Safety Data Sheet

GelBrake(TM) 200
1. Product and company identification
Product name : GelBrake(TM) 200
HS Code : 283340
Material uses : Industrial applications: Delayed Release Breaker
Internal code : OFS1480
System code : OFS1480
Supplier : Innospec Oilfield Services
2600 Technology Forest Blvd
The Woodlands, Texas 77381
Information contact : (713)-936-4340
e-mail address of person : sdsinfo@innospecinc.com
responsible for this SDS

Emergency telephone number

In USA, Canada and North America, 24 hour / 7 day emergency information for our product is provided by the
CHEMTREC® Emergency Call Center based in the USA
Country information : Emergency telephone number
USA, Canada, Puerto Rico, Virgin Islands : +1 800 424 9300
In case of difficulties, or for ships at sea : +1 703 527 3887

In Europe, Middle East, Africa, Asia Pacific and South America 24 hour / 7 day
emergency response for our products is provided by the NCEC CARECHEM 24
global network
The main regional centres are listed here in Section 1.
Other local contact numbers for specific language support in Asia Pacific are listed in Section 16
Country information : Emergency telephone number Location
South America ( all countries ) : +1 215 207 0061 Philadelphia USA
Brazil : +55 11 3197 5891 Brazil
Mexico : +52 555 004 8763 Mexico
Europe ( all countries ) Middle East, Africa ( French, Portuguese, English ) : +44 (0) 1235 239 670 London, UK
Middle East, Africa ( Arabic, French, English ) : +44 (0) 1235 239 671 Lebanon
Asia Pacific ( all countries except China ) : +65 3158 1074 Singapore

China : +86 10 5100 3039 Beijing China

Date of issue/Date of revision : 2018-09-13 1/13

GelBrake(TM) 200

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : OXIDIZING SOLIDS - Category 3
substance or mixture ACUTE TOXICITY (oral) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
RESPIRATORY SENSITIZATION - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY (inhalation) - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (respiratory system)
(inhalation) - Category 1
GHS label elements
Hazard pictograms :

Signal word : Danger

Hazard statements : H272 - May intensify fire; oxidizer.
H302 - Harmful if swallowed.
H319 - Causes serious eye irritation.
H315 - Causes skin irritation.
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 - May cause an allergic skin reaction.
H350 - May cause cancer if inhaled.
H335 - May cause respiratory irritation.
H372 - Causes damage to organs through prolonged or repeated exposure if inhaled.
(respiratory system)
Precautionary statements
Prevention : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P284 - Wear respiratory protection.
P210 - Keep away from heat. - No smoking.
P220 - Keep away from clothing, incompatible materials and combustible materials.
P221 - Take any precaution to avoid mixing with combustibles and other incompatible
materials.
P271 - Use only outdoors or in a well-ventilated area.
P260 - Do not breathe dust.
P270 - Do not eat, drink or smoke when using this product.
P264 - Wash hands thoroughly after handling.
P272 (OSHA) - Contaminated work clothing must not be allowed out of the workplace.
Response : P314 - Get medical attention if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical attention.
P304 + P341 (OSHA) + P312 - IF INHALED: If breathing is difficult, remove person to
fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if
you feel unwell.
P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or
physician.
P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you
Date of issue/Date of revision : 2018-09-13 2/13
GelBrake(TM) 200

Section 2. Hazards identification

feel unwell. Rinse mouth.
P302 + P352 + P363 - IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 - If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical attention.
Storage : P405 - Store locked up.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise : None known.
classified
Target organs : Contains material which causes damage to the following organs: cardiovascular system,
upper respiratory tract, eye, lens or cornea.
Contains material which may cause damage to the following organs: kidneys, lungs,
skin, testes.

See toxicological information (Section 11)

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Ingredient name % CAS number
diammonium peroxodisulphate 60 - 100 7727-54-0
Quartz (SiO2) 4.99 - 9.99 14808-60-7
talc 0.99 - 4.99 14807-96-6
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Additional information

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours. In the event of
any complaints or symptoms, avoid further exposure.
Date of issue/Date of revision : 2018-09-13 3/13
GelBrake(TM) 200

Section 4. First aid measures

Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Remove dentures if any. Wash out mouth with water. Stop if the exposed person feels
sick as vomiting may be dangerous. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low so that vomit does
not enter the lungs. Get medical attention. If necessary, call a poison center or
physician. Never give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Harmful if swallowed.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
See toxicological information (Section 11)

Date of issue/Date of revision : 2018-09-13 4/13

GelBrake(TM) 200

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media
Specific hazards arising : Oxidizing material. May intensify fire.
from the chemical
Hazardous thermal : Decomposition products may include the following materials:
decomposition products nitrogen oxides
sulfur oxides
metal oxide/oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill : Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a
HEPA filter and place in a closed, labeled waste container. Place spilled material in a
designated, labeled waste container. Dispose of via a licensed waste disposal
contractor.
Large spill : Move containers from spill area. Use spark-proof tools and explosion-proof equipment.
Approach release from upwind. Prevent entry into sewers, water courses, basements
or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with
equipment fitted with a HEPA filter and place in a closed, labeled waste container.
Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency
contact information and Section 13 for waste disposal.

