Material Safety Data Sheet

WHMIS (Pictograms) WHMIS (Classification) Protective Clothing TDG (pictograms)

Not controlled

Section 1. Chemical Product and Company Identification

Product Name Code 420-065, DE15
DURON-E 15W-40
Synonym Not available Validated on 6/8/2007.

Manufacturer PETRO-CANADA In case of Petro-Canada: 403-296-

P.O. Box 2844 Emergency 3000
150 –6th Avenue South-West Canutec Transportation:
Calgary, Alberta 613-996-6666
T2P 3E3 Poison Control Centre:
Consult local telephone
Material Uses DURON-E 15W-40 is a superior quality heavy duty diesel engine oil directory f or emergency
specifically designed for ’
07 EPA engine requirements along with number(s).
improved performance benefits in legacy engines. Application
includes modern low emission diesel engines with cooled exhaust gas
recirculation and exhaust after treatment technology. It is suitable
also for passenger car and light truck diesel engines, and spark
ignition engines.

Section 2. Composition and Information on Ingredients

Exposure Limits (ACGIH)

Name CAS # % (W/W) TLV-TWA(8 h) STEL CEILING

Mixture of severely hydrotreated and hydrocracked Mixture 100 5 mg/m³ (oil mist) 10 mg/m³ (oil Not
base oil (petroleum) and other proprietary, non- mist) established
hazardous additives.

Manufacturer Not applicable

Recommendation
Other Exposure Consult local, state, provincial or territory authorities for acceptable exposure limits.
Limits

Section 3. Hazards Identification.

Potential Health Prolonged or repeated contact may cause skin irritation, defatting, drying and dermatitis. Not expected to
Effects cause more than slight skin or eye irritation. With its relatively low vapour pressure, this product is not
expected be inhaled in any appreciable quantity at ambient conditions. If heated to high temperatures or
subjected to mechanical actions which produce vapours or mists, inhalation may cause respiratory tract
irritation. Ingestion may produce a laxative effect. For more information refer to Section 11 of this MSDS.

Section 4. First Aid Measures

Eye Contact No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for
5 minutes or until the chemical is removed. If irritation persists, obtain medical advice.
Skin Contact Quickly and gently, blot or brush away excess chemical.Wash gently and thoroughly with water and non-
abrasive soap for 5 minutes or until chemical is removed. Remove contaminated clothing, shoes and leather
goods (e.g., watchbands, belts, etc.). If irritation persists, repeat flushing.Obtain medical advice immediately.
Completely decontaminate clothing, shoes and leather goods before reuse or discard.
Inhalation Remove source of contamination or move victim to fresh air. If irritation persists, obtain medical advice.
Ingestion NEVER give anything by mouth if victim is rapidly losing consciousness, or is unconscious or convulsing. DO
NOT induce vomiting because of danger of aspirating liquid into lungs. Have victim drink 240 to 300 mL (8 to
10 oz) of water to dilute material in stomach. If vomiting occurs naturally, rinse mouth and repeat
administration of water. Obtain medical attention.
Note to Physician Not available

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Section 5. Fire-fighting Measures

Flammability May be combustible at high temperature. Flammable Limits Not available.
Flash Points Open cup: 235°C (455°F) (ASTM D92, Auto-Ignition 243°C (469.4°F)
Cleveland.). Temperature
Fire Hazards Low fire hazard. This material must be Explosion Do not cut, weld, heat, drill or pressurize
in Presence of heated before ignition will occur. Hazards in empty container. Containers may explode
Various Presence of in heat of fire.
Substances Various
Substances
Products of Carbon oxides (CO, CO2), sulphur oxides (SOx), calcium oxides (CaOx), nitrogen oxides (NOx),
Combustion phosphorus oxides (POx), zinc oxides (ZnOx), smoke and irritating vapours as products of incomplete
combustion.
Fire Fighting NAERG2004, GUIDE 171, Substances (low to moderate hazard). If tank, rail car or tank truck is involved in a
Media and fire, ISOLATE for 800 meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5
Instructions mile) in all directions. Shut off fuel to fire if it is possible to do so without hazard. If this is impossible,
withdraw from area and let fire burn out under controlled conditions. Withdraw immediately in case of rising
sound from venting safety device or any discolouration of tank due to fire. Cool containing vessels with water
spray in order to prevent pressure build-up, autoignition or explosion. SMALL FIRE: use DRY chemicals,
foam, water spray or CO2. LARGE FIRE: use water spray, fog or foam. For small outdoor fires, portable fire
extinguishers may be used, and self contained breathing apparatus (SCBA) may not be required. For all
indoor fires and any significant outdoor fires, SCBA is required. Respiratory and eye protection are required
for fire fighting personnel.

