DOC024.52.93016 EC-sensors 11ed

DOC024.52.
93016
ORBISPHERE Model 31xxx

Electrochemical Sensors
USER MANUAL
10/2018, Edition 11
Table of Contents
Section 1 General Information ......................................................................................................... 3

1.1 Disclaimer .................................................................................................................................... 3
1.2 Safety information ........................................................................................................................ 3
1.2.1 Use of hazard information ................................................................................................... 3
1.2.2 Service and repairs ............................................................................................................. 3
1.2.3 Precautionary labels............................................................................................................ 4
1.3 Product recycling information....................................................................................................... 5
Section 2 Technical Specifications ................................................................................................. 7
2.1 Sensor design .............................................................................................................................. 7
2.2 Sensor weight and dimensions .................................................................................................... 7
2.3 EC sensors and parts used on ORBISPHERE configured systems ............................................ 8
2.4 Sensor membrane specifications ................................................................................................. 8
2.4.1 Hydrogen sensors ............................................................................................................... 8
2.4.2 Oxygen sensors (Table 1)................................................................................................... 9
2.4.3 Oxygen sensors (Table 2)................................................................................................. 10
2.4.4 Ozone sensors .................................................................................................................. 11
Section 3 Introduction ..................................................................................................................... 13
3.1 What you have received ............................................................................................................ 13
3.1.1 An oxygen, ozone, or hydrogen electrochemical sensor .................................................. 13
3.1.2 A sensor maintenance kit.................................................................................................. 13
3.2 Basic principle of operation ........................................................................................................ 13
Section 4 Installation ........................................................................................................................ 17
4.1 Initial sensor cell cleaning .......................................................................................................... 17
4.2 Positioning information............................................................................................................... 17
4.3 Sensor insertion ......................................................................................................................... 18
4.4 Sensor removal .......................................................................................................................... 18
4.5 Mounting accessories ................................................................................................................ 18
4.5.1 External pressure sensor .................................................................................................. 18
4.5.2 Weld-on stainless steel socket.......................................................................................... 19
4.5.3 Insertion/extraction valve .................................................................................................. 20
4.5.4 ORBISPHERE flow chambers .......................................................................................... 20
4.5.5 Multi parameter flow chamber........................................................................................... 22
Section 5 Maintenance..................................................................................................................... 23
5.1 Disassembly and assembly ....................................................................................................... 23
5.1.1 Taking the sensor apart (membrane removal) .................................................................. 23
5.1.2 Sensor assembly (membrane installation) ........................................................................ 24
5.2 Electrochemical cleaning and regeneration center .................................................................... 27
5.3 Chemical cleaning: oxygen and ozone sensor cell .................................................................... 28
5.3.1 Membrane support cleaning.............................................................................................. 28
5.3.2 Electrodes ammonia cleaning ........................................................................................... 29
5.3.3 Anode and cathode nitric acid cleaning ............................................................................ 29
5.3.4 Sensor face polishing........................................................................................................ 30
5.3.5 O3 Sensor only: final center electrode cleaning ................................................................ 31
5.4 Hydrogen sensor cell cleaning ................................................................................................... 31
Section 6 Troubleshooting.............................................................................................................. 33
6.1 Oxygen sensor ........................................................................................................................... 33
6.2 Hydrogen sensor........................................................................................................................ 33
6.3 Ozone sensor............................................................................................................................. 34
Section 7 ............................................................................................................................................ 35
7.1 Sensor parts............................................................................................................................... 35
7.2 Accessories................................................................................................................................ 35
7.3 Flow chambers and installation devices .................................................................................... 35
7.4 Protection caps and related part kits.......................................................................................... 37
1
Table of Contents
7.5 Maintenance kits for EC sensors................................................................................................38

7.5.1 Kits for O2 sensors ............................................................................................................38
7.5.2 Kits for O3 sensors ............................................................................................................39
7.5.3 Kits for H2 sensors ............................................................................................................39
2
Section 1 General Information
1.1 Disclaimer
The information in this manual has been carefully checked and is believed to be accurate.
However, Hach Lange assumes no responsibility for any inaccuracies that may be contained in
this manual. In no event will Hach Lange be liable for direct, indirect, special, incidental, or
consequential damages resulting from any defect or omission in this manual, even if advised of
the possibility of such damages. In the interest of continued product development, Hach Lange
reserves the right to make improvements in this manual and the products it describes at any
time, without notice or obligation.
1.2 Safety information

Please read the entire manual before unpacking, setting up, or operating this sensor.
Pay particular attention to all warning and caution statements. Failure to do so could result in
serious injury to the operator or damage to the equipment.
To the ensure the protection provided by this equipment is not impaired, do not use or install
this equipment in any manner other than that which is specified in this manual.
1.2.1 Use of hazard information
WARNING
A warning is used to indicate a condition which, if not met, could cause serious personal injury
and/or death. Do not move beyond a warning until all conditions have been met.
CAUTION
A caution is used to indicate a condition which, if not met, could cause minor or
moderate personal injury and/or damage to the equipment. Do not move beyond a
caution until all conditions have been met.
Note: A note is used to indicate important information or instructions that should be considered
before operating the equipment.
1.2.2 Service and repairs

None of the sensor’s components can be repaired by the user. Only personnel from Hach
Lange or its approved representative(s) is (are) authorized to attempt repairs to the sensor and
only components formally approved by the manufacturer should be used.
Any attempt at repairing the sensor in contravention of these principles could cause damage to
the sensor and corporal injury to the person carrying out the repair. It renders the warranty null
and void and could compromise the correct working of the sensor and the electrical integrity or
the CE compliance of the sensor.
If you have any problems with installation, or using the sensor please contact the company that
sold it to you. If this is not possible, or if the results of this approach are not satisfactory, please
contact the Customer Service department of Hach Lange.
3
General Information
1.2.3 Precautionary labels

