2 1
 mV 2
2m 2
P2
E 
2m
P2
E radon 
2M
Also
4
P2 P2 mM
  E  P  2E
2m 2M mM
m  4.002mu, M  222.017mu
m  6.64  10 27 kg
1 4v 2
17 – 18. g sin . 2  2R .....  I 
2 g cos 2 
R
h
R 
R 
2
v  Rg sin  .....  2 
From (1) and (2) tan   1
SECTION – C
2.5
T 0.75  3.9m / s  4m / s
19. v 
 0.125
0.75
20.  Angular separation is directly proportional to wave length
21. 2  3
2x
3x x
A
2x 3 2 3x
4 volt
2x  4
1 p
x 
3 q
pq  4
8QE 2
22.    I       2 
mR T
 T  2
 P + n is 3
 r 2 dB
23. Now i 
R R dt
  M  B  2mgr
r 2 dB 2
.r .4  2mg.r
R dt
2 r 4
4 .8t  2mg.r
R
t  2sec
5
SECTION – A
24. CHCl 3  CCl 3  H 


CHF3  CF3  H 
 CCl 3 is more stable than CF3 due to P  d  bonding hence CHCl 3 is more acidic, not CHF3
so, (I) is incorrect.
 In chlorobenzene C  Cl bond length decreases due to resonance and hence its dipole
moment is lesser than chlorocyclohexane ii is also incorrect.
 Dipole moment of fluoromethane is lesser than chloromethane due to very small size of F. ii is
also incorrect.
 Carbon and nitrogen atom containing organic compound gives positive test for nitrogen in
lassaigne’s test
 Dipole moment of difluoromethane is more than dichloromethane .
CH 2F2 CH 2Cl 2
  1.97D 1.60D
25.
A. - B. COOH C.
COO
- HOOC
OOC
2
26. At very high concentration R. O. R = K RCHO  [OD ]2
Mech.
O -
OD O
C -
OD C or
C
H - H H
O
O-
(At very high concentration of OD-)

-
O H
O -
O H
C C O
r.d.s
- H C - + C
O
O H
-
-OD D2 O
DO
H
C H
At very high concentration =

r. o. r =
6
-
O
CHO
C
K'
H
O-
CHO CHO 2
K eqb -
= K' OD
2
CHO 2
-
= K' Keqb OD
2
CHO 2
-
= K OD
27. Ni(CO)4
Fe(CO)5 Extent of synergic bonding M - C bond strength CO bond strength
Cr(CO)6
-
V(CO) 6
Cr(CO) 6 Extent of synergic bonding M - C bond strength CO bond strength

+
Mn(CO) 6
28. It is a semi pinacol – pinacolone type reaction and product is formed after formation of
carbocation and its rearrangement by ring expansion.
+
1HNO2 -H
+
2.
+
OH NH2 OH OH
O
29. 2r  4; n  4

Total energy required + Total energy released = 0
 1 
 2  4.526ev  NA    2  13.6N A    2  13.6   1    N A   30.87  x  NA   0
  16  
x2
30. AgBr  Agaq .  Braq.
K sp   Ag   Br  

Ag   2NH3   Ag  NH3 2 
7

 Ag  NH3  2 
Kf   2
 1 108
 Ag   NH3 

Let s be the solubility of AgBr in NH3, then [Br-] = [Ag+] + [Ag(NH3)2]+ = S

Since , almost all Ag+ in solution state passes to [Ag(NH3)2]+ as Kf is very high. Thus
[Ag+]<<<[Ag(NH3)2]+
 [Br-] = [Ag(NH3)2]+ = S
 Ag (NH )  
3 2
Now Ksp = [Ag ] [Br ] = 
+ -
2
  Br  
 
K f   NH3 
Since [NH3] = 0.4 M
S S
5  1013  2
1.0  108   0.4 
S 2  8  10 6
S  2.82  103 M
31. Fe  Fe 2  2e G10  2  E10  F ............  i 

