Chapter 2
Chapter 2
Chapter 2
The nucleus has two types of particles called protons and neutrons.
The protons are positively charged and the neutrons have no charge
(neutral).
The relative mass and charge of each particle is as shown in the table
below.
Atomic symbol
The structure of an atom can be written in symbol form as:
Mass Number
A
X
(Nucleon number)
Atomic Number
(Proton Number)
B
E.g. What are the atomic particles found in
an atom of fluorine, 199 F?
Electron arrangement
The electrons surround the nucleus like a cloud and move around it in fixed
orbits or shells.
The maximum number of electrons each shell can hold is given by:
1st shell = 2
2nd shell = 8
3rd shell = 8 (for the first 20 elements in the Periodic Table)
The electronic structure can also be stated as a series of numbers called the
electron configuration.
The electronic configuration of the sodium atom shown is: 2.8.1. The
electrons in the outermost shell are called the outer electrons or valence
electrons.
Isotopes
Isotopes are atoms of the same element which have the same number of
protons but different numbers of neutrons.
Isotopes are chemically alike in all aspects, except for their masses.
However, some isotopes are radioactive.
Isotopes of
hydrogen
Chlorine exists as two main isotopes: 3517Cl (75%) and 3717Cl (25%).
The average atomic mass of chlorine is given by the weighted mean of the
two isotopes:
0.75 x 35 + 0.25 x 37 = 35.5
Hence, in the Periodic Table the atomic mass of chlorine is given as 35.517Cl.
Ions
In an atom, the number of electrons is equal to the number of protons, so
an atom is electrically neutral.
However, atoms can lose or gain electrons to form charged particles called
ions.
Atoms form ions so that they can have the stable electronic structure of a
noble gas such as helium, neon or argon.
If an atom gives away its outer electrons, then it has more protons than
electrons and becomes a positively charged ion.
If an atom takes in electrons, then it has more electrons than protons, and
it becomes a negatively charged ion.
Examples:
Mg Mg2+ + 2e-
(Mg loses two electrons to form a positive ion, Mg2+)
Cl + e- Cl-
(Cl gains one electron to form a negative ion, Cl-)
Ions of metals and non-metals.
Metals e.g. sodium, calcium and aluminum which have less than 4
electrons in their outermost shells, always give away electrons to form
positive ions.
Non-metals like chlorine, oxygen and nitrogen which have more than 4
electrons in their outer shell, take in electrons to form negative ions.
Molecules of elements
Molecules of compounds.