Read all labels and tags attached to the sensor. Personal injury or damage to the sensor could
occur if not observed.
This symbol, if noted on the product, indicates the need for protective eye wear.
This symbol indicates the need for protective hand wear.
Electrical equipment marked with this symbol may not be disposed of in European public
disposal systems. In conformity with European local and national regulations, European
electrical equipment users must now return old or end-of-life equipment to the manufacturer
for disposal at no charge to the user.
Products marked with this symbol indicates that the product contains toxic or hazardous
substances or elements. The number inside the symbol indicates the environmental
protection use period in years.
4
General Information
1.3 Product recycling information
ENGLISH
Electrical equipment marked with this symbol may not be disposed of in
European public disposal systems after 12 August 2005. In conformity with
European local and national regulations (EU Directive 2002/96/EC), European
electrical equipment users must now return old or end-of-life equipment to the
manufacturer for disposal at no charge to the user.
Note: For return for recycling, please contact the equipment
manufacturer or supplier for instructions on how to return end-of-life
equipment for proper disposal.
DEUTSCH
Elektrogeräte, die mit diesem Symbol gekennzeichnet sind, dürfen in Europa nach dem 12.
August 2005 nicht mehr über die öffentliche Abfallentsorgung entsorgt werden. In
Übereinstimmung mit lokalen und nationalen europäischen Bestimmungen (EU-Richtlinie
2002/96/EC), müssen Benutzer von Elektrogeräten in Europa ab diesem Zeitpunkt alte bzw. zu
verschrottende Geräte zur Entsorgung kostenfrei an den Hersteller zurückgeben.
Hinweis: Bitte wenden Sie sich an den Hersteller bzw. an den Händler, von dem Sie das Gerät
bezogen haben, um Informationen zur Rückgabe des Altgeräts zur ordnungsgemäßen
Entsorgung zu erhalten.
FRANCAIS
A partir du 12 août 2005, il est interdit de mettre au rebut le matériel électrique marqué de ce
symbole par les voies habituelles de déchetterie publique. Conformément à la réglementation
européenne (directive UE 2002/96/EC), les utilisateurs de matériel électrique en Europe doivent
désormais retourner le matériel usé ou périmé au fabricant pour élimination, sans frais pour
l'utilisateur.
Remarque: Veuillez vous adresser au fabricant ou au fournisseur du matériel pour les
instructions de retour du matériel usé ou périmé aux fins d'élimination conforme.
ITALIANO
Le apparecchiature elettriche con apposto questo simbolo non possono essere smaltite nelle
discariche pubbliche europee successivamente al 12 agosto 2005. In conformità alle normative
europee locali e nazionali (Direttiva UE 2002/96/EC), gli utilizzatori europei di apparecchiature
elettriche devono restituire al produttore le apparecchiature vecchie o a fine vita per lo
smaltimento senza alcun costo a carico dell’utilizzatore.
Nota: Per conoscere le modalità di restituzione delle apparecchiature a fine vita da riciclare,
contattare il produttore o il fornitore dell’apparecchiatura per un corretto smaltimento.
DANSK
Elektriske apparater, der er mærket med dette symbol, må ikke bortskaffes i europæiske offentlige
affaldssystemer efter den 12. august 2005. I henhold til europæiske lokale og nationale regler
(EU-direktiv 2002/96/EF) skal europæiske brugere af elektriske apparater nu returnere gamle eller
udtjente apparater til producenten med henblik på bortskaffelse uden omkostninger for brugeren.
Bemærk: I forbindelse med returnering til genbrug skal du kontakte producenten eller
leverandøren af apparatet for at få instruktioner om, hvordan udtjente apparater bortskaffes
korrekt.
5
General Information
SVENSKA
Elektronikutrustning som är märkt med denna symbol kanske inte kan lämnas in på europeiska
offentliga sopstationer efter 2005-08-12. Enligt europeiska lokala och nationella föreskrifter
(EU-direktiv 2002/96/EC) måste användare av elektronikutrustning i Europa nu återlämna gammal
eller utrangerad utrustning till tillverkaren för kassering utan kostnad för användaren.
Obs! Om du ska återlämna utrustning för återvinning ska du kontakta tillverkaren av utrustningen
eller återförsäljaren för att få anvisningar om hur du återlämnar kasserad utrustning för att den ska
bortskaffas på rätt sätt.
ESPANOL
A partir del 12 de agosto de 2005, los equipos eléctricos que lleven este símbolo no deberán ser
desechados en los puntos limpios europeos. De conformidad con las normativas europeas
locales y nacionales (Directiva de la UE 2002/96/EC), a partir de esa fecha, los usuarios
europeos de equipos eléctricos deberán devolver los equipos usados u obsoletos al fabricante de
los mismos para su reciclado, sin coste alguno para el usuario.
Nota: Sírvase ponerse en contacto con el fabricante o proveedor de los equipos para solicitar
instrucciones sobre cómo devolver los equipos obsoletos para su correcto reciclado.
NEDERLANDS
Elektrische apparatuur die is voorzien van dit symbool mag na 12 augustus 2005 niet meer
worden afgevoerd naar Europese openbare afvalsystemen. Conform Europese lokale en
nationale wetgegeving (EU-richtlijn 2002/96/EC) dienen gebruikers van elektrische apparaten
voortaan hun oude of afgedankte apparatuur kosteloos voor recycling of vernietiging naar de
producent terug te brengen.
Nota: Als u apparatuur voor recycling terugbrengt, moet u contact opnemen met de producent of
leverancier voor instructies voor het terugbrengen van de afgedankte apparatuur voor een juiste
verwerking.
POLSKI
Sprzęt elektryczny oznaczony takim symbolem nie może być likwidowany w europejskich
systemach utylizacji po dniu 12 sierpnia 2005. Zgodnie z europejskimi, lokalnymi i państwowymi
przepisami prawa (Dyrektywa Unii Europejskiej 2002/96/EC), użytkownicy sprzętu elektrycznego
w Europie muszą obecie przekazywać Producentowi stary sprzęt lub sprzęt po okresie
użytkowania do bezpłatnej utylizacji.
Uwaga: Aby przekazać sprzęt do recyklingu, należy zwrócić się do producenta lub dostawcy
sprzętu w celu uzyskania instrukcji dotyczących procedur przekazywania do utylizacji sprzętu po
okresie użytkownia.
PORTUGUES
Qualquer equipamento eléctrico que ostente este símbolo não poderá ser eliminado através dos
sistemas públicos europeus de tratamento de resíduos sólidos a partir de 12 de Agosto de 2005.
De acordo com as normas locais e europeias (Directiva Europeia 2002/96/EC), os utilizadores
europeus de equipamentos eléctricos deverão agora devolver os seus equipamentos velhos ou
em fim de vida ao produtor para o respectivo tratamento sem quaisquer custos para o utilizador.
Nota: No que toca à devolução para reciclagem, por favor, contacte o produtor ou fornecedor do
equipamento para instruções de devolução de equipamento em fim de vida para a sua correcta
eliminação.
6
Section 2 Technical Specifications
Specifications are subject to change without notice.
2.1 Sensor design

Table 1 Sensor design
Max. Press Sensor
Gas Comments
Rating (bar) Models
20 31 11x.yz Where :
50 31 12x.yz x = Sensor special characteristics
O2 (0 or 1; depending on application)
100 31 13x.yz
y = Membrane O-ring material
200 31 14x.yz
(0 = EDPM / 1 = Viton / 2 = Kalrez / 4 = Nitril)
20 31 31x.yz
O3 z = Head material
100 31 33x.yz (1=Stainless Steel / 2=Peek / 4=Hastelloy / 5=Titanium / 7=
50 31 21x.yz Monel)
100 31 23x.yz
Suffixes (when used) :
H2
A denotes a sensor with fast response to temp. change
200 31 24x.yz E denotes an EEx certified sensor (Ex-Proof)
s denotes a Smart sensor
• All ORBISPHERE electrochemical sensors’ enclosures are certified IP68 / NEMA4

• PEEK (Polyetheretherketone) is a highly crystalline thermoplastic
2.2 Sensor weight and dimensions

Sensor weight is from 140 to 700 grams, depending on the construction material.
Figure 1 Sensor dimensions
7
Technical Specifications
2.3 EC sensors and parts used on ORBISPHERE configured systems
Table 2 ORBISPHERE configured systems

Protection Protection Maintenance
Configured System Sensor Membrane
Cap Cap Kit Kit
3625 Package 29111 (as used 28002 Tefzel
31 110.02 2956A 32703
analyzer on TC sensors) washers only
3624 ProBrix 31 110.02 2952A 29104.0 29054 32702
2956A plus one
32703 plus
Goretex®
29981 Pharmapack 31 110A.02 None Not applicable 32918
membrane ref.
(10 piece box)
32918
2.4 Sensor membrane specifications