Fe 2  Fe 3  e G20  1 E20  F .............(ii)
Fe  Fe 3   3e G30  3  E30  F ...........(iii)
Subtracting equation (i) from equation (ii), we get
Fe 2  Fe 3  e
G30  G10  3E30 F  2E10 F ............(iv)
Comparing (ii) and (iv)
G20  G30  G10
E 20 F  3E30 F  2E10 F

E 30  E20  2E10 / 3 
32. Crystal is FCC
33. 2MnO4  5H 2O2  6H   2Mn 2  5O2  8H2O
34. O g   e   Og  H  ve

Og  e   Og2 H  ve
O g   2e   Og2 H  ve
O2g   O2g   e   Electron removed from  2P *
y or * 2Px 
O g   O 
g  e 
 Electron removed from 2P 
H 2g   H2g   e   Electron removed from 1s 
H g   Hg   e   Electron removed from 1s 
35. O
CH3
P1
CH3
8
O
CH3
P2
CH3
O
P3 CH3 R R CH3
Q 3 H3C S S CH3
O
P4 CH3
36. Me Me Me
O O O
Cl - -
NH2 NH2 -
-NH3
- NH2
H -Cl
-
-NH2 NH3
Me
O
NH2
37.
Cl
-
NH2
9
PV
38.  Z At very low P or P  0, Z = 1
nRT
39. PV  RT (for 1 mole of gas)
 P V  R T
 V  R R.V
or    P  RT
 T P
 V 
 
 T P 1
or   
V T
P .V  V .P  0
 V  V
  
 P T P
Also  V 
 
 P T 1
or    
V P
 P

 T
40-41. Alkaline gas C with NaOH indicates that solid should be ammonium salt. Heating the salt, a
colorless non-reacting gas D is formed. The gas D may be nitrogen . The compound may thus be
NH 4 NO2 . Reactions involved are as follows.
HCl
NH 4 NO2   NH 4Cl  HNO2
A
2HNO2  H2O  2NO  O 
2NO  2 O   2NO2 
B
BrownGas
NH 4 NO2  NaOH  NaNO2  H2O  NH3 
C
heat
NH 4 NO2 (s) 
 N2(gas)  2H2O(gas) 
A D
 N2 is a diamagnetic Gas
 Bond order of N2  3
SECTION – C
42. (A), (B), (C), (D), (E), (F), (G), (H) & (I) gives iodoform test
Br O
-
OH (aq.)
(G) H3C C CH3 H3C C CH3
Br
OH- (aq.) -
(I) H3C C OEt H3C C O + EtOH
O O
it show iodoform test
10
43. G & J have zero dipole moment

F H
Cl Cl Cl
C C C C  I I 
Cl Cl Cl
H F
A, B, C, D, E, F, H, I have nonzero dipole moment
44. Correct statements: A, C, D, G, H, I

Incorrect statements: B, E, F
45. A, B, C, D, G, H, I show mutarotation. A sugar whose IUPAC name ends with the suffix ose is a
reducing sugar and they do mutarotation
46. Monochlorination
Cl
Cl
Cl
Dichlorination
Cl Cl
Cl Cl Cl Cl
Cl
Cl Cl Cl
Cl Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
Cl
A, B, C, D, E, F, J are correct.
11
Mathematics PART – IIII
SECTION – A
1  3 1  3  32 3n  1
47. S  1   ......................  
2! 3!  3  1 n!
1 n 3 r  1 1  3r 1 

2 r 1 r!
   
