920.194 Carbonate and Bicarbonate in Water

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11.1.

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AOAC Official Method 920.194
Carbonate and Bicarbonate
in Water
Titrimetric Method
First Action 1920
Final Action
To 100 mL test portion add few drops phenolphthalein, and if pink
is produced, titrate with 0.05M HCl or 0.025M H2SO4, adding drop
every 2–3 s until color disappears. Multiply buret reading by factor 3
to obtain mg CO3 ion in 100 mL. To colorless solution from this
titration, or to original solution if no color is produced with
phenolphthalein, add 1–2 drops methyl orange, continue titration
without refilling buret, and note total reading. If CO3 is absent,
multiply total buret reading by factor 3.05 to obtain value of HCO3
ion in mg/100 mL. If CO3 is present, multiply reading with
phenolphthalein by 2 and subtract from total reading of buret.
Multiply difference by 3.05 to obtain HCO3 ion in mg/100 mL.
Express results as mg/L.

 2005 AOAC INTERNATIONAL

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