—

Manual for installation and operation HB 605/10 en

Use of SF6 insulating gas in ZX Switchgear

Gas-insulated medium voltage switchgear
 Your safety first - always!

That‘s why our instruction manual begins with these recommendations:

− − Operate the switchgear as prescribed for its intended purpose.

−− Ensure that the technical data on the name plate and in the specification are not exceeded during operation of the switch-
gear.

− − Only install the switchgear in enclosed rooms suitable for electrical equipment.

− − With the aim of a smooth installation sequence and ensuring a high quality standard, have installation at site performed by
specially trained personnel or managed and supervised by the ABB Service Department.

− − Ensure that installation, operation and maintenance are only performed by specialist electricians familiar with this manual.

− − Comply in full with the legally recognized standards (IEC / DIN EN), the connection conditions of the local electrical utility
and the applicable safety at work regulations.

− − Follow the instructions in the documentation when performing any work on switching devices and switchgear.

− − Keep all documentation accessible to all persons concerned with installation, operation and maintenance.

− − The user’s personnel bear unlimited responsibility in all matters affecting safety at work and the correct handling of the
switchgear in accordance with EN 50110 and national regulations.

− − Always observe the five safety rules set out in EN 50110 on establishing and securing the off-circuit condition at the place
of work for the duration of work on the switchgear. Gas-insulated switchgear are notable for maximum safety, as the circuit-
breaker performs the earthing switch function in conjunction with the three position disconnector. The sequence of safety
rules therefore deviates from that proposed in the standard as follows:

Isolate,

Check the off-circuit condition,

Earth and short-circuit,

Secure to prevent reconnection,

Cover or guard off adjacent live

parts.

If you have any further questions on this manual, the members of our field organization will be pleased to provide the required infor-
mation.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 3

Content
Page

1.
General 6
1.1 General information on sulphur hexafluoride (SF6) 6
1.2 Influence of SF6 on the environment 6
1.3 Voluntary commitment 6
2.
Insulating gas systems of ZX switchgear 7
2.1 Switchgear type ZX0 block design 7
2.2 Switchgear type ZX0.2 8
2.3 Switchgear type ZX1.2 9
2.4 Switchgear type ZX2 10
2.5 Gas monitoring 11
2.5.1 Gas monitoring with density sensors 11
2.5.2 Gas monitoring with a pressure gauge 11
2.6 Drying agent 11
3 Handling sulphur hexafluoride (SF6) 12
3.1 Safety at work 12
3.2 Hazards to health 12
4 Gas work 13
4.1 General notes 13
4.2 Minimum requirements and the conditions for the certification of personnel recovering SF6 13
4.3 Delivery form of SF6 in gas cylinders 14
4.4 Notes on the filler neck 14
4.5 Topping up insulating gas 15
4.6 Removal of insulating gas 15
4.7 Filling compartments with insulating gas 16
4.8 Testing of insulating gas 16
4.9 Handling of the drying agent 16
5 Actions at the end of the switchgear service life 17
6 Technical data 18
6.1 Ratings 18
6.2 Insulating gas capacities 19
6.3 Number of drying agent bags 20
7 Sample works instructions 21

Appendix A Safety Data Sheet Sulphur Hexafluoride 24

4 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

This manual serves as a supplement to the manuals for ZX0 block Hazard warning, meaning in this manual that death
design, ZX0.2, ZX1.2 and ZX2 switchgear. It contains safety and or serious injury and considerable damage may oc-
environmental topics concerning the insulating gas and describes cur if the actions described are not performed.
the use of insulating gas and its handling.

Fundamental notes on this manual ? Important note, meaning in this manual that injury
and damage may occur if the actions described are
not performed.
Read the relevant sections of this manual through in full before
performing work, so as to ensure correct handling.

Paragraphs in this manual are marked in accordance with their

significance. The markings mean the following:

Take particular account of the relevant standards listed below. Observe the national technical specifications and the accident prevention
regulations of the country in which the switchgear is operated.

IEC 60376 Specification of technical grade sulphur hexafluoride (SF6) for use in electrical equipment

Guidelines for the checking and treatment of sulphur hexafluoride (SF6) taken from electrical equipment and
IEC 60480
specification for its re-use

High-voltage switchgear and controlgear –

IEC 62271-4
Use and handling of sulphur hexafluoride (SF6)

National technical accident prevention regulations e.g. for electrical systems and equipment, SF6 installations and requirements for pressurized gas
bottles.

REGULATION (EU) No 517/2014 Regulation on fluorinated greenhouse gases

Safety data sheet for sulphur hexafluoride

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 5

1 General 1.2 Influence of SF6 on the environment

ZX panels contain sulphur hexafluoride gas (chemical formula SF6) The high infrared absorption of SF6 and its long life in the environ-
as the insulating medium. After leakage testing and evacuation at ment are the reasons for its high GWP (Global Warming Potential),
the works, the gas compartments are filled with SF6 up to the rat- which, according to the latest IPCC Report (IPCC: Intergovern-
ed filling pressure for insulation, and delivered to site in that condi- mental Panel on Climate Change) is 22800 times higher than that
tion, where they can as a rule be installed without any gas work. of CO2 (carbon dioxide).

The gas compartments meet the requirements for sealed pressure The GWP of a greenhouse gas indicates the amount by which a
systems to IEC 62271-1. No further gas or vacuum treatment is certain quantity of the gas released into the atmosphere contrib-
necessary during the expected service life of the switchgear. The utes more or less strongly to the greenhouse effect than the same
leakage rate of the switchgear is less than 0.1 % per year. quantity of CO2. The GWP is based on the average warming effect
over a period of 100 years. CO2 has a GWP of 1.
The SF6 gas density in the gas compartments is permanently mon-
itored during operation of the switchgear by means of density sen- The total contribution of SF6 to the global greenhouse effect is ap-
sors 1) (= temperature-compensated pressure sensors) 2). In the prox. 0.2 %.
most unlikely event of leakage from a gas compartment, a signal
is issued when the warning signal for insulation level is reached The GWP of SF6 represents only one indicator of the environmen-
(see technical data). tal impact of electrical equipment containing SF6. Life Cycle As-
sessments 3) show that the use of equipment containing SF6 also
allows the CO2 emissions of the entire system to be reduced as a
result of the reduction in network losses.
1.1 General information on
sulphur hexafluoride (SF6)
1.3 Voluntary commitment

