ASTRA INDUSTRIAL COMPLEX CO., LTD.

(ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

MATERIAL SAFETY DATA SHEET

BIFLEX® TC
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM SAUDI ARABIA

1. PRODUCT IDENTIFICATION
Product Name: BIFLEX® TC
Chemical Class: Pyrethroid Insecticide
Active ingredient: Bifenthrin
Molecular Formula C23H22ClF3O2

Uses: BIFLEX®TC is a termiticidal concentrate insecticide used in public health for

the termites control before and after constructions.
Producer: Astra Industrial Complex Co., Ltd.
P.O. Box 30447, Al-Khobar 31952
Kingdom of Saudi Arabia
Emergency Tel # (+966) 3 8121 406

2. COMPOSITION / INFORMATION ON INGREDIENTS

Active Substance Chemical structure

Bifenthrin Technical F 3C CH3
CAS No. 82657-04-3
Chemical Name: 2-methylbiphenyl-3- C CH CH3 CO2C H2
ylmethyl (Z)-(1RS,3RS)-3-(2-chloro-3,3,3- Cl H H
trifluoroprop-1-enyl)-2,2-
dimethylcyclopropanecarboxylate CH3

Ingredient Name CAS# OSHA-PEL ACGIH-TLV Other

Bifenthrin (25.1%) 82657-04-3 None None None

Xylene (6.8%)* 1330-20-7 100 ppm 100 ppm 150 ppm STEL

1,2,4-Trimethylbenzene (25%)* 95-63-6 25 ppm 25 ppm None

Ethylbenzene (1.4%)* 100-41-4 100 ppm 100 ppm 125 ppm STEL
3 3
Mineral Oil 8012-95-1 5.0 mg/m 5.0 mg/m None

MSDS: BIFLEX ®TC 1 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

3. HAZARD IDENTIFICATION
Emergency Overview
Immediate Concerns: Viscous liquid, crystalline solid or waxy solid with
a very faint, slightly sweet odor.
Slightly combustible. May support combustion at elevated
temperatures.
Thermal decomposition and burning may form toxic by-products.
For large exposures or fire, wearpersonal protective equipment
Highly toxic to fish and aquatic organisms. Keep out of drains
and water courses.
Moderately toxic if swallowed
Potential Health Effects;
Effects from overexposure result from either swallowing or coming into
contact with the skin. Symptoms of overexposure include bleeding from
the nose, tremors and convulsions. Contact with this product may
occasionally produce skin sensations such as rashes, numbing, burning
and tingling. These sensations are reversible and usually subside within
12 hours.
Medical Conditions Aggravated: None presently known
Primary Routes of Entry:
Acutenand chronic effects from overexposure may resultfrom inhalation,
ingestion, or absorption through the skin.
Acute Effects from Overexposure:
Data available on human exposure indicates that contact with bifenthrin
may produce skin sensations (feelings of numbing, burning or tingling),
which usually subside within 12 hours. Large doses ingested or inhaled
by laboratory animals produced signs of toxicity which included clonic
convulsions, tremors, loss of muscle control, neurotoxicity even though
its principal mode of action is on the mammalian nervous system.
Solvent-refined light paraffinic distillate, another ingredient, can cause
temperory sniging pain when in contact with the eye. This formulation
also contains mixed aromatic hydrocarbons, including xylene. Inhalation
of aromatic hydrocarbon vapors may cause central nervous system
depression, dizziness, disturbances in vision and respiratory irritation.
Contact with eyes and skin may be resulting in pulmonary edema which
is fatal.
Chronic Effects from Overexposure:
In studies with laboratory animals, bifenthrin did not cause reproductive
toxicity or teratogenicity. The effect associated with repeated exposure
of dogs, rats, rabbits and mice to bifenthrin was tremors. In lifetime

