practice sheet-1

Carbon and its Compounds

1. Which one is the top priority functional group in the nomenclature of an organic compound when it
possesses more than one functional group?
(A) –CHO (B) –COOH (C) –OH (D) – CONH 2

2. Which group is always taken as a substituent in the IUPAC nomenclature?

(A)  NH 2 (B) –CN (C)  NO2 (D) > C = O

3. Which of the following properties is generally not true regarding organic compounds.
(A) They are generally covalent compounds
(B) Show isomerism
(C) Compounds have high melting & boiling points
(D) Generally insoluble in water

4. The property of catenation is more marked in the case of ______

(A) Silicon (B) Hydrogen (C) Oxygen (D) Carbon

5. The structural formula of 2-butene is

(A) CH 3  CH  C  CH 2 (B) CH 3  C  C  CH 3
(C) CH 3  CH  CH 2  CH 3 (D) CH 3  CH  CH  CH 3

6. Which of the following statements about graphite & diamond is true

(A) They have the same crystal structure
(B) They have the same degree of hardness
(C) They have the same electrical conductivity
(D) They can undergo the similar chemical reactions

7. Drinking alcohol is very harmful and it ruins the health. In common man’s “Drinking alcohol” stands for
(A) Drinking methyl alcohol
(B) Drinking ethyl alcohol
(C) Drinking propyl alcohol
(D) Drinking isopropyl alcohol

8. Ethane, with the molecular formula C 2 H6 has :

(A) 6 covalent bonds (B)7 covalent bonds
(C)8 Covalent bonds (D)9 Covalent bonds
9. With soap, hard water produces scum due to the formation of
(A) sodium and potassium salts of higher fatty acids
(B) magnesium and calcium salts of higher fatty acids
(C) sodium and ammonium salts of higher fatty acids
(D) potassium and ammonium salts of higher fatty acids

10. All of the following are allotropes or forms of carbon except

(A) graphite (B) diamond (C) sapphire (D) Fullerene

11. The chlorination of methane, is an example of

(A) Addition reaction (B) Reduction reaction
(C) Elimination reaction (D) Substitution chain reactions

12. Other name of methane is also

(A) Laughing gas (B) Ammonia (C) Marsh gas (D) Ester

13. Of the things we use in our daily life, carbon is not present in
(A) Water (B) Food (C) Clothes (D) Petrol

14. Which of the following is an dehydration reaction?

 (A) C2 H 5OH  Na  C2 H 5ONa C2 H5OH   CH3CHO
CrO3
(B)
(C) CH 3  CH 2OH    CH 2  CH 2
Conc . H SO
2 4
(D) None of the above

15. Which of the following is used to coagulate rubber from latex?

(A) Ethanoic acid (B) Ethanol (C) Propanoic acid (D) None of the above

SECTION – II

16. IUPAC name of the following compound is

C2 H5 C2 H5

CH3 CH CH CH3
(A) 1, 2-Diethyl-1, 2-dimethyl ethane (B) 2-Ethyl-3-Methyl pentane
(C) 2, 3-Dimethylbutane (D) 3, 4-Dimethyl hexane

17. Compound (CH 3 ) 4 C is?

(A) 2, 2-Dimethyl propane (B) 1, 1, 1-Trimethyl ethane
(C) 2, 2, 2-Trimethyl ethane (D) Tetra methyl methane

18. Structure of the compound having formula 3-methyl hexane is? .

(A) .

(B) .

. .

(C) .
(D) None of the above
19. On mono chlorination of neopentane, number of possible isomers.
(A) 1 (B) 2 (C) 3 (D) 4

20. Alkenes, readily undergo

(A) Substitution reactions (B) Addition reactions
(C) Elimination reactions (D) Rearrangement reactions

Part – A

One or more than one correct answer Questions

21. The compound CH 3  C  C  CH 3 can be named as

(A) dimethyl acetylene (B) but-1-yne (C) but-2-yne (D) but-2-ene

22. The compound

(CH3 )2 C (OH )CH 2CH 3 is called
(A) 2-methyl butan-2-ol (B) isopropyl alcohol
(C) 2-propanol (D) propanol

23. Which of the following is/are saturated hydrocarbon

(A) C4H10 (B) C2H2 (C) C2H4 (D) C2H6

24. Which of the following structure represents But-1-ene correctly?

(A) CH2  CH  CH2  CH3 (B) CH3  CH2  CH  CH2
(C) CH3  CH  CH  CH3 (D) CH3  CH2  CH2  CH3
25. Which of the following is/are can’t show isomerism?
(A) CH4 (B) C2H6 (C) C3H8 (D) C4H10