SF6 is an inorganic chemical compound of the elements sulphur

and fluorine. It is a non-toxic, colourless and odourless inert gas. ABB AG in Germany has, together with other manufacturers and
As SF6 is heavier than air it displaces the oxygen in the air if it is operators in the associations VIK, ZVEI and VDN which represent
inadvertently set free. The dielectric strength of SF6 is 2.5 times the power engineering industry in Germany, committed itself in a
that of air. It is therefore excellently suitable for use as an insulating voluntary agreement on electrical equipment > 1 kV in the Federal
gas in electrical equipment. Republic of Germany to avoiding SF6 emissions wherever pos-
sible. These agreements involve sustainable strategies, including
SF6 is approximately five times heavier than air and can accumu- responsible handling of equipment which contains SF6 during
late in low-lying spaces. If large quantities escape into the working installation, servicing, maintenance and decommissioning, and in
area, SF6 leads to a displacement of oxygen from the air people the entire process of return, recovery and reuse.
breathe (danger of asphyxiation). SF6 concentrations of over 19 %
by volume reduce the oxygen content of the air to below 17 % by The efforts of the industry are directed at maintaining a closed
volume and special protective measures are therefore required. life cycle. Especial importance is attached to the environmentally
sound recycling of the individual components of electrical equip-
The use of SF6 has made it possible to construct new, more ef- ment and to reuse of the normally reusable sulphur hexafluoride.
ficient switchgear. The change from conventional insulation to the All the businesses involved in the life cycle process must therefore
non-combustible, chemically inactive and non-toxic heavy gas comply with the voluntary commitment.
sulphur hexafluoride has led to considerable savings in space and
materials, and to greater safety of the systems. Recovered SF6 is as a rule either reused directly at site, or re-
turned in a closed system to the manufacturer for reuse.

1)
In the case of the ZX0 without auxiliary voltage, pressure gauges are used
2)
In accordance with EU Regulation 517/2014, leakage testing is not required when density sensors are used.
3)
E.g. the Life Cycle Assessment “SF6 GIS Technology in Power Distribution – Medium Voltage” by various manufacturers and operators of gas-insulated switchgear in 2003

6 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

2 Insulating gas systems of 2.1 Switchgear type
ZX switchgear ZX0 block design

The fundamental structure of the insulating gas system depends Several panel modules form a common gas compartment (figures
on the switchgear type. The insulating gas systems of switchgear 2.1.1 and 2.1.2). This block can consist of up to six panel mod-
types ZX0 in block design, ZX0.2, ZX1.2 and ZX2 are presented ules. Each block is equipped with a filler neck and a density sen-
below. sor or pressure gauge.
The busbars of the panel blocks are connected together at site by
means of plug-in busbar connectors, without any gas work being
required.

Fig. 2.1.1: Sectional view of an example panel in ZX0 block design

Panel module
(gas-filled)

Fig. 2.1.2: Gas diagram of an example ZX0 switchgear installation consisting of 2 panel blocks with 3 panels each

Panel block Legend

(gas-filled)
Density sensor /
pressure gauge

Filler neck

Gas partition

SF6 insulating gas

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 7

2.2 Switchgear type ZX0.2

The gas compartments of adjacent panels are not connected to-

gether (figures 2.2.1 and 2.2.2).
Each panel is equipped with a filler neck and a density sensor.

Fig. 2.2.1: Sectional view of an example ZX0.2 panel

Panel module
(gas-filled)

Fig. 2.2.2: Gas diagram of an example ZX0.2 switchgear installation

Panel module Legend

(gas-filled)
Density sensor

Filler neck

Gas partition
(plug-in busbar
sockets)

Insulating gas SF6

8 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

2.3 Switchgear type ZX1.2

The circuit-breaker compartment and the busbar compartment

each form separate gas compartments (figures 2.3.1 and 2.3.2)
and are filled and monitored by their own filler necks and density
sensors. The gas compartments of the individual panels erected
side by side are not connected together.

Fig. 2.3.1: Sectional view of an example ZX1.2 panel

Circuit-breaker
compartment
(gas-filled)

Busbar compartment
(gas-filled)

Fig. 2.3.2: Gas diagram of an example ZX1.2 switchgear installation

Busbar compartment
(gas-filled) Legend

Density sensor

Circuit-breaker Filler neck

compartment
(gas-filled) Gas partition
(plug-in busbar
sockets)

Insulating gas SF6

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 9

2.4 Switchgear type ZX2

Panels with one feeder and coupler panels Double feeder panels

The circuit-breaker compartment and the two busbar compart- The busbar compartment for the two feeders in a double feeder
ments each form separate gas compartments (figures 2.4.1 and panel is a continuous gas compartment extending over the panel
2.4.2) and are filled and monitored by their own filler necks and width of 800 mm. The two circuit-breaker compartments in a dou-
density sensors. The gas compartments of the individual panels ble feeder panel are two independent units.
erected side by side are not connected together.

Fig. 2.4.1: Sectional view of an example ZX2 panel (panel with one feeder)

Rear busbar Front busbar

compartment compartment
(gas-filled) (gas-filled)

Circuit-breaker
compartment
(gas-filled)

Fig. 2.4.2: Gas diagram of an example ZX2 switchgear installation, double busbar version

Panel with one feeder Double feeder panel

Rear busbar
compartment Legend
(gas-filled)
Density sensor

Front busbar Filler neck

compartment
(gas-filled) Gas partition
(plug-in busbar
Circuit-breaker sockets)
compartment
(gas-filled) Insulating gas SF6

10 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

2.5 Gas monitoring Fig. 2.5.1.1: Density sensor

2.5.1 Gas monitoring with

density sensors

Gas monitoring with density sensors (figure 2.4.1.1) is used in sys-

tems with auxiliary power supply. If the gas pressure falls below
the level for a warning signal, a signal to top up the insulating gas
is issued. In circuit-breaker systems the signal is displayed by a
warning lamp or on a panel control unit. In switch-disconnector
systems, the signal is displayed by a warning lamp.

Note that wire breakages, defective plug-in and terminal connec-

tions for the sensor and defective sensors will also lead to a signal.

When isolating systems for a relatively long period, maintain the

auxiliary power supply to monitor the insulating gas density.

2.5.2 Gas monitoring with pressure

gauges

Gas monitoring with pressure gauges (figure 2.5.2.1) is used in

systems of type ZX0 in block design without auxiliary power sup-
ply. The pressure gauges are located in the low voltage compart-
ment of the relevant panel and can be read even when the low Fig. 2.5.2.1: Pressure gauge with operating pressure diagram.1:
voltage compartment door is closed.