Section 6. Accidental Release Measures

Material Release Consult current National Emergency Response Guide Book (NAERG) for appropriate spill measures if
or Spill necessary. Ensure clean-up personnel wear appropriate personal protective equipment. Extinguish all ignition
sources. Stop leak if safe to do so. Dike spilled material. Use appropriate inert absorbent material to absorb
spilled product. Collect used absorbent for later disposal. Avoid contact with spilled material. Avoid
contaminating sewers, streams, rivers and other water courses with spilled material. Notify appropriate
authorities immediately.

Section 7. Handling and Storage

Handling Avoid contact with any sources of ignition, flames, heat, and sparks. Avoid eye contact. Avoid skin contact.
Avoid inhalation of product vapours or mists. Wear proper personal protective equipment (See Section 8).
Empty containers may contain product residue. Do not pressurize, cut, heat, or weld empty containers. Do
not reuse containers without commercial cleaning and/or reconditioning. Personnel who handle this material
should practice good personal hygiene during and after handling to help prevent accidental ingestion of this
product. Properly dispose of contaminated leather articles including shoes that cannot be decontaminated.
Storage Store away from incompatible and reactive materials (See section 5 and 10). Keep container tightly closed.
Store in dry, cool, well-ventilated area.

Section 8. Exposure Controls/Personal Protection

Engineering For normal application, special ventilation is not necessary. If user's operations generate vapours or mist, use
Controls ventilation to keep exposure to airborne contaminants below the exposure limit. Make-up air should always
be supplied to balance air removed by exhaust ventilation. Ensure that eyewash station and safety shower
are close to work-station.
Personal Protection - The selection of personal protective equipment varies, depending upon conditions of use.
Eyes As a minimum, safety glasses with side shields should be worn when handling this material.
Body If this material may come in contact with the body during handling and use, we recommend wearing
appropriate protective clothing to prevent contact with the skin. (Contact your PPE provider for more
information.)
Respiratory A minimum of NIOSH-approved air-purifying respirator with an organic vapour cartridge or canister with a
dust, fume of mist filter (R, or P series) may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by air-purifying respirators is
limited. A NIOSH-approved positive-pressure, air-supplied respirator or self-contained breathing apparatus
may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
Hands If this material may come in contact with the hands during handling and use, we recommend wearing gloves
of the following material(s): neoprene, nitrile, polyvinyl alcohol (PVA), fluoro-elastomer. Consult your PPE
provider for breakthrough times and the specific glove that is best for you based on your use patterns. It
should be realized that eventually any material regardless of their imperviousness, will get permeated by
chemicals. Therefore, protective gloves should be regularly checked for wear and tear. At the first signs of
hardening and cracks, they should be changed.
Feet Wear appropriate footwear to prevent product from coming in contact with feet and skin.

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Section 9. Physical and Chemical Properties

Physical State and Viscous liquid. Viscosity 116.1 cSt @ 40°C (104ºF), 15.40 cSt @
Appearance 100°C (212ºF), VI=139

Colour Light amber. Pour Point -42ºC (-44ºF)

Odour Mild petroleum oil like. Softening Point Not applicable.
Odour Threshold Not available. Dropping Point Not applicable.
Boiling Point Not available Penetration Not applicable.
Density 0.8725 kg/L @ 15ºC (59ºF) Oil / Water Dist. Not available.
Coefficient
Vapour Density Not available. Ionicity (in water) Not available
Vapour Pressure Negligible at ambient temperature and Dispersion Properties Not available
pressure.
Volatility Not available Solubility Insoluble in water.

Section 10. Stability and Reactivity

Corrosivity Copper corrosion, 3h, 100°C (ASTM D0130): 1a
Stability The product is stable under normal Hazardous W ill not occur under normal working
handling and storage conditions. Polymerization conditions.