2.4.1 Hydrogen sensors
Table 3 Membrane specifications - Hydrogen sensors

Membrane Model 2956A 2952A 2995A 29015A
Recommended Trace Low Average High
applications measurement concentration concentration concentration
Material PFA Tefzel® Tedlar® Saran
Thickness [µm] 25 25 12.5 23
Calibration gas 1% pure H2 10% pure H2 100% pure H2 100% pure H2
Dissolved measurement 0 ppb to 0 ppb to 0 ppb to 0 ppb to
range 75 ppb 300 ppb 3200 ppb 32 ppm
Gaseous measurement 0 Pa to 0 Pa to 0 Pa to 0 kPa to
range 5 kPa 20 kPa 200 kPa 2000 kPa
The greater of ±1% The greater of ±1% The greater of ±1% The greater of ±1%
of reading of reading of reading of reading
Accuracy
or ± 0.03 ppb, or ± 0.09 ppb, or ± 1 ppb, or ± 10 ppb,
or ± 1 Pa or ± 6 Pa or ± 50 Pa or ± 1 kPa
Integrated radiation dose
2 x 104 108 108 N/A
limit
Expected current in air @
N/A
1 bar 25°C [µA]
Expected current in pure
150 50 5 0.5
gas [µA]
Temp. compensation
0 to 50°C 0 to 50°C 10 to 45°C 10 to 45 °C
range
Temp. measuring range –5 to 100° C
Response time1 2 sec. 5 sec. 6 sec. 50 sec.
Recommended min. liquid
50 to 220 40 to 200 20 to 70 20 to 40
flow rate2 [mL/min]
Recommended min. linear
200 150 50 30
flow rate2 [cm/sec]
Recommended gaseous
0.005 to 3
flow rate [L/min]
8
2.4.2 Oxygen sensors (Table 1)
Table 4 Membrane specifications - Oxygen sensors (1)

Membrane Model 2956A 2958A 29552A 2952A
In line wort, Corrosion control,
Recommended Corrosion control, Beverage,
Air/O2 injection, In line beverage,
applications De-aerated water Lab. applications
Sewage treatment De-aerated water
Material PFA Tefzel® PTFE Tefzel®
Thickness [µm] 25 12.5 50 25
Calibration gas Air Air Air Air / Pure O2
Dissolved measurement 0 ppb to 0 ppb to 0 ppb to 0 ppb to
range 20 ppm 40 ppm 80 ppm 80 ppm
Gaseous measurement 0 Pa to 0 Pa to 0 Pa to 0 Pa to
range 50 kPa 100 kPa 200 kPa 200 kPa
The greater of ±1%
The greater of ±1% The greater of ±1% The greater of ±1%
of reading
of reading of reading of reading
or ± 0.1 ppb1,
or ± 1 ppb, or ± 2 ppb, or ± 2 ppb,
Accuracy or ± 1 ppb2,
or ± 2 Pa or ± 5 Pa or ± 5 Pa
or ± 0.25 Pa
1 Accuracy is ± 0.1 ppb for 410, 510, 362x, 360x and 3655 instruments
2 Accuracy is ± 1 ppb for 366x and 3650 instruments
2 x 104 108 N/A 108
limit [rads]
26.4 9.4 6.3 5.4
1 bar 25°C [µA]
132 47 31.4 27
O2 [µA]
O2 consumption in O2
saturated water at 25°C 40 14 9.4 8
[µg/hour]
Temp. compensation
– 5 to 60° C
range
Temp. measuring range – 5 to 100° C
Response time1 7.2 sec. 9.5 sec. 90 sec. 38 sec.
180 120 50 50
flow rate2 [mL/min]
200 100 30 30
flow rate2 [cm/sec]
Recommended gaseous
0.1 to 3
flow rate [L/min]
9
2.4.3 Oxygen sensors (Table 2)
Table 5 Membrane specifications - Oxygen sensors (2)

Membrane Model 2935A 29521A 2995A
Recommended Saturated to super Saturated to super In line hot wort
applications saturated levels saturated levels (up to 70°C)
Material Halar® Tefzel® Tedlar®
Thickness [µm] 25 125 12.5
Calibration gas Air / Pure O2 Air / Pure O2 Pure O2
Dissolved measurement 0 ppb to 0 ppb to
0 ppb to 2000 ppm
range 400 ppm 400 ppm
Gaseous measurement 0 Pa to 0 Pa to
0 Pa to 5000 kPa
range 1000 kPa 1000 kPa
The greater of ±1% The greater of ±1% The greater of ±1%
of reading of reading of reading
Accuracy
or ± 10 ppb, or ± 10 ppb, or ± 50 ppb,
or ± 20 Pa or ± 20 Pa or ± 100 Pa
N/A 108 108
limit [rads]
0.9 0.7 0.2
1 bar 25°C [µA]
4.7 3.8 0.9
O2 [µA]
O2 consumption in O2
saturated water at 25°C 1.4 1.3 0.3
[µg/hour]
Temp. compensation
– 5 to 60° C
range
Temp. measuring range – 5 to 100° C
Response time1 2.5 min. 18 min. 80 sec.
25 25 5
flow rate2 [mL/min]
20 60 5
flow rate2 [cm/sec]
Recommended gaseous
0.1 to 3
flow rate [L/min]
10
2.4.4 Ozone sensors
Table 6 Membrane specifications - Ozone sensors

Membrane Model 2956A 29552A
Recommended Trace High concentration
applications measurement (> 1 mg/l)
Material PFA PTFE
Thickness [µm] 25 50
Span gas
Calibration gas
or air
Dissolved measurement 0 ppb to 0 ppb to
range 50 ppm 200 ppm
Gaseous measurement 0 Pa to 0 Pa to
range 10 kPa 40 kPa
The greater of ±1% The greater of ±1%
of reading of reading
(± 5% for sensors (± 5% for sensors
Accuracy
calibrated in air) calibrated in air)
or ± 5 ppb, or ± 20 ppb,
or ±1 Pa or ± 4 Pa
2 x 104 N/A
limit
26.4 6.5
1 bar 25°C [µA]
105 31.4
gas [µA]
Temp. compensation
–5 to 45° C
range
Temp. measuring range –5 to 100° C
Response time1 30 sec. 6 min.
3503 1003
flow rate2 [mL/min]
30 10
flow rate2 [cm/sec]
Recommended gaseous
0.01 to 3
flow rate [L/min]
1 Response time at 25 °C for a 90% signal change
2 Liquid flow through an ORBISPHERE 32001 flow chamber, with
protection cap and no grille
3 These flow rates take into account the decomposition of ozone in
the tubing between the line and the flow chamber (theoretical flow
rates in the absence of decomposition would be 10 times less)
11
12
Section 3 Introduction
3.1 What you have received

Check that all mounting hardware is included. Note that, unless the sensor is part of
ORBISPHERE equipment that includes it, the sensor must be installed in an ORBISPHERE
socket or flow chamber that allows contact with the sample flow to be analyzed (refer to
Installation on page 17 for details).
3.1.1 An oxygen, ozone, or hydrogen electrochemical sensor

The sensor head is protected by a screw-on plastic storage cap. A plastic screw-on base
protects the connection socket, and provides at the same time a suitable stand.
Figure 2 Electrochemical sensor components
3.1.2 A sensor maintenance kit

The kit includes the material needed to maintain the sensor, including consumables, hardware,
membrane removal and installation tools, plus a polishing device.
3.2 Basic principle of operation