MSDS: BIFLEX ®TC 2 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

feeding studies conducted with rodents, a slight increase in the

incidence of urinary bladder tumors at the highest dose in male mice
was considered to be an equivocal response, not evidence of a clear
compound-related effect. The overall results from a battery of
genotoxicity studies indicate that bifenthrin is not considered to be
genotoxic. Moderate irritation results from prolonged or repeated
contact with solvent-refined paraffinic distillate to the skin.
Overexposure to aromatic hydrocarbons in this formulation, including
xylene, may cause central nervous system effects (including
headaches, dizziness, loss of feelings and sensations) and liver and
kidney damage. Some reversible hematopoietic depression has been
reported in laboratory animals. Damage from xylene may be potentiated
by alcohol.
Medical Conditions Aggravated by Exposure:
Pre-existing liver, kidney and nervous disordors.
Carcinogenicity: IRAC: No, NTP: No, OSHA: No

4. FIRST AID MEASURES

Eye:
Flush eyes with for at least 15 minutes. Lift the upper and lower eyelids
intermittently. See an ophthalmologist.
Skin:
Remove contaminated clothing and wash with soap and water. Iff
irritation persists, see a physician.
Ingestion:
Do not induce vomitting or give anything by mouth to an unconscious
person. Contact a medical doctor.
Inhalation:
Remove victim to fresh air. If not breathing administer artificial
respiration. Avoid unprotected mouth to mouth resuscitation. GET
MEDICAL ATTENTION.
Note to Physician:
Removal of exposure and symptomatic and supportive treatment is
recommended. gastric lavage with an endotracheal tube in place should
be considered as aromatic hydrocarbons in this formulation may
produce a fatal pneumonities if aspirated.

MSDS: BIFLEX ®TC 3 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

5. FIRE FIGHTING MEASURES

Fire and Explosion:
Flash point and Method 42.2 C (108 F)(CC)
Extinguishing Media:
Foam, CO2 or dry chemical. Soft stream water fog only if necessary.
Contain all runoff.
Degree of Fire/Explosion Hazard:
Moderately combustible. When heated above the flash point this
material release flammable vapors which, when mixed with air, can burn
or be explosive. Sealed, overheated containers may present an
explosion hazard
Fire fighting procedures:
Isolate fire area. Evacuate downwind. Wear full protective clothing and
self-contained breathing apparatus. Do not breathe smoke, gases or
vapors generated. Try to keep containers cool with soft stream water
fog.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen chloride and hydrogen
flouride.
Hazardous Polymerization: Will not occur
Conditions to Avoid (Incompatibility)
Excessive heat ,and fire and oxides. Thermal decomposition and
burning may produce toxic by-products.

6. ACCIDENTAL RELEASE MEASURES

Steps to be taken if material is released or spilled:
Isolate and spill area. Wear protective clothing and personal protective
equipment as prescribed in section 8, “Exposure Controls/ Personal
Protection”. Keep unprotected persons and animals out of the area.
Keep material out of streams and sewers. If Liquid: Dike to confine spill
and absorb with an absorbent such as clay, sand or soil. If SOLID:
Large spills should be covered to prevent dispersal. For dry material,
use a wet sweeping compound or water to prevent the formation of
dust. If water is used, prevent runoff or dispersion of excess liquid by
diking and absorbing with a non-combustible absorbent such as clay,
sand or soil. Vacuum, shovel or pump waste into a drum and label
contents for disposal.

MSDS: BIFLEX ®TC 4 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

Open dumping or burning of this material or its packaging is prohibited.

An acceptable method of disposal is to burn in an incinerator in
accordance with all local, state and federal environmental laws, rules,
standards and regulations. Because acceptable methods of disposal
may vary by location, and because regulatory requirements any change,
the appropriate regulatory agencies should be contacted prior to
disposal. Steel containers which held these materials may be cleaned
by being triple-rinsed, and recycled with the rinsate being incinerated.
Do not cut or weld metal containers. Vapors that form inside may create
an explosion hazard
To clean and neutralize spill area, tools and equipment, wash with
suitable solution of caustic or soda ash, and as appropriate alcohol (i.e.,
methanol, ethanol or isopropanol) follow this by washing with a strong
soap and water solution. Absorb, as above, any excess liquid and add
to the drums of waste already collected. Repeat if necessary. Dispose
of drummed waste according to the method outlined in Section 13,
“Disposal Considerations”

7. HANDLING AND STORAGE

Genaral Procedures:
Store in a cool, dry, well-ventilated place. Do not use or store near heat,
openflame or hot surfaces. Store in original containers only. Keep out of
reach of children and animals. Do not contaminate other pesticides,
fertilizers, water, food or feed by storage or disposal

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Personal protection recommendations for mixing or applying this
product are prescribed on the product label. Those directions should be
followed. Information stated below provides useful, additional guidance.
Ventilation:
Use local exhaust at all process locations to control employee exposure.
Store in a well-ventilated area. Thoroughly ventilate all transport
vehicles prior to unloading.