Incompatible Reactive with oxidizing agents, acids, Decomposition May release COx, H2S, aldehydes, alkyl
Substances / halogens, halogenated compounds. Products mercaptans, sulfides, methacrylate
Conditions to Avoid monomers, smoke and irritating vapours when
heated to decomposition.

Section 11. Toxicological Information

Routes of Entry Skin contact, eye contact, inhalation and ingestion.
Acute Lethality Acute toxicity information is not available for the product as a whole, therefore, data for the base
oils are provided below:
Acute Oral toxicity (LD50): >5000 mg/kg (rat)
Acute Dermal toxicity (LD50): >2000 mg/kg (rabbit)
Acute Inhalation toxicity (LC50): >2500 mg/m³/4h (rat)
Chronic or Other Toxic Effects
Dermal Route: Prolonged or repeated contact may defat and dry skin, and cause dermatitis. Short-term exposure
is expected to cause only slight irritation, if any.
Inhalation Route: With its relatively low vapour pressure, this product is not expected be inhaled in any appreciable
quantity at ambient conditions. If heated to high temperatures or subjected to mechanical actions
which produce vapours or mists, inhalation may cause respiratory tract irritation.
Oral Route: Ingestion of this product may lead to aspiration of the liquid, especially if vomiting occurs. This may
result in chemical pneumonitis (inflammation of the lungs) and/or pulmonary edema (an
accumulation of fluid in the lungs). May produce a laxative effect.
Eye Irritation/Inflammation: Short-term exposure is expected to cause only slight irritation, if any.
Immunotoxicity: Not available.
Skin Sensitization: Contact with this product is not expected to cause skin sensitization, based upon the available data
and the known hazards of the components.
Respiratory Tract Sensitization: Contact with this product is not expected to cause respiratory tract sensitization, based upon the
available data and the known hazards of the components.
Mutagenic: This product is not known to contain any components at >= 0.1% that have been shown to cause
mutagenicity. Therefore, based upon the available data and the known hazards of the
components, this product is not expected to be a mutagen.
Reproductive Toxicity: This product is not known to contain any components at >= 0.1% that have been shown to cause
reproductive toxicity. Therefore, based upon the available data and the known hazards of the
components, this product is not expected to be a reproductive toxin.
Teratogenicity/Embryotoxicity: This product is not known to contain any components at >= 0.1% that have been shown to cause
teratogenicity and/or embryotoxicity. Therefore, based upon the available data and the known
hazards of the components, this product is not expected to be a teratogen/embryotoxin.
Carcinogenicity (ACGIH): This product is not known to contain any chemicals at reportable quantities that are listed as Group
A1 or A2 carcinogens by ACGIH.
Carcinogenicity (IARC): This product is not known to contain any chemicals at reportable quantities that are listed as Group
1, 2A, or 2B carcinogens by IARC.

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Carcinogenicity (NTP): This product is not known to contain any chemicals at reportable quantities that are listed as
carcinogens by NTP.
Carcinogenicity (IRIS): This product is not known to contain any chemicals at reportable quantities that are listed as
carcinogens by IRIS.
Carcinogenicity (OSHA): This product is not known to contain any chemicals at reportable quantities that are listed as
carcinogens by OSHA.
Other Considerations No additional remark.

Section 12. Ecological Information

Environmental Not available Persistance/ Not available
Fate Bioaccumulation
Potential
BOD5 and COD Not available. Products of Not available.
Biodegradation
Additional Remarks No additional remark.

Section 13. Disposal Considerations

Waste Disposal Spent/ used/ waste product may meet the requirements of a hazardous waste. Consult your local or regional
authorities. Ensure that waste management processes are in compliance with government requirements and
local disposal regulations.

Section 14. Transport Information

TDG Classification Not a hazardous material for transport Special Provisions Not applicable.
according to the TDG Regulations. for Transport
(Canada)

Section 15. Regulatory Information

Other This product is acceptable for use under the provisions of WHMIS-CPR. All components of this formulation
Regulations are listed on the CEPA-DSL (Domestic Substances List).

All components of this formulation are listed on the US EPA-TSCA Inventory.

All components of this product are on the European Inventory of Existing Commercial Chemical Substances
(EINECS) or the European List of Notified Chemical Substances (ELINCS).

