Environment
Environment
Environment
Clean coal technologies (CCTs) have an important role to play over the coming decades to
minimise the environmental impact of the substantial coal use that is forecast. This briefing
paper focuses primarily on the technologies to reduce sulphur dioxide (SO2), oxides of
nitrogen (NOx) and carbon dioxide (CO2).
CCT projects have demonstrated technologies in four key areas: environmental control
technologies applicable to conventional plants, advanced power generation, coal processing
and industrial applications.
FBC reduces emissions of SO2 and NOx by the controlled combustion of crushed coal in a bed
fluidised with jets of air. Sulphur released from the coal as SO2 is captured by a sorbent (e.g.
limestone) injected into the combustion chamber along with the coal. Around 90% of the
sulphur can be removed as a solid compound with the ash. FBCs operate at a much lower
temperature than conventional pulverised coal boilers, greatly reducing the amount of thermal
NOx formed. The relatively simple FBC is particularly suited to poorer quality fuels and is
widely used in developing countries.
IGCC systems involve gasification of coal, cleaning the gas produced, and combusting it in a
gas turbine generator to produce electricity. Residual heat in the exhaust gas from the gas
turbine is recovered in a heat recovery boiler as steam, which can be used to produce
additional electricity in a steam turbine generator. IGCC systems are among the cleanest and
most efficient of the emerging clean coal technologies: sulphur, nitrogen compounds, and
particulates are removed before the gas is burned in the gas turbine and thermal efficiencies of
over 50% are likely in the future.
In the gasifier, sulphur from the coal forms hydrogen sulphide (H2S) which is readily
removed by commercially available processes. Sulphur removal can exceed 99.9% and
by-products are saleable sulphur or sulphuric acid. High levels of nitrogen removal are also
possible. Some of the coal’s nitrogen is converted to ammonia (NH3) which can be almost
totally removed by established chemical processes, thus limiting the formation of fuel-NOx.
Thermal-NOx formation in the gas turbine is limited by staged combustion or by adding
moisture or nitrogen to control flame temperature.
Industrial applications
This category includes iron-making, with coal replacing a proportion of the more expensive
coke traditionally used in blast furnaces. It also includes processes to remove SO2 and other
pollutants from the flue gases produced during cement manufacture.
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