2  r! r! 
1 1
n 2
 
lim  Sn    e3  1   e  1   e3  e   8.59
 2
 Sn   8
4 3 2
48. Let f  x   a  x  2   b  x  2   C  x  2   d  x  2   1
2
f  x   12  x  2   12  x  2   2
f '' 1  26
49. Let En denote the event that the score is n

En  En  2  H  En 1  T 
1
P  En   Pn 2  Pn1 
2
1 1
Pn  Pn 1  Pn 1  Pn  2
2 2
1 1
 Pn 2  Pn 3  P2  P1
2 2
1 3
As, P1  P  T    P2  P   T  T   H 
2 4
1
 Pn  Pn 1  1
2
2
2 1 2  1  2
 Pn    Pn 1       Pn  2  3 
3 2 3  2   
n 2
 1  2 1 1 2
    P1       
 2  3 2 2 3
2 1
P100  
3 3.2100
50. x  1   x  x
1 1 1
3
1  3   3
   
 1  1
x 5  3  1  x 5  3   x 2
  x 
1
 lim x5  3   0
x 0
x 
12
51. Re quired number of ways  coefficiant of x150 in

3
x 0
 x  x 2 ............x 50  x 0
 x  x 2 .......x100 
153 102
c150  3 c 99 52 c 49  3.51 c 48
 70176  40375  110551
x
 dx   dx 
52. e xy  xy 2  y 3 e
y
y  x  0
 dy   dy 
 x
 
d exy  d  e y   0
 
 
x
e xy  e y  c  0
A B  1
53. Normal through given point be the axis of

=0
parabola, y +1
x+
y – 2= - 4(x – 1) (-1, 0)
4x + y = 6
(1, 2)
 29 14 
P , 
 17 17 
(3, 1)
y-2
x+
5=
0
4y = x + 1
54. Let a, b, c are the roots of equation

a0 x 3  a1x 2  a2 x  a3  0
Then, s1  5 s2  12, s 3  25
Now, a0 s1  a1  0  a1  5a0
13
a0 s2  a1s1  2a2  0  a 2  a0
2
5
a0 s3  a1s2  a 2 s1  3a3  0  a3  a0
6
13 5
x 3  5x 2  x 0
2 6
6x 3  30x 2  39x  5  0
 6x 4  30x 3  39x 2  5x  0
257
6s4  30s3  39s2  5s1  0  s4 
6
13
5  b 5  b

55. tan   a  r ar
2
b  5
1 2 2
a r
2
Now,a2   r  4   52
 r 2  9  8r
2
b  5 9
O
r
(0, -b)T 
1 S 2
P Q (a1-5) R
(01- 5) (a + r, -5)
(a - r, -5)
x x
2 2 2
56.  g  t  dt  2  K x  2   2K tdt
0 0
x
Let f  x    2k 2 t  g  t   dt  2
0
As, 2K 2 t and g  t  are continuous

 2K 2 t  g  t   is also continuous
f  0   2, lim f  x   
x 
As f  x  changes its sign

 f  x   0 for some x  R & K  R
     

57. DA  a, DB  b, DC  c
    
 
AD.BC  a . c  b  A
 
 a.c  a.b
Q
0 P
    D
Hence, AD r BC  AB  CD G
 1     1   B

Now, PG   3a  2b  c & DQ  a  b
6 2
  
   C
Let a  b  c  K
 K  3
 PG  & DQ  K
2 2
  1    1  

 PG.DQ   3a  2b  c . a  b
6 2
  
5  5 
cos         cos 1  
6 3 6 3
14
58. f  x   x 2  7x  13
In both cases gain > loss Gain
4 4 Gain
 P   f  x  dx & Q   f  x  dx
Loss Loss
3 3
3 3.5 4
59. & 60.

As, f  x   x & cos n  1   cos n  1   2cos n  .cos 
fn 1  x   fn 1  x   2x.fn  x 
1
fn  x    fn 1  x   fn 1  x  
2x 
Now, Put x  cos ,  x 2  1  isin 
10 10
x  x2  1   x  x2  1  10 10
  cos   isin     cos   isin  
 2cos 10   2f10  cos    2f10  x 
61. & 62.