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.

Please contact Product Safety for more information.

DSD/DPD (Europe) Not classified under the Dangerous HCS (U.S.A.) Does not meet the definitions of a health or
Substances or Dangerous Preparations physical hazard according to the OSHA -
Directives. Hazard Communication Standard. (United
States)
ADR (Europe) DOT (U.S.A)
(Pictograms) (Pictograms)

HMIS (U.S.A.) Health Hazard 1 NFPA (U.S.A.) Rating 0 Insignificant

1 Fire Hazard
Fire Hazard 1 1 Slight
Health 1 0 Reactivity 2 Moderate
Reactivity 0 3 High
Specific hazard
Personal Protection B 4 Extreme

Section 16. Other Information

References Available upon request.
* Marque de commerce de Petro-Canada - Trademark
Glossary

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ACGIH - American Conference of Governmental Industrial Hygienists HCS - Hazardous Communication System
ADR - Agreement on Dangerous goods by Road (Europe) HMIS - Hazardous Material Information System
ASTM - American Society for Testing and Materials IARC - International Agency for Research on Cancer
BOD5 - Biological Oxygen Demand in 5 days IRIS - Integrated Risk Information System
CAS - Chemical Abstract Services LD50/LC50 - Lethal Dose/Concentration kill 50%
CEPA - Canadian Environmental Protection Act LDLo/LCLo - Lowest Published Lethal Dose/Concentration
CERCLA - Comprehensive Environmental Response, Compensation NFPA - National Fire Prevention Association
and Liability Act NIOSH - National Institute for Occupational Safety & Health
CFR - Code of Federal Regulations NPRI - National Pollutant Release Inventory
CHIP - Chemical Hazard Information and Packaging Approved Supply NSNR - New Substances Notification Regulations (Canada)
List NTP - National Toxicology Program
COD - Chemical Oxygen Demand OSHA - Occupational Safety & Health Administration
CPR - Controlled Products Regulations PEL - Permissible Exposure Limit
DOT - Department of Transportation (U.S.A.) RCRA - Resource Conservation and Recovery Act
DSCL - Dangerous Substances Classification and Labeling (Europe) SARA - Superfund Amendments and Reorganization Act
DSD/DPD - Dangerous Substance or Dangerous Preparations STEL - Short Term Exposure Limit (15 minutes)
Directives (Europe) TDG - Transportation Dangerous Goods (Canada)
DSL - Domestic Substance List (Canada) TDLo/TCLo - Lowest Published Toxic Dose/Concentration
EEC/EU - European Economic Community/European Union TLV-TWA - Threshold Limit Value-Time Weighted Average
EINECS - European Inventory of Existing Commercial Chemical TLm - Median Tolerance Limit
Substances TSCA - Toxic Substances Control Act
EPCRA - Emergency Planning And Community Right-To-Know Act USEPA - United States Environmental Protection Agency
FDA - Food and Drug Administration USP - United States Pharmacopoeia
FIFRA - Federal Insecticide, Fungicide, and Rodenticide Act WHMIS - Workplace Hazardous Material Information System

For Copy of MSDS Prepared by Product Safety - DSR on 6/8/2007.

The Canadian Controlled Products Regulations (CPR) (Under the Hazardous Data entry by Product Safety - DSR.
Products Act, part of the WHMIS legislation) only apply to WHMIS Controlled (i.e.,
hazardous) products. Therefore, the CPR and the 3-year update rule specified
therein do not apply to WHMIS Non-Controlled products. Although this is true,
customarily Petro-Canada reviews and updates Non-Controlled product MSDS if a
customer requests such an update. These Non-Controlled product updates are given
a lower priority than Controlled products but are handled as soon as practicable. If
you would like to verify if the MSDS you have is the most current, or you require
any further information, please contact:

Internet: www.petro-canada.ca/msds

Lubricants:
Western Canada, telephone: (001) 1-800-661-1199; fax: (001) (780) 464-9564
Ontario & Central Canada, telephone: (001) 1-800-268-5850 and (001) (905) 822-
4222; fax: (001) 1-800-201-6285
Quebec & Eastern Canada, telephone: (001) 1-800-576-1686; fax: (001) 1-800-201-
6285

For Product Safety Information: (905) 804-4752

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.