? Check the insulating gas pressure at regular inter-

vals. The insulating gas pressure must be within the
limits shown in the operating pressure diagram (in relation to
the temperature in the low voltage compartment).

? The pressure gauge is not temperature-compensat-

ed. Note that the temperature in the gas compart-
ment is assumed to be equal to the temperature in the low
voltage compartment. Deviations in temperature can lead to
inaccurate readings.

2.6 Drying agent

The gas compartments contain a drying agent in the form of dry-

ing agent bags. These are used to bind the residual moisture in
the gas compartments. The drying agent is maintenance-free.
Replacement of drying agent bags is only necessary when a gas
compartment has been opened for repair purposes.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 11

3 Handling sulphur hexafluoride (SF6) Do not enter the switchgear room when an arc fault
has occurred, or leave it immediately. Ventilate the
switchgear room sufficiently before entering it with-
out protective equipment.
3.1 Safety at work
Details of first aid procedures after inhaling or contact with SF6
decomposition products can be found in the technical report
Observe IEC 62271-4 and the accident prevention regulations IEC 62271-4.
issued by the relevant professional bodies. Keep these accident
prevention regulations accessible to all staff who perform work on Do not smoke, eat, drink or weld while performing cleaning work.
SF6 gas compartments.
Observe the requirements for wearing protective equipment as set
Compile instructions for work on SF6 gas compartments and out in IEC 62271-4 and national regulations.
display them at a clearly visible location in the switchgear room.
Sample instructions can be found at the end of this document.

Use the instruction sheets to instruct staff performing work on

SF6 gas compartments on the possible hazards and protection
required before they commence their activities and then at least
once each year.

3.2 Hazards to health

− − Pure SF6 is non-toxic, colourless and odourless.

− − The limit for SF 6 in air is 1000 ml / m3 or 6100 mg / m3.

− − Observe IEC 62271-4.

SF6 is around five times heavier than air. SF6 there-

fore displaces the oxygen in the air we breathe. It
can lead to a risk of asphyxiation in opened, non-
ventilated SF6 gas compartments, or when relatively large
quantities of SF6 escape from SF6 gas compartments or
pressure vessels and there is insufficient ventilation at the
floor level of constricted, enclosed switchgear rooms or
spaces beneath switchgear rooms, e.g. basements or cable
ducts. If SF6 accumulates in low-lying spaces, remove it im-
mediately.
Avoid generating heat, e.g. by smoking or performing welding
work, when handling SF6.

SF6 decomposition products are created by arc faults in an SF6

gas compartment. These decomposition products can be toxic or
hazardous to health when inhaled, swallowed or allowed to come
into contact with the skin, or can cause irritation or even possibly
acid burns to the eyes, respiratory organs or skin.

Decomposition products can be detected at an early stage by a

pungent, unpleasant odour (like rotten eggs).

12 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

4 Gas work increase in humidity in the gas compartment. Temporarily
apply drying agent in opened gas compartments during
any unavoidable extended breaks in work and seal the gas
compartments at least provisionally with plastic sheeting.
Panels of the ZX range are tested for gas-tightness at the works
(leakage rate measurement by the integrated leakage testing sys-
tem) and then filled with insulating gas. Topping up of insulating
gas during the expected service life of the switchgear is therefore 4.2 Training and certification of
not necessary.
personnel

As a result of the plug-in busbar technology, no gas work is re-
quired during installation at site in the majority of cases. Please note that under the terms of EU Regulation No. 517/2014,
certification is required for personnel who work on the SF6 system
Gas work during installation of the switchgear is only necessary in gas-insulated switchgear in the course of installation, servicing,
when maintenance and gas recovery.

− − heat sinks are used (panels with Ir > 2000 A and cooling That training and certification can be performed by our specialized
with heat sinks; the heat sinks are fitted at site and filled training departments.
with SF 6),

−− the panels have been transported by air freight,

−− application of integrated busbarmetering equipped with

isolating device at ZX2-switchgear.

4.1 General notes

− − We recommend calling in ABB after-sales service personnel

for work in gas compartments.

− − Never discharge SF6 into the atmosphere.

− − Replacement of the insulating gas in the system is not nec-

essary. SF 6 can be considered as good as new even after
long periods of use as an insulating gas.

−− A two stage vacuum pump with a delivery of at least

6 m 3 / h is required for evacuation of a gas compartment
prior to filling with insulating gas.

−− An SF 6 gas filling unit is required for filling and topping up

the insulating gas.

− − A leakage tester and a dew point measuring instrument are

required for filling of insulating gas when the gas compart-
ment has previously been opened.

− − A gas service unit with the facility for recovery of the gas is
required for removal of SF 6.

− − Protect the gas hoses on the equipment from moisture.

Use hose fittings with non-return necks to prevent the in-
gress of humid air into the hoses. Close off the hose fittings
with caps after use.

− − Limit the ingress of ambient air during work on emptied

and opened gas compartments so as to minimize any

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 13

4.3 Delivery form of SF6 in gas 4.4 Notes on the filler neck
cylinders
Figure 4.4.1 shows the filler neck with protective cap. The protec-
If required in exceptional cases, SF6 is delivered in liquid form in tive cap can be unscrewed by turning it counter-clockwise (figure
pressure vessels (gas cylinders). Only use SF6 which complies 4.4.2).
with IEC 60376 or IEC 60480. Handle, store and use the gas ves-
sels in accordance with IEC 62271-4 and the local regulations.

A gas analysis is available for every gas delivery.

? Do not press the valve pin (2) (Fig 4.4.2) in, as gas
would flow out of the neck.

Store the pressurized gas vessels in a dry, clean place protected A coupling is necessary to connect a hose to the filler neck (figure
from direct sunlight at a maximum temperature of 50 °C. If tem- 4.4.3). The coupling has an M 24 x 1.5 thread. Different adapters
peratures of over 50 °C cannot be ruled out during storage or for other connection systems are available on request.
transport, order gas vessels with a correspondingly reduced filling
factor.

As a rule, no deliveries of gas cylinders are required.

Fig. 4.4.1: Filler neck (1) with protective cap (2) Fig. 4.4.3: Filler neck with coupling for hose connection

1
1 2 3 4 5

1 Filler neck
2 Locking ring
3 Coupling
4 M 24 x 1.5 thread
5 Union nut on the hose set

Fig. 4.4.2: Filler neck, protective cap removed

1 Filler neck
2 Protective cap
3 Valve pin

14 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

4.5 Topping up insulating gas − − Remove the filling hose. To do this, pull the coupling piece
from the filler neck by pulling the locking ring.