1
1 Put  2x  3  6 t
x 1 3
 2  Put t
1 x
63. & 64.

x  3 y  4 z 1
equation of line L 2 is  
1 3 1
1 equation of plane containing L1 & L 2
x  3 y 1 z  2
0 3 1  0  y  3z  5  0
1 6 2
3 4 1
1 7
 2  volume of tetrahedron  5 4 1 
6 3
7 7 0
SECTION – C
65. equation of chord whose mid  point is  t, K  t 

2
tx K  t  y t 2 K  t 
   ......  i 
8 2 8 2
 2, 1 satisfy  i

 5t 2   6  8K  t  4 K 2  K  0 
15
For two distinct chords,

D0
2
 6  8K   
 4.4.5 K 2  K  0
2
 4K  4K  9  0
1  10 1  10 
K ,   ab 1
 2 2 
b b
66. Let f  x   ax2  c f '  x   2ax 
x x2
1 2
 b 3  b 3 b 27ab2
f '  x   0, x     a    1
c  4
 2a   2a  c3
 b  3
 
 2a 
67. xyz 1
 y  z  z  x  x  y  2
Let y  z  A, z  x  B, xy C
1  x 1  y 1  z   B  C  C  A  A  B 
 1  x 1  y 1  z   8  x  y  y  z  z  x  ......  i
As,  x  y  y  z  z  x   1  x 1  y 1  z 
 1   x  y  z    xy  yz  zx   xyz
 xy  yz  2x  xyz
1 1 1 
 x  y  y  z  z  x   xyz     1
x y z 
 xyz  x 1  y 1  z 1  1
1
x 1  y 1  z 1  x  y  z 
Now,  
3  3 
  x  y  y  z  z  x   8xyz ........ ii 
 1  x 1  y 1  z   8.8xyz
 1  1  1
 1  x   1  y   1  z   64
   
22
 B   10 
68.  
adj I  2A 1      
 A   8 
 
cos3  sin3 
69.   3
9a 5b
9a 5b
  56
cos  sin 
9a 5b
1
 1
 56
  9a  3   5b  3
2 2 3
  2
 9a    5b     56 
3 3
 

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FIITJEE JEE (Main), 2018

Time Allotted: 3 Hours Maximum Marks: 360

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate

Planck constant h = 6.6 1034 J-s

Charge of electron e = 1.6  1019 C

Mass of electron me = 9.1  1031 kg

Permittivity of free space 0 = 8.85  1012 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K1 mol1

Gas Constant R = 8.314 J K1 mol1

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

1. A man moving on track ABC, getting rain drops vertical for

3. A force F acts tangentially on a part of a F

Space for rough work

5. In the figure shown ABCD is a lamina of mass 12 kg. The moment A 2m B

6. For the arrangement as shown in the figure,

7. One mole of a monoatomic gas undergoes a linear process P

Space for rough work

10. Find minimum value of F such that m 2 starts its motion on F

11. Molecule of a gas in a container hits one wall (1) normally

Space for rough work

12. A thermometer uses density of water as thermometric

Space for rough work

16. If L = 25 mH, C = 1 mF and R = 10 then R.M.S current across

Space for rough work

19. A wire carrying 10 A current is bent to pass through various y

Space for rough work

20. Above Curie temp

23. Above figure shows variation of current with anode potential I

Space for rough work

27. The figure shows the initial position of a point source L

Space for rough work

28. The figure shows a portion of a circuit. Resistor are known 9

29. A liquid of density  has to spray with help of aspirator pump at A B

Space for rough work

31. For the following elementary first order reaction:

33. Which of the following is bio-degradable polymer?

Space for rough work

Order of basic nature is A > B > C.

Space for rough work

41. Zn  conc. HNO3  Zn NO3 2  X  H2 O

45. Acetylene on passing through excess of HOCl solution forms

Space for rough work

51. Correct order of pKa values of

I, II, III , IV is:

Space for rough work

54. In the reaction

56. Cu2  aq   K 4 Fe  CN6   aq  

57. In which of the following set of orbitals, nodal plane is absent?

Space for rough work

58. Which of the following is enantiomer of OH

Space for rough work

Mathematics PART – III

62. Differential co-efficient of log10 x w.r.t logx 10 is

Space for rough work