Date of issue/Date of revision : 2018-09-13 5/13

GelBrake(TM) 200

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems or asthma, allergies or chronic or recurrent
respiratory disease should not be employed in any process in which this product is used.
Avoid exposure - obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not get in eyes or on skin or clothing.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use. Keep away from
clothing, incompatible materials and combustible materials. Keep away from heat.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Store locked up. Separate from reducing agents
and combustible materials. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to
prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
diammonium peroxodisulphate ACGIH TLV (United States, 4/2014).
TWA: 0.1 mg/m³, (as persulfate) 8 hours.
Quartz (SiO2) OSHA PEL Z3 (United States, 2/2013). Notes: 250/(%SiO2+5)
TWA: 250 MPPCF / (%SiO2+5) 8 hours. Form: Respirable
OSHA PEL Z3 (United States, 2/2013). Notes: 10/(SiO2+2)
TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form: Respirable
OSHA PEL 1989 (United States, 3/1989).
TWA: 0.1 mg/m³, (as quartz) 8 hours. Form: Respirable dust
ACGIH TLV (United States, 4/2014).
TWA: 0.025 mg/m³ 8 hours. Form: Respirable fraction
NIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. Form: respirable dust
talc OSHA PEL 1989 (United States, 3/1989).
TWA: 2 mg/m³, 0 times per shift, 8 hours. Form: Respirable dust
ACGIH TLV (United States, 4/2014).
TWA: 0.1 f/cc 8 hours. Form: Respirable fibers: length greater than
5 uM; aspect ratio equal to or greater than 3:1 as determined by the
membrane filter method at 400-450X magnification (4-mm objective)
phase contrast illumination.
NIOSH REL (United States, 10/2013).
TWA: 2 mg/m³, 0 times per shift, 10 hours. Form: Respirable
fraction

Date of issue/Date of revision : 2018-09-13 6/13

GelBrake(TM) 200

Section 8. Exposure controls/personal protection

OSHA PEL Z3 (United States, 2/2013).
TWA: 0.1 f/cc 8 hours. Form: containing asbestos
STEL: 1 f/cc 30 minutes. Form: containing asbestos
TWA: 20 mppcf, 0 times per shift, 8 hours. Form: not containing
asbestos
STEL: 1 f/cc, 0 times per shift, 30 minutes. Form: not containing
asbestos

Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
controls or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Date of issue/Date of revision : 2018-09-13 7/13

GelBrake(TM) 200

Section 9. Physical and chemical properties

Appearance
Physical state : Solid. [Granular solid.]
Color : White. Off-white. Orange.
Odor : Acrid. [Slight]
Odor threshold : Not available.
pH : 4.5 to 5.5 [Conc. (% w/w): 1%]
Melting point : Not available.
Boiling point : Not available.
Flash point : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Specific gravity : 1.814
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Not available.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability : The product is stable.
Possibility of hazardous : Hazardous reactions or instability may occur under certain conditions of storage or use.
reactions Conditions may include the following:
contact with combustible materials
Reactions may include the following:
risk of causing or intensifying fire
Conditions to avoid : No specific data.
Incompatible materials : Reactive or incompatible with the following materials:
combustible materials
reducing materials
Avoid acids, bases, halides, strong reducing agents, combustible materials, and
powdered metals.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Date of issue/Date of revision : 2018-09-13 8/13

GelBrake(TM) 200

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Test Species Result Dose
diammonium - Rat LD50 Oral 689 mg/kg -
peroxodisulphate
Potential chronic health effects
Not available.
Irritation/Corrosion
Product/ingredient name Test Species Result
talc - Human Skin - Mild irritant -

Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
Quartz (SiO2) - 1 Known to be a human carcinogen.
talc - 1 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.

Specific target organ toxicity (single exposure)

Name Category Route of Target organs
exposure
GelBrake(TM) 200 Category 3 Not applicable. Respiratory tract
irritation
diammonium peroxodisulphate Category 3 Not applicable. Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
GelBrake(TM) 200 Category 1 Inhalation respiratory system
Quartz (SiO2) Category 1 Inhalation Not determined
Aspiration hazard
Not available.