In its simplest form, an electrochemical cell consists of a metal anode and a metal cathode
dipped into an electrolyte solution contacting these electrodes. An electronic circuit is linked to
the anode and cathode. Through an applied voltage, current will flow between the anode and
the cathode.
Figure 3 Sensor cell components
13
Introduction
The sensor is designed with one center electrode (cathode) and one counter electrode (anode)
immersed in an electrolytic solution. The electrodes and the electrolyte are separated from the
gaseous or liquid sample by a membrane permeable to gas.
Note: Anode and cathode positions are inverted on the H2 sensor
Additionally, the sensor's design includes a guard ring electrode which surrounds the sensor's
center electrode. Its role is to reduce the influence of other gases on the center electrode,
improving analysis stability.
The sensor head is covered with a protection cap and, in some applications, a grille to protect
the membrane. Materials used for the components of the sensors differ with the application.
Gas penetrating through the membrane into the cell dissolves in the electrolyte. It undergoes a
reaction at the cathode, causing a measurable electric current to flow. This current is
proportional to the amount of gas entering the cell. The amount of gas entering the cell is
proportional to the partial pressure of this gas in the sample, outside the cell.
The result is shown as gas concentration, which can then be displayed with a choice of several
measuring units, according to instrument setup.
The sensor electronics perform four functions:
• Apply constant voltage to the anode
• Measure the current flowing through the sensor
• Compensate for temperature variation in the gaseous or liquid sample
• Convert the cell’s electric current into an analog signal for sensor output
Electrochemical sensor assembly Protection cap and cable removed
Sensor cell, with membrane and electrolyte Membrane and its support removed
Figure 4 Electrochemical sensor overview
14
Introduction
Figure 5 Electrochemical sensors
15
Introduction
16
Section 4 Installation
4.1 Initial sensor cell cleaning

Your ORBISPHERE electrochemical sensor has been thoroughly cleaned and tested at the
factory. To protect the electrodes from oxidation, the cell has been filled with electrolyte and a
membrane has been installed.
However, shipping and storage conditions can adversely affect electrochemical sensor cells,
therefore a sensor service (cell cleaning & membrane replacement) must be performed before
using the sensor.
To perform a sensor service, see the instructions in the section entitled Maintenance on
page 23. If you are not familiar with sensor servicing, your Hach Lange representative will be
glad to assist you.
Note: Electrochemical H2 sensors do not require a complete cleaning procedure, as dechloridization and
rechloridization processes are normally not required.
4.2 Positioning information

Unless the sensor is part of the ORBISPHERE equipment that includes it, the sensor must be
installed in an ORBISPHERE socket or flow chamber, that allows the contact with the sample
fluid to be analyzed.
The sensor and measuring instrument are connected by a cable and two 10 pin connectors.
The standard sensor cable length is 3 meters, but extension cables of up to 1'000 m. are
available, still retaining the same signal sensitivity. (If the model 28117 pressure sensor is
used, the maximum cable length is 50 m.)
Check that the sensor will be mounted:
• perpendicular to the pipe.
• horizontal.
• on a horizontal pipe section (or on flow-ascending vertical pipe).
• min. 15 meters away from pump's discharge side.
• in a place where sample flow is stable and rapid; as far as possible from:
• valves
• pipe bends
• suction side of pumps
• CO2 injection system or similar
Note: There may be situations where not all the above conditions can be met. Please consult your Hach
Lange representative to appraise the situation and define the best applicable solution.
17
Installation
4.3 Sensor insertion

• Insert the sensor straight into the flow chamber or socket.
• Hand tighten the attaching collar.
• Connect the sensor cable.
• Check for leaks; replace O-rings if product leaks are visible.
Micro volume flow chambers:

Do not twist the sensor when inserting it into a micro volume flow chamber. This rotation may
twist the membrane holding ring, thus changing the membrane position. This can modify the
membrane measuring conditions, and affect measurement precision.
Figure 6 Sensor insertion
Note: Check that the small O-ring at the bottom of the flow chamber is present during removal and
installation of the sensor, as it may stick to the sensor head and fall.
4.4 Sensor removal

• Shut off the sample flow and drain the sampling circuit of liquid or gas.
• Remove the sensor cable connected at the sensor end.
• Hold the sensor body in one hand to avoid rotation and unscrew the collar with the other.
• Pull the sensor straight out of the socket or flow chamber.
• Check that both O-rings remain in place inside the flow chambers.
• Install sensor storage cap and sensor base (to protect the connection).
4.5 Mounting accessories

Note: Check the spare part list at the end of this manual for ordering information.
4.5.1 External pressure sensor

The system can be fitted with an external pressure sensor. This enables a measurement of
fraction of gas under variable pressure conditions during gas phase measurement.
Two models are available, depending on the application:

• 28117 Pressure sensor 0 - 5 bar absolute
• 28117C Pressure sensor 0 - 1 bar absolute
18
Installation
CAUTION
Do NOT exceed the pressure range of the sensor. This would permanently deform the
sensor membrane, thus delivering incorrect pressure values in the future.
The external sensor connects to the ORBISPHERE measuring equipment with a 1 meter
cable and a 4 pin connector (an optional extension cable can be used, but total length should
not exceed 50 m.).
The external pressure sensor can be installed in the 32002.xxx multi parameter flow chamber.
It is held in place by a blue threaded collar. Tightness is assured by the O-ring on the sensor
seat.
4.5.2 Weld-on stainless steel socket

The 29501 weld-on sensor socket can be used to install a sensor into a stainless steel pipe
(min.Ø 50 mm or 2”). When welding the socket to the pipe, check that setback between the
pipe’s inner diameter and the sensor tip does not exceed 4 mm (see diagram).
Figure 7 Weld-on sensor socket
Note: Be sure to remove the two O-rings from the socket before welding. Leave the sensor’s stainless
steel cap screwed on during welding to prevent thread distortion.
Recommendation:
To facilitate sensor removal and installation, we suggest installing the socket in a location
where the liquid can be drained quickly and easily. By creating a one meter long piece of pipe
with shut off valves at both ends, just a small volume of liquid needs to be drained to enable
sensor removal. Refer to Figure 8.
Also, a precise sensor and socket installation can be performed in the workshop, and this
assembly can be placed in the production line with minimal down time.
Figure 8 Installation in-line
19
Installation
4.5.3 Insertion/extraction valve

The ORBISPHERE 32003 insertion/extraction valve allows for sensor removal and installation
without having to drain the fluid in the line. It can withstand a pressure of up to 20 bars, with the
sensor in place or not. This device is held in place by a stainless steel clamp to a Tuchenhagen
Varivent® In-Line Access Unit.
Sensor insertion is done by aligning the sensor with the valve and tightening the retaining collar
until it stops. Removal is done by unscrewing the collar and pulling the sensor out.
Tuchenhagen Varivent® In-Line Access Unit

Purchasing a Tuchenhagen Varivent® In-Line Access
Unit, or an equivalent fitting with a 68mm flange
diameter from the fitting manufacturer is required to
make use of the 32003 ProAcc Valve.
Figure 9 Insertion/extraction valve
4.5.4 ORBISPHERE flow chambers

The ORBISPHERE 32001. xxx flow chambers are used to draw liquid and gaseous samples
past the sensor. They are available in several materials, depending on the application.
They connect to 6-mm or ¼" stainless steel tubing by means of two Swagelok™ fittings. If
necessary, copper or plastic tubing with low permeability can be substituted. Stainless steel
tubing is normally enough to hold the assembly in place, but for a more stable installation, a
large U-bolt can be used to mount the flow chamber to a support.
Dimensions of sensor and flow chamber assembly :

• Width: 50 mm
• Height: 210 mm
(add 100 mm for connection length)
20
Installation
Table 7 Flow chamber orientation

Sample Orientation of flow chamber
Vertically, with connections down and

sensor up
Gaseous or
liquid media • Center connection is the inlet
• Outer connection is the outlet
Horizontally, to allow for drainage

