0620 s13 Ms 32 PDF
0620 s13 Ms 32 PDF
0620 s13 Ms 32 PDF
0620 CHEMISTRY
0620/32 Paper 3 (Extended Theory), maximum raw mark 80
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners’ meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2013 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2 Mark Scheme Syllabus Paper
IGCSE – May/June 2013 0620 32
(ii) measure volume at room temperature / gas has different volumes at different
temperatures / volume of gas depends on temperature / hot gas has higher volume /
heat causes expansion (of gases) / ORA [1]
(iii) no oxygen left or all the oxygen has reacted (with copper) [1]
2 (a) B 39
19 K [1]
positive charge + [1]
65
C 30 Zn [1]
D 168 O [1]
charge 2– [1]
70
E 31 Ga [1]
oxygen [1]
second reaction
volume / moles / molecules of reactants and products are the same [1]
or 2H3O+ + 2e → H2 + 2H2O
accept: –2e on right hand side accept: e–
note: not balanced = 1
cond: making soap / degreasing / making paper / detergents / bio-diesel / paint stripper /
clearing drains / alumina from bauxite / oven cleaner / bleach [1]
(c) glucose two products (polymer and water) / condensation (polymerisation) / (small)
molecules removed [1]
6 (a) (i) ions cannot move / no free ions in solid state [1]
ions can move / free ions in liquid state [1]
note: ions can only move in liquid state = 2
(ii) reduce melting point / reduce energy costs / better conductor when dissolved in cryolite
[1]
(iii) burns in oxygen / reacts with oxygen / oxidised by oxygen / forms carbon dioxide / forms
carbon monoxide [1]
(ii) two correct ester linkages, e.g. –OOC / –O2C and –COO / –CO2 [1]
8 (a) (i) (the number of particles which is equal to the number of atoms in) 12 g of carbon 12
or
the mass in grams which contains the Avogadro’s constant number of particles
or
Avogadro’s constant or 6 to 6.023 × 1023 of atoms / ions / molecules / electrons /
particles
or
(the amount of substance which has a mass equal to) its relative formula mass / relative
atomic mass / relative molecular mass in grams
or
(the amount of substance which has a volume equal to) 24 dm3 of a gas at RTP
[1]
(ii) (Avogadro’s constant is the) number of particles / atoms / ions / molecules in one mole of
a substance
or
the number of carbon atoms in 12 g of C(12).
or
the number of particles / molecules in 24 dm3of a gas at RTP
or
6 to 6.023 × 1023 (particles / atoms / ions / molecules / electrons) [1]
2/16 = 1/8 or 0.125 moles of CH4 AND 8/64 = 1/8 or 0.125 moles of SO2 [1]
(ii) Ca is in excess (no mark) (because 0.12 moles of Ca need) 0.24 moles / 4.32 g of H2O
to react [1]
there is not enough / there are 0.2 moles / 3.6 g of H2O [1]
or
Ca is in excess (no mark) (because 0.2 moles / 3.6 g of water will react with)
0.1moles/4.0 g of Ca [1]
there is more than that / there are 0.12 moles / 4.8 g of Ca [1]
or
Ca is in excess (no mark) because the mole ratio Ca:H2O is 3:5 / mass ratio 4:3 [1]
which is bigger than the required mole ratio of 1:2 / mass ratio 10:9 [1]
or
Ca is in excess (no mark) because the mole ratio H2O:Ca is 5:3 / mass ratio 3:4 [1]
which is smaller than the required mole ratio of 2:1 / mass ratio 9:10 [1]