− − Finally refit the protective cap to the filler neck.

Erection of the switchgear

If the panels are to be transported by air freight (an exceptional

case), the gas compartments are delivered with a reduced SF6 4.6 Removal of insulating gas
pressure. In such cases, the pressure is to be increased to the
rated filling pressure prior to installation of the panels.
Removal of insulating gas from the gas compartments in the
Switchgear in service switchgear system is only necessary

It is not necessary to top up the insulating gas during the expect- − − before repair work inside a gas compartment, and
ed service life of the system. Should a pressure loss signal never-
theless be issued, the following procedure is to be adopted: − − at the end of the service life of the switchgear.

−− Record the time of the pressure loss signal. SF6 must never be discharged into the atmosphere. The gas can
be removed, tested and stored using a gas recovery unit.
−− Clarify the cause of the pressure loss signal. A pressure
loss signal may also result from a defective electrical Procedure
connection in the secondary circuit or a defective density
sensor. − − Connect the hose of the gas recovery unit to the coupling
(figure 4.4.3).
−− According to EU Regulation 517/2014, repairs are to
be made in the case of leakage. Notify the ABB service − − Unscrew the protective cap from the filler neck (figure
department immediately and agree the further action to be 4.4.2). A fastening cord prevents the cap from being lost.

?
taken.
Do not press the neck pin in, as gas would flow out
−− Note: Temporary operation of the panels at atmospheric of the neck!
pressure is in principle possible if the SF6 content of the
insulating gas is at least 95 %. (Exceptions: double feeder − − Fit the coupling (figure 4.4.3) to the filler neck by turning
panels with a rated voltage of 24 kV, panels with a rated the locking ring until it stops and pressing the coupling
voltage of 40.5 kV, switching of the switch-disconnector onto the filler neck.
and panels with switch-disconnectors and fuses. See sec-
tion 6.1.) − − Test the gas, remove and store it in accordance with the
operating instructions for the gas recovery unit.
Topping up the insulating gas
− − Remove the filler hose. In that process the locking ring is to
−− Connect the hose of the gas filling unit to the coupling be turned and the coupling withdrawn from the filler neck.
(figure 4.4.3).
− − Finally refit the protective cap to the filler neck.
−− Unscrew the protective cap from the filler neck (figure
4.4.2). A fastening cord prevents the cap from being lost.

? Do not press the neck pin in, as gas would flow out
of the neck!

− − Pull the locking ring (figure 4.4.3) of the coupling piece,

press the coupling piece onto the filler neck and slide the
locking ring in the direction of the filler neck.

− − Allow the insulating gas to flow into the gas compartment

as described in the operating instructions for the SF 6 gas
filling unit used. The required filling pressure is equivalent to
the rated filling pressure for insulation.

−− Monitor the pressure rise during the topping up process.

Perform the checks during temporary interruptions to the
gas feed.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 15

4.7 Filling compartments with 4.8 Testing of insulating gas
insulating gas
We recommend you to conduct dew point measurement of the
Filling of individual gas compartments with insulating gas is only insulating gas after gas work at site. The dew point measurement
necessary can take place during operation of the panel concerned, and
should be performed a few weeks after filling it with gas. After that
− − after fitting of heat sinks and/or to-mounted boxes for the period, a constant gas humidity has been established.
busbar metering system with isolating device at ZX2 and
Use dew point measuring instruments with return lines for the SF6
− − after repair work inside a gas compartment. to avoid emissions of SF6 into the atmosphere.

The air or the N2 transport gas is removed from the gas compart- Testing of the insulating gas is not necessary during normal opera-
ment. The gas compartment concerned can be filled with SF6 at a tion of the ZX switchgear.
pressure of ≤ 1 kPa (= 10 mbar).
Procedure for dew point measurement
New drying agent must always be used in the gas compartments
when they are filled with insulating gas (see section 4.9). Connect the filler neck of the gas compartment to a dew point
measuring instrument. Determine the dew point of the gas as de-
Procedure scribed in the operating instructions for the measuring instrument.

−− Pull the locking ring (figure 4.4.3) of the coupling piece, In connection with the operating conditions for indoor switch-
press the coupling piece onto the filler neck and slide the gear, the dew point must not exceed a value of -5 °C. For safety
locking ring in the direction of the filler neck. reasons, we recommend a maximum value for the dew point of
-15 °C.
−− Unscrew the protective cap from the filler neck (figure
4.4.2). A fastening cord prevents the cap from being lost.

−− Fit the coupling (figure 4.4.3) to the filler neck by pulling the 4.9 Handling of the drying agent
locking ring on the coupling back and pressing the cou-
pling onto the filler neck.
Replacement of drying agent bags is not necessary while the
−− Evacuate the gas compartment to a pressure of ≤ 1 kPa switchgear is in service.
(= 10 mbar). Perform pressure measurements during the
evacuation process with the pump or hose necks tempo- Replace the existing drying agent bags after work in opened gas
rarily closed. Leave the pump switched on for a further 30 compartments. Consult the tables in section 6.3 for the number of
minutes. drying agent bags.

− − Connect an SF6 gas filling unit to the filler neck in place of Replace the drying agent bags immediately before sealing the gas
the vacuum pump. compartment. Fill the gas compartment with SF6 immediately after
sealing.
− − Allow the SF 6 to flow into the gas compartment as de-
scribed in the operating instructions for the SF6 gas filling Notes:
unit used. The required filling pressure is equivalent to the
rated filling pressure for insulation. − − The drying agent bags are heat-sealed in film to protect
them from moisture. An indicator inserted in the protective
−− Remove the filling hose. To do this, pull the coupling piece bag shows the moisture content, as follows:
from the filler neck by pulling the locking ring.
− − When the indicator is blue in colour, the drying agent
−− Refit the protective cap to the filler neck. bags are dry and usable.

− − Carefully check the tightness of the gas compartment and − − When the indicator is pink in colour, the drying agent
the filler necks with a gas leakage tester. The scanning bags are moist and not usable.
speed should not exceed 1-2 cm / s.

16 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

− − Only open the protective bags immediately before the dry-
ing agent bags are to be placed in the gas compartment.

− − Drying agent bags which have not been contaminated

with SF6 decomposition products can be disposed of as
residual waste.