Comprehension - 1

On the basis of IUPAC nomenclature name the following compounds

26. CH3 CH2 C CH CH3

CH2 CH3
(A) 3-methyl-2-ethylbut-1-ene (B) 2-ethyl-3-methylbut-1-ene
(C) 3-ethyl-3-methylbut-1-ene (D) 2-Isopropylbut-1-ene

27. CH3

CH3 C C CH

CH3
(A) 1, 1-Dimethyl but-2-yne (B) 4, 4-Dimethyl but-2-yne
(C) 4-Methyl pent-2-yne (D) 2-Methyl pent-4-yne

28. CH 3  C  CH 2
|
C2H5
(A) 2-methyl but-1-ene (B) 3-methyl but -1-ene
(C) Vinyl Methyl ethane (D) 2-Ethyl propene

Comprehension – 2

Based on the IUPAC nomenclature identify the structure of the compound matching the name

29. Identify the IUPAC, name of the following compound? .

.
.
.
.
.

(A) 2, 2, 6, 7 – tetramethyl heptane (B) 2, 2, 6, 6, 7 – pentamethyl octane

(C) 2, 3, 3, 7, 7 – pentamethyl octane (D) none of the above

CH3
|
30. CH 3  CH 2  CH  CH  CH  CH 2  CH 3
(A) 3-methyl hept-4-ene (B) 5-methyl hept-3-ene
(C) 2-ethyl hex-3-ene (D) None of these

CH3 CH3
| |
31. CH 3  CH  CH  C  C  CH 3
(A) 4, 5-dimethyl 2-hexyne (B) 2, 3-dimethyl-4-hexyne
(C) 2, 3-dimethyl-4-hexene (D) None of the above

Comprehension – 3

Alcohols can be classified as primary secondary and tertiary alcohol. Ethanol is mixed with methanol to make it
poisonous

32. Which of the following is an example of 2 alcohol?

(A) Butanol (B) Propan-1-ol (C) Propan-2-ol (D) none of these
33. Methanol on oxidation produces
(A) Formic acid (B) Ethanoic acid (C) ethanol (D) none of these

34. Alcohols on reaction with carboxylic acid in presence of conc. H2SO4 produces
(A) aldehyde (B) ketone (C) ester (D0 none of these

Part - B
Match the following
M1.
COLUMN – I COLUMN – II

A Cn H 2 n P Alcohols, ethers

B Cn H 2  Cn H 2n2 Q Alkenes, cycloalkanes

C Cn H 2 n  2O R Aldehydes, Ketones

D Cn H 2 nO S Alkynes, Alkadienes

M2.
COLUMN – I COLUMN – II

A P Alcohol

B HCHO Q Acid

C CH3COOH R Aldehyde

D CH3CH2OH S Ketone

M3.
COLUMN – I COLUMN – II

A CH3COOH P Ethanol

B CH3OCH3 Q Ethanoic acid

C CH3CH2OH R Ethanol

D CH3CHO S Methoxy methane

Part – C
Numerical
N1. pC2H5 OH  qO2 
Combustion
 rCO2  sH2O
In the above equation. Calculate the sum of the values of p, q, r and s.

X
N2. The Ethanol reacts with sodium forming a hydrogen gas and compound X, molecular mass of is?
34
N3. Identify the number of primary carbon atoms present in the following structure.
CH3 CH3

CH3 C CH2 CH CH2 CH3

CH3
 ANSWER KEY

1.B 2.C 3.C 4.D 5.D

6.D 7.B 8.B 9.B 10.C

11.D 12.C 13.A 14.C 15.A

16.D 17.A 18.A 19.A 20.B

Chemistry

1..A, C 2..A 3 A,D 4 A,B 5 A,B,C

6.B 7.C 8.A 9.C 10.B

11.A 12 C 13 A 14 C

M1. A-Q B-S C-P D-R

M2 A-S B-R C-Q D-P

M3 A-Q B-S C-P D-R

N1.9 N2.2 N3.5

Practice sheet-2

1. The IUPAC name of CH3C(CH3)2CH2CH=CH2 is

(A)2,2-dimethyl-4-pentene (B)4,4-dimethyl-1-pentene
(C)1,1,1-trimethyl-3-butene (D)4,4,4-trimethyl-1-butene

2. How many isomers are possible for the alkane C6 H14 ?

(A)5 (B)4 (C)6 (D)7

3. In methane molecule the four hydrogen atoms arranged in

(A)square planar (B)square pyramid (C)tetrahedral (D)octahedral

4. The suffixes for alcohols, aldehydes and ketones according to IUPAC system respectively:
(A)-alc, -ald, ket (B)–ol, -al,-ket (C)–ol, -al,-one (D)–coh,-ald,-one

5. The IUPAC name of the following compound is

O

CH3 CH2 CH C O CH2 CH3

CH3
(A)Ethyl butanoate (B)Ethyl-2-methyl butanoate
(C)Ethyl pentanoate (D)Ethyl-2-methyl pentanoate