MSDS: BIFLEX ®TC 5 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

Work Clothing:
Depending upon concentrations encountered, wear long-sleeved
uniform or coveralls and head covering. For larger exposures as in the
case of spills, wear full body cover barrier suit such as a rubber rain suit.
A safety shower should be located nearby. Launder all clothing before
reuse.
Eye Protection:
For splash, vapor or mist exposure, wear chemical protective goggles or
full-face shield. Emergency eyewash fountain should be located nearby.
Engineering Controls:
General air replacement or dilution ventilation is sufficient for material
handling and storage, but local ventilation should be used when
removing this product from containers. Ventilate all transport vehicles
prior to unloading.
Personal Protective Equipment
Eyes and Face: For splash, mist, vapor or dust exposure wear chemical
protective goggles or a face shield.
Respiratory:
For vapor or mist exposure, wear, as a minimum, a properly fitted half-
face or full face air-purifying respirator which is approved for pesticides
(U.S. NIOSH/MSHA, EU CEN or comparable certification organization).
Respirator use and selection must be based on airborne concentrations.
Protective clothing:
Depending upon concentrations encountered, wear coveralls or long-
sleeved uniform and head covering. For larger exposures as in the case
of spills, wear full body cover barrier suit, such as a PVC suit. Leather
items-such as shoes, belts and watchbands – that become
contaminated should be removed and destroyed. Launder all work
clothing before reuse(Separately from household laundry).
Work hygienic practices:
Clean water should be available for washing in case of eye or skin
contamination. Wash skin prior to eating, drinking or using tobacco.
Shower at the end of the workday.
Gloves:
Wear chemical protective gloves made of materials such as rubber,
neoprene, or PVC. Thoroughly wash the outside of gloves with soap
and water prior to removal. Inspect regularly for leaks.

MSDS: BIFLEX ®TC 6 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

9. PHYSICAL AND CHEMICAL PROPERTIES

Assay "Bifenthrin" 25.1 %w/w

(240 g ± 10 g / L)
Appearance Light brown Liquid
Odour Aromatic hydrocarbon
Flash Point 42.2°C (108°F)(CC)
pH Not applicable
Vapor pressure Not available
Melting Point Not applicable
Solubility in Water Emulsifiers
Specific Gravity Not applicable

10. STABILITY AND REACTIVITY

Stability: Stable
Condition to avoid: Excessive heat and fire.
Hazardous polymerization: will not occur

11. TOXICOLOGICAL INFORMATION

Toxicology Data:
Technical Bifenthrin:
Acute Oral LD50 (rat) 53.4 mg/kg
Dermal LD50 (rat) >2000 mg/Kg (rabbit)

Acute effects from overexposure:

Bifenthrin is moderately toxic if swallowed and has low dermal toxicity. It
is non-irritating to the skin and practically non-irritating to the eyes.
Large does of bifenthrin ingested by laboratory animals produced signs
of toxicity including convulsions, tremors and bloody nasal discharge.
Bifenthrin does not cause acute delayed neurotoxicity. Experience to
date indicates that contact with befenthirn may occasionally produce
skin sensations such as rashes, numbing, burning or tingling. These
sensations are reversible and usually subside within 12 hours.
Chronic effects from Overexposure:
In studies with laboratory animals, bifenthrin did not cause reproductive
toxicity or teratogenicity. Tremors were associated with repeated
exposure of laboratory animals to bifenthrin. In lifetime feeding studies
MSDS: BIFLEX ®TC 7 / 10
ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

conducted with rodents, a slight increase in the incidence of urinary

bladder tumors at the highest does in male mice was considered to be
an equivocal response, not evidence of a clear compound –related
effect. The overall absence of genotoxicity has been demonstrated in
mutagenicity tests with bifenthrin.
Carcinogenicity:
IARC: Not listed
NTP: Not listed
OSHA: Not listed
Other: (ACGIH) Not listed