Gaseous media,
• Center connection (inlet) must be up
with occasional
liquid or vapor • Outer connection (outlet) must be
down
The connection diagram below is a recommended installation that allows for measuring and
calibrating without having to disconnect a line manually. "A" and "B" represent 3-way valves.
For measuring, calibration gas inlets and outlets are shut off. During calibration, the flow is
reversed to drive the remaining sample out. The calibration gas enters at the "sample out" port
and exits at the "sample in" port, as shown.
Figure 10 Flow chamber connections
21
Installation
4.5.5 Multi parameter flow chamber

Note: Suitable only for gaseous media.
The ORBISPHERE 32002.xxx multi parameter flow chamber can accommodate one or two
sensors and one sample pressure sensor. If only one gas sensor is used, the unused socket is
plugged with the stainless steel plugs provided (model 28123). The flow chamber is connected
to 6 mm or ¼" stainless steel tubing by two Swagelok™ fittings. If necessary, copper or plastic
tubing with a very low permeability can be substituted.
The flow chamber should be mounted in such a way that the sample outlet port is located at
the lowest point to allow condensation to escape with the outgoing gas. Attach the flow
chamber to a vertical support with the screws supplied. The pressure sensor must be on top.
Note: A user manufactured spacer (~15 mm thick) may be used between the flow chamber and support
for improved access for sensor removal.
Figure 11 32002.xxx multi parameter flow chamber
Shown here with:

• gas sensor (right),
• pressure sensor (center),
• optional second sensor (left)
22
Section 5 Maintenance
5.1 Disassembly and assembly

5.1.1 Taking the sensor apart (membrane removal)
It is important to install the electrochemical sensor standing

on its base. This base offers good protection for the delicate
connector socket, at the same time providing a suitable work
stand.
Remove the plastic storage cap.

Unscrew the protection cap, using the tool provided in the
maintenance kit.
Pay attention to the components inside the protection cap.

Note the assembly order of each item (see protection cap
application tables in Protection caps and related part kits on
page 37).
Note: The illustration on the right is an example only. Your
configuration may differ.
Pull up the attaching ring with the tool provided in the

maintenance kit.
Remove the membrane and mask (if applicable).
Drain the electrolyte into a sink and rinse the sensor cavity
with tap water.
CAUTION
Avoid eye or skin contact with electrolyte which can be
slightly corrosive.
Insert the prongs of the

membrane support removal
tool into the membrane
support holes, and unscrew
the membrane support.
23
Maintenance
Note: The membrane support is individually machined and paired

with the sensor. For correct sensor operation, it is ESSENTIAL to
keep a membrane support with its respective sensor. Should the
membrane support require replacement, contact your Hach Lange
representative.
5.1.2 Sensor assembly (membrane installation)

Before starting the sensor reassembly, proceed to the sensor maintenance section for anode
and cathode cleaning instructions.
Install the membrane support with the groove on the upper

side.
Note: The membrane support is individually machined and paired
with the sensor. Therefore make sure that the correct membrane
support is used on the correct sensor.

support holes.
Tighten the membrane
support finger tight.
CAUTION
Too much torque will damage the sensor electrodes.
The membrane mounting surface must be clean and even.

Replace the membrane O-ring on the sensor head with a
new one.
Note: The 29039.4 Nitril O-ring can be reused if it is still in good
condition. Membrane O-rings are part of the protection cap kit.
24
Maintenance
For the correct electrolyte selection, please refer to the table

in Sensor parts on page 35.
Using the syringe or bottle nozzle included in the
maintenance kit, fill up the sensor cavity with electrolyte.
Note: Be careful not to touch the electrodes with the needle, as a
scratch on the surface may lead to loss of performance.
Tilt the sensor slightly and inject into the lower hole, pushing
bubbles out at the upper hole. Gently tap on the sensor side
to move trapped bubbles.
Return the sensor to the vertical position. The last drop of
electrolyte should form a cupola on top of the sensor tip.
In the maintenance kit, pick up the two part membrane

mounting tool.
Install the sleeve over the sensor head (end with shoulder
downwards).
Note: Once installed, a membrane cannot be reused. Avoid
touching the membrane with bare fingers, as this may affect its
sensitivity.
Take a few membranes out of the storage box.

Using tweezers included in the kit, pick up one membrane of
the stack, and gently place it on the sensor tip.
Make sure it is centered, and no bubble is trapped.
If a sensor mask is used, place it directly on top of the
membrane.
For correct membrane selection, please refer to the tables in
Sensor membrane specifications on page 8.
Note: Distinguish the membrane from the protection paper:

- The membrane is transparent (translucent).
- The protection paper is opaque.
The membrane diameter is larger than sensor head

diameter. This is normal, as the membrane will fold over the
sensor tip.
The membrane holding ring comes in two slightly different

internal diameters, depending on the membrane(s) total
thickness.
For a correct membrane installation, be sure to use the
correct holding ring for the application.
25
Maintenance
Place the membrane holding ring on the installation tool tip.
CAUTION p
To avoid damaging the membrane, make sure that the
tool tip is totally clean and its surface is even.
Insert the installation tool inside the guiding sleeve.
Push the installation tool firmly downwards. This clasps the

mounting ring onto the sensor head, folding the membrane
over the sensor tip.
Remove the installation tool and guiding sleeve.
Visually check for correct ring placement, try to push it down
with your fingers.
Check that the membrane is tight, with no wrinkles, and no
bubbles are present.
Rinse the sensor with tap water and wipe dry with a clean
cloth.
Check for electrolyte leaks.
Prepare the protection cap for installation:
Replace all the parts inside the protection cap with new ones
(except the grille), and place them in the order they were
removed.
The Tefzel washers, under the cap, should be slightly
lubricated with silicone grease.
Note: The illustration on the right is an example only. Your
configuration may differ.
Tighten the protection cap finger tight.

Then, complete the process using the tool provided in the
maintenance kit. Insert into each of the four holes in turn,
and tighten as far as possible. Tighten each hole only once.
Note: The grille inside the protection cap should be free to move
during tightening. Therefore, and to avoid damage to the
membrane, do not touch the grille during the tightening process.
26
Maintenance
Always store the sensor with the storage cap and base
installed.
Put a few drops of clean water in the storage cap to prevent
the sensor cell drying.
Note: A sensor that has been taken apart or serviced must always be calibrated. Allow the sensor to settle
for 30 minutes, before performing the sensor calibration.
5.2 Electrochemical cleaning and regeneration center

The ORBISPHERE 32301 is a very efficient cleaning and regeneration tool for ORBISPHERE
electrochemical sensors. This tool reverses the electrochemical process that is taking place in
the sensor cell during normal operation. This removes oxidation and at the same time
regenerates the electrodes' surface. In addition, the regeneration center offers a continuity
tester for checking the sensor electronics.
Use of this tool is recommended because the regeneration of the electrodes allows for a
noticeably extended sensor life.
Detailed information on how to use the ORBISPHERE 32301 cleaning and regeneration center
is included in the related Operator's Manual.
Figure 12 Model 32301 cleaning and regeneration center
Note: It is mandatory to use the 32301 Sensor Cleaning and Regeneration Center for servicing
electrochemical H2 sensors. This process is called dechloridization and rechloridization of the electrodes.
See Hydrogen sensor cell cleaning on page 31.
27
Maintenance
5.3 Chemical cleaning: oxygen and ozone sensor cell

Note: Not applicable for H2 sensors.
The following supposes that the sensor has been taken apart. For disassembly and assembly
procedures, see Disassembly and assembly on page 23.
Conditions
Wear on the membrane, and chemical reactions within the sensor, requires that the sensor be
serviced regularly to restore its original sensitivity. Service includes electrode cleaning and
membrane replacement. A clear sign that a sensor maintenance is required is when
measurements are noticeably less stable than usual, and when a calibration does not improve
the situation.
Method description (see following step-by-step procedure)

• Electrochemical cleaning with 32301 (if available)
… when not available or results are insufficient.