− − Follow the regulations of the responsible local authorities

when disposing of drying agent bags which are contami-
nated with SF 6 decomposition products.

5 Actions at the end of the switchgear

service life

SF6 must never be discharged into the atmosphere.

ABB can be appointed to decommission and dismantle the

switchgear. The switchgear system is then professionally disman-
tled by ABB and the SF6, which is normally reusable, removed
before the switchgear is broken down into its remaining com-
ponents. In ZX systems, the SF6 can be removed at site after
decommissioning with appropriate equipment connected to the
filler necks. If it complies with IEC 60480 (DIN EN 60480) standard
after removal, it can be directly reused by the operator. If it is in
accordance with the gas manufacturer’s “Re-use Specification”
according to IEC 62271-4, it can be returned to ABB or the gas
manufacturer as a product.

Drying agent bags which have not been contaminated with SF6
decomposition products can be disposed of as residual waste.

If there are discernible signs of discharges in the gas compart-

ment (e.g. white dust on surfaces) or if switches other than
vacuum switching devices are used in the gas compartment, it is
to be assumed in the case of doubt that the drying agent bags are
contaminated by decomposition products.

Follow the regulations of the responsible local authorities when

disposing of drying agent bags which are contaminated with SF6
decomposition products.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 17

6 Technical data

6.1 Ratings

The following table applies to all ZX0 block design, ZX1.2 and ZX2
panel types.

Table 6.1.1: ZX0, ZX1.2, ZX2 Ratings

> 1000
Site altitude m ≤ 1000
(only ZX2)
Rated voltage Ur kV ...24 ...36 ...40.5 ...36
Alarm level for insulation pae kPa 1) 2)
120 100
Rated filling level for insulation p re kPa 130 110
Minimum functional level for insulation 3)
pme kPa 120 100
Minimum functional level for operation 4)
pmm kPa 120
- -
Rated filling level for switch 4)
psw kPa 130
Insulating gas density, relative to the rated filling level for insulation g / dm3 7.9 6.7
Dew point service level °C ≤ -5 5)

Response level of pressure relief system kPa > 200 > 200
Set points of the density sensors
(= temperature-compensated pressure sensors)
Lower threshold (= alarm level for insulation) pae kPa 120 100
Upper threshold for optional rapid shutdown kPa 190 170

The following table applies to all ZX0.2 panel types.

Table 6.1.2: ZX0.2 Ratings

Site altitude m ≤ 1000 > 1000

Rated voltage Ur kV ...24 ...36 ...24

Alarm level for insulation pae kPa 1) 2)
120 6)
140 100
Rated filling level for insulation pre kPa 130 7)
150 110
Minimum functional level for insulation 3)
pme kPa 120 140 100
Minimum functional level for operation 4)
pmm kPa 140
- -
Rated filling level for switch 4)
psw kPa 150
Insulating gas density, relative to the rated filling level for insulation g / dm 3 7.9 8)
9.1 6.7
Dew point service level °C ≤ -5 5)

Response level of pressure relief system kPa > 240

Set points of the density sensors
(= temperature-compensated pressure sensors)
Lower threshold (= alarm level for insulation) pae kPa 120 6)
140 100
Upper threshold for optional rapid shutdown kPa 190 9)
210 170

1)
All pressures stated are absolute pressures at 20 °C
2)
100 kPa = 1 bar
3)
Some ratings and panel variants allow the lower minimum lever of 100 kPa in case the SF6 content is unchanged despite a leakage.
4)
Only relevant to three position switch disconnector (ZX0)
5)
We recommend: ≤ -15 °C.
6)
Panels with three position switch disconnector: 140 kPa
7)
Panels with three position switch disconnector: 150 kPa
8)
Panels with three position switch disconnector: 9.1 g / dm3
9)
Panels with three position switch disconnector: 210 kPa

18 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

6.2 Insulating gas capacities

The insulating gas capacities stated below are maxi-

mum capacities. The actual values vary according to
the equipment fitted in the panels. The exact capaci-
ties can be found in the test records for the panels
supplied.

Table 6.2.1: Insulating gas capacities for switchgear type ZX0 block design
Panel width [mm] 400 600
Gas weight [kg] 1)

Panel module 1.4 2.7

Table 6.2.2: Insulating gas capacities for switchgear type ZX0.2

600
(panels with three
Panel width [mm] 450 600 position switch 900 1200
disconnector and
fuses)

Gas weight [kg] 1)

Rated voltage: ... 24 kV 2.4 3.5 3.9 4.5 6.9

Panel module
Rated voltage: ... 36 kV - 4.0 - 5.2 8.0

Table 6.2.3: Insulating gas capacities for switchgear type ZX1.2

Top of floor topping to top of
- 1800 2070
circuit-breaker compartment [mm]
Panel width [mm] 2 x 400 1)
600 800 600 800
Gas weight [kg] 1)

Panel depth 1300 mm 2.2 2.9 3.2 4.3

Circuit-breaker-
Panel depth 1500 mm 2 x 1.6 2.7 3.6 4.0 4.5
compartment
Panel depth 1800 mm 4.6 6.9
Busbar compartment 2.5 1.9 2.6 1.9 2.6
Heat sink, low (Height 210 mm) 0.3
Heat sink, high (Height 670 mm) 1.1

Table 6.2.4: Insulating gas capacities for switchgear type ZX2

Panel width [mm] 2 x 400 2)
600 800
Gas weight [kg] 1)

Circuit-breaker-compartment 2 x 2.0 3.4 4.6

Busbar compartment I 2.2 1.7 2.3
Busbar compartment II 2.2 1.7 2.3
Heat sink circuit-breaker-compartment 0.7
Heat sink busbar compartment 1.4

1)
The CO2 equivalent masses in metric tons can be calculated by multiplying the SF6 gas capacities (in kg) by 22.8.
2)
Double feeder panel with two outgoing feeders

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 19

6.3 Number of drying agent bags

Table 6.3.1: Number of drying agent bags for switchgear type ZX0 block design
Number of panel modules Number of drying agent bags
1 and 2 1
Block design 3 and 4 2
5 and 6 3

Table 6.3.2: Number of drying agent bags for switchgear type ZX0.2
Panel width [mm] 450 600 900 1200
Number of drying agent bags
2 1 2 2 1)