12. ECOLOGICAL INFORMATION

Environmental Data
Bifenthrin has moderate stability in the soil under aerobic conditions
(half-life range from 65 – 125 days depending on soil type) and is stable
at a wide range of pH values. Bifenthrin has a high log pow (>6.0), a
high affinity for organic matter, and is not mobile in soil. Therefore, there
is little potential for movement into ground water. There is the potential
for bifenthrin to bioconcentrate (BCF = 11,750)
Ecotoxicological Information:
Bifenthrin is highly toxic to fish and aquatic arthropods and LC50 values
range from 0.0038 to 17.8 µg/L. in general, the aquatic arthropods are
the most sensitive species. Care should be taken to avoid
contamination of the aquatic environment. Bifenthrin had no effect on
mollusks at its limit of water solubility. Bifenthrin is only slightly toxic to
both water fowl and upland game birds (LD50 Values range from 1,800
mg/Kg to >2,150 mg/kg)

13. DISPOSAL CONSIDERATION

Disposal Method:
Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label
instructions, an acceptable method of disposal is to incinerate in
accordance with local, state and national environmental laws, rules,
standards and regulations. However, because acceptable methods of
disposal may vary by location and regulatory requirements may change,
the appropriate agencies should be contacted prior to disposal.
Empty Container

MSDS: BIFLEX ®TC 8 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

Non-returnable containers, which held this material, should be cleaned,

prior to disposal, by triple rinsing. Containers which held this material
may be cleaned by being triple-rinsed, and recycled, with the rinsate
being incinerated. Do not cut or weld metal containers. Vapors that form
may create an explosion hazard.

14. TRANSPORT INFORMATION

DOT: Insecticide, NOI other than Poison. NMFC Item 102120. Biflex®TC
UN. Flammable, Liquid n.o.s.(containing xylene), Class 3.3, UN 1993,
Packaging Group III, ERG Guide 27. Insecticides, NOI. Biflex™TC.

Proper Shipping name: Pyrethroid pesticide, liquid, toxic, flammable, flash

point ≥23°C (Bifenthrin)
UN. No: UN 3351
Hazard Class: 6.1
Classification Code: TF2
Packing group: III
Subsidiary Risks: 6.1 +3
Special provisions: 61
Limited quantities: LQ19
Packaging: Packing instructions P001 IBC03 R001
Special packing provisions -
Mixed Packaging Provisions MP15
Instructions T7
UN Portable tanks: Special Provisions TP2 TP28
Tank Code L4BH
ADR Tank: Special Provision TU15 TE1 TE15 TE19
Vehicle for tank carriage FL
Transport Category 2
Special provision carriage: Packages -
Bulk -
Loading, unloading & CV13 CV28
Handling
Operation S2 S9
Hazard Identification 63

Marine Pollutant #1 : bifenthrin (Severe Marine Pollutant)

Reportable Quantity(RQ): NONE
NERG: 151

MSDS: BIFLEX ®TC 9 / 10

ASTRA INDUSTRIAL COMPLEX CO., LTD. (ASTRACHEM)
P.O. BOX 30447, AL-KHOBAR 31952
KINGDOM OF SAUDI ARABIA
www.astra-agri.com.sa

15. REGULATORY INFORMATION.

Section 302 Extremely Hazardous Substances (40 CFR 355); not listed
Section 311 Hazard Categories (40 CFR 370); Immediate, Delayed
Section 312 Threshold Planning Quantity (40 CFR 370);
The threshold planning quantity (TPQ) for this product, if treated as a
mixture, is 10,000 Ibs. This product contains the following ingredients
with a TPQ of less than 10,000 Ibs: None
Section 313 Reportable Ingredients (40 CFR 372); This product
contains the following ingredients subject to section 313 reporting
requirements: (Bifenthrin)
Cercla (Comprehensive Environmental response compensation and
liability Act)
Cercla regulatory (40 CFR 302.4): Not listed
Comments : Australian Hazard Code : 3 XE
U.S.EPA Signal Word: Warning

16. OTHER INFORMATION

Buyer assumes all responsibility for safety and use not in accordance
with the product label instructions.

MSDS: BIFLEX ®TC 10 /

10