... for sensors used in harsh environments (e.g., hydrocarbon industry) or very dirty sensors.
• Anode and cathode chemical cleaning
• Central electrode polishing
• Final rinsing
Note: To eliminate any silver residue that ammonia cleaning cannot remove, it is sometimes required to
repeat the chemical cleaning using nitric acid (HNO3, not over 70% by weight).
5.3.1 Membrane support cleaning
Empty and rinse the electrolyte reservoir under tap water.

Rinse membrane support under water and wipe it dry.
Check for the presence of any residue on the surfaces.
Residue can be removed by placing the support in a
container of nitric acid (HNO3, not over 70% by weight) until
it recovers its original appearance (normally within 30
seconds).
Note: Only use nitric acid to clean very dirty membrane support.
Rinse one minute under tap water and check again for
surface cleanliness.
CAUTION
Nitric acid is dangerous! Please refer to the safety information from your chemical
supplier.
28
Maintenance
5.3.2 Electrodes ammonia cleaning

Note: Only use ammonia to clean very dirty sensors.
Fill the sensor electrolyte reservoir with a solution of 25% by

weight ammonium hydroxide (NH4OH) in water and leave for
10 minutes.
Rinse with tap water for at least one minute.
Inspect the sensor head. The counter electrode should be a
silver-white color.
If the counter electrode still shows deposits, repeat the
procedure.
CAUTION
Ammonia is dangerous! Please refer to the safety information from your chemical
supplier.
5.3.3 Anode and cathode nitric acid cleaning

Note: Only use nitric acid to clean very dirty sensors.
Check for the absence of silver deposit on the central guard

ring electrode walls, as such deposits can make contact with
the counter electrode.
To eliminate any silver residue inside the sensor cell, it is
sometimes required to repeat the chemical cleaning using
nitric acid (HNO3, not over 70% by weight).
Also, the 32301 electrochemical cleaning does not remove
deposit on the cell’s plastic parts, so nitric acid cleaning may
be required.
Note: This procedure is not recommended for normal maintenance,

and should not be used more often than twice a year, as the acid
degrades the metal of the counter electrode, thus reducing the
sensor's life.
Place concentrated nitric acid into the sensor electrolyte

reservoir, and add 1 drop on the center electrode.
Leave for no longer than 3 seconds.
Quickly empty the acid and rinse thoroughly under tap water
for one minute.
CAUTION
supplier.
29
Maintenance
5.3.4 Sensor face polishing
Once the sensor has been cleaned, the face of the center
electrode must be polished together with the membrane
support.
Note: Install the membrane support with the groove on the upper
side. The membrane support is individually machined and paired
with the sensor. Therefore make sure that the correct membrane
support is used on the correct sensor.

support holes.
Tighten the membrane
support finger tight.
CAUTION
Too much torque will damage the sensor electrodes
Place the dish with the polishing cloth on a flat surface.
Spread a little polishing powder onto the cloth.
Mix with a few drops of water to get a grey, milky liquid.
Make sure to use the correct polishing powder for your
application. See the spare parts tables in Sensor parts on
page 35.
Note: Use one polishing cloth per sensor model, to prevent a
possible contamination through metal particle transfer.
Holding the sensor vertically, and using a circular motion,

polish the sensor face for at least 30 seconds, until the
electrodes are clean and shiny.
This step may need to be repeated several times.
Make sure to avoid skin contact with the polishing cloth; it
should be kept free of dust and grease.
Remove the membrane support with installation tool.

Rinse the support and sensor cavity with a strong jet of clean
water.
Use distilled water if the water quality is doubtful.
30
Maintenance
Carefully inspect that the tiny groove between the center

electrode and the guard ring electrode is totally clean and
free of polishing residue.
Clean only with a strong water spray. The edge of a paper
sheet can be used to remove sticking residue.
5.3.5 O3 Sensor only: final center electrode cleaning

Once the O3 sensor has been successfully cleaned and polished, a final nitric acid treatment
should be applied, as follows:
Place the sensor in a vertical position on its base.

Fill the electrolyte reservoir with a few drops of water, just
enough to cover the outer electrode. The center electrode
must be kept dry.
Place a drop of nitric acid on the center electrode, covering
only the electrode and guard ring. Avoid spilling acid into the
water. Wait less than a minute, then rinse thoroughly under
tap water.
CAUTION
supplier
5.4 Hydrogen sensor cell cleaning

Conditions
The hydrogen analyzer works on the principle that hydrogen molecules, passing through the
membrane, generate an electric current at the platinum anode surface. For this to take place, an
extremely clean metal surface is essential. If any film, grease or other impurity covers the
platinum surface, the reaction is impeded and may even be stopped.
In addition, the chemical reaction that takes place on the chloridized silver cathode leads to loss
of performance after a certain operation time.
As a result, a sensor service must be carried out to restore its original performance.
Method
The procedure for cleaning the H2 electrochemical sensor requires the use of the
ORBISPHERE 32301 Sensor Cleaning and Regeneration Center. This procedure is explained
in detail in the 32301 Operator's Manual.
As an overview, H2 electrochemical sensor cleaning consists of the following sequence of
operations:
• Dechloridization of the cathode: This process removes the chloride film from the silver
cathode surface (carried out by the ORBISPHERE 32301).
• Rechloridization of the cathode: A layer of silver chloride is grown on the cathode's surface
(carried out by the ORBISPHERE 32301).
• Activation of the platinum anode: The center anode surface is polished, and treated with
nitric acid.
31
Maintenance
32
Section 6 Troubleshooting
6.1 Oxygen sensor

Table 8 Troubleshooting - Oxygen sensor
Problem Probable Cause Possible Solution
MOCA 3600 only:
Repeated calibrations go beyond Select membrane from
"expected limits" of instrument. "Options/Membrane" menu. Then,
calibrate the sensor.
Sensor won't calibrate, Instrument internal barometric Calibrate "Barom. Pressure" menu.
even after thorough pressure sensor needs Check against a certified barometer. Do
servicing. calibration. not correct for sea level !
Wipe dry with a tissue and
Wet membrane interface.
re-calibrate.
"H2S insensitivity" option Disable from the “Options/Gas" menu
enabled. on the measuring instrument.
Change reading scale by selecting
"0000" O2 levels Wrong reading scale "XXXX"
"X.XXX, XX.XX or XXX.X" from.
displayed. selected for display unit.
"Options/Display Units" menu.
Shorter than expected Install a less permeable membrane.
sensor operation in High O2 concentrations generate
Turn off the analyzer when sensor is not
relatively high dissolved deposits more quickly.
in a low O2 concentration.
O2 concentration.
Set flow rate to 100 ml/min. Wait until
stable, then slowly double this flow rate.
The stable value of dissolved O2.
Air leak on product sample line.
reading must be the same as before. A
variation related to flow rate is a clear
sign of an air leak in the line.
Unexpected or inaccurate Place sensor in de-aerated sample;
dissolved O2 readings. wait for low reading:
Check concentration against low
High residual current. measurement limit (see tables in
Sensor membrane specifications on
page 8). If concentration is significantly
higher than low limit, try a sensor
service.
6.2 Hydrogen sensor