Table 6.3.2: Number of drying agent bags for switchgear type ZX1.2
Top of floor topping to top of circuit-breaker
- 1800 2070
compartment [mm]
Panel width [mm] 2 x 400 2)
600 800 600 800
Number of drying agent bags
Panel depth 1300 mm 2 2 3 3
Circuit-breaker
Panel depth 1500 mm 2x2 2 2 4 4
compartment
Panel depth 1800 mm 2 5
Busbar compartment 1 1 1 1 1

Table 6.3.4: Number of drying agent bags for switchgear type ZX2
Panel width [mm] 2 x 400 2)
600 800
Number of drying agent bags
Circuit-breaker compartment 2x2 4 1)
5 1)

Busbar compartment I 1 1 1
Busbar compartment II 1 1 1

1)
Maximum number; quantity dependent on equipment fitted.
2)
Double feeder panel with two outgoing feeders

20 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

7 Sample works instructions

The sample works instructions shown are intended to serve as examples for the compilation of instructions in your company. Adjust-
ments to national technical standards and the accident prevention regulations of the country in which the switchgear is operated might
be necessary.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 21

Fig. 7.1: Sample work instruction, “Handling of uncontaminated SF6”

Works department: Work Instruction Issue date:

Working area:
Work place:
Responsible Person: Activity: Handling of uncontaminated SF6
Sign

HAZARDOUS MATERIAL DESIGNATION

Sulphur hexafluoride (SF6)

HAZARDS TO PERSONS AND THE ENVIRONMENT

Uncontaminated SF6 is odourless, tasteless, colourless and non-toxic. It contains no contaminants

which are harmful to health. On contact with liquid SF6 there is a risk of freeze burns.

SF6 is approximately five times heavier than air, and can accumulate in low-lying spaces. If a large quan-
tity escapes into the working environment, SF6 displaces the oxygen in the air people breathe (danger
of asphyxiation). SF6 is a greenhouse gas, and emissions of SF6 are therefore to be avoided.

PROTECTIVE MEASURES AND RULES OF BEHAVIOUR

Do not discharge SF6 into the atmosphere.

Use an SF6 servicing unit with ___________ filler system.

Check the connections for gas-tightness.

Work which generates strong heat, e.g. welding, is prohibited.

Do not smoke, eat, drink or store foodstuffs in the switchgear room.

Protect your hands: Wear protective gloves to avoid physical injury and contact with
liquid gas.

PROTECTIVE ACTION AND RULES OF BEHAVIOUR

Leakage: Turn off the gas supply. Ensure that necks and connections are tight and ventilate the
room well with fresh air.
SF6 does not burn, but fire will create decomposition products. Wear protective equipment when
firefighting.
Move cylinders/equipment out of the hazard zone or cool them.

FIRST AID

For all first aid actions: Ensure that you yourself are adequately protected, and contact a doctor
immediately.
On inhalation: Provide fresh air immediately. Lay the person in an inclined position with the head
downwards, and if they have breathing problems ensure they receive medical treatment.

First Aid staff_______________________ Emergency tel.: ________________________

CORRECT DISPOSAL

Return to the manufacturer if necessary.

22 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

Fig. 7.2: Sample works instruction, “Handling of contaminated SF6”

Works department: Work Instruction Issue date:

Working area:
Work place:
Responsible Person: Activity: Handling of contaminated SF6
Sign

HAZARDOUS MATERIAL DESIGNATION

Sulphur hexafluoride (SF6) with decomposition products (contaminated SF6)

SF6 in electrical systems may contain decomposition products – gaseous sulphur fluorides and
sulphur oxyfluorides, solid (dust-form) metal fluorides, sulphides and oxides, hydrofluorides and
sulphur dioxide – as a result of arcing effects.

HAZARDS TO PERSONS AND THE ENVIRONMENT

−− Decomposition products can be toxic or hazardous to health on inhalation, swallowing

or contact with the skin or eyes. They can irritate the respiratory organs or skin or cause
acid burns. On inhalation of large quantities there is a risk of lung damage (pulmonary
oedema) which may only become apparent at a much later date.
− − On escape of gas, there is a danger of asphyxiation due to displacement of oxygen,
especially at floor level and in deeper spaces.

PROTECTIVE MEASURES AND RULES OF BEHAVIOUR

Filling, emptying or evacuation of SF6 systems:
−− Check the condition of the SF6 (e.g. humidity, proportion of air, decomposition products).
− − Do not discharge SF 6 into the atmosphere. Use servicing equipment and check the con-
nection for tightness after connecting.
−− Only channel contaminated SF 6 into marked SF6 pressure vessels.
−− Work generating strong heat and smoking are prohibited in the system room.
Opening of and working on or in opened SF6 gas compartments
(additional measures; please complete and delete where not applicable)
−− Only open SF6 gas compartments after complete emptying and equalization with atmos-
pheric pressure.
− − Use personal protective equipment:
Protective gloves, acid resistant Disposable goggles
Protective overalls with hood Overshoes
Breathing mask (filter or closed-circuit type) Skin protection
Safety shoes Helmet
−− Remove dust with industrial vacuum cleaner ______________________ .
− − Remove adhering decomposition products with _______________________.
− − Before breaks and after work, thoroughly clean the face, neck, arms and hands with
large amounts of water.
− − Do not store foodstuffs or smoke, eat or drink in the system room.

PROTECTIVE ACTION AND RULES OF BEHAVIOUR

On escape of gas or perception of an unpleasant, pungent odour (like rotten eggs) indicating SF6
decomposition products, immediately leave or do not enter the system room or spaces below.
Only re-enter the room after thorough ventilation or with breathing apparatus (isolating equipment
___________________).

FIRST AID

−− When decomposition products come into contact with the skin or eyes, immediately rinse
the skin with ample water,
− − Thoroughly rinse the eye with water, covering the unaffected eye.
−− Move persons with breathing difficulties out of the hazardous area into the fresh air,
ensure they rest, cover them with blankets and call in a doctor (risk of toxic pulmonary
oedema).
− − First Aid staff_______________________ Emergency tel.: ________________________

CORRECT DISPOSAL

−− Only dispose of decomposition products, cleaning fluids and materials, disposable

overalls and filters (e.g. from SF6 systems, maintenance units, industrial vacuum clean-
ers or breathing masks) in __________________________________ waste containers.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 23

Appendix A SAFETY DATA SHEET
(to Directive 2001/58/EG)

SULPHUR HEXAFLUORIDE
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

1.1. Identification of the substance/preparation

Product name : SULPHUR HEXAFLUORIDE
Chemical name : Sulphur hexafluoride
Molecular formula : SF6
Molecular weight : 146 g/mol

1.2. Use of the Substance/Preparation

Recommended use : - Electrical industry

- Metallurgy
1.3. Company / Undertaking Identification
Adress : SOLVAY FLUOR GmbH
HANS-BOECKLER-ALLEE 20
D- 30173 HANNOVER
Tel. : +495118570
Fax : +495118572146

1.4. Emergency and contact telephone numbers

Emergency telephone : +44(0)208 762 8322 [CareChem 24] Europe)

E-mail-adress : sdstracking@solvay.com

2. HAZARDS IDENTIFICATION

Appearance : compressed liquefied gas

Colour : colourless
Odour : odourless

−− This substance is not classified as dangerous according to Directive 67/548/EEC..

