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    Tutorial 1 v1

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    Ravi Mohan Prasad
    This document provides a tutorial on metallurgical thermodynamics and kinetics. It contains 8 questions covering key concepts such as deriving equations for work and heat transfer during various thermodynamic processes involving gases, calculating property changes for ideal gases, and applying thermodynamic laws like Hess' law and Kirchoff's law. The questions involve calculating values for processes like isothermal and adiabatic expansions of ideal gases as well as determining entropy changes.

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    Tutorial 1 v1

    Uploaded by

    Ravi Mohan Prasad
    23 views1 page
    This document provides a tutorial on metallurgical thermodynamics and kinetics. It contains 8 questions covering key concepts such as deriving equations for work and heat transfer during various thermodynamic processes involving gases, calculating property changes for ideal gases, and applying thermodynamic laws like Hess' law and Kirchoff's law. The questions involve calculating values for processes like isothermal and adiabatic expansions of ideal gases as well as determining entropy changes.

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    This document provides a tutorial on metallurgical thermodynamics and kinetics. It contains 8 questions covering key concepts such as deriving equations for work and heat transfer during various thermodynamic processes involving gases, calculating property changes for ideal gases, and applying thermodynamic laws like Hess' law and Kirchoff's law. The questions involve calculating values for processes like isothermal and adiabatic expansions of ideal gases as well as determining entropy changes.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    23 views1 page

    Tutorial 1 v1

    Uploaded by

    Ravi Mohan Prasad
    This document provides a tutorial on metallurgical thermodynamics and kinetics. It contains 8 questions covering key concepts such as deriving equations for work and heat transfer during various thermodynamic processes involving gases, calculating property changes for ideal gases, and applying thermodynamic laws like Hess' law and Kirchoff's law. The questions involve calculating values for processes like isothermal and adiabatic expansions of ideal gases as well as determining entropy changes.

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    Tutorial 1: MM201, Metallurgical Thermodynamics and Kinetics

    1. Derive the equation for work done by the system and heat transferred to the system
    for a process with initial and final state variables (P1,V1,T1) and (P2,V2,T2) for the
    following conditions.
    a. Isobaric process
    b. Isochoric process
    c. Reversible isothermal process
    d. Reversible adiabatic process

    2. Derive the expression for change in volume (dV) of and ideal gas in terms of
    isothermal compressibility (βT) and coefficient of thermal expansion (α).

    3. Calculate the value of the ratio βT and α for an ideal gas in terms of its volume.

    4. An Ideal gas at 300 K has a volume of 15 litres at a pressure of 15 atm. Calculate (a)
    the final volume of the system, (b) the work done by the system, (c) the heat entering
    or leaving the system, (d) the change in the internal energy, and (e) the change in the
    enthalpy when the gas undergoes
    i. A reversible isothermal expansion to a pressure of 10 atm.
    ii. A reversible adiabatic expansion to a pressure of 10 atm.

    5. Two moles of a monoatomic ideal gas are contained at a pressure of 1 atm and a
    temperature of 300 K. 34,166 joules of heat are transferred to the gas, as a result of
    which the gas expands and does 1216 joules of work against its surroundings. The
    process is reversible. Calculate the final temperature of the gas.

    6. The initial state of a monoatomic ideal gas is P=10 atm and T=300 K. Calculate the
    change in the entropy of the gas for (a) an isothermal decrease in the pressure to 5
    atm. (b) a reversible adiabatic expansion to a pressure of 5atm (c) a constant-volume
    decrease in the pressure to 5 atm.

    7. Drive Hess’ law and Kirchoff’s law.

    8. Calculate the standard entropy of solid copper at 1073 ˚C.


    Given, S˚ (300, Cu(s)) = 8 cal/deg/mol, Cp (Cu(s)) = 5.41 + 1.510-3 T cal/deg/mol

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