6. Carbon generally forms

(A)covalent bond (B)ionic bond
(C)coordinate covalent bond (D)metallic bond

7. CH3CH2CH  CH2 and CH3  CH  CH  CH3 show

(A)Chain isomerism (B)Position isomerism
(C)Functional isomerism (D)tautomerism

8. IUPAC name of the compound is

 CH3
|
CH3 CH2CH2CH2CH2  CH  C  CH2CH3
| |
CH3 CH CH CH
2 2 3

(A) 3, 4-dimethyl-3-n-propyl nonane (B)5, 7-dimethyl-7-n-propyl nonane

(C) 4-ethyl-4, 5-dimethyldecane (D)6, 7-dimethyl-7-ethyl decane

9. Which of the following cannot form a cyclic compound?

(A) C6H14 (B) C6H12 (C) C6H6 (D) C6H10

10. Which of the following is a secondary alcohol?

(A)butanol-1 (B)butanol -2
(C)2-methylpropanol-2 (D)3-methylpentanol-3

11. Open –chain saturated hydrocarbons are called

(A)alkenes (B)paraffin’s (C)alkynes (D)olefins

12. Dimethyl ether and ethyl alcohol are

(A)Metamers (B)Homologues (C)Functional isomers (D) Position isomers

13. No of pentagonal and hexagonal rings present in the Buckminster fullerene

(A)5&6 (B)12&20 (C)20&12 (D)15&20

14. Pentanenitrile is a compound with functional group

(A)aldehyde (B)alcohol (C)cyanide (D)carboxylic acid

15. Hydrocarbons having double or triple bonds are called

(A) Saturated hydrocarbon (B) carbohydrates
(C) Unsaturated hydrocarbons (C) paraffin’s

16. The property by which carbon atoms form long chain hydrocarbons is called as?
(A)Combination (B)Catenation (C)Polymerization (D)Addition

17. Which of the following is not an unsaturated hydrocarbon?

(A)Acetylene (B)Ethene (C)Ethane (D)Butyne

18. To which of the following functional group last preference is given while taking into account in IUPAC naming?
(A)–COOH (B) C  C  (C)–OH (D)–CHO

19. Which of the following is/are crystalline allotropic form of carbon?

(A)Diamond (B)Graphite (C)Coal (D)both a & b

20. Which of the following statement is false about diamond?

(A)It is a good conductor of electricity (B)It has got a tetrahedral arrangement
(C)Melting point of diamond is about 3930o C (D)It is a good conductor of heat

Answer key
1.B 2.A 3. C 4.C 5. B

6.A 7.B 8.C 9.A 10.B

11.B 12.C 13.B 14.C 15.C

16.B 17.C 18.B 19.D 20.A

1. Synthetic diamonds can be prepared by subjecting pure carbon to

(A)high temperature (B)low temperature (C)high pressure (D) both a & c

2. What is added to make the soap come out of solution?

(A)sodium hydroxide (B)sodium carbonate (C)sodium chloride (D)sodium bicarbonate
 O
||
3. The IUPAC name of CH3  C O  C2H5 is
(A)ethylacetate (B)propylacetate (C)methyl ethanoate (D) ethylethanoate

4. Which of the following show allotropy apart from carbon?

(A)phosphorus (B)radium (C)iodine (D)nitrogen

5. Which of the following represents a ketonic group?

(A)  C  0 (B) O  (C) CHO (D)–OH

6. What is the IUPAC name of CH3  CH  CH 2  CH 2  COOH

|
OH
(A)4-hydroxy pentanoic acid (B)2-hydroxy pentanoic acid
(C)1-carboxy pentanol (D)3-hydroxy pentanoic acid

7. Pentane with molecular formula C5 H12 has_________ covalent bonds

(A)5 (B)12 (C)16 (d) 17

8. Scum is formed when soap reacts with

(A) Ca 2  (B) Mg 2  (C)both a & b (D) Al 3

9. Weak vander waal’s forces exist between the layers in

(A)diamond (B)fullerenes (C)coke (D)graphite

10. What is the IUPAC name of CH3 – CH = CH – C  CH

(A)Pent-3-en-1-yne (B)Pent-1-yn-3-ene (C)Pent-2-en-4-yne (D)Pent-4-yn-2-ene

11. How many structural isomers possible for a compound having molecular formula C3 H 7 Br ?
(A)3 (B)4 (C)2 (D)5

12. Members of homologous series will have same__________

(A)physical properties (B)chemical properties
(C)physical as well as chemical properties (D)neither physical nor chemical properties

Answer keys
1.D 2.C 3.D 4.A 5.A

6.A 7.C 8.C 9.D 10.A

11.C 12.B