−− Hazardous decomposition products formed under fire conditions.
−− Gaseous hydrogen fluoride(HF)

3. COMPOSITION / INFORMATION ON INGREDIENTS

Substance name Concentration Classification R-phrase(s)

(CAS-Nr./ EG-Nr./ Anhang-1 (W/W)

Sulphur hexafluoride ≥ 99,9%

(2551-62-4 / 219-854-2) / --

24 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

4. FIRST AID MEASURES

4.1. Inhalation
−− Remove to fresh air
−− Oxygen or artificial respiration if needed.
−− If symptoms persist, call a physician.

4.2. Eye contact

−− K eep eyelids open to allow evaporation of product.
−− Rinse thoroughly with plenty of water, also under the eyelids.
−− -If eye irritation persists, consult a specialist.

4.3. Skin contact

−− Allow to evaporate.
−− Rinse with lukewarm running water.
−− If symptoms persist, call a physician.

4.4. Ingestion
−− Not applicable

5. FIRE-FIGHTING MEASURES

5.1. Suitable extinguishing media

−− Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Extinguishing media which shall not be used for safety reasons
−− None.

5.3. Special exposure hazards in a fire

−− The product is not flammable.
−− Heating can release hazardous gases.

5.4. Special protective measures equipment for fire-fighters

−− Wear self-contained breathing apparatus and protective suit.
−− Fire fighters must wear fire resistant personnel protective equipment.
−− Wear chemical resistant oversuit
−− Protect intervention team with a water spray as they approach the fire.
−− Clean contaminated surface thoroughly.

5.5. Other information

−− Approach from upwind.
−− Evacuate personnel to safe areas.
−− Keep containers and surroundings cool with water spray.
−− After the fire, proceed rapidly with cleaning of surfaces exposed to the fumes in order to limit equipment damage.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 25

 6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions

− − Refer to protective measures listed in section 7 and 8
− − Approach from upwind.
− − Suppress (knock down) gases/vapours/mists with a water spray jet.
− − Avoid spraying the leak source.
− − Try to re-position leaking containers, to have the leak in the gaseous phase.
− − Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.
− − Prevent further leakage or spillage if safe to do so.
− − Keep away from open flames, hot surfaces and sources of ignition.
− − K eep away from incompatible products

6.2. Environmental precautions

− − Should not be released into the environment.

6.3. Methods for cleaning up

− − Allow to evaporate.
−− Prevent product from entering drains.

7. HANDLING AND STORAGE

7.1. Handling
− − Used in closed system
− − Use only in well-ventilated areas.
− − Use only equipment and materials which are compatible with the product.
− − Prevent product vapours decomposition from contacting hot spots.
− − Never return unused material to storage receptacle.
− − Keep away from incompatible products
− − Keep away from heat.

7.2. Storage
− − Keep in a cool, well-ventilated place.
− − Keep away from heat and sources of ignition.
− − Keep container tightly closed.
− − Store in original container.
− − Keep away from incompatible products.

7.3. Special use(s)

− − For further information, please contact: Supplier

7.4. Packaging material

− − Steel drum

7.5. Other precautions

− − Refer to protective measures listed in sections 7 and 8.

26 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Exposure Limit values

Sulphur hexafluoride

−− UK. EH40 Workplace Exposure Limits (WELs) 2005

time weighted average = 1,000 ppm
time weighted average = 6,070 mg / m3
−− UK. EH40 Workplace Exposure Limits (WELs) 2005
Short term exposure limits = 1,250 ppm
Short term exposure limits = 7,590 mg / m3
−− US. ACGIH Threshold Limit Values 01.2006
time weighted average = 1,000 ppm

8.2. Exposure controls

−− Provide appropriate exhaust ventilation at machinery.

−− Apply technical measures to comply with the occupational exposure limits.
−− Refer to protective measures listed in sections 7 and 8.

8.2.1. Occupational exposure controls

8.2.1.1. Respiratory protection
−− Self-contained breathing apparatus in medium confinement/insufficient oxygen/ in case of large
uncontrolled emissions/in all circumstances when the mask and cartridge do not give adequate
protection.
− − Use only respiratory protection that conforms to international/ national standards.
− − In the case of vapour formation use a respirator with an approved filter.

8.2.1.2. Hand protection

− − Take note of the information given by the producer concerning permeability and
break through times, and of special workplace conditions (mechanical strain, duration of contact).
− − Protective gloves
− − Heat insulating gloves
−− Suitable Material : PVC, Neoprene, Natural Rubber

8.2.1.3. Eye protection

−− Chemical resistant goggles must be worn.
− − If splashes are likely to occur, wear:
−− Face-shield

8.2.1.4. Skin and body protection

−− Wear suitable protective clothing.
− − In case of contact through splashing:
−− Apron
− − Boots
− − Neoprene

8.2.1.5. Hygiene measures

− − Use only in an area equipped with a safety shower.
− − Eye wash bottle with pure water
− − When using do not eat, drink or smoke.
−− Gloves, overalls and boots have to be double layered (protection against cold temperature).
− − Handle in accordance with good industrial hygiene and safety practice.