Table 9 Troubleshooting - Hydrogen sensor
MOCA 3600 only:
Sensor won't calibrate,
Repeated calibrations go beyond Select membrane from
even after thorough
"expected limits" of instrument. "Options/Membrane" menu. Then,
servicing.
calibrate the sensor.
"0000" H2 levels Wrong reading scale "XXXX"
"X.XXX, XX.XX or XXX.X" from
Shorter-than-expected High H2 concentrations require
sensor operation (in more work from electrochemical Shut off analyzer when not needed.
relatively high H2). sensor.
Unexpected/incorrect H2 If concentration is significantly higher
High residual current.
readings. than low limit, try a sensor service.
33
Troubleshooting
6.3 Ozone sensor

When the O3 sensor has been properly calibrated using the ORBISPHERE measuring
instrument, the sensor has to settle down for up to 24 hours when used in very low O3
concentration conditions.
Table 10 Troubleshooting - Ozone sensor

MOCA 3600 only:
Select membrane from
Repeated calibrations go beyond
"Options/Membrane" menu. Then,
"expected limits" of instrument.
Sensor won't calibrate, calibrate the sensor.
even after thorough O3 sensor cleaned with HNO3
servicing. Instrument internal barometric Calibrate "Barom. Pressure" menu.
pressure sensor needs Check against a certified barometer. Do
calibration. not correct for sea level !
Wet membrane interface. Wipe dry with a tissue and re-calibrate.
"0000" O3 levels Wrong reading scale "XXXX"
"X.XXX, XX.XX or XXX.X" from
If concentration is significantly higher
High residual current.
than low limit, try a sensor service.
Regulate flow equivalent to membrane
Insufficient flow rate.
Unexpected/incorrect specified levels.
dissolved O3 reading. Length of sample line allows O3
Reduce length of sample tubing.
time to react.
Take samples at close proximity to
Doesn't match lab samples.
sensor.
34
Section 7
Spare Parts and Accessories
7.1 Sensor parts

Table 11 Sensor spare parts
Part N° Description
28113 Membrane mounting tool for EC and TC sensor (except for 3654-3658)
28114 Membrane support mounting tool
28129 Delrin storage cap (sensor's storage cap)
28614 Combined protection cap and membrane holding ring removal tool
29010 Electrolyte for H2 sensor (50 ml)
29011 Chloridizing solution for H2 sensor (50 ml)
2959 Electrolyte for oxygen sensor (50 ml)
2961 Electrolyte for H2 insensitive oxygen sensor (50 ml)
2969 Electrolyte for ozone sensor (50 ml)
2978 Polishing kit, including 0.05 µm powder (2933) and cloth - suitable for O2 sensors
29781 Polishing kit, including 3µm powder (29331) and cloth - for O3 and H2 sensors
32205 Sensor support (base) for 31xxx sensors
7.2 Accessories
Table 12 Sensor accessories
28117 Pressure sensor, 0-5 bar absolute
28117.C Pressure sensor, 0-1 bar absolute
29006.0 EPDM O-rings for flow chamber/sensor socket 28x2 and 32x2mm
7.3 Flow chambers and installation devices

Table 13 Flow chambers and installation devices
29501.0 Sensor socket for welding to SS pipe, with EPDM O-ring
29501.1 Sensor socket for welding to SS pipe, with Viton O-ring
29508 Multi parameter flow chamber for headspace piercing device
Flow chamber in stainless steel (316) with 6 mm fittings.
32001.010
Supplied with EPDM O-rings.
Flow chamber in stainless steel (316) with ¼" fittings.
32001.011
32001.030 Flow chamber in Delrin with 6 mm fittings. Supplied with EPDM O-rings.
32001.031 Flow chamber in Delrin with ¼" fittings. Supplied with EPDM O-rings.
32001.0N1 Flow chamber in Inconel with ¼" fittings. Supplied with EPDM O-rings.
32001.141 Flow chamber in Hastelloy with ¼" fittings. Supplied with Viton O-rings.
Flow chamber in titanium with ¼" fittings (6 mm fittings not available in titanium)
32001.151
Supplied with Viton O-rings.
32001.181 Flow chamber in Kynar with ¼" fittings. Supplied with Viton O-rings.
32001.191 Flow chamber in PTFE with ¼" fittings. Supplied with Viton O-rings.
32001.030 Flow chamber, Delrin, 6 mm fittings, EPDM O-rings
32001.031 Flow chamber, Delrin, ¼ in. fittings, EPDM O-rings
Multi parameter flow chamber in stainless steel with 6 mm fittings.
32002.010
Multi parameter flow chamber in stainless steel with ¼" fittings.
32002.011
35
Table 13 Flow chambers and installation devices
32003 ProAcc sensor insertion device ; for use with Tuchenhagen adapter
Flow chamber in stainless steel (316) for use with for model 28117 and 28117.C
32006
pressure sensors.
32007D Flow chamber in Delrin for the power logger (3655), with one meter of tubing.
Flow chamber in stainless steel (316) with 6 mm fittings for use with 3650Ex. Supplied
32007E.110
with Viton O-rings.
Flow chamber in stainless steel (316) with ¼" fittings for use with 3650Ex.
32007E.111
Supplied with Viton O-rings.
Flow chamber in Delrin for the 3650. Includes check valve, 1 meter of inlet tubing,
32007F quarter turn flow valve, and outlet metal U-tube (6mm outside diameter). (replaces
32007B)
Flow chamber in Delrin with 6 mm stainless steel Swagelok fittings for use with liquids
32007W.030
with suspended particles. Supplied with EPDM O-rings.
Flow chamber in Delrin with ¼" stainless steel Swagelok fittings for use with liquids
32007W.031
with suspended particles. Supplied with EPDM O-rings.
Flow chamber in acrylic with 1/8" Swagelok fittings for small volume liquid phase
32009
measurements using 311XX sensors.
Flow chamber in acrylic with 1/8" Swagelok fittings for small volume liquid phase
32011
measurements, with port for 32562 external temperature sensor.
Flow chamber in PEEK, with spiral flow path for reduced flow demand for use with TC
32013 sensors for 3654 Micro logger. Supplied with check valve, 1 meter tubing, and needle
valve.
Flow chamber in PEEK with 6 mm Swagelok fittings, for use with H2 3654 radiation
32015.020 resistant applications. With spiral flow path for reduced flow demand. Supplied with
EPDM O-rings. No tubing supplied. Suitable for use up to 10 bar.
Flow chamber in PEEK with ¼" Swagelok fittings, for use with H2 3654 radiation
32015.021 resistant applications. With spiral flow path for reduced flow demand. Supplied with
EPDM O-rings. No tubing supplied. Suitable for use up to 10 bar.
32017 Flow chamber used with 29981 Pharmapack. Must be ordered separately.
36
7.4 Protection caps and related part kits
Protection cap, typical
1. Protection cap
2. Tefzel® washers
3. Grille
4. Dacron® (or Gore-Tex®) mesh
5. Silicon (or Viton®) washer
6. O-ring (membrane tightness)
Note: Depending on the application, O-rings (membrane
tightness) are available in EPDM, Viton®, Kalrez®, or Nitril®
Table 14 Protection caps and related part kits