Date of issue/Date of revision : 2018-09-13 9/13

GelBrake(TM) 200

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
diammonium Acute LC50 170000 µg/l Crustaceans - Cyclops strenuus 48 hours
peroxodisulphate
Acute LC50 87000 µg/l Daphnia - Daphnia pulicaria 48 hours
Persistence and degradability
Bioaccumulative potential
Not available.

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal
contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product
residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information

DOT Classification IMDG IATA

UN number UN1444 UN1444 UN1444

UN proper Ammonium persulfate AMMONIUM PERSULPHATE Ammonium persulphate

shipping name
Transport 5.1 5.1 5.1
hazard class(es)

Packing group III III III

Environmental No. No. No.

hazards
Additional Limited quantity Emergency schedules (EmS) Passenger and Cargo Aircraft
information Yes. F-A, S-Q Quantity limitation: 25 kg
Packaging instructions: 559
Packaging instruction Cargo Aircraft Only Quantity
Passenger aircraft limitation: 100 kg
Quantity limitation: 25 kg Packaging instructions: 563
Limited Quantities -
Cargo aircraft Passenger Aircraft Quantity
Quantity limitation: 100 kg limitation: 10 kg
Date of issue/Date of revision : 2018-09-13 10/13
GelBrake(TM) 200

Section 14. Transport information

Packaging instructions: Y546
Special provisions
A1, A29, IB8, IP3, T1, TP33 Special provisions
A803

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Section 15. Regulatory information

U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.

SARA 302/304
Composition/information on ingredients
No products were found.
SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
diammonium peroxodisulphate 60 - 100 Yes. No. No. Yes. No.
Quartz (SiO2) 4.99 - 9.99 No. No. No. No. Yes.
talc 0.99 - 4.99 No. No. No. No. Yes.
SARA 313
Product name CAS number %
Form R - Reporting diammonium peroxodisulphate 7727-54-0 60 - 100
requirements
Supplier notification diammonium peroxodisulphate 7727-54-0 60 - 100

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: SILICA, CRYSTALLINE, QUARTZ; SOAPSTONE
New York : None of the components are listed.
New Jersey : The following components are listed: AMMONIUM PERSULFATE;
PEROXYDISULFURIC ACID ([(HO)S(O)2]2O2), DIAMMONIUM SALT; SILICA,
QUARTZ; QUARTZ (SiO2); SOAPSTONE
Pennsylvania : The following components are listed: QUARTZ (SIO2); SOAPSTONE DUST
California Prop. 65

Date of issue/Date of revision : 2018-09-13 11/13

GelBrake(TM) 200

Section 15. Regulatory information

: WARNING: This product contains a chemical known to the State of California to cause
cancer.

Ingredient name Cancer Reproductive No significant Maximum Contains

risk level acceptable :
dosage level % or ppm
Quartz (SiO2) Yes. No. No. No. 4.99 - 9.99
International lists
National inventory
Australia inventory (AICS) : All components are listed or exempted.
Canada inventory : All components are listed or exempted.
China inventory (IECSC) : All components are listed or exempted.
Europe inventory : Not determined.
Japan inventory (ENCS) : Japan inventory (ENCS): All components are listed or
exempted.
Japan inventory (ISHL): Not determined.
New Zealand Inventory of Chemicals (NZIoC) : Not determined.
Philippines inventory (PICCS) : All components are listed or exempted.
Korea inventory (KECI) : All components are listed or exempted.
Taiwan inventory (TCSI) : Not determined.
United States inventory (TSCA 8b) : All components are listed or exempted.
Our REACH (pre-) registrations DO NOT cover the following:
1. The manufacture of these products by our company outside the EU unless covered by the Only Representative provisions, and
2. The importation of these products into Europe by other companies. Re-importation by other companies is not covered by our (pre-) registrations
Customers and other third parties importing and/or re-importing our products into Europe will need either:
- Their own (pre-) registration for substances contained in the imported product, or constituent monomers (imported above 1 tonne per year and >2% by
weight) in the case of imported polymers, or
- In the case of importation only, to make use of the "Only Representative" provisions, if available.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health * 1
Flammability 0
Physical hazards 1

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks
Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used
with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be
purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

National Fire Protection Association (U.S.A.)

0 Flammability
Health 1 0 Instability/Reactivity
Special

Date of issue/Date of revision : 2018-09-13 12/13

GelBrake(TM) 200

Section 16. Other information

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire
Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association,
on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by
properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with
recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or
not, anyone using the 704 systems to classify chemicals does so at their own risk.

History
Date of printing : 2018-09-13
Date of issue/Date of : 2018-09-13
revision
Date of previous issue : 2018-09-13
Version : 1.07
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 2018-09-13 13/13