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    Nickel de La Cruz Fortuna

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    Federico Tito
    This document contains experimental data and rate equations for the oxidation of copper(I) by oxygen in an aqueous solution. Rate (R) was measured for various concentrations of copper(I) ([Cu(I)]) at 22°C. The data was fitted to the rate equation R=K[O2][Cu(I)]1.5. Higher copper(I) concentrations resulted in higher reaction rates.

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    Nickel de La Cruz Fortuna

    Uploaded by

    Federico Tito
    21 views11 pages
    This document contains experimental data and rate equations for the oxidation of copper(I) by oxygen in an aqueous solution. Rate (R) was measured for various concentrations of copper(I) ([Cu(I)]) at 22°C. The data was fitted to the rate equation R=K[O2][Cu(I)]1.5. Higher copper(I) concentrations resulted in higher reaction rates.

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    This document contains experimental data and rate equations for the oxidation of copper(I) by oxygen in an aqueous solution. Rate (R) was measured for various concentrations of copper(I) ([Cu(I)]) at 22°C. The data was fitted to the rate equation R=K[O2][Cu(I)]1.5. Higher copper(I) concentrations resulted in higher reaction rates.

    Copyright:

    © All Rights Reserved
    Download as XLS, PDF, TXT or read online from Scribd
    Download as xls, pdf, or txt
    21 views11 pages

    Nickel de La Cruz Fortuna

    Uploaded by

    Federico Tito
    This document contains experimental data and rate equations for the oxidation of copper(I) by oxygen in an aqueous solution. Rate (R) was measured for various concentrations of copper(I) ([Cu(I)]) at 22°C. The data was fitted to the rate equation R=K[O2][Cu(I)]1.5. Higher copper(I) concentrations resulted in higher reaction rates.

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    Pappassiopi

    R=K[O2][Cu(I)]1.5
    K= 2800000 cm4.5mol-1.5s-1 1.60E-01
    T= 22 °C
    [HCl]= 0.0625 M 1.40E-01
    [NaCl]= 2 M
    [O2]= 1.07E-04 M
    1.20E-01
    [Cu(I)] M R
    0.0009 8.09E-03
    0.0013 1.40E-02 1.00E-01
    0.0016 1.92E-02
    0.002 2.68E-02 8.00E-02
    0.0024 3.52E-02
    0.0028 4.44E-02
    0.0032 5.42E-02 6.00E-02
    0.0036 6.47E-02
    0.004 7.58E-02 4.00E-02
    0.0044 8.74E-02
    0.0048 9.96E-02
    2.00E-02
    0.0052 1.12E-01
    0.0056 1.26E-01
    0.006 1.39E-01 0.00E+00
    0.0062 1.46E-01 0 0.001 0.002 0.003 0.0
    ssiopi

    Cu(I) vs R

    Polynomial (Cu(I) vs
    R)

    1 0.002 0.003 0.004 0.005 0.006 0.007 R:


    K2
    [CuCl]: 0.15-0.09 M
    [HCl]: 5 M
    R: 1.99 cal/K 4500000000
    T (°C) K2
    4000000000
    10 110581650.009271
    3500000000
    20 183421677.201866
    30 294247067.236748 3000000000
    40 457991982.959765 2500000000
    50 693595138.060468
    2000000000
    60 1024538985.99964
    70 1479353888.79907 1500000000
    80 2092070760.40054 1000000000
    90 2902608175.13115 500000000
    100 3957082892.17788
    0
    R2: 0.8745869461
    0 10 20 30 40 50 60 70 80 9
    Error 486692905.94369
    30 40 50 60 70 80 90 100
    [CuCl]: 0.15-0.7
    [NaCl]: 3.75
    R: 1.99
    T (°C) K2
    10 166906985.919344
    20 238648880.608375
    30 333268649.19268
    40 455577329.823422
    50 610833832.113722
    60 804701393.871573
    70 1043196572.88955
    80 1332632810.19861
    90 1679560525.09433
    100 2090705548.89804
    R2: 0.9378393749
    Error 172135423.764418
    M
    M
    cal/K 2500000000
    K2
    166906985.919344 2000000000
    238648880.608375
    333268649.19268 1500000000
    455577329.823422
    610833832.113722 1000000000
    804701393.871573
    1043196572.88955 500000000
    1332632810.19861
    1679560525.09433 0
    2090705548.89804 0 10 20 30 40 50 60 70 80 90 100
    0.9378393749
    172135423.764418
    100
    Pappassiopi Jhav
    R=K[O2][Cu(I)]1.5

    K= 2800000 cm4.5mol-1.5s-1
    T= 22 °C
    [HCl]= 0.0625 M
    [NaCl]= 2 M
    [O2]= 1.07E-04 M

    Mode
    [Cu(I)] M R !R Mode
    2.500
    0.0009 0.008 0.047
    0.0013 0.014 0.098
    0.0016 0.019 0.148
    2.000
    0.002 0.027 0.231

    1.500
    2.000

    0.0024 0.035 0.333


    0.0028 0.044 0.453
    1.500
    0.0032 0.054 0.592
    0.0036 0.065 0.749
    0.004 0.076 0.924
    0.0044 0.087 1.119 1.000
    0.0048 0.100 1.331
    0.0052 0.112 1.562
    0.0056 0.126 1.812 0.500
    0.006 0.139 2.080
    0.0062 0.146 2.221
    0.000
    0 0.001 0.002
    Jhaveri-Sharma-Awakura
    R=K2[O2][Cu(I)]2

    K= 540000000 cm6mol-2s-1
    T= 25 °C
    [Cl-]= 2.1 M

    [O2]= 1.07E-04 M

    Modelo de Pappassiopi
    Modelo de Jhaveri-Sharma-Awakura
    500

    000

    500
    000

    500

    000

    500

    000
    0 0.001 0.002 0.003 0.004 0.005 0.006 0.007

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