Application Ref. Protection Cap Ref. Kit Includes:
28002 Tefzel washer x 6 (2)
Protection cap for use in
29060 St steel grille 0.2mm
liquids & dry gases.
29106.0 29046.0 29049 Dacron mesh x10 (1)
Supplied with 29046.0 28003 Silicone washers x 3 (1)
Liquids And Dry Gases
and EPDM O-rings. 29039.0 EPDM O-ring x 5 (1)

liquids and dry gases.
29106.1 29046.1 29049 Dacron mesh x10 (1)
Supplied with 29046.1
28003 Silicone washers x 3 (1)
and Viton O-rings. 29039.1 Viton O-rings x 5 (1)
liquids and dry gases.
29106.4 29046.4 29049 Dacron mesh x10 (1)
Supplied with 29046.4 28003 Silicone washers x 3 (1)
and Nitril O-rings. 29039.4 Nitril O-ring (1)
Prot. cap without grille 28002 Tefzel washer x 6 (2)
29104.0 Supplied with 29054 and 29054 28003 Silicone washers x 3 (1)
EPDM O-rings. 29039.0. EPDM O-ring x 5 (1)
Standard
Prot. cap in titanium. 28002 Tefzel washer x 6 (2)

29104.15 Supplied with 29054.1 29054.1 28508.1 Viton washer x (1)
and Viton O-rings. 29039.1 Viton O-rings x 5 (1)
Prot. cap in titanium 28002 Tefzel washer x 6
29104.25 Supplied with 29054.2 29054.2 28508.1 Viton washer (1)
and Kalrez O-rings. 29039.2 Kalrez O-ring x 1 (1)
Gases
moist gases.
Moist
29107.0 29063 28003 Silicon washer x3 (1)

Supplied with 29063 and 29031A Gore-Tex disc x3 (1)
EPDM O-rings. 29039.0 EPDM O-ring x5 (1)
37
7.5 Maintenance kits for EC sensors
The maintenance kit delivered with a new ORBISPHERE sensor includes enough
consumables for several sensor services. Order additional consumable parts in order to keep
this sensor maintenance kit complete. Please contact your Hach Lange representative.
7.5.1 Kits for O2 sensors
Table 15 Kits for oxygen sensors

Kit for oxygen electrochemical sensors for H2S insensitive applications. Includes
2980A
membranes 2956A, electrolyte 2961, and tools for sensor maintenance.
Kit for oxygen electrochemical sensors. Includes membranes 2935A, electrolyte 2959,
32701
membrane holding ring 29228, and tools for sensor maintenance.
Kit for oxygen electrochemical sensors. Including membranes 2952A, electrolyte 2959,
32702
Kit for oxygen electrochemical sensors used with 365x instruments. Includes membranes
32702A 2952A, electrolyte 2959, membrane holding ring 29228, kit 29046, and tools for sensor
maintenance.
32703
maintenance.
32704
maintenance.
32705
32706 membrane holding ring 29229, and tools for sensor maintenance. (Replaces 32706L &
32706M.)
Kit for oxygen electrochemical sensors used with 365X instruments. Includes
32706A membranes 29552A, electrolyte 2959, membrane holding ring 29229, kit 29046, and
tools for sensor maintenance.
32707
32711
mask 29026A, membrane holding ring 29229, tools for sensor maintenance.
32712
32713
32713A 2956A, electrolyte 2959, mask 29026A, membrane holding ring 29229, kit 29046, and
32714
mask 29026A, ring 29229, and tools for sensor maintenance.
32717
38
7.5.2 Kits for O3 sensors
Table 16 Kits for ozone sensors

Kit for ozone electrochemical sensors. Includes membranes 2956A, electrolyte 2969,
32731
mask 29027A, membrane holding ring 29229.05, and tools for sensor maintenance.
Kit for electrochemical ozone sensors for use with 3660. Includes membranes 29552A,
32732 electrolyte 2969, membrane holding ring 29229.05, and tools for sensor maintenance.
(Replaces 32732L.)
7.5.3 Kits for H2 sensors
Table 17 Kits for hydrogen sensors

Kit for hydrogen electrochemical sensors. Includes membranes 2952A, electrolyte
32720 29010, chloridizing solution 29011, membrane holding ring 29228, and tools for sensor
maintenance.
maintenance.
maintenance.
maintenance.
32725 29010, chloridizing solution 29011, mask 29026A, membrane holding ring 29229, and
39
40
HACH COMPANY World Headquarters HACH LANGE GMBH HACH LANGE Sàrl
P.O. Box 389, Loveland, CO 80539-0389 U.S.A. Willstätterstraße 11 6, route de Compois
Tel. (970) 669-3050 D-40549 Düsseldorf, Germany 1222 Vésenaz
(800) 227-4224 (U.S.A. only) Tel. +49 (0) 2 11 52 88-320 SWITZERLAND
Fax (970) 669-2932 Fax +49 (0) 2 11 52 88-210 Tel. +41 22 594 6400
orders@hach.com info-de@hach.com Fax +41 22 594 6499
www.hach.com www.de.hach.com
© Hach Company/Hach Lange GmbH, 2012–2015, 2018. All rights reserved.

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DOC024.52.93016 EC-sensors 11ed

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ORBISPHERE Model 31xxx

Section 1 General Information ......................................................................................................... 3

7.5 Maintenance kits for EC sensors................................................................................................38

1.2 Safety information

1.2.1 Use of hazard information

1.2.2 Service and repairs

1.2.3 Precautionary labels

This symbol indicates the need for protective hand wear.

1.3 Product recycling information

2.1 Sensor design

• All ORBISPHERE electrochemical sensors’ enclosures are certified IP68 / NEMA4

2.2 Sensor weight and dimensions

Figure 1 Sensor dimensions

2.3 EC sensors and parts used on ORBISPHERE configured systems

Table 2 ORBISPHERE configured systems

2.4 Sensor membrane specifications

Table 3 Membrane specifications - Hydrogen sensors

2.4.2 Oxygen sensors (Table 1)

Table 4 Membrane specifications - Oxygen sensors (1)

2.4.3 Oxygen sensors (Table 2)

Table 5 Membrane specifications - Oxygen sensors (2)

2.4.4 Ozone sensors

Table 6 Membrane specifications - Ozone sensors

3.1 What you have received

3.1.1 An oxygen, ozone, or hydrogen electrochemical sensor

Figure 2 Electrochemical sensor components

3.1.2 A sensor maintenance kit

3.2 Basic principle of operation

Figure 3 Sensor cell components

Electrochemical sensor assembly Protection cap and cable removed

Figure 5 Electrochemical sensors

4.1 Initial sensor cell cleaning

4.2 Positioning information

4.3 Sensor insertion

Micro volume flow chambers:

Figure 6 Sensor insertion

4.4 Sensor removal

4.5 Mounting accessories

4.5.1 External pressure sensor

Two models are available, depending on the application:

4.5.2 Weld-on stainless steel socket

Figure 7 Weld-on sensor socket

Figure 8 Installation in-line

4.5.3 Insertion/extraction valve

Tuchenhagen Varivent® In-Line Access Unit

4.5.4 ORBISPHERE flow chambers

Dimensions of sensor and flow chamber assembly :

Table 7 Flow chamber orientation

Vertically, with connections down and

Horizontally, to allow for drainage

Figure 10 Flow chamber connections

4.5.5 Multi parameter flow chamber

Figure 11 32002.xxx multi parameter flow chamber

Shown here with:

5.1 Disassembly and assembly

It is important to install the electrochemical sensor standing

Remove the plastic storage cap.

Pay attention to the components inside the protection cap.