8.2.2. Environmental exposure controls

−− Dispose of rinse water in accordance with local and national regulations.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 27

 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. General information (appearance, odour)

Form : Compressed liquefied gas
Colour : colourless
Odour : odourless

9.2. Important health, safety and environment information

pH : Remarks: neutral
Boiling point/boiling range : -63,8 °C
Remarks: Sublimation point
Flash point: : Remarks: does not flash
Flammability : Remarks: This product is not flammable.
Explosive properties : Explosion danger:
Remarks: See section 10
Oxidizing properties : Remarks: Non oxidizer
Vapour pressure : 21.4 bar
Temperature: 20 °C
: 37.1 bar
Temperature: 45 °C
Relative Density / Density : 1.56

Solubility : Water
0.04 g / l
Remarks: slightly soluble
Temperature: 20 °C
: Alcohol
: Ether
Partition coefficient log P o/w
n-octanol/water : 1.68

Vapour density (air = 1) : 5.1

9.3. Other data

Freezing point : -50.8 °C

Decomposition temperature 200 °C
Remarks: Decomposition under influence of moisture is highly accelerated by
heating.
800 °C
Remarks: Dry air

10. STABILITY AND REACTIVITY

10.1. Stability
−−Stable under recommended storage conditions.
−−Vapours are heavier than air and may spread along floors.
−−Hazardous Polymerisation/Polymerization: no

10.2. Conditions to avoid
− −Heat

10.3. Materials to avoid

− −Oxidizing agents

10.4. Hazardous decomposition products

−−Gaseous hydrogen fluoride (HF)., Sulphur dioxide, Sulphur compounds

28 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

11. TOXICOLOGICAL INFORMATION

11.1. Toxicological data

Acute inhalation toxicity

−− NOEC, 24 h, rat, > 4.777 g / l

Acute dermal toxicity

−− LC50, Remarks: not applicable

Skin irritation
−− Rat, no skin irritation

Eye irritation
−− Rat, no eye irritation

Sensitisation
−− No data available

Irritation (other route)

−− No irritation signs noted during toxicity testing.

Chronic toxicity
−− Inhalation, Prolonged exposure, Human experience, no observed effects

Genetic toxicity in vitro

−− In vitro tests did not show mutagenic effects

Possible hazards (summary)

−− Health injuries are not known or expected under normal use

11.2. Health Effects

Inhalation
−− Symptoms: narcosis.
−− (in case of higher concentration): Asphyxia.

Eye contact
−− gas
−− Irritation
−− Liquefied gas
−− Severe eye irritation
−− Lachrymation
−− Redness
−− Swelling of tissue
−− Frostbite
−− Causes burns

Skin contact
−− Gas
−− None
−− Liquefied gas
−− Cold sensation followed by redness of the skin.
−− Frostbite.
−− Prolonged skin contact may defat the skin and produce dermatitis

Ingestion
−− gas
−− not applicable

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 29

 12. ECOLOGICAL INFORMATION

12.1. Ecotoxicity

Acute toxicity
− − Remarks: no data available

12.2. Mobility
−− Air, Henry’s law constant (H) = 452 kPa . m3 / mol
Conditions: calculated value
Remarks: considerable volatility
−− Soil/sediments
Remarks: Non-significant adsorption.
− − Water, Evaporates, t 1/2 = 3.5 h
Conditions: calculated value

12.3. Persistence and degradability

Abiotic degradation
−− Air, t 1/2 > 1000 years
Result: not significant photolysis
−− Water/soil, t 1/2 > 1000 years
Result: Non significant hydrolysis

Biodegradation
The methods for determining biodegradability are not applicable to inorganic substances.
− Remarks:
−

12.4. Bioaccumulative potential

−− Bioconcentration: Bioconcentration factor (BCF) = 89
Remarks: Calculated value

12.5. Other adverse effects

−− Global Warming Potential
= 23,900
Remarks: GWP (ITH 100 y), Source IPCC (International Panel on Climate Change)

12.6. Possible hazards (summary)

−− This product has no known eco-toxicological effects.
−− Product is persistent in air.
−− Other dangerous properties can not be excluded.

13. DISPOSAL CONSIDERATIONS

13.1. Waste from residues / unused products

−− In accordance with local and national regulations.
−− Refer to manufacturer/supplier for information on recovery/recycling.

13.2. Packaging treatment

−− To avoid treatments, as far as possible, use dedicated containers.

30 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

14. TRANSPORT INFORMATION

UN-Number 1080

IATA-DGR
Class 2,2
ICAO-Labels NON-FLAMMABLE COMPRESSED GAS
Proper shipping name: SULPHUR HEXAFLUORIDE

IMDG

Class 2,2
IMDG-labels NON-FLAMMABLE COMPRESSED GAS
HI/UN-No. 1080
EmS: F-C,S-V
Proper shipping name: SULPHUR HEXAFLUORIDE

ADR
Class 2
ADR/RID-Labels 2,2
HI/UN-Nr. 20/1080
Proper shipping name: SULPHUR HEXAFLUORIDE

15. REGULATORY INFORMATION

15.1. EG-Label
−− This substance is not classified as dangerous according to Directive 67/548/EEC.

15.2 Inventory Informations

Australian Inventory of Chemical Sustances : - In compliance with inventory

Canadian Domestic SubstancesList (DSL) : - In compliance with inventory
Inventory of Existing Chemical Substances (China)(IECS) : - In compliance with inventory
Japan (ENCS) List (ENCS((JP)) : - In compliance with inventory
New Zealand Single ComponentSub. List (NZ CLSC) : - In compliance with inventory
Toxic Substance Control Act -Liste (TSCA) : - In compliance with inventory
Liste der EU-Altstoffe (EINECS) : - In compliance with inventory
Korea Existing Chemicals Inv. (KECI) (KECI(KR)) : - In compliance with inventory
Philippines PICCS (PICCS (PH)) : - In compliance with inventory

15.3. Other regulations

−− European Waste Catalogue, Decision (2000/532/EC), Hazardous waste, Waste codes should be assigned by the user
based on the application for which the product was used.

Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10 | 31

 16. OTHER DETAILS

16.1. Administrative information

− −General revision
−−Distribute new edition to clients

This SDS is only intended for the indicated country to which it is applicable. The European SDS format compliant with the applicable
European legislation is not intended for use nor distribution in countries outside the European Union with the exception of Norway and
Switzerland. Safety data sheets applicable in other countries/regions are available upon request. The information given corresponds
to the current state of our knowledge and experience of the product, and is not exhaustive. This applies to product which conforms
to the specification, unless otherwise stated. In this case of combinations and mixtures one must make sure that no new dangers can
arise. In any case, the user is not exempt from observing all legal, administrative and regulatory procedures relating to the product,
personal hygiene, and protection of human welfare and the environment.

32 | Manual: Use of SF6 insulating gas in ZX-switchgear HB 605 en - Revision 10

For your notes…
 1VB680605P0102 REV 10 - Februar 2018

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potential errors or possible lack of infor-
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