Chemistryb Abeh

Midterm I Results
Mean: 35.5 (out of 100 pts)

Median: 33 Compare to:
2013 Mean: 59%
Mode: 25
Max: 104 2014 Mean: 51% ??
Min: 2
SD: 18
Crystal Thermodynamics and
Electronic Structure
Chapter 7
Monday, October 26, 2015

Explaining Simple Ionic Structures
The crystal structure adopted depends mostly on:
• The relative sizes of the atoms/ions
• The relative number of the two types of atoms/ions
• The electronic structure of the atoms/ions
The radius ratio is typically defined as r+/r–, where r+ is the radius of
the cation and r– is the radius of the anion.
Radius Ratio Rules
In order to maximize the net electrostatic attraction between ions in a
structure, the Coordination Number of the Cation will be Maximized
subject to the criterion of Maintaining Cation-Anion Contact
_ _
+
_ _
stable transitional unstable
Determined by comparison of the ratio of the ionic radii (r+/r-),

with values derived from the geometric contact criterion
Radius Ratio Rules

The Radius Ratio Rules are correct ONLY 2/3 of the time!
Thermodynamics of Ionic Crystal Formation
The energetics associated with the formation of an ionic crystal can
be calculated using Hess’ Law (Born-Haber cycle).
Li s  
 Li g  ∆Hsub
1
F2 g  
 F g  BDE
2
Li g  
 Li  g   e IP
F g   e – 
 F  g  EA
Li  g   F  g  
 LiF s  -∆Hlattice = -∆U - ∆nRT
1
Li s   F g  
 LiF s  ∆Hf
2
Thermodynamics of Ionic Crystal Formation
The energetics associated with the formation of an ionic crystal can
be calculated using Hess’ Law (Born-Haber cycle).
Li s  
 Li g  ∆Hsub
1
F2 g  
 F g  BDE
2
Li g  
 Li  g   e IP
F g   e – 
 F  g  EA
Li  g   F  g  
 LiF s  -∆Hlattice = -∆U - ∆nRT
1
Li s   F g  
 LiF s  ∆Hf
2
Lattice Energy
Ionic structures are held together by electrostatic forces and, therefore, are arranged
so that cations are surrounded by anions, and vice versa
Lattice Energy (U) = energy required to completely separate one

mole of a crystal into a gas of its ions.
NaCl (s) → Na+ (g) + Cl- (g) , ΔHlattice ≈ U Electrostatic potential energy
(attraction & repulsion):
2
Z Z e
V 
r
Short-range Pauli repulsion:
B
V n
r
B: Born constant
n: Born exponent (n = 5-12)
UNaCl = 778 kJ/mol
Madelung Constant
2
Z  Z e 12 8 6
V  (6     ....)
r 2 3 4
Madelung Constant (A): Madelung
The numerical value of the series summation
• Depends only on the geometrical arrangements of ions

(the crystal structure), not the lattice constant
Crystal structure Madelung constant Coordination

Rock salt 1.748 6:6
CsCl 1.763 8:8
Zincblende 1.638 4:4
Fluorite 5.039 8:4
Rutile 4.816 6:3
Born-Landé Equation for Lattice Energy
U is the sum of net Coulombic attraction and Pauli repulsion:
2
Z  Z  e NA BN
U   n
r r
2
dU Z  Z  e NA nBN
 2
 n 1  0
dr re re
2 n 1
Z  Z  e Ar
B e
n
2
Z  Z  e NA 1
U  (1  )
re n
This is the Born-Landé equation (1918)
Some Lattice Energies
• for a given crystal structure, U depends most strongly

on the charge on the ions
• the internuclear separation re has a smaller effect
increasing
lattice constant
Melting point: MgO: 2800°C

CaO: 2572°C
BaO: 1923°C
Limits of the Ionic Model
The Born-Landé equation is a poor approximation to the lattice
energy for compounds with significant non-ionic character
UBorn-Lande UBorn-Haber ΔU
(calculation) (experiment)
AgF 920 953 33

Rock
Salt
AgCl 832 903 71
AgBr 815 895 80
AgI 777 882 105

CN 4
structure
Increasingly covalent!
From MOs to Band Theory
We’ve seen before how AOs on atoms are combined to give MOs for
molecules.
LUMO
Energy
HOMO
Ha H2 Hb
Look at what happens when we move from two hydrogens to four
hydrogens in a chain (look familiar?).
LUMO
LUMO
Energy
߶ୟ ߶ୠ ߶ୡ ߶ୢ
HOMO
HOMO
H2 Ha Hb Hc Hd
H4
Eight hydrogens gives eight MOs and an even smaller HOMO-LUMO
gap.
LUMO
LUMO
LUMO
Energy
HOMO
HOMO
HOMO
H2
H4
H8
Infinite 1D Chain of H Atoms
Interaction of many atoms: band
N atomic orbitals always give N molecular orbitals.

when N is enormous, the MOs form continuous bands (ΔE << kT)
Energy band is half full

band
for 1D H atom chain
Density of States (DOS)

Band Theory of 3D Solids
Now consider what happens in a three-dimensional solid with many,
many atoms within bonding distance...
conduction band (empty)
Energy
band gap (Eg = 1.1 eV for silicon)
valence band (filled)
crystalline silicon
DOS
Instead of a discrete MOs, we get a band of filled orbitals (valence
band) and a band of empty orbitals (conduction band).

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Midterm I Results

Mean: 35.5 (out of 100 pts)

Monday, October 26, 2015

stable transitional unstable

Determined by comparison of the ratio of the ionic radii (r+/r-),

Radius Ratio Rules

Lattice Energy (U) = energy required to completely separate one

• Depends only on the geometrical arrangements of ions

Crystal structure Madelung constant Coordination

• for a given crystal structure, U depends most strongly

• the internuclear separation re has a smaller effect

Melting point: MgO: 2800°C

AgF 920 953 33

AgBr 815 895 80

AgI 777 882 105

Interaction of many atoms: band

N atomic orbitals always give N molecular orbitals.

Energy band is half full

Density of States (DOS)

conduction band (empty)

valence band (filled)

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